A non-reactive model system comprising a highly concentrated and unstable oil-in-water emulsion was used to investigate the retention of oil by the membrane in producing biodiesel with a membrane reactor. Critical flux was identified using the relationship between the permeate flux and transmembrane pressure along with the separation efficiency of the membrane. It was shown that separation efficiencies above 99.5% could be obtained at all operating conditions up to the critical flux. It was observed that the concentration of oil in all collected permeate samples using the oil-water system was below 0.2 wt% when operating at a flux below the critical flux. Studies to date have been limited to the characterization of low concentrated emulsions below 15 vol.%. The average oil droplet size in highly concentrated emulsions was measured as 3200 nm employing direct light scattering (DLS) measurement methods. It was observed that the estimated cake layer thickness of 20 to 80 mm was larger than external diameter of the membrane tube i.e. 6 mm based on a large particle size. Settling of the concentrated emulsion permitted the detection of a smaller particle size distribution (30-100 nm) within the larger particles averaging 3200 nm. It was identified that DLS methods could not efficiently give the droplet size distribution of the oil in the emulsion since large particles interfered with the detection of smaller particles. The content of the smaller particles represented 1% of the total weight of oil at 30°C and 5% at 70°C. This was too low to be detected using DLS measurements but was sufficient to affect ultrafiltration. In order to study the critical flux in the presence of transesterification reaction and the effect of cross flow velocity on separation, various oils were transesterified in another membrane reactor providing higher cross flow velocity. higher cross flow velocity provides better separation by reducing materials deposition on the surface of the membrane due to higher shearing. The oils tested were canola, corn, sunflower and unrefined soy oils (Free Fatty Acids (FFA< 1%)), and waste cooking oil (FFA= 9%). The quality of all biodiesel samples was studied in terms of glycerine, mono-glyceride, di-glyceride and tri-glyceride concentrations. The composition of all biodiesel samples were in the range required by ASTM D6751 and EN 14214 standards. A critical flux based on operating pressure in the reactor was reached for waste cooking and pre-treated corn oils. It was identified that the reaction residence time in the reactor was an extremely important design parameter affecting the operating pressure in the reactor. / Natural Sciences and Engineering Research Council of Canada (NSERC)

Der Einfluss des Biofilms, der Inkrustation, der Fließgeschwindigkeit und der Wasserqualität auf die Freisetzung von PAK wurde in Batch-, Drehkolbenreaktorversuchen und an einem Rohrleitungssystem untersucht. Chlorung von tauchgeteerten Edelstahlcoupons mit Biofilm führten zu einer fast vollständigen Ablösung des Biofilms und einer Zunahme der Freisetzung von Fluoren, Phenanthren und Fluoranthen. Die PAK-Freisetzung von tauchgeteerten Edelstahlcou-pons in einer Lösung von Trinkwasser mit 0,1% Natriumazid als Hemmstoff der Atmungskette, der den Biofilm nicht ablöst, führten zu einer Zunahme aller untersuchten PAK in der gleichen Größenordnung wie ohne Bio-film. In chloriertem Teerleachat wurden unter der teilweisen Anwendung einer einfachen Methode der kontinu-ierlichen Extraktion folgende PAK-Derivate analysiert: Chloracenaphthen, 1-Chlorpyren, 9-Fluorenon, Anthron. Da Reaktionsprodukte von Phenanthren und Fluoranthen nicht gefunden werden konnten, wird eine Weiterreaktion zu 9-Fluorenon vorgeschlagen, die durch die Pechoberfläche katalysiert wird. Instationäre Korrosion und nicht vorhandener aerober Abbau sind die Gründe für eine PAK-Zunahme während Stagnationphasen. / The influence of biofilm, encrustation, flow velocity and water quality on the release of PAHs was investigated in batch, continuously flown reactor experiments and in a pipe rig system. Chlorination of coal-tar coated stainless steel slides with biofilm resulted in an almost complete removal of the biofilm and an increase of the release of fluorene, phenanthrene and fluoranthene. PAH release of coal-tar coated stainless steel slides exposed to a solution of drinking water with 0,1% sodium azide as an inhibitor of the respiratory chain which did not remove the biofilm led to an increase of all observed PAHs up to the same magnitude as without biofilm. In chlorinated coal-tar leachate the following derivatives were detected while partly utilizing an easy method for a continuously extrac-tion: chloroacenaphthene, 1-chloropyrene, 9-fluorenone, anthrone. While reaction products of phenanthrene and fluoranthene could not be found a further reaction to 9-fluorenone catalysed by the coal-tar surface is proposed. Instationary corrosion and no aerobic degradation are the reasons for PAH increase during stagnation periods.

