The paper at hand presents the environmental impact analysis of a photovoltaic (PV) power station sited in Stockholm, Sweden, using life cycle assessment (LCA). The LCA considers the primary energy return on investment and global warming potential of the PV-station, including; resource extraction, manufacturing, transportation, operation and maintenance, and decommissioning. Other environmental impact indicators are also presented, such as; the eutrophication, acidification, human toxicity, and ozone depletion potentials. The results show that the most critical phase of the lifecycle is the upgrade from metallurgical to solar grade silicon due to the high consumption of energy. The emissions results are compared to the emissions factors used for calculations in Sweden in accordance with the Swedish Energy agency and the European Commission’s directive for emissions calculations. The results for the other environmental indicators showed inconsistencies compared to existing studies, something that is according to the IEA’s guideline for PV-systems LCA caused by data scarcity and the indicators lacking consensus within the PV LCA-community. The studied PV-station is expected to reach energy neutrality after 2,4 years and offset annual GHG emissions of up to18 ton of CO 2 equivalents. / Studien tillhands presenterar miljöutvärderingen av en fotovoltaisk solcellsanläggning i Stockholm. Detta utfördes med hjälp av livscykelanalysverktyget. Analysen använder energiåterbetalningstiden och den globala uppvärmningspotentialen som indikatorer på anläggningens miljöinverkan. Både återbetalningstiden och den globala uppvärmningspotentialen beräknas för gruvarbetet, transporten, drift och underhåll samt avveckling och bortskaffning av anläggningen. Överföringsförluster beräknas också över anläggningens livscykel. Andra indikatorer som beräknas i denna studie är potentialen för försurning, övergödning, ozonnedbrytning och humantoxicitet. Dessa beräknas endast för modulens tillverkningskedja. Studiens resultat visar att den mest kritiska processen under solcellsanläggningens livscykel är kiselmetallens omvandling till solkisel, detta med avseende på energiförbrukningen och utsläpp av växthusgaser. Anläggningens globala uppvärmningspotential uttrycks i växthusgasutsläpp och jämförs med den nordiska elmixens utsläppsfaktor. Jämförelsen görs enligt dem gällande EU-direktiven. Resultaten för dem andraindikatorerna har visat på väsentliga avvikelser jämfört med tidigare studier. Detta beror enligt det internationella energirådet på databrist och på att dessa indikatorer saknar stöd inomLCA samfundet. Solcellsanläggningen beräknas bli energineutral efter 2,4 år samt eutralisera utsläpp på upp till 18 ton koldioxidekvivalenta per år.

As U.S. landfills continue to grow in size, concerns about odorous gas emissions from landfills are increasing. For states that are expanding in population, such as Florida, odors from landfills are a major concern because new housing developments, needed to accommodate the rapid population growth, are creeping closer and closer to the existing landfills. As homes get closer to landfills, odor complaints are likely to become more frequent, causing landfill managers increased problems with public interactions. Odor buffer zones around landfills need to be established to give municipalities tools to help prevent the building of future homes too close to landfills. Using the latest air dispersion model, AERMOD, research predicted downwind odor concentrations from a Central Florida landfill. Accurate estimates of methane emissions throughout a Central Florida landfill were determined using a new technique developed as part of this research that uses hundreds of ambient air VOC measurements taken within a landfill, as receptors. Hundreds of point sources were placed on the landfill, and the standard Gaussian dispersion equations were solved by matrix inversion methods. The methane emission rates were then used as surrogates for odor emissions to predict downwind odor concentrations via AERMOD. By determining a critical zone around a landfill with regards to odor, stakeholders will be able to meet regulatory issues and assist their communities. Other beneficial uses from this research include: determination of existing gas collection system efficiencies, calculation of fugitive greenhouse gas emissions from municipal solid waste (MSW) landfills, and improved landfill gas management.

