No description available.

No description available.

Field experiments were conducted in Virginia to evaluate the efficacy of AEF-130060 03 plus AEF-107892 applied postemergence (POST) for the control of Italian ryegrass [Lolium multiflorum (Lam)] in barley [Hordeum vulgare (L.)] in comparison to other herbicides currently registered for use in wheat [Triticum aestivum (L.)] and barley. Laboratory experiments were also conducted to evaluate absorption, translocation and metabolism of AEF-130060 03 plus AEF-107892 in wheat, barley, and Italian ryegrass with or without the addition of dicamba. AEF-130060 03 plus AEF-107892 was applied alone at three POST timings. All of these applications were effective in controlling Italian ryegrass. The third application timing of AEF-130060 03 plus AEF-107892 commonly resulted in lower yields than the first or second application timing, due to increased duration of Italian ryegrass competition, increased barley injury and insufficient time for barley recovery from this injury. In the field experiment, significantly greater barley injury was observed when AEF-130060 03 plus AEF-107892 was combined with 2,4-D and dicamba. Early postemergence (EP) treatments of AEF-130060 03 plus AEF-107892 provided control of Italian ryegrass equivalent to that of delayed preemergence (DPRE) applications of flufenacet plus metribuzin when rainfall was received. However, when rainfall was not received AEF-130060 03 plus AEF-107892 provided superior control. Because the efficacy of AEF-130060 03 plus AEF-107892 is not dependant on rainfall, it should provide more consistent control of Italian ryegrass than DP treatments. Laboratory experiments indicated that Italian ryegrass absorbed greater than 2.5, 2.0, and 1.5 times the amount of applied radioactivity at 24, 48, and 96 hours after treatment (HAT), respectively, than wheat or barley. Metabolism experiments indicated that quantity of parent compound in the three species was greatest in Italian ryegrass, followed by barley and then wheat. However, the sum total of metabolites was not different between species. A higher rate of metabolism of AEF-130060 03 plus AEF-107892 was also observed in wheat and barley than in Italian ryegrass. Thus, lower absorption of herbicide by wheat and barley, coupled with a more rapid rate of metabolism, most likely accounts for differential selectivity between these plant species. No differences in absorption, translocation or metabolism were observed within the three plant species due to the addition of dicamba. An additional experiment was conducted in 2000 and 2001 to evaluate the efficacy of preemergence (PRE) and EP applications of DPX-R6447 for the control of Italian ryegrass in wheat and barley in comparison to other herbicides currently registered for use in these crops. Barley and wheat injury and yield were similar with treatments of DPX-R6447 at rates below 176 g ai/ha and treatments of flufenacet plus metribuzin applied alone in both years. Consistent Italian ryegrass control with DPX-R6447 occurred only with rates of 176 g ai/ha or greater in both years. However, these rates resulted in variable injury in both wheat and barley between years. Rates higher than 176 g ai/ha of DPX-R6447 resulted in unacceptable barley and wheat injury. The lack of consistency with regard to barley and wheat injury could limit the utility of this compound in these crops. Field trials were conducted in Virginia to evaluate herbicide programs for control of Italian ryegrass in no-till corn [Zea mays (L.)] establishment. Herbicide programs using transgenic corn hybrids were compared to standard programs that utilize non-selective herbicides in combination with high rates of triazine herbicides. Italian ryegrass control and corn yields similar to those provided by standard programs could be attained through the use of paraquat plus atrazine, and glyphosate applied in combination with atrazine or rimsulfuron plus thifensulfuron-methyl. In glyphosate-tolerant corn, EP applications of glyphosate controlled Italian ryegrass, but yield did not differ from yields of corn treated with standard PRE applications of glyphosate plus atrazine. The use of glufosinate, imazethapyr plus imazapyr, or sethoxydim with appropriate herbicide-tolerant hybrids did not demonstrate potential for improved control of Italian ryegrass. Field experiments were also conducted to investigate the incidence and severity of maize chlorotic dwarf virus (MCDV) and maize dwarf mosaic virus (MDMV) in response to POST johnsongrass control in two corn hybrids. Recent observations have indicated a lack of virus-tolerance in glyphosate-tolerant corn hybrids in Virginia. The rapidity of virus disease development in corn resulting from application of glyphosate or nicosulfuron was also investigated. The virus-susceptible glyphosate-tolerant hybrid developed significantly higher levels of virus incidence three weeks after treatment than the virus-tolerant, non-transgenic hybrid, and virus incidence and severity increased throughout the duration of the growing season. Little or no disease incidence occurred in the virus-tolerant hybrid. The virus-susceptible hybrid exhibited significant increases in disease incidence in response to any herbicide treatment applied to johnsongrass-containing plots relative to the same treatment applied to weed free plots. Johnsongrass control with nicosulfuron or glyphosate caused similar disease incidence and severity in the virus-susceptible hybrid, regardless of application method. Results of these experiments indicated that growers' choice of hybrid should focus primarily on disease resistance rather than herbicide resistance. / Ph. D.