A non-reactive model system comprising a highly concentrated and unstable oil-in-water emulsion was used to investigate the retention of oil by the membrane in producing biodiesel with a membrane reactor. Critical flux was identified using the relationship between the permeate flux and transmembrane pressure along with the separation efficiency of the membrane. It was shown that separation efficiencies above 99.5% could be obtained at all operating conditions up to the critical flux. It was observed that the concentration of oil in all collected permeate samples using the oil-water system was below 0.2 wt% when operating at a flux below the critical flux. Studies to date have been limited to the characterization of low concentrated emulsions below 15 vol.%. The average oil droplet size in highly concentrated emulsions was measured as 3200 nm employing direct light scattering (DLS) measurement methods. It was observed that the estimated cake layer thickness of 20 to 80 mm was larger than external diameter of the membrane tube i.e. 6 mm based on a large particle size. Settling of the concentrated emulsion permitted the detection of a smaller particle size distribution (30-100 nm) within the larger particles averaging 3200 nm. It was identified that DLS methods could not efficiently give the droplet size distribution of the oil in the emulsion since large particles interfered with the detection of smaller particles. The content of the smaller particles represented 1% of the total weight of oil at 30°C and 5% at 70°C. This was too low to be detected using DLS measurements but was sufficient to affect ultrafiltration. In order to study the critical flux in the presence of transesterification reaction and the effect of cross flow velocity on separation, various oils were transesterified in another membrane reactor providing higher cross flow velocity. higher cross flow velocity provides better separation by reducing materials deposition on the surface of the membrane due to higher shearing. The oils tested were canola, corn, sunflower and unrefined soy oils (Free Fatty Acids (FFA< 1%)), and waste cooking oil (FFA= 9%). The quality of all biodiesel samples was studied in terms of glycerine, mono-glyceride, di-glyceride and tri-glyceride concentrations. The composition of all biodiesel samples were in the range required by ASTM D6751 and EN 14214 standards. A critical flux based on operating pressure in the reactor was reached for waste cooking and pre-treated corn oils. It was identified that the reaction residence time in the reactor was an extremely important design parameter affecting the operating pressure in the reactor. / Natural Sciences and Engineering Research Council of Canada (NSERC)

INTRODUÇÃO: A utilização de enxertos arteriais na revascularização cirúrgica do miocárdio já está bem estabelecida atualmente pelos cirurgiões cardiovasculares, e sua esqueletização tem apresentado algumas vantagens, a princípio com a artéria torácica interna esquerda. OBJETIVO: Com o objetivo de analisar esse método de dissecção na artéria radial, foram avaliados os desempenhos funcional e hemodinâmico bem como as características morfoanatômicas e histológicas dos enxertos aortocoronários de artéria radial, esqueletizados ou com tecidos adjacentes, na revascularização cirúrgica do miocárdio. MÉTODOS: Foram comparados 40 pacientes, distribuídos randomicamente em dois grupos. No grupo I foi utilizada artéria radial esqueletizada (20 pacientes) e no grupo II, artéria radial com tecidos adjacentes (20 pacientes), para os ramos marginais da artéria coronária esquerda. No total, 39 pacientes foram submetidos a cinecoronariografia e fluxometria com cateter-guia Doppler de 12 MHz (0,014 polegada, Flowire, Jometrics Inc.), no pós-operatório imediato. RESULTADOS: Os dois grupos apresentaram características demográficas semelhantes. As variáveis intra-operatórias principais da artéria radial também foram semelhantes, com comprimento de 17,1 cm no grupo I e de 16,3 cm no grupo II, e débito livre de 80,3 ml/min no grupo I e de 95,5 ml/min no grupo II. Não foram observadas diferenças morfoanatômicas e histológicas nos grupos comparados. Os diâmetros dos enxertos de artéria radial, calculados por meio de angiografia quantitativa no pós-operatório, foram semelhantes (2,66 mm no grupo I e 2,53 mm no grupo II), assim como as variáveis fluxométricas (fluxo sanguíneo de 54,9 ml/min no grupo I e de 44,28 ml/min no grupo II, e reserva de fluxo de 2,12 no grupo I e de 2 no grupo II). Por outro lado, a cinecoronariografia revelou presença de oclusão em um enxerto e estenose em cinco enxertos no grupo II, enquanto o grupo I apresentou estenose em apenas um enxerto de artéria radial (p = 0,091). CONCLUSÕES: Os enxertos aortocoronários de artéria radial tiveram bom