Compost is commonly used as an organic amendment in cropping systems such as vineyards, and has been shown to be beneficial to carbon (C) sequestration and soil health. As perennial crops, grapevines have a larger potential for C sequestration than most crops. Yet, there is a lack of understanding regarding the relationship between compost application rate, the magnitude of C sequestration, and its environmental tradeoff in the form of greenhouse gas (GHG) emissions. In the study, we investigated the effects of compost application rate on soil C sequestration, GHG emissions, crop growth, and overall soil health after two annual compost treatments at J. Lohr Vineyards and Wines, Paso Robles, CA. Compost was broadcasted to the entire plot area between harvest and the first precipitation in fall at the rate of 0 (control), 2, 4, and 6 tons/acre/year. Soil C sequestration, cumulative carbon dioxide (CO2) and nitrous oxide (N2O) emissions and soil physical properties were assessed at two functional locations (tractor row and vine row) and three depth increments (0-15, 15-30, and 30-60 cm). Cover crop biomass was determined in spring before mowing, while clusters per vine, cluster weight and yield were determined each year at harvest. Although compost application did not significantly affect total soil C stocks, significant increases in early indicators of C sequestration such as permanganate oxidizable carbon (POXC), aggregate distribution, and aggregate C content in large macroaggregates without increasing C mineralization suggests that C input from compost increased C stabilization in soil. Cumulative GHG emissions were not significantly affected by compost application. Both CO2 and N2O emissions were higher in the vine row than the tractor row in the dry season, but the trend for CO2 emissions was the opposite in the wet seasons. Seasonal patterns of GHG emissions were likely due to differences in plant activity and irrigation between functional locations. The lower bulk density in topsoil than subsoil, and the higher water holding capacity and aggregate stability in tractor row topsoil than in the vine row demonstrates how high C content improves soil physical properties. Cover crop growth and grape yield components were unaffected by compost application. Based on our results, early signs of C sequestration and improvements on overall soil health can be achieved in a coarse-texture vineyard in the Central Coast region after annually applying compost at a rate between 2 and 6 tons/acre for two years, without increasing GHG emissions or affecting grape yield. Further investigation is recommended to study the potential synergistic effects between compost application and cover cropping in vineyards if both practices are implemented at the same time.

Underground Coal Gasification (UCG), although not a new concept, is now attracting considerable global attention as a viable process to provide a "clean" and economic fuel from coal. Climate change legislation and the declining position of coal reserves (i.e., deeper and thinner seams) in many parts of the world are promoting and fueling the UCG renaissance. This research presents an analysis of operational parameters of UCG technology to determine their significance and to evaluate the effective range of values for proper control of the process. The study indicates that cavity pressures, gas and water flow rates, development of linkage between wells, and continuous monitoring are the most important operating parameters. A protocol for the selection of suitable sites for UCG projects is presented in this study. The site selection criteria are developed based on successes and failures of previous experiments and pilot studies. The criteria take into account the site characteristics, coal quality parameters, hydrology of the area, availability of infrastructure and regulatory and environmental restrictions on sites. These criteria highlight the merits and demerits of the selected parameters, their importance in site selection and their economic and environmental potentials. Based on the site selection criteria, a GIS model is developed to assist in selecting suitable sites for gasification in any given area of interest. This GIS model can be used as a decision support tool as well since it helps in establishing the tradeoff levels between factors, ranking and scaling of factors, and, most importantly, evaluating inherent risks associated with each decision set. The potential of UCG to conform to different frameworks defined to assess the capability and potential of any project that merits the label, "sustainable," has been evaluated. It has been established that UCG can integrate economic activity with ecosystem integrity, respect for the rights of future generations to the use of resources and the attainment of sustainable and equitable social and economic benefits. The important aspects of UCG that need to be considered for its sustainable development are highlighted. In addition, the environmental benefits of UCG have been evaluated in terms of its potential for reduction in greenhouse gas (GHG) emissions. The findings indicate that UCG significantly reduces GHG emissions compared to other competitive coal exploiting technologies. A model to compute the life cycle greenhouse emissions of UCG has been developed, and it reveals that UCG has distinctive advantages in terms of GHG emissions over other technologies and competes favorably with the latest power generation technologies. In addition to GHG emissions, the environmental impacts of these technologies based on various impact assessment indicators are assessed to determine the position of UCG in the technology mix. It is clear from the analysis that UCG has prominent environmental advantages and has the potential to develop and utilize coal resources in an environmentally friendly and economically sound manner. / Ph. D.

