In recent years, there has been a growing trend for the use of industrial by-products in the production of blended cements because of economical, environmental, ecological and diversified product quality reasons. Granulated blast furnace slag, a by-product of the transformation of iron ore into pig-iron in a blast furnace, is one of these materials which is used as a cementitious ingredient. The aim of this study is to investigate the properties of Portland slag cement (CEMII/B-S) by using separate grinding and intergrinding of granulated blast furnace slag and Portland cement clinker. For this purpose, granulated blast furnace slag was used as mineral admixture replacing 30% of the clinker. Clinker and granulated blast furnace slag were ground to four different Blaine fineness values of 3000 cm2/g, 3500 cm2/g, 4000 cm2/g and 4500 cm2/g by intergrinding and separate grinding in a laboratory ball mill. Then, eight Portland slag cement mixes and four Portland cement control mixes were prepared, in order to determine and compare 2-, 7-, 28-, and 90-day compressive and flexural strengths, normal consistencies and setting times. It was found that for the Blaine fineness values of 3000 cm2/g, 3500 cm2/g and 4000cm2/g, the 2-, 7-, 28-, and 90-day compressive strength of the interground Portland slag cements had higher values than the separately ground Portland slag cements. However, for the Blaine fineness values of 4500 cm2/g, separately ground Portland slag cement specimens had slightly higher 2-, 7-, 28-, and 90-day compressive strength values than the interground ones.

El presente estudio tiene por finalidad determinar la viabilidad de la instalación de una planta de producción de panela granula en la región de Lima a través del desarrollo de los principales aspectos comerciales, tecnológicos y financieros. Se desarrolló el estudio de mercado para definir el mercado meta al cual irá el producto, que está conformado por los habitantes de Lima Metropolitana de 18 a 60 años de edad del sector socioeconómico A con un estilo de vida sofisticado1. Utilizando esta segmentación y las encuestas realizadas para medir la intención e intensidad de compra del producto se determinó que la demanda del proyecto será de 177 toneladas de panela granulada para el último año del mismo / This project aims to determine the feasibility of installing a production plant of granulated panela in the region of Lima through the development of major commercial, technological and financial aspects. A market research was developed to define the target market of the product, which is conformed by the inhabitants of Lima from 18 to 60 years of socioeconomic sector A with a sophisticated lifestyle2. Using this segmentation and surveys to measure the intent and intensity of purchase, it was determined that the demand of the project is 177 tons of granulated panela for the last year of it. / Trabajo de investigación

This diploma thesis is focused on methods of using cement kiln by-pass dust in building materials technology. By-pass dust was treated to remove chlorides and could then be used as other constituent to various types of cements in the amount of 0–5 wt. % according to ČSN EN 197-1. The properties of dusts before and after chloride removal were examined and after incorporating modified by-pass dust into the cement, the properties of fresh and hardened cement pastes and mortars were studied. It was found that modified by-pass dust after incorporation into cement fulfill requirements of ČSN EN 197-1.

This diploma thesis is engaged in problems of micropollutants removal by water treatment process. The first part aims to define single micropollutants, possibilities of their removal in laboratory and micropollutants removal on water treatment plant. In the second part, there is data evaluation of water analyses on factual water treatment plant. Also there is description and evaluation of experiment, which aims to pesticide removal from river by using filtration across granulated active carbon.

yes / The present paper reports the testing of 12 alkali-activated mortars and a control ordinary portland cement (OPC) mortar. The main aim is to develop cementless binder activated by sodium silicate powder. An alkali quality coefficient combining the amounts of main compositions of source materials and sodium oxide (Na2O) in sodium silicate is proposed to assess the properties of alkali activated mortars, based on the hydration mechanism of alkali-activated pastes. Fly ash (FA) and ground granulated blast-furnace slag (GGBS) were employed as source materials. The ratio of Na2O-to-source material by weight for different mortars ranged between 0.038 and 0.164; as a result, alkali quality coefficient was varied from 0.0025 to 0.0365. Flow loss of fresh mortar, and shrinkage strain, compressive strength and modulus of rupture of hardened mortars were measured. The compressive strength development of alkali activated mortar was also compared with the design equations for OPC concrete specified in ACI 209 and EC 2. Test results clearly showed that the flow loss and compressive strength development of alkali-activated mortar were significantly dependent on the proposed alkali quality coefficient. In particular, a higher rate of compressive strength development achieved at early age for GGBS-based alkali-activated mortar and at long-term age for FA-based alkali-activated mortar. In addition, shrinkage strain and modulus of rupture of alkali-activated mortar were comparable to those of OPC mortar.

In view of the challenges of decarbonisation of the cement industry, the use of low-clinker ternary cements especially with calcined clays is becoming increasingly important. The combination of Portland cement clinker (K), ground granulated blast furnace slag (S) and calcined clay (Q) in ternary cements is very promising in terms of cement and concrete properties. In this study the CO2 footprint of such cements as well as the energy required for their production was determined over a wide range of cement compositions systematically for the first time. The results were related to the strength development of the cements and the mineralogical com-position as well as the moisture of the used clays. Compared to an OPC (CEM I 42.5), both the CO2 and energy saving potentials for the production of ternary KSQ cements are between 25 and 55 % respectively, depending on the cement composition.