desempenho funcional e hemodinâmico precoce. Não houve diferença entre os grupos quanto ao desempenho funcional e hemodinâmico precoce, e quanto às características morfoanatômicas e histológicas. / BACKGROUND: The use of artery grafts in the surgical revascularization of the myocardium is currently a well-established procedure by cardiovascular surgeons, and its skeletonization has posed some advantages, in principle, with the left internal thoracic artery. OBJECTIVE: With the purpose of analyzing this radial artery harvest method, the study evaluated the functional and hemodynamic early performance, as well as the morphological anatomic and histological features of the aortic coronary grafts of the radial artery, skeletonized or with surrounding tissues, in the surgical revascularization of the myocardium. METHODS: The study compared 40 patients, randomly distributed in two groups. In Group I, we employed a skeletonized radial artery (20 patients), and in Group II, the radial artery with surrounding tissues (20 patients), for the marginal branches of the left coronary artery. In total, 39 patients underwent cinecoronariography and fluxometry with a 12-MHz Doppler guide catheter (0.014 in., Flowire, Jometrics Inc.), in the immediate postoperative period. RESULTS: Both groups presented similar demographic features. The main intra-surgical variables of the radial artery were also similar, with an extension of 17.1 cm in Group I, and 16.3 cm in Group II, and the free flow was of 80.3 ml/min in Group I, and of 95.5 ml/min in Group II. No morphological anatomic and histological differences were observed in the compared groups. The diameters of the radial artery grafts, which were calculated by quantitative angiography in the postoperative period, were similar (2.66 mm in Group I, and 2.53 mm in Group II), as well as the flow variables (blood flow of 54.9 ml/min in Group I, and of 44.28 ml/min in Group II, and a flow reserve of 2.12 in Group I, and of 2 in Group II). On the other hand, the cinecoronariography revealed the presence of an occlusion in one graft, and of stenosis in five grafts of Group II, while Group I presented stenosis in only one radial artery graft (p = 0.091). CONCLUSIONS: The aortic coronary grafts of the radial artery displayed good functional and hemodynamic early performance. There was no difference between the groups regarding functional and hemodynamic early performance, and the morphological anatomical and histological features.

Der Einfluss des Biofilms, der Inkrustation, der Fließgeschwindigkeit und der Wasserqualität auf die Freisetzung von PAK wurde in Batch-, Drehkolbenreaktorversuchen und an einem Rohrleitungssystem untersucht. Chlorung von tauchgeteerten Edelstahlcoupons mit Biofilm führten zu einer fast vollständigen Ablösung des Biofilms und einer Zunahme der Freisetzung von Fluoren, Phenanthren und Fluoranthen. Die PAK-Freisetzung von tauchgeteerten Edelstahlcou-pons in einer Lösung von Trinkwasser mit 0,1% Natriumazid als Hemmstoff der Atmungskette, der den Biofilm nicht ablöst, führten zu einer Zunahme aller untersuchten PAK in der gleichen Größenordnung wie ohne Bio-film. In chloriertem Teerleachat wurden unter der teilweisen Anwendung einer einfachen Methode der kontinu-ierlichen Extraktion folgende PAK-Derivate analysiert: Chloracenaphthen, 1-Chlorpyren, 9-Fluorenon, Anthron. Da Reaktionsprodukte von Phenanthren und Fluoranthen nicht gefunden werden konnten, wird eine Weiterreaktion zu 9-Fluorenon vorgeschlagen, die durch die Pechoberfläche katalysiert wird. Instationäre Korrosion und nicht vorhandener aerober Abbau sind die Gründe für eine PAK-Zunahme während Stagnationphasen. / The influence of biofilm, encrustation, flow velocity and water quality on the release of PAHs was investigated in batch, continuously flown reactor experiments and in a pipe rig system. Chlorination of coal-tar coated stainless steel slides with biofilm resulted in an almost complete removal of the biofilm and an increase of the release of fluorene, phenanthrene and fluoranthene. PAH release of coal-tar coated stainless steel slides exposed to a solution of drinking water with 0,1% sodium azide as an inhibitor of the respiratory chain which did not remove the biofilm led to an increase of all observed PAHs up to the same magnitude as without biofilm. In chlorinated coal-tar leachate the following derivatives were detected while partly utilizing an easy method for a continuously extrac-tion: chloroacenaphthene, 1-chloropyrene, 9-fluorenone, anthrone. While reaction products of phenanthrene and fluoranthene could not be found a further reaction to 9-fluorenone catalysed by the coal-tar surface is proposed. Instationary corrosion and no aerobic degradation are the reasons for PAH increase during stagnation periods.

