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A Mechanistic Model for CO<sub>2</sub> Localized Corrosion of Carbon SteelLi, Hui 26 July 2011 (has links)
No description available.
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Corrosion in the coolant circuit of Pansarterrängbil 203Danielsson, Olivia, Jonsson, Sonja, Mildenberger, Ida January 2016 (has links)
The military vehicle, Pansarterrängbil 203 (PATGB 203) demonstrates a fault. There are some components in a coolant circuit that fail due to corrosion while others are unaffected. One of the affected components that will be investigated in this report is the water heater. The subject of this technical investigation has been an issue for FMV, Swedish Defence Materiel Administration since a decade. While seeking out the cause of the coolant circuit failing, this investigation aim to analyzing the underlying problems considering material, factors of corrosion and organization. In order to establish the origin of material and appearance of corrosion, experiments were performed. The experiments showed that the original material is an Al-Si alloy. The micrographs indicated varying stratification of the corrosion throughout the unit. The corrosive deposits consisted mainly of oxygen, silicon, aluminum and sodium. Consequently, the protecting passive oxide layer is compromised, which results in a direct connection between the coolant and the underlying material. This direct connection gives rise to the development of corrosion in the material. Clear underlying causes of the corrosion were not found but the most probable suggest on galvanic corrosion accelerated by a stray current. Properly grounding the components decreases the stray current in the system and is essential to avoid corrosion. If grounding the components is not sufficient, additional checks of the coolant with attention to the pH-value and the function of corrosion inhibitors may indicate corrosion at an earlier stage.
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Caracterização da reatividade das ligas alumínio AA2024-T3 e AA7475-T651 soldadas por fricção (FSW) / Characterization of the reactivity of aluminium alloys AA2024-T3 and AA7475-T651 welded by Friction Stir Welding (FSW)Abreu, Caio Palumbo de 09 December 2016 (has links)
A soldagem por fricção (Friction Stir Welding - FSW) é um processo eficiente de unir ligas de alumínio de alta resistência evitando defeitos que são usualmente criados quando técnicas convencionais de soldagem são utilizadas. A indústria aeronáutica tem mostrado grande interesse neste método de soldagem, tanto para a união de ligas similares como dissimilares. Entretanto, este processo causa modificações microestruturais dependentes das condições de tratamento térmico ou termomecânico. Contato elétrico entre zonas de microestruturas diferentes, por sua vez, pode resultar em acoplamento galvânico. No presente estudo, a soldagem por FSW foi usada para unir duas ligas de alumínio dissimilares, AA2024-T3 e AA7475-T651 e o efeito desta soldagem na resistência à corrosão das juntas soldadas e na microestrutura das ligas foi avaliada. Na investigação da resistência à corrosão foram utilizados ensaios eletroquímicos, especificamente, medidas de potencial de circuito aberto (OCP) em função do tempo de exposição ao meio corrosivo, ensaios de polarização e de espectroscopia de impedância eletroquímica, global (EIS) ou local (LEIS), em duas soluções, seja 0,1 M Na2SO4 ou 0,1 M Na2SO4 + 1 mM NaCl. Os ensaios eletroquímicos evidenciaram efeito de acoplamento galvânico nas juntas soldadas. A caracterização microestrutural foi realizada por microscopia ótica, microscopia eletrônica de varredura, microscopia eletrônica de transmissão e por calorimetria diferencial. As zonas afetadas pela solda tiveram importantes modificações na microestrutura indicadas pela precipitação e dissolução de precipitados que afetam a resistência à corrosão localizada. A resistência à corrosão intergranular e a resistência à esfoliação das