Esse trabalho é dedicado ao desenvolvimento de um simulador para sistema de pesagem e embalagem de produto em pó granulado. Tal simulador reproduz a variabilidade de peso dos cartuchos observados em um sistema de embalagem real. Para esse desenvolvimento foram aplicadas técnicas de Identificação de Sistemas para obter o modelo determinístico do processo e conceitos de Processos Estocásticos para reproduzir as perturbações. O simulador tem como objetivo a avaliação de propostas de melhorias nesse sistema de pesagem, visando reduzir o sobrepeso médio e a quantidade de cartuchos rejeitados por subpeso, denominados de scraps, diminuindo consequentemente as perdas monetárias do processo industrial de embalagem de produtos granulados, com grande potencial de reaplicação para outros tipos de produtos industrializados e sistemas de pesagem. O desempenho do simulador é muito bom, uma vez que as oscilações observadas nos pesos dos cartuchos, devido à variação de densidade, são bem reproduzidas. Portanto as principais contribuições desse trabalho são: 1) o uso de uma abordagem estatística e inovadora para modelar as perturbações, evitando o estudo profundo de suas causas, alcançando um modelo preciso, que simula resultados de sobrepeso e número de cartuchos rejeitados bem próximo da realidade; 2) identificação e quantificação de melhorias no sistema de pesagem e embalagem, sem a necessidade de altos investimentos, dando a opção de decisão de quais melhorias realmente serão implementadas; 3) sobrepeso e scrap normalmente estão entre as três principais perdas monetárias das indústrias que produzem produtos embalados por peso e esse simulador representa uma forma de redução significativa dessas perdas, trazendo uma grande vantagem competitiva em um mercado cada vez mais acirrado. / This work describes the development of a simulator for a packing and weighing system of granulated powder. This simulator reproduces the weight variability of observed cartons in a real packing system. In this development, System Identification techniques were used to obtain the deterministic part of the model and Stochastic Processes to reproduce disturbances. Its objective is to evaluate proposed improvements in the packing and weighing system, aiming at reducing the overweight average and the quantity of rejected cartons by underweight, denominated scraps, cutting down consequently the monetary losses of the granulated product packing process in the industry, with great reapplication potential to other kind of industry products and weighing systems. The simulator performance is very satisfactory, once the oscillations observed in the carton weights, due to powder density variability, are well reproduced. Hence, the main contributions of this work are: 1) use of a statistical and innovative approach to model the disturbances, avoiding a deep study of their causes, achieving a model that provided precise simulated overpacking and scrap results when compared to reality; 2) identification and quantification improvements of the weighing and packing system, with no large investment, giving the option of decision of which improvement will be actually implemented; 3) overweight and scrap are among the three main monetary losses in the industries that make products packed in weight and so this simulator of a packing and weighing system of granulated powder represents a way of reducing significantly these losses, bringing a big competitive advantage in a demanding market.

A crescente preocupação ambiental e a atual crise energética fazem com que indústrias, de um modo geral, intensifiquem esforços para maximização de processos de produção e reutilização de subprodutos gerados. Na siderurgia a produção do aço é realizada por meio da extração do minério de ferro adicionando-se fundentes, gerando como subproduto uma ganga em forma de escória de alto forno. Na presente pesquisa foram compostas misturas de concreto compactado com rolo CCR visando o emprego como base de pavimentos, utilizando três diferentes materiais de granulometria miúda: areia natural, areia industrial e escória granulada de alto forno (com dimensão máxima de 4,8 mm) nas quantidades de 50 % e 100 %; para fins de análise da influência destas diferentes areias foram confeccionados corpos de prova cilíndricos e prismáticos moldados na umidade ótima e no ramo seco da curva de compactação. Foram investigados parâmetros referentes à umidade de compactação, massa específica, resistências à tração indireta e à tração na flexão, módulos de elasticidade por pulso ultrassônico, além de módulos de elasticidade estáticos obtidos a partir de curvas tensão-deformação e por analogia de Möhr (medida de flecha em vigotas em flexão). Visando avaliar a aplicabilidade dos CCR estudados, em especial aquele com escória, foi utilizado o programa computacional MnLayer (para análise de tensões em pavimentos asfálticos) empregando camada de base rígida em CCR para estruturas de pavimentos sujeitos à ação de cargas do tráfego de veículos rodoviários, portuários e aeroportuários, observando a influência dos três tipos de agregados miúdos no nível de tensões da camada cimentada, o que depende em grande parte do módulo de elasticidade da camada de base. Observou-se queda nas resistências dos CCR quando da incorporação de 50 % ou 100 % de escória granulada; por outro lado, essas misturas apresentaram ganhos de resistência em idades mais avançadas em comparação a misturas que empregaram areias natural ou industrial. O módulo de elasticidade dos CCR, com a presença da escória, parcial ou total como fração areia, em geral decresceu à exceção de seu emprego em conjunto com areia natural. As misturas com escória granulada, do ponto de vista de análise mecanicista, resultaram em exigências de maiores espessuras do material, o que não pode fazer tal mistura economicamente viável em qualquer situação, para os casos de misturas com 100 % de escória granulada de alto forno e com fração mista de areia natural e escória. / The increasing environmental concerns as well as energy sources shortage leads industry to consider both optimization of production processes and sustainable use and disposal of its by-pass products. In siderurgical steel manufactures the most common by-pass product is the blast furnace slag with emphasis to its granulated shape. This study considered the evaluation of rolled compacted concretes (RCC) mixtures containing natural or industrial sands as well as such slags at 50% and 100% (with maximum diameter of 4.8 mm) as candidates for pavement base layers. The analysis considered laboratory compaction tests in order to verify the influence of such sands on concrete physical parameters as bulk density and optimum moisture content. Evaluation of mechanical parameters as indirect tensile strength, flexural strength, ultrasonic modulus of elasticity and static modulus of elasticity were carried out as part of the study. Through mechanistic analysis using the elastic layered theory-based computational program MnLayer it was possible to verify implications of each RCC mixture design on pavement thickness and tensile stresses in cemented base layers, in consideration of highway, harbor and airport vehicles. Loss of resistance was verified for RCC mixtures at 50% and 100% slag sand; on the other hand such mixtures have improved its strengths at advanced ages (180 days) compared to the other sands. The modulus of elasticity also decreased for mixtures containing slag sands with exception to the blend of natural and slag sand. Under the mechanistic stand point slag sand mixtures requires thicker base layers in pavements that could lead, depending on several factors, to less cost-effective results in the case of 100% slag sands mixtures and blend (50%-50%) natural and slag sands mixtures.