[ES] El cambio climático y la conciencia social sobre el impacto de las infraestructuras en el medio está llevando a la necesidad de diseñar diques en talud con cotas de coronación reducidas frente a eventos de rebase más extremos. Además, la mayoría de estos diques se construyen en zonas de profundidades reducidas, donde el oleaje rompe a causa de la limitación por fondo. Estudios recientes apuntan a la necesidad de considerar no sólo la caudal medio de rebase (q) sino también el máximo volumen individual de rebase (Vmax), el espesor de lámina de agua (OLT) y la velocidad del flujo de rebase (OFV) en el diseño de la cota de coronación de un dique en talud según criterios de rebase. No obstante, existen pocos estudios en la literatura científica centrados en Vmax en estructuras costeras sometidas a oleaje limitado por fondo. Además, estos estudios proporcionan resultados contradictorios en relación a la influencia de la limitación por fondo del oleaje sobre Vmax. En cuanto a OLT y OFV, no se han encontrado estudios en la literatura científica que permitan su predicción en diques en talud. En esta tesis doctoral, se han realizado ensayos físicos 2D en diques en talud rebasables (0.3≤Rc/Hm0≤2.5) sin espaldón y con tres mantos principales (Cubípodo®-1L, cubo-2L y escollera-2L) sobre dos pendientes de fondo suaves (m=2% and 4%) en condiciones de oleaje limitado por fondo (0.2≤Hm0/h≤0.9). Vmax junto con q son las variables más recomendadas en la literatura científica para diseñar la cota de coronación de diques en talud según criterios de rebase. En el presente estudio, los mejores resultados en la estimación de Vmax*=Vmax/(gHm0T012) se han obtenido empleando la función de distribución Weibull de dos parámetros con un coeficiente de determinación R2=0.833. Durante la fase de diseño de un dique en talud, es necesario predecir q para calcular Vmax cuando se emplean los métodos dados en la literatura científica. Por tanto, se debe estimar q con fines de diseño si no se dispone de observaciones directas. En caso de emplear la red neuronal CLASH NN para estimar q (R2=0.636), la bondad de ajuste de la función de distribución Weibull de dos parámetros propuesta en esta tesis para predecir Vmax* es R2=0.617. Así, el ratio entre Vmax* medido y estimado cae dentro del rango de 1/2 a 2 (banda de confianza del 90%) cuando se emplea q estimado con CLASH NN. Los nuevos estimadores desarrollados en la presente disertación proporcionan resultados satisfactorios en la predicción de Vmax* con un método más simple que aquellos propuestos en la literatura científica. No se ha encontrado una influencia significativa de la pendiente de fondo ni de la limitación por fondo del oleaje sobre Vmax* en este estudio. OLT y OFV están directamente relacionados con la estabilidad hidráulica de la coronación del dique y la seguridad peatonal frente a rebase. Por tanto, se requiere estimar OLT y OFV en la coronación del dique para diseñar apropiadamente su cota de coronación empleando criterios de rebase. En este estudio, se han empleado redes neuronales para desarrollar nuevos estimadores explícitos que permiten predecir OLT y OFV superados por el 2% del oleaje incidente con un alto coeficiente de determinación (0.866≤R2≤0.867). El número de cifras significativas apropiado para los coeficientes experimentales de dichos estimadores se ha determinado en base a su variabilidad. El punto óptimo en el que las características del oleaje deben ser estimadas para predecir OLT y OFV se ha identificado a una distancia de 3h desde el pie de la estructura (siendo h la profundidad a pie de dique). La pendiente de fondo tiene influencia sobre OLT y OFV. Los valores más extremos de OLT y OFV se han descrito empleando las distribuciones Exponencial de un parámetro y Rayleigh, respectivamente, con resultados satisfactorios (0.803≤R2≤0.812). / [CA] El canvi climàtic i la consciència social sobre l'impacte de les infraestructures al medi està portant a la necessitat de dissenyar dics en talús amb cotes de coronació reduïdes front a esdeveniments d'ultrapassament més extrems. A més, la majoria dels dics es construeixen en zones amb profunditats reduïdes on l'onatge es trenca a causa de la limitació per fons. Estudis recents apunten a la necessitat de considerar no solament el cabal mitjà de sobrepasse (q) sinó també el màxim volum individual de sobrepasse (Vmax), l'espessor de la làmina d'aigua (OLT) i la velocitat del flux de sobrepasse (OFV) pel disseny de la cota de coronació d'un dic en talús segons criteris de sobrepasse. No obstant, existeixen