Laser-Directed Energy Deposition (L-DED), an Additive Manufacturing (AM) processused for the fabrication of parts in a layer-wise approach has displayed an immense potential over the last decade. The aerospace industry stands as the primary beneficiary due to the L-DED process capability to build near-net-shape components with minimal tooling and thereby producing minimum wastage because of reduced machining. The widespread use of Alloy 718 in the aero-engine application has prompted huge research interest in the development of L-DED processing of this superalloy. AM processes are hindered by low build rates and high cycle times which directly affects the process costs. To overcome these issues, the present work focusses on obtaining high deposition rates through a high material feed. Studying the influence of process parameters during the L-DED process is of prime importance as they determine the performance of in-service structures. In the present work, process parameters such as laser power, scanning speed, feed rate and stand-offdistances are varied and their influence on geometry and microstructure of Alloy 718 single-track deposits are analyzed. The geometry of deposits is measured in terms of height, width and depth; and the powder capture efficiency is determined by measuring areas of deposition and dilution. The microstructure of the deposits shows a column ardendritic structure in the middle and bottom region of the deposits and equiaxed grains in the top region. Nb-rich segregation involving laves and NbC phases, typical of Alloy718 is found in the interdendritic regions and grain boundaries. The segregation increases along the height of the deposit with the bottom region having the least and the top region showing the highest concentration of Nb-rich phases due to the variation in cooling rates. A high laser power (1600 W – 2000 W) and a high scanning speed (1100 mm/min) are found to be the preferable processing conditions for minimizing segregation. Another approach to minimize segregation is by performing post-build heat treatments. The solution treatment (954 °C/1 hr) and double aging (718 °C/8 hr + 621 °C/ 8 hr) standardized for the wrought form of Alloy 718 is applied to as-built deposits which showed a reduction in segregation due to the dissolution of Nb-rich phases. Upon solution treatment, this reduction is accompanied by precipitation of the delta phase, found predominantly in top and bottom regions and sparsely in the middle region of the deposit.

Additive Manufacturing (AM), commonly known as 3D Printing, is a disruptive modern manufacturing process, in which parts are manufactured in a layer-wise fashion. Among the metal AM processes, Powder Bed Fusion (PBF) technology has opened up a design space that was not formerly accessible with conventional manufacturing processes. It is, now, possible to manufacture complex geometries, such as topology-optimized structures, lattice structures and intricate internal channels, with relative ease. PBF is comprised of Electron Beam Melting (EBM) and Selective Laser Melting (SLM) processes. Though AM processes offer several advantages, the suitability of these processes to replace conventional manufacturing processes must be studied in detail; for instance, the capability to produce components of consistent quality. Therefore, understanding the relationship between the AM process together with the post treatment used and the resulting microstructure and its influence on the mechanical properties is crucial, to enable manufacturing of high-performance components. In this regard, for AM built Alloy 718, only a limited amount of work has been performed compared to conventional processes such as casting and forging. The aim of this work, therefore, is to understand how the fatigue properties of EBM and SLM built Alloy 718, subjected to different thermal post-treatments, is affected by the microstructure. In addition, the effect of as-built surface roughness is also studied. Defects can have a detrimental effect on fatigue life. Numerous factors such as the defect type, size, shape, location, distribution and nature determine the effect of defects on properties. Hot Isostatic Pressing (HIP) improves fatigue life as it leads to closure of most defects. Presence of oxides in the defects, however, hinders complete closure by HIP. Machining the as-built surface improves fatiguelife; however, for EBM manufactured material, the extent of improvement is dependent on the amount of material removed. The as-built surface roughness, which has numerous crack initiation sites, leads to lower scatter in fatigue life. In both SLM and EBM manufactured material, fatigue crack propagation is transgranular. Crack propagation is affected by grain size and texture of the material.