O presente projeto avaliou um reator anaeróbio operado em batelada e batelada alimentada seqüenciais (ASBR), em ciclos de 8 horas, utilizando biomassa granulada e agitação mecânica em um draft-tube, alimentado com água residuária sintética (500 mgDQO/L), contendo sulfato em diferentes relações DQO/[\'SO IND.4\' POT.2-\']. Em todos os ensaios o reator apresentou uma operação estável, produzindo alcalinidade e com concentração de ácidos voláteis totais em níveis adequados. Para os tempos de alimentação de 10 min, 3 h e 6 h, respectivamente, as eficiências de remoção de sulfato foram de 30, 72 e 72% nas operações nas quais o reator foi alimentado com uma relação DQO/[\'SO IND.4\'POT.2-\'] de 1,34. Nos ensaios nos quais o reator foi alimentado na relação DQO/[\'SO IND.4\'POT. 2-\'] de 0,67, as eficiências para a redução de sulfato foram de 25, 58 e 55%, respectivamente. Na operação com relação DQO/[\'SO IND.4\'POT.2-\'] de 0,34, as eficiências para redução de sulfato foram de 23, 37 e 27%, respectivamente. Desta maneira, pode-se concluir que as operações em batelada alimentada favoreceram a remoção de sulfato, enquanto foi observado que nas operações em batelada a remoção de matéria orgânica atingiu melhores eficiências. / This present work evaluate an anaerobic sequencing batch reactor (ASBR), fed in batch and fed-batch, and cycles of 8 hours, using granulated biomass and mechanical stirring in a draft-tube, fed with synthetic wastewater (500 mgCOD/L), enriched with sulfate in some COD/[\'SO IND.4\'POT.2-\'] relations. In all operations the reactor showed a stable operation, producing alkalinity and maintaining the volatile acids in adequate levels. Considering the fed periods of 10 min, 3 h and 6 h, respectively, the removal efficiencies of the sulfate was 30, 72 e 72%, in the operations when the reactor was fed with a COD/[\'SO IND.4\'POT.2-\'] relation of 1,34. In the essays when the reactor was fed in COD/[\'SO IND.4\'POT.2-\'] relation of 0,67, the efficiencies of the sulfate reduction was 25, 58 e 55%, respectively. When the reactor was operated with COD/[\'SO IND.4\'POT.2-\'] relation of 0,34, the efficiencies of sulfate reduction 23, 37 e 27%, respectively. Thus, is possible to conclude that the operations in fed-batch increased the efficiency of sulfate removal, at what time was observed that in batch operations the organic matter removal attained improved efficiencies.

In well cementing, the cement slurry is exposed to the conditions far different than those of ordinary Portland cement (PC) used in construction. After placement, hardened cement paste should preserve integrity and provide zonal isolation through the life of the well. American Petroleum Institute (API) Class G cement is the most common cement type used in various well conditions. Class G cement has a high degree of sulfate resistance which makes it more stable than PC when subjected to the compulsive well conditions. Ground granulated blast furnace slag (GGBFS) blended cement has a long history of use in the construction industry, but is not extensively used in well cementing applications. This study presents an experimental program to investigate the applicability of CEM I and GGBFS blended cement pastes in the well cementing industry. Class G cement and blends of CEM I and GGBFS with the proportions (80:20), (60:40), (40:60) and (20:80) are prepared with same water/cement ratio (0.44) as restricted for Class G cement in API Specification 10A to be tested. The cement pastes are cured for ages of 1 day, 7 days and 28 days at 80