The James Webb Space Telescope near-infrared camera (JWST NIRCam) has two 2.'2 x 2.'2 fields of view that can be observed with either imaging or spectroscopic modes. Either of two R similar to 1500 grisms with orthogonal dispersion directions can be used for slitless spectroscopy over lambda = 2.4 to 5.0 mu m in each module, and shorter wavelength observations of the same fields can be obtained simultaneously. We describe the design drivers and parameters of the grisms and present the latest predicted spectroscopic sensitivities, saturation limits, resolving powers, and wavelength coverage values. Simultaneous short wavelength (0.6 to 2.3 mu m) imaging observations of the 2.4 to 5.0 mu m spectroscopic field can be performed in one of several different filter bands, either infocus or defocused via weak lenses internal to the NIRCam. The grisms are available for single-object time-series spectroscopy and wide-field multiobject slitless spectroscopy modes in the first cycle of JWST observations. We present and discuss operational considerations including subarray sizes and data volume limits. Potential scientific uses of the grisms are illustrated with simulated observations of deep extragalactic fields, dark clouds, and transiting exoplanets. Information needed to plan observations using these spectroscopic modes is also provided. (C) The Authors. Published by SPIE under a Creative Commons Attribution 3.0 Unported License. Distribution or reproduction of this work in whole or in part requires full attribution of the original publication, including its DOI.

During the COVID-19 outbreak, PCR tests were widely used for large-scale testing and screening. Yet, this technique requires bulky and time-consuming procedures to prepare the samples collected from the patients before their analysis by well-trained experts with expensive and specific equipment. PCR is therefore not competitive as a technique of detection for a widespread and rapid use in point-of-care sites. Thus, the COVID-19 pandemic highlighted the need for cheap and easy-to-implement biosensors. Surface plasmon resonance based sensors were suggested as a promising alternative in recent years. Indeed, they enable real-time and label-free detection of a wide range of analytes. That explains their widespread use in various fields of applications such as pharmacology, toxicology, food safety, and diagnosis. This thesis proposes and demonstrates a new plasmonic configuration of detection, which can address challenges posed by point-of-care settings. The gratings used as transducers in this configuration were fabricated based on laser interference lithography combined with a nanoimprinting process. The responses of these nanostructures interrogated by a p-polarized light beam result in a transfer of energy between two diffracted orders over an angular scan. This optical phenomenon termed as “optical switch”, was theoretically and experimentally investigated and optimized. The principle of detection based on this specific configuration was demonstrated for the detection of small variations in the bulk refractive index with solutions comprised of different ratios of de-ionized water and glycerol. A limit of detection in the range of 10−6 RIU was achieved. In addition, preliminary bio-assays obtained by combining this configuration with a functionalization are presented and demonstrate the selectivity and the potential of this new plasmonic configuration for biosensing applications. This thesis work paves the way for the use of the optical switch configuration as a biosensor aligned with low-cost manufacturing and relevant for diagnosing in point-of-care sites.

Applications of surface plasmon polaritons (SPPs) have thus far emphasized visible and near-infrared wavelengths. Extension into the long-wave infrared (LWIR) has numerous potential advantages for biosensors and waveguides, which are explored in this work. A surface plasmon resonance (SPR) biosensor that operates deep into the infrared (3-11 µm wavelengths) is potentially capable of biomolecule recognition based on both selective binding and characteristic vibrational modes. The goal is to operate such sensors at wavelengths where biological analytes are strongly differentiated by their IR absorption spectra and where the refractive index is increased by dispersion, which will provide enhanced selectivity and sensitivity. Potentially useful IR surface plasmon resonances are investigated on lamellar gratings formed from various materials with plasma frequencies in the IR wavelength range including doped semiconductors, semimetals, and conducting polymers. One outcome of this work has been the demonstration of a simple analytic formula for calculating the SPP absorption resonances in the angular reflectance spectra of gratings. It is demonstrated for Ag lamellar gratings in the 6-11 µm wavelength range. The recipe is semi-empirical, requiring knowledge of a surface-impedance modulation amplitude, which is found here by comparison to experiment as a function of the grating groove depth and the wavelength. The optimum groove depth for photon-to-SPP energy conversion was found by experiment and calculation to be ~10-15% of the wavelength. Hemicylindrical prism couplers formed from Si or Ge were investigated as IR surface plasmon couplers for the biosensor application. Strong Fabry-Perot oscillations in the angular reflectance spectra for these high index materials suggest that grating couplers will be more effective for this application in the LWIR. A variety of materials having IR plasma frequencies were investigated due to the tighter SPP mode confinement anticipated in the IR than for traditional noble metals. First doped-Si and metal silicides (Ni, Pd, Pt and Ti) were investigated due to their inherent CMOS compatibility. Rutherford backscattering spectroscopy, x-ray diffraction, scanning electron microscopy, secondary ion mass spectrometry and four point probe measurements complemented the optical characterization by ellipsometry. Calculation of propagation length and mode confinement from measured permittivities demonstrated the suitability for these materials for LWIR SPP applications. Semimetals were also investigated since their plasma frequencies are intermediate between those of doped silicon and metal silicides. The semimetal antimony, with a plasma frequency ~80 times less than that of gold was characterized. Relevant IR surface plasmon properties, including the propagation length and penetration depths for SPP fields, were determined from optical constants measured in the LWIR. Distinct resonances due to SPP generation were observed in angular reflection spectra of Sb lamellar gratings in the wavelength range of 6 to 11 µm. Though the real part of the permittivity is positive in this range, which violates the usual condition for the existence of bound SPP modes, calculations based on experimental permittivity showed that there is little to distinguish bound from unbound SPP modes for this material. The SPP mode decays exponentially away from the surface on both sides of the permittivity sign change. Water is found to broaden the IR plasmon resonances significantly at 9.25 micron wavelength where aqueous extinction is large. Much sharper resonances for water based IR SPR biosensor can be achieved in the 3.5 to 5.5 µm range. Nano-structured Au films (Au-black) were investigated as IR absorbers and possible solar cell enhancers based on surface plasmon resonance. The characteristic length scales of the structured films vary considerably as a function of deposition parameters, but the absorbance is found to be only weakly correlated with these distributions. Structured Au-black with a broad range of cluster length scales appear to be able to support multiple SPP modes with incident light coupling to the corrugated surface as seen by photoelectron emission microscopy (PEEM) and SPR experiments, supporting the hypothesis that Au-black may be a suitable material for plasmon-resonance enhancement solar-cell efficiency over the broad solar spectrum.