juntas soldadas também foram avaliadas e comparadas com as das ligas AA2024-T3 e AA7475-T651 não soldadas. Os resultados mostraram aumento da suscetibilidade das juntas soldadas a estas formas de corrosão em comparação com as ligas não soldadas sendo observado ataque mais severo na liga AA7475-T651. A identificação das áreas anódicas e catódicas resultantes do acoplamento galvânico nas juntas soldadas foi realizada por teste que consistiu na deposição de camada de gel (ágar-ágar) com indicador universal na superfície das ligas soldadas. A liga AA2024-T3 atuou como cátodo, enquanto a AA7475-T651, como ânodo no par galvânico. Além disso, evolução de hidrogênio foi observada na região de interface entre a zona termomecanicamente afetada e a termicamente afetada da liga AA7475-T651 mostrando que reações catódicas também ocorreram localmente nesta última liga. Resultados de LEIS obtidos nas diferentes zonas das duas ligas soldadas por FSW mostraram acoplamento galvânico na interface entre elas para tempos curtos de ensaio e deslocamento da região mais ativa com o tempo de ensaio para a liga AA7475-T651, mais precisamente para a interface entre a zona termomecanicamente afetada e a térmicamente afetada desta liga. / Friction Stir Welding (FSW) is an efficient process of joining high strength aluminum alloys avoiding defects that are usually created when conventional welding techniques are used. The aircraft industry has shown great interest in this welding method, both for welding of similar or dissimilar alloys. However, this process causes microstructural changes that are dependent on the thermal or thermomechanical conditions applied. Electrical contact between zones of different microstructures, in turn, can result in galvanic coupling. In the present study, FSW was used to join two dissimilar aluminum alloys, AA2024-T3 and AA7475-T651 and the effect of this process on the corrosion resistance of the welded joints and on the microstructure of the alloys was evaluated. For corrosion resistance evaluation, electrochemical tests were used, specifically, open circuit potential measurements (OCP) as a function of time of exposure time to the corrosive environment, polarization tests, and electrochemical impedance spectroscopy, global (EIS) or local (LEIS), in two solutions, either 0.1 M Na2SO4 or 0.1M Na2SO4 + 1 mM NaCl. The electrochemical tests showed galvanic coupling effects in the welded joints. Microstructural characterization was carried out by optical microscopy, scanning electron microscopy, transmission electron microscopy and differencial scanning calorimetry. The welded affected zones showed significant microstructural changes indicated by precipitation and dissolution of precipitates that affect the localized corrosion resistance. Intergranular and exfoliation corrosion resistance of the welded joints were also evaluated and compared to those of unwelded AA2024-T3 and AA7475-T651 alloys. The results showed increased susceptibility of welded joints to these forms of corrosion in comparison with the unwelded alloys with more severe attack associated to the AA7475-T651 alloy. Identification of anodic and cathodic areas due to galvanic coupling in the welded joints was evaluated by a test consisting in depositing a gel layer (ágar-ágar) with universal indicator on the surface of the welded alloys. The AA2024-T3 alloy worked as cathode, while the AA7475-T651 as anode in the galvanic coupling. Furthermore, hydrogen evolution was observed at the interface region between the thermomechanically affected zone and the heat affected alloy AA7475-T651 showing that cathodic reactions also occurred on this last alloy. LEIS results obtained in different zones of the two FSW welded alloys showed galvanic coupling at the interface between them for short test times and displacement of the most active region to the AA7475-T651 alloy, at longer periods of test, specifically to the interface between the thermomechanically affected and the heat affected zones of this last alloy.
