<p> Effects of siltation were measured by determination of growth rates through x-radiography and trapped clastics sediments through coral sample decalcification. Results show an increase in growth rate with an increase in suspended particulate matter. This is attributed to an increase in nutrient levels with increased SPM values.</p> <p> Support of algal banding being an annual indicator was given by comparison of x-radiographs to actual coral slabs.</p> <p> Observation of radiographs reveal an offshore trend in regard to the distinctiveness of annual banding, with the bands being less obvious on outer shelf corals.</p> <p> Large variations in growth rates found within the sample population as a whole, as well as intra-reef samples reveal the limited applications to which these determinations can be used.</p> / Thesis / Bachelor of Science (BSc)

Production of fine sediments in reef environments is a poorly understood but probably significant process. On the Great Barrier Reef, Cliona viridis is locally abundant. The sponge has been found from Lizard Island in the north, down to the southern part of the Central Region, and it is likely even more widespread. Although on individual reefs the sponge may occur almost anywhere, it is most abundant on lagoon path reefs ("bommies" in Australian), where it overgrows the substrate and bores to a constant depth of about 1.3cm. Sponge infestation reaches a maximum at a depth of 4 m covering almost 8% of the vertical sides of bommies. It is frequently the dominant benthic organism. Serial underwater photography demonstrates that colonies can expand laterally at a rate of about 1 cm yr⁻¹ removing approximately 40% of the substrate. This species is a major producer of fine sediment on the Great Barrier Reef. / Thesis / Master of Science (MS)

I resolved the sedimentary architecture of a shallow water (< 500 m), hemipelagic sediment drift located on the Marion Plateau, seaward and downstream of the Great Barrier Reef (GBR). The drift responded increasingly to sea-level fluctuations during the Pleistocene. In the early Pleistocene, local climatic variations introduce a precessional rhythm to drift architecture that is out of phase with sea level-forced cyclicity. Beginning in the mid Pleistocene, sea level variations dominate drift architecture, with the highest carbonate and terrigenous fluxes likely occurring during highstand and transgression, respectively. At the sea-level transgression of MIS 15 and subsequent isotope stages, the phasing of maximum terrigenous flux corresponds to sea-level transgression, indicating siliciclastic sediment accumulated on the continental shelf behind an exposed barrier reef during the lowstand of MIS 16 and was remobilized by rising sea-level. These sedimentological data indicate GBR initiation occurred during MIS 17. The normal polarity exhibited by the central GBR and thick section of underlying sediments rules out initiation during MIS 19. MIS 17 was the first of the asymmetric glacial cycles characteristic of the Late Pleistocene. If the Florida Keys and Belize barrier reef initiations were indeed simultaneous with that of the GBR, then the changing nature of cyclicity in global sea level and climatic fluctuations likely influenced the initiation of the world's major, modern barrier reefs.