pocs estudis a la literatura científica centrats en Vmax en estructures costeres sotmeses a onatge limitat per fons. Addicionalment, aquests estudis proporcionen resultats contradictoris en relació a la influència de la limitació per fons de l'onatge sobre Vmax. Quant a OLT i OFV, no s'han trobat estudis a la literatura científica que permeten la seua predicció a dics en talús. En aquesta tesi doctoral, s'han realitzat assajos físics 2D amb dics en talús amb sobrepassos rellevants (0.3≤Rc/Hm0≤2.5) sense espatlló i amb tres elements al mantell principal (Cubípode-1L, cubs-2L i esculleres-2L) ubicats sobre pendents de fons suaus (m=2% i 4%) en condicions d'onatge limitat pel fons (0.2≤Hm0/h≤0.9). Vmax conjuntament amb q són les variables més recomanades a la literatura científica per dissenyar la cota de coronació en dics en talús segons criteris d'ultrapassament. Al present estudi, els millors resultats en l'estimació de Vmax*=Vmax/(gHm0T012) s'han obtingut utilitzant la funció de distribució Weibull de dos paràmetres amb un elevat coeficient de determinació R2=0.833. Durant la fase de disseny d'un dic en talús, és necessari predir q per calcular Vmax quan s'utilitzen els mètodes donats a la literatura científica. Per tant, es deu estimar q amb fins de disseny si no es disposa d'observacions directes. Si s'aplica la xarxa neuronal de CLASH NN per estimar q (R2=0.636), la bondat d'ajust de la funció de distribució Weibull de dos paràmetres proposada a aquesta tesi per predir Vmax* és R2=0.617. Així doncs, el ràtio entre el Vmax* mesurat i estimat es troba dins del rang de 1/2 a 2 (banda de confiança del 90%) quan s'usa q predit amb CLASH NN. Els nous estimadors desenvolupats a aquesta dissertació proporcionen resultats satisfactoris en la predicció de Vmax* amb un mètode més senzill que aquells proposats a la literatura científica. No s'ha trobat una influència significativa de la pendent de fons ni de la limitació de l'onatge per fons sobre Vmax* a aquest estudi. OLT i OFV estan directament relacionats amb l'estabilitat hidràulica de la coronació de dics i la seguretat de vianants front a ultrapassaments. Per tant, es requereix estimar OLT i OFV en la coronació de dics per dissenyar apropiadament la seua cota de coronació utilitzant criteris de sobrepasse. En aquest estudi, s'han usat xarxes neuronals per desenvolupar nous estimadors explícits que permeten predir OLT i OFV superats pel 2% de l'onatge incident amb un elevat coeficient de determinació (0.866≤R2≤0.867). El nombre de xifres significatives apropiat per als coeficients experimentals dels mencionats estimadors s'ha determinat basant-se en la seua variabilitat. El punt òptim on determinar les característiques de l'onatge deuen ser estimades per predir OLT i OFV s'ha identificat a una distància de 3h des del peu de l'estructura (on h és la profunditat a peu de dic). La pendent de fons té influència sobre OLT i OFV. Els valors més extrems de OLT i OFV s'han descrit amb les distribucions Exponencial d'un paràmetre i Rayleigh, respectivament, amb resultats satisfactoris (0.803≤R2≤0.812). / [EN] Climate change and the social concern about the impact of infrastructures is leading to mound breakwaters with reduced crest freeboards facing higher extreme overtopping events. In addition, most mound breakwaters are built in the surf zone where depth-limited wave breaking takes place. Recent studies point out the need of considering not only the mean wave overtopping discharge (q) but also the maximum individual wave overtopping volume (Vmax), the overtopping layer thickness (OLT) and the overtopping flow velocity (OFV) when designing mound breakwater crest elevation using overtopping criteria. However, few studies in the literature are focused on Vmax on coastal structures under depth-limited breaking wave conditions. In addition, those few studies report contradictory conclusions regarding the significance of depth-limited breaking waves on Vmax. With respect to OLT and OFV, no studies are found in the literature for their prediction on mound breakwaters. In this PhD thesis, 2D physical model tests were conducted on overtopped mound breakwaters (0.3≤Rc/Hm0≤2.5) without a crown wall armored with three armor layers (Cubipod®-1L, cube-2L and rock-2L) on two gentle bottom slopes (m=2% and 4%) in depth-limited breaking wave conditions (0.2≤Hm0/h≤0.9). Vmax together with q are the most recommended variables in the literature to design mound breakwater crest elevation based on overtopping criteria. In the present study, the 2-parameter Weibull