The current patterns of consumption are threatening the availability of natural resources. These natural resources, such as raw materials and biomass, are critical for different economic activities. ProductService System (PSS) has received attention as a solution to drive resource efficiency by extending the life cycle of products. Given the many barriers to shifting from product to PSS-based offering, the literature has acknowledged the importance of partnerships to support Small and Medium-SizedManufacturers (SMMs) during the life cycle of PSS. However, the role played by the partner in supporting the SMM, as well as how are they supporting to overcome existing barriers, remains unclear. To address this gap, the present thesis to aims comprehensively identify the multifaceted role of external partners throughout the life cycle of PSS developed by SMM. The research follows a cross-sectional design to investigate three industry sectors located in Finland, Norway, and Sweden: forestry, farming, and mining machinery manufacturers. Through semi-structured qualitative interviews with CEOs and directors, data was collected and analyzed by thematic analysis. The results show the existence of eight key partners along the life cycle of PSS: Dealers, Suppliers, End Customers, Service Providers, Industry Hubs, Parent Company, New Partners (such as KIBS firms),and Other, such as the ones associated with delivery. These partners were found to support SMMs by co-creation (joint activities involving the exchange of resources between the partner and SMM), education (knowledge sharing from the partner to the SMM), market-related roles (activities associated with the end user, such as sales, marketing, and service provision), and supply chain (roles liked to supply of components and logistics). Partners can drive the shift from current product-oriented PSStowards use- and result-oriented ones, which have a higher potential of creating environmental benefits. The findings of this thesis contribute to the existing literature in many ways. First, it clarifies how partners are supporting SMMs along the life cycle of PSS. Second, it shows that some partners, such as dealers, are more important through the life cycle than other partners. Third, it shows that SMMs opt for different partners to perform the same role. Therefore, it opens the opportunity for future research questions to investigate the causes behind such choices. In terms of practical implications, the thesis support SMMs to optimize and diversify their network of partners by considering partnership alternatives. From the partner’s point of view, it shows the expectations of the SMMs for their partners. Therefore, it can be used to improve the existing solutions aiming to better address the SMMs’ needs.

Sustainability and sustainable production methods are becoming more important in the manufacturing industry all around the world. Within this trend, United Nations’ formulated 2030 Sustainable Development Goals are used as a target and guideline for developing a roadmap in manufacturing companies’ schedules. For this purpose, there are some existing methods used in practice such as Triple Bottom Line (TBL) management, which is based on the environmental, economic, and social aspects of sustainability. The purpose of this study is aiming to provide insights into the role of the TBL management approach in supporting companies to achieve the UN 2030 sustainability goals. As well as contributing to the ongoing discussions on the importance of sustainable practices in achieving the significance of the study. The findings of this study, gathered through a combination of qualitative primary and secondary data collection, show that there are some similarities and differences between the sustainability practices depending on the SDGs. Approaches of the companies vary with factors such as legislations, culture, and other formal and informal institutions of the country. It is found that most of the Dutch companies act more proactive regarding the SDGs whereas Turkish organisations are more reactive to change. It can be seen that Turkish organisations are very much still primarily focused on the economical perspective of TBL. Dutch organisations tend to prioritise the social and the environmental aspects more than their Turkish counterparts. It can also be identified that Turkish organisations tend to be incredibly focused on legislations, whereas Dutch organisations are more often moving towards their own visions and how they want to position themselves in the market. Even though there is a significant difference between the Dutch and Turkish organisations, it can be identified that the economical aspect plays a major role in both cases. Yet the way they work towards this differs strongly.

The demand for Advanced High Strength Steel (AHSS) in the automotive industry is increasing day by day. It is mainly motivated by the fact that AHSS can be used as thin sheets while having high strengths. It enables weight reduction of the automobiles which consequently increases the fuel efficiency and has proven to be less harmful to the environment. It is also expected that AHSS will have even higher strength in the near future. Cold work tools steels with 5 wt.% Cr are commonly used to process AHSS. Therefore, the tool steel must meet the challenges in the future, i.e. have even higher hardness, compressive strength and toughness. One way of increasing the mechanical properties of the tool steel is by improving the heat treatment parameters. However, it is not possible without a deeper understanding of the heat treatment process. Therefore, this work presents investigations related to phase transformations occurring in a 5 wt.% Cr cold work tool steel during heat treatment. Furthermore, the influence of austenitisation and tempering temperatures on the microstructure and mechanical properties were investigated. The studies revealed that a higher austenitisation temperature can be used to achieve a higher hardness, good compressive strength and adequate toughnessof the steel. However, too high austenitisation temperature may result inexcessive coarsening of prior austenite grains which reduced the impact toughness. It was also found that retained austenite can transform during tempering by two different mechanisms. Firstly, when tempering at 525°C, carbides precipitate in retained austenite lowering its stability and permitting a transformation to marten site on cooling. Secondly, when tempering at 600°Cfor extended holding time retained austenite isothermally transforms to ferrite and carbides. This occurs by precipitation of carbides in retained austenite followed by a final transformation to ferrite and carbides.These results were used to understand the standard tempering procedure of the 5 wt.% Cr cold work tool steel. Furthermore, alternative heat treatment procedures are discussed based on the important findings presented in this thesis.