yes / Heavy petroleum industries, including the Fluid Catalytic Cracking (FCC) unit, are among some of the biggest contributors to global greenhouse gas (GHG) emissions. The FCC unit’s regenerator is where these emissions originate mostly, meaning the operation of FCC regenerators has come under scrutiny in recent years due to the global mitigation efforts against climate change, affecting both current operations and the future of the FCC unit. As a result, it is more important than ever to develop models that are accurate and reliable at predicting emissions of various greenhouse gases to keep up with new reporting guidelines that will help optimise the unit for increased coke conversion and lower operating costs. Part 1 of this paper was dedicated to reviewing the riser section of the FCC unit. Part 2 reviews traditional modelling methodologies used in modelling and simulating the FCC regenerator. Hydrodynamics and kinetics of the regenerator are discussed in terms of experimental data and modelling. Modelling of constitutive parts that are important to the FCC unit, such as gas–solid cyclones and catalyst transport lines, are also considered. This review then identifies areas where the current generation of models of the regenerator can be improved for the future. Parts 1 and 2 are such that a comprehensive review of the literature on modelling the FCC unit is presented, showing the guidance and framework followed in building models for the unit.

This study has focused on investigating the perceived effect on knowledge, retention and engagement from using a gamified app developed to reduce employee greenhouse emissions. Data was gathered using a “deed-based” mobile application at a large nordic commercial IT company. The employees of the company entered a month-long campaign commitment to try and improve their knowledge of sustainable emission behavior. After completing the campaign period we conducted interviews with select people to gather qualitative insight of their experience. The results found indicate that participants do not conclusively perceive a knowledge increase of sustainability and greenhouse emissions after the campaign ended. Participants generally enjoyed the competitive aspect of the gamified app, often referring to it as fun and engaging. In some cases, participants became very engaged and initiated deeper sustainability discussions with their teammates during the campaign. / Denna studie har fokuserat på att undersöka upplevd påverkan på kunskap, bibehållande av kunskap och engagemang från att använda en spelapp utvecklad för att minska anställdas CO2-utsläpp. Denna uppdragsbaserade mobilapp användes som utgångspunkt för den här studien på ett stort nordiskt IT-företag. De anställda i företaget gick in i en månadslång kampanj för att försöka förbättra sina kunskaper om hållbart utsläppsbeteende. Efter att ha slutfört kampanjperioden genomfördes intervjuer med utvalda personer för att få insikt i deras erfarenheter från kampanjen. Resultaten indikerar att deltagarna inte upplevde en kunskapsökning inom hållbarhet och växthusgasutsläpp efter kampanjens slut. Deltagarna uppskattade i allmänhet tävlingsmomentet i appen, som ofta ansågs rolig och engagerande. I i vissa fall blev deltagarna väldigt engagerade i djupare hållbarhetsdiskussioner inom laget.

Coastal ecosystems continue to face numerous negative impacts from human activities ranging from local nutrient enrichment to global warming. These threats have complex effects on coastal biogeochemistry, which in turn alters ecosystem ecology and climate. While sediments have long been recognized as cornerstones of marine ecosystem functioning, the impacts of anthropogenic change on benthic biogeochemical cycling remain challenging to constrain. This knowledge gap stems from technological issues as measuring marine sediment processes under natural conditions is a formidable challenge. To help move the field of sediment biogeochemistry forward, I developed a novel mass spectrometer-based system and used it to quantify dissolved gas fluxes from marine sediments. In Chapter One, I survey the field of underwater mass spectrometry from its inception three decades ago to the present. Through comprehensive descriptions of the current status of the technology, field applications to date, and future trends, I provided guidance for how to leverage this powerful new tool to measure gaseous compounds in the under sampled ocean. In Chapter Two, I review the role of permeable shelf sediments in marine nitrogen cycling. My synthesis of the small but growing body of work on nitrogen cycling in shelf sands exposed conflicting evidence surrounding the nitrogen removal capacity of permeable sediments, and I proposed targeted approaches, such as the development of noninvasive in situ technologies, to resolve these controversies. In Chapter Three, I present a newly developed flow-injection sampling system that can be coupled to a mass spectrometer to measure a range of dissolved gas species in the pore water of highly permeable sandy sediments. Rigorous calibration and validation experiments demonstrate that this novel system can quantify dissolved gas depth profiles, as well as fluxes across the sediment-water interface, in permeable sediments. Furthermore, with my prescribed design improvements, this tool promises to provide in situ data in dynamic sandy environments. In Chapter Four, I used the flow-injection mass spectrometer system to measure benthic fluxes of gaseous nitrogen and methane from cohesive sediments subjected to low oxygen conditions and varying organic matter loads. The unprecedented high temporal resolution of the gas flux data revealed the complex and dynamic effects of changing environmental conditions on the capacity of sediments to remove reactive nitrogen and regulate methane emissions. / 2024-11-08T00:00:00Z