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Mechanistic studies of localized corrosion of Al alloys by high resolution in-situ and ex-situ probing techniquesDavoodi, Ali January 2007 (has links)
A multi-analytical approach based on in-situ and ex-situ local probing techniques was employed to investigate localized corrosion mechanisms of some aluminum alloys in chloride containing solutions, focusing on the influence of intermetallic particles (IMPs) in the alloys. In the EN AW-3003 alloy, SEM-EDS analysis revealed constituent and dispersoid IMPs. There are two types of constituent IMPs, with size ranging from 0.5 to several μm, and composition typically Al6(Fe,Mn) or Al12(Mn,Fe)3Si, respectively,having a Mn/Fe ratio of about 1:1. Fine dispersoids of 0.5 μm or less in size normally have the composition Al12Mn3Si1-2. Scanning Kelvin probe force microscopy (SKPFM measurements showed that the constituent IMPs have a higher Volta potential compared to the matrix, and the Volta potential difference increased with particle size, probably related to the composition of the IMPs. The SKPFM results also showed a Volta potential minimum in the boundary region adjacent to some larger IMPs. The open-circuit potential and electrochemical impedance spectroscopy measurements indicated local electrochemical activities occurring on the surface, and active-like dissolution in the acidic solutions, but a passive-like behavior in the near-neutral solutions. Infrared reflection-absorption spectroscopy measurements after exposure and thermodynamic calculations suggested the formation of mixtures of aluminum oxyhydroxide and acetate on the surface in acetic acid solutions. The formation and fraction of dominant species of the corrosion products depend on the pH of the solution, and aluminum chloride compounds may form at very low pH. Moreover, an integrated in-situ atomic force microscopy (AFM) and scanningelectrochemical microscopy (SECM) set-up was used to investigate the localized activities on the surface. With a dual mode probe, acting as both AFM tip and SECM microelectrode, concurrent topography and electrochemical current images were obtained on the same area of the surface. Numerical simulations of the SECM suggested a micrometer lateral resolution under favorable conditions and the ability to resolve μmsized active sites with a separation distance of about 3 μm or larger. The simulations were verified by SECM mapping of the aluminum alloys in the chloride solutions. The AFM/SECM measurements revealed enhanced cathodic activity on some larger IMPs and local anodic dissolution around larger IMPs. In-situ AFM monitoring confirmed preferential dissolution in the boundary region adjacent to some of these IMPs. The results elucidate the micro-galvanic effect and size effect of the IMPs during the initiation of localized corrosion of the Al alloys. Furthermore, differences in corrosion properties between EN AW-3003 and a newly developed Al–Mn–Si–Zr alloy were studied with a similar approach. Compared to EN AW-3003, the new alloy had a smaller number of particles with a large Volta potential difference relative to the matrix. In slightly corrosive solutions extensive localized dissolution and deposition of corrosion products occurred on EN AW-3003, whereas only a small number of corroding sites and “tunnel-like” pits occurred on the Al–Mn–Si–Zr alloy. The lower corrosion activity and the smaller tunnel-like pits resulted in lower material loss of the Al–Mn–Si–Zr alloy, which is beneficial for applications using a thin material. / QC 20100702
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The face-in-the-crowd and anxiety and cognitionLahti, Dawn 05 March 2008
Hansen and Hansen (1988) found that angry targets in happy crowds were found more quickly and accurately than happy targets in angry crowds. This finding, they dubbed the Face-in-the-Crowd effect. Gilboa-Schechtman and colleagues (1999) found that high anxious participants show a greater enhancement of detecting angry versus happy targets. The purpose of the current studies was to replicate these findings, and to determine whether Rational and Experiential decision-making styles play a role in target detection (Study One) and crowd searching (Study Two), and if these decision-making styles interact with affective predisposition for both reaction time and galvanic skin response in the face-in-the-crowd task. In Study One, I replicated the anger superiority effect and the Anxiety x Target interaction. I also found that the Rational Group tended to be faster than the Experiential Group overall. I found that the High Trait Anxious group had higher GSR than the Low Trait Anxious group averaged over both target conditions. The Rational group had higher GSR when presented with happy targets than when presented with angry targets whereas the Experiential group did not show this difference. In Study Two, I failed to replicate the anger inferiority effect of crowd searching, but I did find that the Rational group tended to be faster than the Experiential group, especially for angry crowd searching. I also found that the Low-State-Anxious-Rational group had lower galvanic skin responses than all other groups across all analyses. The most exciting finding of these two studies was that he Rational Group demonstrated a facility for the face-in-the-crowd task, validating decision-making style as an important dimension to be considered in future face-in-the-crowd research. The research also provided support for network theories and it is hoped that future studies might endeavor to explore facial processing with this theoretical framework in mind.