Two experiments were designed to study efficacy and uptake and translocation of an ester formulation of triclopyr (3,5,6-trichloro-2-pyridinyloxyacetic acid) in four solvents, aromatic solvent, aliphatic solvent, vegetable oil, and kerosene following stem applications to red maple (Acer rubrum), white oak (Quercus alba), and Virginia pine (Pinus virginiana). Another objective was to explore correlations between efficacy and uptake and translocation. Additional objectives included examining the influence of concentration, dose, and stem diameter on efficacy and the influence of bark thickness and season of treatment on uptake and translocation. Concentration ranged from 0.25 to 1 lb a.e./gallon in the efficacy study and was 1 lb a.e./gallon in the uptake study. Dose ranged from 0.4 to 2 ml/cm of stem diameter in the efficacy study and was 0.15 ml/cm of stem diameter in the uptake study. Efficacy evaluations were made 14 months following treatment in June. C¹⁴- triclopyr was used to determine uptake and translocation. Saplings in the uptake study were harvested three weeks following treatments in February, May, and July. Aliphatic solvent, vegetable oil, and kerosene treatments resulted in excellent crown volume control, largely independent of concentration, dose, and stem diameter. Aromatic solvent gave poorer results, dependent on concentration, dose, and stem diameter, except among the maples. Herbicide uptake with the vegetable oil treatment was greatest. The other solvents provided similar levels of uptake. Uptake was greatest among the maples, the thinnest-barked species, and about equal in the oaks and pines. Discrepancies between solvent differences in the efficacy and the uptake studies may have been, in part, a consequence of smaller doses used in the uptake study along with conditions which likely promoted greater solvent evaporation than those under which the efficacy study was performed. Faster evaporation of the kerosene and aliphatic solvents may have reduced their penetration of the outer bark while slower evaporation of aromatic solvent and vegetable oil likely had less influence on their penetration. Stem diameter correlated negatively with crown volume control, despite basing dose on stem diameter, suggesting that the square of diameter, or stem volume, may be a more appropriate basis for determining doses. Uptake correlated negatively with bark thickness. Uptake did not vary significantly among seasons but translocation did. Movement to the leaves occurred following the May and July treatment but virtually none to leaves or buds following the February treatment. The high degree of sprouting which occurred among saplings in the May treatment compared with none among saplings in the July treatment would suggest that downward translocation of herbicide was greater in July. / Master of Science

No description available.

Le delta du Rhône est une vaste plaine alluviale recouverte d’étangs et de lagunes, parsemée de cultures diverses, principalement du riz (21’100 ha en 2009, Centre Français du Riz, 2010). Des herbicides répandus en avril (pré levée, prétilachlor) et en juin (poste levée, bentazone ; MCPA et dichlorprop) sont utilisés dans la riziculture pour lutter contre les mauvaises herbes. L’étang de Vaccarès, qui est classé «réserve de biosphère» par l’UNESCO pour sa grande richesse biologique reçoit des pesticides directement issus des rizières par les canaux de drainage. D’un point de vue scientifique, peu d’études sont consacrées au devenir des pesticides dans les eaux estuariennes. En outre, la plupart de ces études ont été focalisées sur la photochimie bien que la biodégradation soit impliqué dans l’atténuation des pesticides. Alors le but de ce travail de thèse est de comprendre le devenir des herbicides de riziculture en évaluant le rôle de la photochimie direct et indirect et de la biodégradation. Nous avons développé donc un modèle capable de décrire la transformation de molécules organique par la voie photochimique dans les eaux estuariennes. Enfin nous avons déterminé les processus principaux impliqués dans l'atténuation rapide des herbicides de riziculture en Camargue. / The Ile de Camargue basin is the central part of the Rhône Delta in the south of France included between the two branches of the river. The higher parts of this area are agricultural lands, mainly rice fields, whereas the lower parts are lagoons and natural wetlands of international importance for biodiversity preservation.Bentazone, dichlorprop, and MCPA are post-emerging herbicides applied in rice fields from mid April to mid June. Rice fields grown under flooded conditions represent an environment where these conditions increase the potential for pesticides to transport in runoff from rice fields to non- target surface waters.To predict their fate in the surface waters of the Camargue and to asses their risk, it is necessary to understand their chemical reaction under environmental conditions.Reactive photoinduced species (RPS, hydroxyl radical HO., singlet oxygen 1O2 and dissolved organic matter triplet state) in estuarine waters (Vaccarès lagoon) were characterized experimentally to estimate the role of photochemistry in rice paddy. We then developed a kinetic model describing the solar photo-transformation of xenobiotic organic compounds induced by the three different photooxidants RPS. Sunlight photodegradation of bentazone, dichlorprop (DCPP), MCPA and alachlor (used as a surrogate for the similar Pretilachlor, pre-emergence herbicide) and microbial transformation were conducted experimentally to estimate near-surface half-lives in surface water. Parallel to the experimental study, an assessment of the elimination rates of those herbicides by sorption and sedimentation, and volatilization were obtained by the model MASAS (Modelling of Anthropogenic Substances in Aquatic Systems).The half-lives of the herbicides obtained experimentally were then compared with those obtained from field data. This allowed to assessing the main processes involved in the attenuation of herbicide concentrations.