This bachelor thesis was made in collaboration with Scania. The objective was to find the cause for defects found in some rear axle welds. It was known axle material was coated with anti-corrosive oil. Oils were examined through ICP-AES, and then compared to the composition found on the surface of the steel samples. Elements found in the oils vastly differed from one another. One of the oils contains large amounts of aluminium while the other contains high levels of calcium. When samples surfaces were analysed using EDS, phases consisting of aluminium and calcium were observed. These results indicate that the wrong anti-corrosive had been used for the axle material which gave substandard welds. The oil used contained elements with a low vaporisation temperature, such as calcium. This causes instabilities in the keyhole, leading to collapse. Collapse of the keyhole facilitates the formation of defects.

In Laser Materials Processing there has always been a need for suitable methods to supervise and monitor the processes on line, to ensure correct production quality or to trigger alarms when failures are detected. Numerous investigations have been made in this field, including experimental and theoretical work. It is common practice in this field to monitor surface temperature, plasma radiation and back-reflected laser light, coaxially with the laser beam. Traditionally, the monitoring systems involved carry out no statistical analysis of the signals received - they merely involve thresholds. This thesis looks at the feedback collected during laser welding using such a co-axial setup from a Digital Signal Processing point of view and also uses high speed video photography to correlate signal perturbations with process anomalies.Modern Digital Signal Processing techniques such as Kalman filtering, Principal Component Analysis and Cluster Analysis have been applied to the measurement data and have generated new ways to describe the weld behaviour using parameters such as reflected pulse shape. The limitations of commercially available welding supervision systems have been studied and design suggestions for the next generation of on line weld monitoring equipment have been formulated.

There are a need for reducing the weight of vehicles, one solution is to implement cast lightweight materials such as the high pressure die cast AM50 magnesium alloy. The weldability of this cast alloy is poor and to implement the use of the alloy commercially a welding process is needed that limits the porosity of the weld. The aim of this thesis is to study the effect of the welding parameters on the porosity in the weld, for three laser welding methods. The welding methods examined are single spot and twin spot laser using either a beam splitter or separate optics. The microstructure of the base material are also examined in order to evaluate relations between the components of the microstructure and the porosity in the weld. It was concluded that the hydrogen in the base material was the main reason for the observed porosity in the weld and that the material contains high pressure gas. The welding parameters did not influence the porosity for the single beam laser process, however, for the dual beam processes the welding parameters could affect the amount of pores. It was found that a double weld reduced the amount of pores and that the size and distribution of the secondary phase particles would benefit from the treatment. The cleaning of the samples prior to welding increased the porosity, however, non-cleaned samples contained more oxide inclusions. The results indicate that a twin beam process could reduce the porosity in the weld of the AM50 alloy. / Det finns ett behov av att reducera vikten på fordon, en lösning är att implementera gjutna lätta material såsom formsprutad AM50-magnesiumlegering. Svetsbarheten hos denna gjutna legering är dålig och för att kommersiellt kunna använda legeringen krävs en svetsprocess som begränsar svetsens porositet. Syftet med detta examensarbete är att studera svetsparametrarnas effekt på svetsens porositet för tre lasersvetsmetoder. De svetsmetoder som undersöks är enkelpunkts och dubbelpunktslaser där antingen en stråldelare eller separat optik använts. Basmaterialets mikrostruktur undersöks också för att utvärdera sambandet mellan mikrostrukturen och porositeten i svetsen. Man drog slutsatsen att väte i basmaterialet var huvudorsaken till den observerade porositeten i svetsen och att materialet innehåller gas under högt tryck. De undersökta svetsparametrarna påverkade inte porositeten för processen med en laserstråle, men för dubbelstråleprocesserna kan svetsparametrarna påverka mängden porer. Det visade sig att en svets utförd med två strålar minskade mängden porer och att storleken och fördelningen av sekundärfaspartiklarna gynnas av behandlingen. Prover som rengjordes före svetsning hade ökad porositet, men icke-rengjorda prover innehöll mer oxidinneslutningar. Resultaten indikerar att en dubbelstråleprocess kan minska porositeten då AM50-legeringen lasersvetsas.