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The face-in-the-crowd and anxiety and cognitionLahti, Dawn 05 March 2008 (has links)
Hansen and Hansen (1988) found that angry targets in happy crowds were found more quickly and accurately than happy targets in angry crowds. This finding, they dubbed the Face-in-the-Crowd effect. Gilboa-Schechtman and colleagues (1999) found that high anxious participants show a greater enhancement of detecting angry versus happy targets. The purpose of the current studies was to replicate these findings, and to determine whether Rational and Experiential decision-making styles play a role in target detection (Study One) and crowd searching (Study Two), and if these decision-making styles interact with affective predisposition for both reaction time and galvanic skin response in the face-in-the-crowd task. In Study One, I replicated the anger superiority effect and the Anxiety x Target interaction. I also found that the Rational Group tended to be faster than the Experiential Group overall. I found that the High Trait Anxious group had higher GSR than the Low Trait Anxious group averaged over both target conditions. The Rational group had higher GSR when presented with happy targets than when presented with angry targets whereas the Experiential group did not show this difference. In Study Two, I failed to replicate the anger inferiority effect of crowd searching, but I did find that the Rational group tended to be faster than the Experiential group, especially for angry crowd searching. I also found that the Low-State-Anxious-Rational group had lower galvanic skin responses than all other groups across all analyses. The most exciting finding of these two studies was that he Rational Group demonstrated a facility for the face-in-the-crowd task, validating decision-making style as an important dimension to be considered in future face-in-the-crowd research. The research also provided support for network theories and it is hoped that future studies might endeavor to explore facial processing with this theoretical framework in mind.
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Validating User Engagement and Effectiveness of Training Simulations : A mixed-methods approach informed by embodied cognition and psychophysiological measures / Validering av användarengagemang och effektivitet hos träningssimulatorer : En kombinerad metodansats informerad av kroppslig kognition och psyko-fysiologiska måttEkanayake, Hiran B. January 2015 (has links)
Simulation-based training has gained widespread attention recently as a response to drawbacks associated with traditional training approaches, such as high training costs (instructors, equipment, etc.), high risks (e.g. pilot training), and ethical issues (e.g. medical training), as well as a lack of availability of certain training environments (e.g. space exploration). Apart from their target training domains, many of aspects of simulations differ, such as their degree of physical realism (fidelity), scenarios (e.g. story), and pedagogical aspects (e.g. after-action reviews and collaborative learning). Among those aspects, designers have mostly focused on developing high-fidelity simulations with the expectation of increasing the effectiveness of training. However, some authors suggest that the above belief is a myth as researchers have failed to identify a linear relationship between the (physical) fidelity and training effectiveness of simulations. Most researchers have therefore evaluated the correspondence between the behaviours of trainees in both real world and simulated contexts, however, the existing methods of simulation validation using behavioural measures have a number of drawbacks, such as the fact that they do not address certain complex phenomena of skills acquisition. Bridging the above knowledge gap, this research reports on empirical investigations using an improved methodology for validating training simulations. This research includes an investigation of the user experience of trainees, with respect to the acceptance of virtual scenarios provoking a similar psychophysiological response as in real world scenarios, and the training potential of simulations with respect to the positive transfer of training from a simulator to real world operational contexts. The most prominent features of the proposed methodology include the use of psychophysiological measures in addition to traditional behavioural measures and the use of natural (quasi-) experiments. Moreover, its conceptual framework was influenced by contemporary theories in cognitive science (e.g. constructivism and embodied cognition). The results of this research have several important theoretical and methodological implications, involving, for example, the dependency of the effectiveness of simulations on the perceived realism of trainees, which is more embodied than has been predicted by previous researchers, and the requirement of several different types/levels of adaptive training experience, depending on the type of trainee. / Träning i simulatorer har på senare år fått ökad uppmärksamhet som en respons på problem och svårigheter förknippade med traditionella träningsansatser, såsom höga kostnader (instruktörer och utrustning, etc.), hög