Bibliography: leaves 125-141. / xiii, 141 leaves : ill. ; 30 cm. / Title page, contents and abstract only. The complete thesis in print form is available from the University Library. / Addresses the poor control of major weed species under southern Australian winter conditions by the non-selective post-emergence herbicide, glufosinate in order to determine the best way to use it. Dose response experiments were performed under simulated southern Australian winter conditions, and demonstrated a variable glufosinate efficacy between Lollium rigidum and Avis sterilis. Glutamine synthetase assays showed that target site sensitivity did not influence these results. Spray retention experiments showed no influence from plant size or morphological features, while metabolic studies showed that only a small proportion of glufosinate was metabolised in both species. Tests of several populations of Raphanus raphanistrum showed that all populations, despite geographical origin, were poorly controlled by glufosinate, in both field and simulated conditions. Experiments conducted at higher temperatures showed enhanced glufosinate efficiency. Experiments with the use of co-herbicides, chelating agents, fertilizer salts and hormones were also carried out. Studies on the effect of the pH of the herbicide solution on cell uptake showed that uptake into the cell wall only was enhanced by reducing the buffer pH. Shows that the poor efficacy of glufosinate against these species is mainly due to poor translocation of the herbicide. / Thesis (Ph.D.)--University of Adelaide, Dept. of Applied and Molecular Ecology, 2003

Giant ragweed is an extremely competitive weed and poor control in soybean could lead to significant yield losses for Ontario producers. In 2008, a giant ragweed biotype near Windsor, ON was not controlled with glyphosate and further testing confirmed it as the first glyphosate-resistant (GR) weed in Canada. Giant ragweed seed was collected from 102 locations in Essex (70), Kent (21), Lambton (10) and Waterloo (1) counties to document the occurrence and distribution of GR giant ragweed in Ontario. Giant ragweed seedlings were sprayed with glyphosate at 1800 g a.e. ha-1, and evaluated 1, 7, 14 and 28 days after application (DAA). Results from the survey concluded that there are 47 additional locations in southwestern Ontario with GR giant ragweed. The majority of the sites were found in Essex county, but there was one location in both Chatham-Kent and Lambton counties. Field trials were established at six sites with GR giant ragweed during the 2010 and 2011 growing seasons. The objectives were to determine the level of giant ragweed control with increasing doses of glyphosate, and glyphosate tank mixes applied either preplant or postemergence. Control of giant ragweed increased with higher doses of glyphosate, but only at doses that are not economical for producers. The most effective glyphosate tank mixes were 2, 4-D ester, saflufenacil, linuron, and cloransulam-methyl providing up to 98, 94, 99 and 97% control 4 weeks after application (WAA), respectively. Glyphosate plus dicamba in dicamba-tolerant soybean provided up to 100% giant ragweed control, 4 WAA at the three confined field trial locations. / Monsanto Canada Inc.; Canadian Agricultural Adaptation Program; Grain Farmers of Ontario

Bibliography: leaves 125-141. / xiii, 141 leaves : ill. ; 30 cm. / Title page, contents and abstract only. The complete thesis in print form is available from the University Library. / Addresses the poor control of major weed species under southern Australian winter conditions by the non-selective post-emergence herbicide, glufosinate in order to determine the best way to use it. Dose response experiments were performed under simulated southern Australian winter conditions, and demonstrated a variable glufosinate efficacy between Lollium rigidum and Avis sterilis. Glutamine synthetase assays showed that target site sensitivity did not influence these results. Spray retention experiments showed no influence from plant size or morphological features, while metabolic studies showed that only a small proportion of glufosinate was metabolised in both species. Tests of several populations of Raphanus raphanistrum showed that all populations, despite geographical origin, were poorly controlled by glufosinate, in both field and simulated conditions. Experiments conducted at higher temperatures showed enhanced glufosinate efficiency. Experiments with the use of co-herbicides, chelating agents, fertilizer salts and hormones were also carried out. Studies on the effect of the pH of the herbicide solution on cell uptake showed that uptake into the cell wall only was enhanced by reducing the buffer pH. Shows that the poor efficacy of glufosinate against these species is mainly due to poor translocation of the herbicide. / Thesis (Ph.D.)--University of Adelaide, Dept. of Applied and Molecular Ecology, 2003

Thesis (M.S.)--Louisiana State University. / Vita. Bibliography: leaves 55-56.