Chronic anthropogenic disturbance has left many marine systems at risk of degrading into undesirable states. In many cases, ecosystem shifts are triggered by catastrophic disturbance events that are beyond the control of local management, such as coral bleaching or cyclones. Recognition of this risk has instigated what has been referred to as a new paradigm for marine stewardship; managing areas with the explicit goal of maintaining ecosystem resilience. Despite this, there has been little synthetic influence of resilience theory on marine conservation planning. This thesis focuses on how to make good decisions regarding the selection of marine protected areas (MPAs), in the face of catastrophic disturbance events and for the conservation of highly dynamic marine systems. Large-scale catastrophic events, although rare, lie generally beyond the control of local management and can prevent marine reserves from achieving biodiversity outcomes. In Chapter 2, I formulate a new conservation planning problem that aims to minimize the probability of missing marine conservation targets as result of catastrophic events. To illustrate this approach, I address the problem of minimizing the impact of large scale coral bleaching events on a reserve system for the Great Barrier Reef, Australia. By explicitly considering the threat of catastrophic bleaching as part of the reserve design problem, it was possible to substantially improve the likely persistence of coral reefs within reserve networks, for a negligible increase in reserve cost. The results also demonstrate that simply aiming to protect the reefs at lowest risk of catastrophic bleaching does not necessarily lead to the best conservation outcomes. It is thought that recovery of marine habitats from uncontrollable disturbance may be faster in marine reserves than in unprotected habitats. But which marine habitats should be protected, those areas at greatest risk or those at least risk? In Chapter 3, I define this problem mathematically for two alternate conservation objectives and determine under which conditions each of the different protection strategies are optimal. With regard to the risk of uncontrollable disturbance, the optimal protection strategy depends on both the conservation objective and the expected rate of habitat recovery inside and outside protected areas. I illustrate this decision making with an example of cyclone disturbance of coral reefs on Australia’s Great Barrier Reef. An adequate consideration of risk can indicate surprising routes to conservation success. The resilience of coral reef systems is closely linked to the presence of grazing herbivores. Although herbivore populations are generally protected through permanent static reserves, the benefits of protection are dynamic in both time and space. Periodically moving protection between reefs allows access to the greatest potential benefits of reservation and can help address social reluctance to permanently close areas. Using analytic methods to solve a theoretical case study, I demonstrate that periodically rotating protection around a reef system can lead to greater average reef resilience than under static protection, but only if the overall level of reservation is high enough or the rotation does not include all reefs in the system. The past ten years have seen increasing enthusiasm for MPAs as a tool for pelagic conservation. However, numerous criticisms have been levelled against the use of place-based management in such a dynamic environment. Evidence, tools and information to address these criticisms and establish the feasibility and relevance of pelagic MPAs are dispersed across the conservation, oceanography and fisheries management literature. In Chapter 5, I review this information and present a synthetic framework for systematic planning of pelagic MPAs. Although many of the lessons learned so far about MPA design in coastal systems can be transferred to pelagic systems, there are some fundamental differences and new challenges involved in the conservation of patchy and highly dynamic resources. These challenges are very much at the leading edge of new conservation science and are likely to stimulate solutions with impact far beyond the design of pelagic MPAs.

Polychlorinated dibenzo-p-dioxins (PCDDs) and polychlorinated dibenzofurans(PCDFs) are two groups of lipophilic, persistent organic pollutants that are produced as by-products of various anthropogenic and industrial processes. Due to their relatively high toxic potencies and potential to bioaccumulate and biomagnify in organisms and through the food chain, the contemporary widespread distribution of these compounds is a concern to the health of the environment, wildlife and humans. This study determined the distribution, pathways and fate of PCDD/Fs in the coastal zone of Queensland, Australia, including the inshore marine environment of the World Heritage Great Barrier Reef Marine Park. This ecosystem supports unique fauna and flora such as the marine herbivorous mammal dugong (Dugong dugon) and its food source, seagrass. Elevated PCDD/Fs were present in soils and sediments along the entire Queensland coastline. Highest concentrations were found in soil from agricultural irrigation drains and in sediments near the mouths of major rivers. Elevated concentrations were associated with rural and urban types of land-use, and PCDD/Fs were present even in locations remote from anthropogenic activities. PCDD/F congener-specific analysis revealed an unusual profile in all samples, dominated by OCDD, with PCDFs present in low concentrations or below the limit of detection. Distinct HxCDD isomer patterns were observed, with the 1,2,3,7,8,9-HxCDD/1,2,3,4,6,7-HxCDD isomer pair dominating the 2,3,7,8-substituted HxCDDs. Similar congener and isomer characteristics were reported in sediments, soil and clay samples from other continents, but could not be attributed to any known source. Possible PCDD/F sources in Queensland were assessed using segmented estuarine sediment cores, for which radiochemical chronologies were established for each depth. Variations of PCDD/F concentrations in the sediment cores over several centuries of depositional history were relatively small. Elevated PCDD levels were still present in sediment slices from the early 17th century. PCDD/F homologue profiles in sediments deposited during the last 350 years were almost identical and correlated well to the characteristic profiles observed in surface sediments and soils from the entire Queensland coastline. These results suggested the presence of an unidentified PCDD source prior to the production of commercial organochlorine products. To investigate the formation of the unusual PCDD/F profiles, congener and isomer specific analyses were undertaken in soils, sediments and dated sediment cores. The results demonstrated that specific transformation processes in the environment have resulted in the observed PCDD profile characteristics. Dechlorination of OCDD was proposed to result in distinct 1,4-pattern characteristics (i.e. formation of isomers chlorinated in the 1,4,6,9-positions). Consequently, the environmental samples do not reflect the signatures of the original source. An alternative hypothesis to natural formation is discussed evaluating these processes and their implications for possible source contributions. This hypothesis explores the potential for the influence of anthropogenic PCDD precursors (e.g. pentachlorophenol) during the 1940s to 1990s. Transport of PCDD/Fs from the land-based source via impacted tributary river systems, and subsequent deposition processes are proposed to result in PCDD/F accumulation in the inshore marine ecosystem. The extent of the sediment PCDD/F contamination governs the concentrations in the extensive inshore marine seagrass meadows of Queensland. Partitioning processes in the sediment-seagrass system lead to increased toxic equivalency (TEQ) in the seagrass, compared to sediment.The relationship between contaminated inshore sediments, seagrass and dugongs were evaluated using six dugong habitat regions along the coastline. PCDD/F body burdens in dugongs are governed by sediment (and seagrass) PCDD/F concentrations in their habitat. High seagrass (and incidental sediment) ingestion rates, selective retention of toxicologically potent congeners and relatively low PCDD/F elimination capacities in dugongs are proposed to result in elevated PCDD/F concentrations and TEQ levels in adult animals. Transfer efficiencies of 4 and 27% of maternal TEQ levels to foetuses and calves (respectively) during gestation and lactation result in relatively high exposure potentials to offspring. Compared to no-observed-adverse-effect-levels in other mammals, and based on the results of this study, a tolerable daily intake (TDI) of 10-24 pg TEQ kg-1 day-1 was estimated for dugongs. The results of the present study found that dugongs from some regions along the coastline of Queensland exceed this TDI by up to 20 fold, suggesting that these populations may be at risk from PCDD/F contamination in their habitat. These results have important implications for the health of the environment, wildlife and humans and were used to develop a conceptual understanding of the sources, pathways and fate of dioxins in Queensland, Australia.