No description available.

<p> Forest ecosystems play an important role in the global carbon (C) cycle by exchanging large amounts of carbon dioxide (CO₂) with the atmosphere. Their potential to act as significant sink for atmospheric CO₂ has been recognized and is relevant to current efforts in reducing atmospheric CO₂ concentrations. Besides the most important greenhouse gas CO₂, forests also emit and consume methane (CH₄) and nitrous oxide (N₂O) as the two other important atmospheric greenhouse gases (GHGs). To date, few attempts have been made to quantify the net effect of forest GHG exchange on the global warming potential. Furthermore, a better understanding of successional and environmental effects on forest processes is required to improve large scale estimates of forest C and GHG exchange. </p> <p> This thesis examines C dynamics and the exchange of the three major greenhouse gases (CO₂, CH₄, and N₂O) in an age-sequence (7-, 20-, 35-, and 70-years-old as of 2009) of afforested pine forests, in southern Ontario, Canada. The impacts of environmental controls on these GHG exchanges were also evaluated. Forest C exchange was determined for 2003 to 2008 using the eddy-covariance (EC) technique and inventory-based biometric measurements. Soil CH₄ and N₂O measurements were conducted from 2006 to 2007 using the static closed-chamber method. In addition, concentrations and fluxes of dissolved organic carbon (DOC) throughout the vertical profile in forest canopy and soil were determined from 2004 to 2005 using throughfall buckets and lysimeters. </p> <p> During periods without climatic constraints, monthly gross ecosystem productivity (GEP) and ecosystem respiration (RE) corrected for differences in site index increased with stand age, whereas monthly net ecosystem productivity (NEP) peaked at the 35-year-old site. In contrast, during constrained periods (e.g. seasonal drought events), monthly GEP and NEP at the 20-year-old site were higher compared to the 35-year-old site because trees may have benefited from sustained availability of soil water in deeper layers. This study further demonstrates that differences in site quality may affect the interpretation of age-related C flux dynamics in chronosequence and synthesis studies (Chapter 2). </p> <p> The temperature-RE relationship was an important control on daily NEP anomalies under optimum growing conditions, whereas constrains on GEP primarily determined NEP during environmentally constrained periods. Furthermore, effects from single environmental variable constrains on NEP anomalies were enhanced as well as outbalanced under multiple environmental variable constrains. The results further indicate that future changes in temperature and precipitation patterns towards drier and warmer conditions as well as greater cloud cover may result in reduced C sequestration potentials in these temperate pine forests (Chapter 3). </p> <p> Early summer drought and heat events in 2005 caused NEP to decrease by approximately 100 g C m⁻² y⁻¹ at each site compared to the other years. This decrease was primarily driven by a decrease in photosynthesis, while the effect of these events on ecosystem respiration was small. Overall, for the years 2003-2007, annual NEP was 219, 155, 36, 148, and 120 g C m⁻² y⁻¹ at the 68-year-old site, 666, 318, 346, 511 and 366 g C m⁻² y⁻¹ at the 33-year-old site, 768, 885, 684, 708 and 826 g C m⁻² y⁻¹ at the 18-year-old site, and-18, 145, 125, 34 and 164 g C m⁻² y⁻¹ at the 5-year-old seedling site, respectively (negative numbers indicating net C source (Chapter 4). </p> <p> Four-year mean values of biometric NEP_(B) and EC-based NEP_(EC) were similar at the 7-year-old seedling (77 and 66 g C m⁻² y⁻¹) and the 70-year-old mature site (135 and 124 g C m⁻² y⁻¹), but differed considerably at the 20-year-old (439 and 736 g C m⁻² y⁻¹) and the 35-year-old sites (170 and 392 g C m⁻² y⁻¹). Integrating NEP across the age-sequence resulted in a total net C sequestration of 137 and 229 t C ha⁻¹ over the initial 70 years as estimated by the biometric and EC method, respectively. The total ecosystem C pool at the 70-year-old site suggested an accumulation of 160 t C ha⁻¹. These three estimates resulted in a mean C sequestration of 175 ± 48 t C ha⁻¹ (Chapter 5). </p> <p> For both CH₄ and N₂O, we observed uptake and emission ranging from -160 to 245 μg CH₄ m⁻² hour⁻¹ and -52 to 21 μg N₂O m⁻² hour⁻¹, respectively (negative values indicate net uptake). Mean N₂O fluxes from mid-April to mid-December across the 7-, 20-, 35-, 70-years old stands were -3.7, 1.5, -2.2, and-7.6 μg N₂O m⁻² hour⁻¹, without age-related pattern, whereas the uptake rates of CH₄ increased with stand age from 6.4 to -7.9, -10.8, and-23.3 μg CH₄ m⁻² hour⁻¹, respectively. For the same period, the combined contribution of CH₄ and N₂O exchanges to the global warming potential (GWP) calculated from net ecosystem exchange of CO₂ and aggregated forest floor exchanges of CH₄ and N₂O was on average <4% (Chapter 6). </p> <p> DOC concentration in forest floor leachates was positively correlated to stand age, aboveground biomass and forest floor carbon pools. From the period of Mid-April to December, DOC fluxes via precipitation, throughfall, and leaching through forest floor and Ah-horizon were in the range of ~1 to 2, 2 to 4, 0.5 to 3.5, and 0.1 to 2 g DOC m⁻², respectively. DOC export from the forest ecosystem during that period through infiltration and groundwater discharge decreased with increasing stand age from ~7 to 4, 3, and 2 g DOC m⁻² (Chapter 7). </p> <p> This thesis improved our understanding of C and GHG exchange dynamics and their environmental, physical, and physiological controls in forest ecosystems. This study will also contribute to efforts being made to better predict future forest C and GHG dynamics and their feedbacks on climate under changing environmental conditions. <p> / Thesis / Doctor of Philosophy (PhD)