distribution provides the best results when estimating Vmax*=Vmax/(gHm0T012) with coefficient of determination R2=0.833. During the design phase of a mound breakwater, q is needed to predict Vmax using methods given in the literature. Thus, q must be estimated for design purposes when direct observations are not available. If CLASH NN is used to estimate q (R2=0.636), the goodness-of-fit of the 2-parameter Weibull distribution proposed in this thesis to predict Vmax* is R2=0.617. Hence, the ratio between the estimated and measured Vmax* falls within the range 1/2 to 2 (90% error band) when q is predicted using CLASH NN. The new estimators derived in this study provide satisfactory estimations of Vmax* with a method simpler than those found in the literature. Neither the bottom slope nor the depth-induced wave breaking seem to significantly influence the dimensionless Vmax* in this study. OLT and OFV are directly related to the hydraulic stability of the armored crest and the pedestrian safety. Thus, OLT and OFV are required to properly design crest elevation using overtopping criteria. Neural Networks (NNs) are used in this study to develop new explicit unbiased estimators for the OLT and OFV exceeded by 2% of the incoming waves with a high coefficient of determination (0.866≤R2≤0.867). The appropriate number of significant figures of the empirical coefficients of such estimators is selected according to their variability. The optimum point where wave characteristics are determined to predict OLT and OFV was identified at a distance of 3h from the toe of the structure (where h is the water depth at the toe of the structure). The bottom slope does influence both OLT and OFV. The most extreme values of OLT and OFV are described with the 1-parameter Exponential and Rayleigh distribution functions, respectively, with satisfactory results (0.803≤R2≤0.812). / Al Ministerio de Educación, Cultura y Deporte, por la financiación brindada con el programa de Formación de Profesorado Universitario (FPU16/05081). Al Ministerio de Economía y Competitividad, por la financiación de los proyectos ESBECO (EStabilidad hidráulica del manto, BErmas y COronación de diques en talud con rebase y rotura por fondo, BIA2015-70436-R) y HOLOBREAK (Estabilidad Hidráulica y Transmisión de Diques Rompeolas Homogéneos de Baja Cota Diseñados a Rotura por Fondo, RTI2018-101073-B-I00-AR). / Mares Nasarre, P. (2021). Overtopping flow on mound breakwaters under depth-limited breaking wave conditions [Tesis doctoral]. Universitat Politècnica de València. https://doi.org/10.4995/Thesis/10251/163154 / TESIS

The quest to achieve high resolution in ion mobility spectrometry (IMS) has continued to challenge scientist and engineers in the field of separation science. The low resolution presently attainable in IMS has continued to negatively impact its utility and acceptance. Until now, efforts to improve the resolution have mainly focused on better instrumentation and detection methods. However, since the resolution of IMS is diffusion limited, it makes sense to address this limitation in order to attain high resolution. This dissertation presents a new IMS technique, which utilizes a high electric field and opposing high gas flow velocity with the aim to improve resolution. This approach essentially reduces the residence time of ions in the analyzer. This new technique is called "counter-flow ion mobility analysis" (CIMA). Theoretical modeling of this new technique predicted that a resolution of over 1000 is possible, which is over one order of magnitude better than that of conventional IMS techniques currently used. A wind tunnel was designed and constructed to produce a plug gas flow profile that is needed for CIMA. The test region of the wind tunnel was used as the CIMA analyzer region and was constructed from power circuit boards, PCBs, (top and bottom walls) and conductive plastic side walls. An inclined electric field was created by applying suitable voltages to multiple electrode traces on the PCBs. This inclined field, when resolved into its x- and y-components, was used to oppose the counter-gas flow and transport the ions to the detector, respectively. The results obtained did not show an improvement over conventional IMS techniques because of a limitation in the voltage that could be applied to the analyzer region. However, the results predict that high resolution is possible if (1) the ratio of the electric fields in the horizontal (x direction) to the vertical (y direction) is within the range of 2--0.5, (2) very high electric