risk (t.ex. träning av piloter), och etiska aspekter (t.ex. träning av kirurger), likaväl som avsaknaden av träningsmöjligheter och miljöer (t.ex. forskning om rymden). Bortsett från vad som specifikt tränas så skiljer sig simuleringar åt i ett flertal olika aspekter såsom fysisk realism (eng. fidelity), scenarier (handling) och pedagogiska aspekter (t.ex. genomgång efter övning och kollaborativt lärande). Bland dessa aspekter så har designers ofta fokuserat att utveckla simuleringar med hög realism med förväntningen att detta ska göra träningen mer effektiv. Litteraturen antyder dock att denna föreställning inte stämmer och att de flesta simuleringar med hög realism inte har lyckats uppnå denna målsättning. En slutsats är därför att det finns ett behov av metoder som kan validera potentialen hos simuleringar avsedda att stödja träning – redan innan dessa används. Enligt litteraturen så är utbildningspotentialen hos en simulering starkt kopplad till hur väl den psykologiska effekten en simulering har, stämmer överens med en verklig upplevelse. Forskning har emellertid identifierat ett flertal svagheter hos existerande ansatser för att validera simuleringar; de är oftast baserade på prestations- och/eller subjektiva mätningar; de har fokuserat en eller ett fåtal psykologiska aspekter; och de bygger på traditionella teorier. Baserat på resultat från studier av en kör-simulator presenteras och föreslås i denna avhandling ett förbättrat ramverk för utvärdering. De mest centrala egenskaperna hos det föreslagna ramverket inbegriper användandet av psyko-fysiologiska mått tillsammans med mer traditionella mått; det konceptuella ramverket bygger på samtida teoretiska ansatser (tex konstruktivism och kroppslig kognition); samt användandet av fält (kvasi-) experiment. Utöver uppnåendet av uppsatta mål för forskningen så har resultaten ett flertal teoretiska och metodologiska implikationer. Bland dessa återfinns beroendet mellan effektiviteten hos en simulering och den upplevelse av realitet som de tränade har, vilken är mer grundläggande än vad som rapporterats i tidigare forskning, samt kravet på flera och olika typer av anpassning av träningsupplevelse för den tränade för att förhöja potentialen hos träningssimulatorer. / SIDA Funded National e-Learning Centre Project at the University of Colombo School of Computing, Sri Lanka
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Optimizing the Removal of Natural Organic Matter in Drinking Water While Avoiding Unintended Consequences Following CoagulationKnowles, Alisha 27 May 2011 (has links)
Over the past decade, the objectives for coagulation based drinking water treatment processes have changed significantly. These changes are a result of stringent goals related to natural organic matter (NOM) removal to mitigate the formation of subsequent harmful and health-related disinfection by-products (DBPs) and the need to achieve adequate filtration performance to ensure sufficient particle removal for pathogen control. Another concern associated with coagulation optimization is the potential unintended consequences of a coagulant change on the distribution system, specifically related to lead release from lead pipe and solder materials. Optimizing these multi-objectives in a direct filtration treatment process presents significant challenges for source waters characterized by low levels of turbidity, alkalinity and organic matter content.
Bench and pilot-scale experiments were conducted to evaluate the performance of ferric sulfate, polyaluminum chloride (PACl) and aluminum chlorohydrate (ACH) against aluminum sulfate (alum) using variable coagulation dosage and pH conditions for a direct filtration facility. Bench-scale experiments were conducted to optimize NOM removal during coagulation using traditional organic matter surrogates coupled with molecular size characterization techniques. Pilot-scale studies provided a snapshot of feasibility in terms of filtration performance for favourable bench-scale conditions and also identified optimal conditions for filtration performance. Results from pilot testing demonstrated that favourable conditions identified for increased potential NOM removals during bench-scale testing were significantly different than optimal filtration conditions identified during pilot studies; and, in fact, severely compromised direct filtration performance due to increased solids loading to the filters.
Bench-scale experiments evaluated lead leaching from lead and lead:tin solder galvanically connected to copper under stagnant conditions using variable chloride-to-sulfate mass ratio (CSMR) conditions for alum, ferric sulfate and PACl. Although recent research identifies high CSMRs (>0.5) as the main mechanism of attack in distribution systems following coagulant changeovers, CSMR was not the primary catalyst for lead leaching following the coagulant changeover conditions evaluated in this study. Residual concentrations of iron and aluminum remaining following coagulation were the principal contributors. Positive correlations were revealed between particulate iron and particulate lead concentrations following stagnation demonstrating that the adsorption of lead to iron oxides is a viable hypothesis for lead release.