The use of biofuels as an alternative to gasoline in the transportation sector is seen by policy makers as an important strategy to reduce global greenhouse gas emissions. Biobutanol is one such biofuel that is gathering increasing attention in the biofuel community, because of its preferable fuel qualities over bioethanol. However, despite increasing research into biobutanol production, the thermochemical route for biobutanol production has not been adequately studied in the peer-reviewed literature. In light of this motivation, this thesis considers the design, and economic and environmental assessment of thermochemical plants for producing second and third generation biobutanol. In addition, the potential for using process intensification technology such as dividing wall columns (DWC) in place of conventional distillation columns is also investigated as a way to improve thermochemical biobutanol plants. As a first step, a novel thermochemical plant for producing second generation biobutanol is developed. Detailed economic analysis of this plant show that it is competitive with gasoline under certain process, and market conditions. The designed plant is then extended, with some modifications, to evaluate the economic and environmental potential of a thermochemical plant for producing third generation biobutanol from macroalgae. It was concluded from the results that the thermochemical route is preferable for producing second generation biobutanol over third generation biobutanol. The novel thermochemical plant design is then updated by using a kinetic model of a pilot-scale demonstrated catalyst to represent the critical mixed alcohol synthesis reaction step. This change allows optimal unreacted syngas recycle configurations for maximizing butanol yield to be established. Furthermore, integrating a DWC, designed using a methodology developed in the thesis, into the updated thermochemical plant leads to additional plant improvements. Overall, the work carried out in this thesis demonstrates that the thermochemical route is a viable option for producing second generation biobutanol. / Thesis / Doctor of Philosophy (PhD)