field and high gas flow velocities are applied, and (3) wall effects in the counter-flow gas profile are eliminated. While the resolution obtained using the present instrumentation is far from what was predicted, the foundation for ultimately achieving high resolution has been laid. The use of a wind tunnel has made the instrumentation possible. As far as the author knows, this is the first time a wind tunnel has been used in chemical measurement instrumentation. Chapter 5 of this dissertation, reports a method developed for predicting the reduced mobility constants, of chemical compounds. This method uses a purely statistical regression analysis for a wide range of compounds which is different from similar methods that use a neural network. The calculated value for this method was 87.4% when calculated values were plotted against experimental K0 values, which was close to the value for the neural network method (i.e., 88.7%).

A non-reactive model system comprising a highly concentrated and unstable oil-in-water emulsion was used to investigate the retention of oil by the membrane in producing biodiesel with a membrane reactor. Critical flux was identified using the relationship between the permeate flux and transmembrane pressure along with the separation efficiency of the membrane. It was shown that separation efficiencies above 99.5% could be obtained at all operating conditions up to the critical flux. It was observed that the concentration of oil in all collected permeate samples using the oil-water system was below 0.2 wt% when operating at a flux below the critical flux. Studies to date have been limited to the characterization of low concentrated emulsions below 15 vol.%. The average oil droplet size in highly concentrated emulsions was measured as 3200 nm employing direct light scattering (DLS) measurement methods. It was observed that the estimated cake layer thickness of 20 to 80 mm was larger than external diameter of the membrane tube i.e. 6 mm based on a large particle size. Settling of the concentrated emulsion permitted the detection of a smaller particle size distribution (30-100 nm) within the larger particles averaging 3200 nm. It was identified that DLS methods could not efficiently give the droplet size distribution of the oil in the emulsion since large particles interfered with the detection of smaller particles. The content of the smaller particles represented 1% of the total weight of oil at 30°C and 5% at 70°C. This was too low to be detected using DLS measurements but was sufficient to affect ultrafiltration. In order to study the critical flux in the presence of transesterification reaction and the effect of cross flow velocity on separation, various oils were transesterified in another membrane reactor providing higher cross flow velocity. higher cross flow velocity provides better separation by reducing materials deposition on the surface of the membrane due to higher shearing. The oils tested were canola, corn, sunflower and unrefined soy oils (Free Fatty Acids (FFA< 1%)), and waste cooking oil (FFA= 9%). The quality of all biodiesel samples was studied in terms of glycerine, mono-glyceride, di-glyceride and tri-glyceride concentrations. The composition of all biodiesel samples were in the range required by ASTM D6751 and EN 14214 standards. A critical flux based on operating pressure in the reactor was reached for waste cooking and pre-treated corn oils. It was identified that the reaction residence time in the reactor was an extremely important design parameter affecting the operating pressure in the reactor. / Natural Sciences and Engineering Research Council of Canada (NSERC)

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The topic of this diploma thesis is heating of apartment buildings, where an attention was focused on thermal comfort in heated rooms. The first theoretical part brings results of CFD simulations which compare radiators with floor heating. The second part consits of practical application o the given building. There are two options in this project - heating by radiators or floor heating. The third part describes two experiments - measurement of indoor environment in two rooms and measurement of gas consumption in apartment buildings with different heating concepts. In the last part the mean radiant temperature is simulated. There are compared different kind of heating, which have impact to distribution of mean radiant temperature in the room. The personal software was created for deeper understanding of mean radiant temperature.