No description available.

Much of the analytical and computational work necessary for the development of distributed fiber-optic strain sensors using photo induced Bragg gratings is presented. The one dimensional wave equation is solved for a slowly varying sinusoidal modulation of the index of refraction. The solution is found to take the form of a fourier transform for low reflectivity «15%) gratings. As a result, the process can be inverted, and if the phase and amplitude of the reflected light can be measured over frequency, the phase and amplitude of the bragg grating as a function of length can be computed using the inverse fourier transform. These results are computationally verified, and then further analysis of critical engineering parameters is carried out. A measurement system and procedure are described. A method of writing long, low-reflectivity bragg grating is proposed. / Master of Science

No description available.

No description available.

Soft X-ray spectroscopy is a useful observational tool, offering information about high-temperature (10⁶ -- 10⁷ K) astrophysical plasmas and providing useful characterizations of a number of energetic systems, including accreting young stars, cosmic filaments between galaxies, and supermassive black holes. In order to yield high resolution spectra with good signal-to-noise, however, soft X-ray spectrometers must realize improvements in resolving power and effective area through the development of high performance gratings. Off-plane reflection gratings offer the capability to work at high dispersions with excellent throughput, and are a viable candidate technology for future X-ray spectroscopy missions. The off-plane geometry requires a customizable grating meeting distinct fabrication requirements, and a process for producing gratings meeting these requirements has been developed. These fabricated gratings have been evaluated for performance in terms of resolution and diffraction efficiency. Furthermore, these gratings have been conceptually implemented in a soft X-ray spectrometer, the Off-Plane Grating Rocket Experiment (OGRE), whose optical design provides a template for future missions to achieve high performance within a small payload envelope.

Les éléments de diffraction sont largement utilises aujourd'hui dans un nombre grandissant d'applications grâce à la progression des technologies de micro-structuration dans le sillage de la microélectronique. Pour un design optimal de ces éléments, des méthodes de modélisation précises sont nécessaires. Plusieurs méthodes ont été développées et sont utilisées avec succès pour des réseaux de diffraction unidimensionnel de différents types. Cependant, les méthodes existantes pour les réseaux deux dimensionnel ne couvrent pas tous types de structures possibles. En particulier, le calcul de l'efficacité de diffraction sur les réseaux métalliques à deux dimensionnel avec parois verticales représente encore une grosse difficulté pour les méthodes existantes. Le présent travail a l'objectif le développement d'une méthode exacte de calcul de l'efficacité de diffraction de tels réseaux qui puisse servir de référence. La méthode modale développée ici - dénommée -true-mode" en anglais - exprime le champ électromagnétique sur la base des vrais modes électromagnétiques satisfaisant les conditions limites de la structure 2D à la différence d'une méthode modale où les modes sont ceux d'une structure approchée obtenue, par exemple, par développement de Fourier. L'identification et la représentation de ces vrais modes 'a deux dimensions restait 'a faire et ce n'est pas le moindre des résultats du présent travail que d'y avoir conduit. Les expressions pour la construction du champ sont données avec des exemples de résultats concrets. Sont aussi fournies les équations pour le calcul des intégrales de recouvrement et des éléments de la matrice de diffusion.

This thesis describes the creation of a metrology system based upon an actively controlled diffraction grating interferometer, which measures relative linear distances. The dynamics of this sensor are estimated based on experimental testing, and a suitable controller is designed to maintain the position of the sensor in the most sensitive operating region. This controller is implemented on a field programmable gate array (FPGA) processor, which allows for flexible programming and real-time control. The sample under test is mounted atop a three axis linear stage system, which allows the diffraction grating interferometer to scan across the surface of the device, creating maps of the static and dynamic measurements. The controller is shown to maintain the sensitivity of the sensor during this operation. This insures all data are taken on the same scale, creating more accurate results. The controller increases the signal to noise ratio as compared to the system without the controller. The specifications of the entire metrology system are detailed including the sensor and controller bandwidth, the vertical and horizontal resolution, and the signal to noise ratio. A case study utilizing a capacitive micromachined ultrasonic transducer (cMUT) is presented. The sensor generates static and dynamic displacement maps of the surface of this MEMS device. The controller improves these measurements by maintaining a position of high sensitivity during operation. Finally, the preliminary results of a miniaturized version of this system are presented including the implementation of two fully independent parallel sensors. This allows for array implementation of these sensors, which is crucial for the batch fabrication photolithography techniques used to create many MEMS devices. Recommendations on the future work needed to complete the array implementation are given in conjunction with methods for increasing the resolution and robustness of the macroscale system described in this thesis.