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Design, fabrication and characterization of a VMOS monolithic integrated optical detector / L'intégration monolithique d'un photodétecteur à l'intérieur des transistors de puissance verticaux pour des fins de commandeVafaei, Raha 01 July 2014 (has links)
Les travaux présentés dans ce manuscrit traite de l'intégration monolithiqued'une unité d'isolement galvanique optique à l'intérieur de la structure d'un transistor depuissance vertical à ffet de champ 600V. L'unité d'isolement galvanique optique est unphotodétecteur qui est responsable du transfert du signal de commande de parti une unitéde commande externe à le transistor de puissance. L'énergie nécessaire pour commuter ledispositif de puissance est fournie au moyen d'un TIA, suivie d'une commande de grille.Le mémoire de thèse se structure en quatre chapitres équivalents: Introduction et motivation:l'isolement glavanic intégrée pour les dispositifs de puissance, photodiodes intégréscompatibles (JVP) pour les interrupteurs de puissance: Modélisation et conception, IPDfabrication et la caractérisation, et les conclusions et les travaux futurs. Les résultats de cestravaux de recherche sont intéressants pour un large spectre d'applications, spécialementpour les fonctions d'alimentation entièrement intégrés avec et coût de fabrication réduitet des solutions fiables, de haut niveau galvaniques isolement qui sont compacts et rentable. / The work presented in this PhD manuscript deals with the monolithic integrationof an optical galvanic isolation unit within the vertical FET structure of a 600Vpower transistor. The optical galvanic isolation unit is a photodetector that is responsiblefor transferring the gating information signal from an external control unit to the powerswitch. The necessary energy to switch the power device is provided by means of a TIAfollowed by a gate driver. This document has four chapters: introduction and motivation:Integrated glavanic isolation for power devices, Compatible integrated phootdiodes (IPDs)for power switches: Modeling and design, IPD fabrication and characterization, and conclusionsand future work. The results of this research work are interesting for a wide rangeof applications specially as the power electronic community strives for a fully integratedpower function with lower implementation costs and reliable, high level galvanic isolationsolutions that are compact and cost effective.
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Caracterização da reatividade das ligas alumínio AA2024-T3 e AA7475-T651 soldadas por fricção (FSW) / Characterization of the reactivity of aluminium alloys AA2024-T3 and AA7475-T651 welded by Friction Stir Welding (FSW)Caio Palumbo de Abreu 09 December 2016 (has links)
A soldagem por fricção (Friction Stir Welding - FSW) é um processo eficiente de unir ligas de alumínio de alta resistência evitando defeitos que são usualmente criados quando técnicas convencionais de soldagem são utilizadas. A indústria aeronáutica tem mostrado grande interesse neste método de soldagem, tanto para a união de ligas similares como dissimilares. Entretanto, este processo causa modificações microestruturais dependentes das condições de tratamento térmico ou termomecânico. Contato elétrico entre zonas de microestruturas diferentes, por sua vez, pode resultar em acoplamento galvânico. No presente estudo, a soldagem por FSW foi usada para unir duas ligas de alumínio dissimilares, AA2024-T3 e AA7475-T651 e o efeito desta soldagem na resistência à corrosão das juntas soldadas e na microestrutura das ligas foi avaliada. Na investigação da resistência à corrosão foram utilizados ensaios eletroquímicos, especificamente, medidas de potencial de circuito aberto (OCP) em função do tempo de exposição ao meio corrosivo, ensaios de polarização e de espectroscopia de impedância eletroquímica, global (EIS) ou local (LEIS), em duas soluções, seja 0,1 M Na2SO4 ou 0,1 M Na2SO4 + 1 mM NaCl. Os ensaios eletroquímicos evidenciaram efeito de acoplamento galvânico nas juntas soldadas. A caracterização microestrutural foi realizada por microscopia ótica, microscopia eletrônica de varredura, microscopia eletrônica de transmissão e por calorimetria diferencial. As zonas afetadas pela solda tiveram