The focus in this work is on the use of ultrasonic testing as a method for inspecting components manufactured through additive manufacturing (AM) processes. The research is rooted in the need for effective non-destructive testingtechniques that can adapt to the unique challenges posed by AM-produced materials, including complex defect geometries and surface conditions. Ultrasonic testing is a versatile form of non-destructive testing, offering theability to detect internal flaws, such as voids, cracks, and inclusions, with highprecision and in real-time. Unlike many competing methods, ultrasonic testing works on most types of materials. Ultrasonic testing has been applied forinspection purposes for a long time. Now with emerging manufacturing methods, there is a need for evaluation techniques to keep up with this development.New data processing algorithms open up possibilities of extracting more information from the acquired signal. The thesis provides a review of UT’s capabilities in detecting and classifyingdefects within AM components, with a particular emphasis on the subtletiesintroduced by the layer-by-layer construction method inherent to AM technologies. The work advances development and validation of simulation modelsaimed at predicting the ultrasonic response from manufactured defects. Thesemodels are crucial for understanding the interaction between ultrasound wavesand material anomalies, offering insights into the potential for enhanced defectdetection strategies. The research also explores the practical case of integrating UT into the quality assurance processes by relying on mathematical simulation rather than experimental data. The findings suggest avenues for the refinement of creation of inspection procedure, including the the use of meta-models to cheaply acquire worst-case scenario defects, to better accommodate the specificities of AM materials. / Den här avhandlingen handlar om ultraljudsprovning av additivt tillverkade metalkomponenter. Ultraljud är en av flera metoder som används för att detektera defekter i komponenter utan att förstöra komponenten i processen. Samlingsnamnet för dessa metoder är oförstörande provning. Oförstörande provning är en viktig pusselbit i samhällets säkerhet då det möjliggör identifiering och utvärdering av potentiella defekter i material, vilket förebygger olyckor och strukturella fel. Vidare är det en viktig del inom hållbar utveckling genom att maximera nyttjandet av komponenter då dessa inte behöver ersättas med ett överdrivet försiktigt underhållsintervall. Ultraljudsprovning fungerar genomatt ultraljud introduceras in i en komponent, varefter en givare registrerar ekon som uppstår när ljudvågorna interagerar med eventuella defekter. Detta möjliggör både lokalisering och storleksbedömning av defekter, t.ex. sprickor, bindfel eller porer. Resultaten av den här avhandlingen syftar till att ge förutsättningar för att förbättra tolkningen av dessa signaler, dels genom att experimentellt validera simuleringsmodeller, samt tillämpning av dessa modeller för att utveckla en metamodell för att prediktera amplitudsvaret från en mängd defekter inom en viss parameterrymd. Med verktyg som detta kan billigare inspektionsprocedurer möjliggöras genom att man till större del kan förlita sig på simulering av signaler snarare än att skaffa stort underlag med experimentell data. / <p>Paper A, B and C are not included in the eletronic version. Paper C is under submission.</p>

Thermoelectrics is the reversible process which transforms a temperature gradient across a material into an external voltage through a phenomenon known as the Seebeck effect. This has resulted in niche applications such as solid-state cooling for electronic and optoelectronic devices which exclude the need for a coolant or any moving parts and long-lasting, maintenance-free radioisotope thermoelectric generators used for deep-space exploration. However, the high price and low efficiency of thermoelectric generators have prompted scientists to search for new materials and/or methods to improve the efficiency of the already existing ones. Thermoelectric efficiency is governed by the dimensionless figure of merit 𝑧𝑇, which depends on the electrical conductivity, thermal conductivity and Seebeck coefficient value of the material and has rarely surpassed unity. In order to address these issues, research conducted on early transition metal nitrides spearheaded by cubic scandium nitride (ScN) thin films showed promising results with high power factors close to 3000 μWm−1K−2 at 500 °C. In this thesis, rock-salt cubic chromium nitride (CrN) deposited in the form of thin films by reactive magnetron sputtering was chosen for its large Seebeck coefficient of approximately -200 μV/K and low thermal conductivity between 2 and 4 Wm−1K−1. The results show that CrN in single crystal form has a low electrical resistivity below 1 mΩcm, a Seebeck coefficient value of -230 μV/K and a power factor close to 5000 μWm−1K−2 at room temperature. These promising results could lead to CrN based thermoelectric modules which are cheaper and more stable compared to traditional thermoelectric material such as bismuth telluride (Bi2Te3) and lead telluride (PbTe). In addition, the project resulting this thesis was prompted to investigate prospective ternary nitrides equivalent to ScN with (hopefully) better thermoelectric properties. Scandium nitride has a relatively high thermal conductivity value (close to 10 Wm−1K−1), resulting in a low 𝑧𝑇. A hypothetical ternary equivalent to ScN may have a similar electronic band structure and large power factor, but with a lower thermal conductivity value leading to better thermoelectric properties. Thus the elements magnesium, titanium, zirconium and hafnium were chosen for this purpose. DFT calculations were used to simulate TiMgN2, ZrMgN2 and HfMgN2. The results show the MeMgN2 stoichiometry to be stable, with two rivaling crystal structures: trigonal NaCrS2 and monoclinic LiUN2. / <p>The series name <em>Linköping Studies in Science and Technology Licentiate Thesis</em> is incorrect. The correct series name is <em>Linköping Studies in Science and Technology Thesis</em>.</p>