The relatively understudied intermediate waters of the world have been implicated as an important part of the global ocean circulation. This thesis discusses the intermediate waters of the Pacific over space and time. Initially, by using geochemical tracers to look at the present distribution, sources and mixing of the water masses. Secondly, by using oxygen and carbon isotopes from sediment cores to study changes in Antarctic Intermediate Waters (AAIW) over the late Quaternary in the north Tasman Sea. The sediment cores also provide sedimentological data on the hemipelagic sedimentation in the Capricorn Channel in the southern Great Barrier Reef as well information on changes in the East Australian surface current (EAC) over the last glacial-interglacial transition. [A more extended Abstract can be found in the files]

Spatial and temporal information on catchment sediment sources and sinks can provide an improved understanding of catchment response to human-induced disturbances. This is essential for the implementation of well-targeted catchment-management decisions. This thesis investigates the nature and timing of catchment response to human activities by examining changes in sediment sources and sinks in a dry-tropical subcatchment of the Great Barrier Reef (GBR) catchment area, in northeastern Australia. Changes in catchment sediment sources, both in terms of spatial provenance and erosion type, are determined using sediment tracing techniques. Results indicate that changes in sediment source contributions over the last 250 years can be linked directly to changes in catchment land use. Sheetwash and rill erosion from cultivated land (40???60%) and channel erosion from grazed areas (30-80%) currently contribute most sediment to the river system. Channel erosion, on a basin-wide scale, appears to be more important than previously considered in this region of Australia. Optically stimulated luminescence and 137Cs dating are used to determine pre-and post- European settlement (ca. 1850) alluvial sedimentation rates. The limitations of using 137Cs as a floodplain sediment dating tool in a low fallout environment, dominated by sediment derived from channel and cultivation sources, are identified. Low magnitude increases in post-disturbance floodplain sedimentation rates (3 to 4 times) are attributed to the naturally high sediment loads in the dry-tropics. These low increases suggest that previous predictions which reflect order of magnitude increases in post-disturbance sediment yields are likely to be overestimates. In-channel bench deposits, formed since European settlement, are common features that appear to be important stores of recently eroded material. The spatially distributed erosion/sediment yield model SedNet is applied, both with generic input parameters and locally-derived data. Outputs are evaluated against available empirically-derived data. The results suggest that previous model estimates using generic input parameters overestimate post-disturbance and underestimate pre-disturbance sediment yields, exaggerating the impact of European catchment disturbance. This is likely to have important implications for both local-scale and catchment-wide management scenarios in the GBR region. Suggestions for future study and the collection of important empirical data to enable more accurate model performance are made.

Thesis (Ph.D.)--University of Wollongong, 2006. / Typescript. Includes bibliographical references: p. 161-192.