importantes modificações na microestrutura indicadas pela precipitação e dissolução de precipitados que afetam a resistência à corrosão localizada. A resistência à corrosão intergranular e a resistência à esfoliação das juntas soldadas também foram avaliadas e comparadas com as das ligas AA2024-T3 e AA7475-T651 não soldadas. Os resultados mostraram aumento da suscetibilidade das juntas soldadas a estas formas de corrosão em comparação com as ligas não soldadas sendo observado ataque mais severo na liga AA7475-T651. A identificação das áreas anódicas e catódicas resultantes do acoplamento galvânico nas juntas soldadas foi realizada por teste que consistiu na deposição de camada de gel (ágar-ágar) com indicador universal na superfície das ligas soldadas. A liga AA2024-T3 atuou como cátodo, enquanto a AA7475-T651, como ânodo no par galvânico. Além disso, evolução de hidrogênio foi observada na região de interface entre a zona termomecanicamente afetada e a termicamente afetada da liga AA7475-T651 mostrando que reações catódicas também ocorreram localmente nesta última liga. Resultados de LEIS obtidos nas diferentes zonas das duas ligas soldadas por FSW mostraram acoplamento galvânico na interface entre elas para tempos curtos de ensaio e deslocamento da região mais ativa com o tempo de ensaio para a liga AA7475-T651, mais precisamente para a interface entre a zona termomecanicamente afetada e a térmicamente afetada desta liga. / Friction Stir Welding (FSW) is an efficient process of joining high strength aluminum alloys avoiding defects that are usually created when conventional welding techniques are used. The aircraft industry has shown great interest in this welding method, both for welding of similar or dissimilar alloys. However, this process causes microstructural changes that are dependent on the thermal or thermomechanical conditions applied. Electrical contact between zones of different microstructures, in turn, can result in galvanic coupling. In the present study, FSW was used to join two dissimilar aluminum alloys, AA2024-T3 and AA7475-T651 and the effect of this process on the corrosion resistance of the welded joints and on the microstructure of the alloys was evaluated. For corrosion resistance evaluation, electrochemical tests were used, specifically, open circuit potential measurements (OCP) as a function of time of exposure time to the corrosive environment, polarization tests, and electrochemical impedance spectroscopy, global (EIS) or local (LEIS), in two solutions, either 0.1 M Na2SO4 or 0.1M Na2SO4 + 1 mM NaCl. The electrochemical tests showed galvanic coupling effects in the welded joints. Microstructural characterization was carried out by optical microscopy, scanning electron microscopy, transmission electron microscopy and differencial scanning calorimetry. The welded affected zones showed significant microstructural changes indicated by precipitation and dissolution of precipitates that affect the localized corrosion resistance. Intergranular and exfoliation corrosion resistance of the welded joints were also evaluated and compared to those of unwelded AA2024-T3 and AA7475-T651 alloys. The results showed increased susceptibility of welded joints to these forms of corrosion in comparison with the unwelded alloys with more severe attack associated to the AA7475-T651 alloy. Identification of anodic and cathodic areas due to galvanic coupling in the welded joints was evaluated by a test consisting in depositing a gel layer (ágar-ágar) with universal indicator on the surface of the welded alloys. The AA2024-T3 alloy worked as cathode, while the AA7475-T651 as anode in the galvanic coupling. Furthermore, hydrogen evolution was observed at the interface region between the thermomechanically affected zone and the heat affected alloy AA7475-T651 showing that cathodic reactions also occurred on this last alloy. LEIS results obtained in different zones of the two FSW welded alloys showed galvanic coupling at the interface between them for short test times and displacement of the most active region to the AA7475-T651 alloy, at longer periods of test, specifically to the interface between the thermomechanically affected and the heat affected zones of this last alloy.
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