Thesis (M.Sc.)--University of Wollongong, 2006. / Typescript. Includes bibliographical references: p. 87-93.

The principal research question addressed in this thesis is how the effectiveness of an environmental legal system can best be evaluated. A legal system is effective if it is achieving or likely to achieve its objectives. For an environmental legal system this means achieving sustainable development. The hypothesis tested in relation to this research question is that the pressure-state-response ("PSR") method of State of the Environment ("SoE") Reporting provides the best available framework for evaluating the effectiveness of an environmental legal system. A subsidiary research question addressed in this thesis is whether the environmental legal system protecting the Great Barrier Reef ("GBR") in north-eastern Australia is likely to achieve sustainable development of it. The hypothesis tested in relation to this research question is that the environmental legal system protecting the GBR is likely to achieve sustainable development of the GBR. The principal method used to address these research questions and test the hypotheses is a case study of the effectiveness of the laws protecting the GBR. Particular emphasis is given in the case study to climate change both because it is now recognised as the major threat to the GBR and is a topic of significant international and national interest. This thesis is intended to contribute, in particular, to the current public and policy debate on responding effectively to climate change by using the GBR as a yardstick against which to measure "dangerous climate change" and, conversely, acceptable climate change. There are five major findings of the research. First, most of the legal writing regarding environmental legal systems is descriptive, explanatory and interpretative rather than evaluative. Second, most legal writers who attempt to evaluate the effectiveness of part or the whole of an environmental legal system implicitly use the PSR method and refer to pressures, conditions, and responses but do not acknowledge this conceptual framework. Third, the best available conceptual and analytical framework for evaluating the effectiveness of an environmental legal system is the PSR method. It is the simplest, most systematic, comprehensive and meaningful framework with the greatest predictive power for evaluating the effectiveness of the total social and legal response to human-induced environmental degradation currently available. Fourth, current practice in SoE reporting, at least in relation to the GBR, is largely descriptive and rarely evaluates the effectiveness of the response. The fifth major finding of this research is that, while there are many effective parts of the response to pressures on the GBR, the current environmental legal system is not likely to be effective in preventing climate change from causing very serious damage to the GBR. Based on what we know at this point in time, particularly the technology that is currently available and current greenhouse gas emissions, the impacts of climate change appear likely to swamp the many good aspects of the legal system protecting the GBR. Atmospheric concentrations of carbon dioxide in 2005 were approximately 379 parts per million ("ppm") and rising by 2 ppm per year. Including the effect of other greenhouse gases such as methane, the total concentration of atmospheric greenhouse gases was around 455 ppm carbon dioxide equivalents ("CO2-eq") in 2005, although the cooling effect of aerosols and landuse changes reduced the net effect to around 375 ppm CO2-eq. Limiting the total increase in mean global temperature to approximately 1°C requires stabilization of atmospheric greenhouse gases and aerosols around 350 ppm CO2-eq. Increasing the net effect of greenhouse gases and aerosols to 450-550 ppm CO2-eq is expected to result in a 2-3°C rise in mean surface temperatures. There are currently no international or national legal constraints to hold greenhouse gas concentrations beneath these levels and they appear likely to be exceeded. These increases in mean global temperatures are expected to severely degrade the GBR by 2030-2040. Even the targets being set by the new Australian Government of reducing Australia's greenhouse gas emissions by 60% by 2050 appear insufficient to protect the GBR. If a 60% reduction in emissions can be achieved globally by 2050 a rise in mean global temperature of around 2.4°C is expected. This indicates the environmental legal system protecting the GBR is not likely to be effective in relation to climate change and, therefore, is failing to reach its objective of sustainable development. Three major recommendations arise from the research. First, legal writers attempting to evaluate the effectiveness of the whole or part of an environmental legal system should use and acknowledge the PSR method. Second, SoE reports should include a stand-alone chapter evaluating the effectiveness of the response. Third, the environmental legal system protecting the GBR should take strong and comprehensive measures to reduce greenhouse gas emissions if the objective of sustainable development is to be achieved. Such measures should include setting policy targets for stabilizing atmospheric greenhouse gas and aerosol concentrations around 350 ppm CO2-eq to limit increases in mean global temperature to 1°C. Policy targets of stabilizing atmospheric greenhouse gases and aerosols at 450-550 ppm CO2-eq to limit increases in mean global temperatures to 2-3°C are likely to be too high to avoid severe impacts of coral bleaching to the GBR.