La corrosion des canalisations métalliques pour le transport de gaz ou d’hydrocarbures est un problème critique qui peut avoir des répercussions financières et environnementales très importantes. Les revêtements polyoléfines tricouches sont largement utilisés pour préserver l’intégrité des structures. Ils sont constitués d’une sous couche mince époxy, d’une couche mince d’adhésif et d’une couche épaisse le plus souvent en polyéthylène. Ce système de revêtement bénéficie de très bonnes qualités d'adhérence. Néanmoins, des cas de décollements de ces revêtements à l’interface époxy/acier ont été constatés sur des pipelines en service depuis quelques années seulement, alors que la durée minimale de vie escomptée des tubes dans le sol est de quelques dizaines d’années. Ces décollements pourraient être dus à une dégradation progressive des liaisons interfaciales entre le primaire époxy et la surface métallique, associée à la présence de contraintes interfaciales importantes entre les différentes couches de l'assemblage. Cette étude vise alors d'une part à proposer des solutions permettant d’aboutir à la meilleure performance en vieillissement de la liaison adhésive, et d'autre part à quantifier les niveaux de contraintes au sein de la canalisation en acier revêtue depuis sa mise en œuvre, jusqu'à sa mise en service.Les liaisons interfaciales dépendant nécessairement de la préparation de surface de l’acier, des procédés de nettoyage ont été testés afin d’évaluer leur influence sur l’adhérence initiale et la durabilité des assemblages. Les préparations de surface permettent d'obtenir un degré de propreté et une rugosité. Ces deux éléments maximisent les forces de liaison et donc l'adhérence du revêtement. Le revêtement résiste alors mieux dans des environnements agressifs. Tous les procédés de nettoyage testés ont conduits à des niveaux de propreté équivalents du substrat en acier. Les essais effectués sur substrats polis miroir ont mis en évidence qu’une rugosité est nécessaire pour améliorer la durabilité des assemblages. La rugosité permet d'obtenir des adhérences supérieures à celles sur substrats polis miroir, de ralentir les effets du vieillissement humide et donc de prolonger la durée de vie du système. Il a été mis en évidence que les fortes rugosités étaient particulièrement bénéfiques pour les adhérences sèches. Par contre, au-delà d’une certaine rugosité, l’augmentation de la rugosité ne s’accompagne pas d’une amélioration significative de l’adhérence humide. Une étude sur l’apport des traitements de surface a aussi été menée. L’addition d’un traitement de surface a peu d’impact sur les adhérences initiales des assemblages, en comparaison avec une préparation de surface classique. Par contre les traitements de surfaces améliorent considérablement les adhérences humides, et donc la durabilité des assemblages. Notre travail prouve que le traitement aminosilane est un candidat potentiel en vue du remplacement du traitement toxique de chromatation, référence en matière de traitements de surface dans l'industrie des pipelines et dont l'utilisation sera interdite dans un futur proche compte tenu de l'évolution de la réglementation. Dans de bonnes conditions d'application et associé avec des primaires époxy appropriés, les adhérences sèches et humides obtenues avec les silanes sont comparables (voire supérieures) à celles de la chromatation.Par ailleurs, la modélisation par éléments finis du système tricouches a permis de préciser les niveaux de contraintes aux interfaces résultant de la mise en œuvre et de prévoir leur évolution au cours du temps et du vieillissement humide. / External Corrosion can weaken underground steel pipelines and render them unsafe for transporting oil or gas. Premature damage of this network could lead to dramatic financial and environmental consequences. Three layers polyolefin coatings composed by a fusion bonded epoxy, a modified polyolefin adhesive and a thick polyolefin topcoat, are the most widely systems used to preserve the structure integrity. This protective coating system presents excellent adhesion. Nevertheless, in some specific cases, loss of adhesion has been observed at steel/epoxy interface on operating pipelines on shorter period than their expected lifetime of about fifty years. This disbonding can be assigned to the progressive degradation of interfacial bonds between the epoxy primer and the metallic surface combined to substantial interfacial stresses between the different layers of the assembly. This study thus aims both to provide solutions to achieve the best ageing performance of the adhesive bond, and secondly to quantify the stress levels in a coated steel pipe since coating manufacturing to pipeline commissioning.Given that interfacial bonds depend necessarily on steel surface preparation, cleaning methods were compared to appraise their influence on assemblies dry and wet adhesion. Surface preparations allow to achieve a level of cleanness and to create a surface roughness. These two elements maximize binding forces and therefore the adhesion of the coating. The coating is thus more resistant to aggressive environments. All cleaning process have led to equivalent level of cleanness of steel substrate. Experiments carried out on mirror polished steel substrates highlighted that a surface roughness is necessary to improve joints durability. Roughness allows to obtain higher adhesion compared to mirror polished steel substrates, slows the effects of humid ageing and thus contributes to extend the durability of the system. It has been demonstrated that a high roughness is particularly beneficial for dry adhesion. By cons, beyond a certain roughness, increasing the surface roughness does not lead to significant improvement of wet adhesion. The benefits of surface treatments were also investigated. The addition of a surface treatment has little impact on dry adhesion in comparison with a conventional surface preparation. However, surface treatments substantially enhance the adhesion strength in wet stage, and therefore increase the durability of the assemblies. We also demonstrate that aminosilane surface treatments are competitive alternatives to traditional chromate conversion, which is the surface treatment of reference in pipeline industry, and whose use will be prohibited in a near future considering changes in legislation. Under good conditions of application and associated with appropriate fusion bonded epoxy, dry and wet adhesion obtained with silane surface treatments are comparable (or even higher ) than those obtained with chromate surface treatments.Furthermore, finite element modeling has allowed to specify interfacial stresses levels inside the assembly resulting from coating's manufacturing process and to predict their evolution over time and during wet ageing.

The aim of this thesis is to investigate to what extent regulated office clothing affects the perception and adaptation of office workers to the thermal conditions surrounding their work environments, focusing on the city of Enugu in South Eastern Nigeria which has hot humid climatic conditions. Clothing, regarded as a second skin, allows us to adapt or adjust to the thermal conditions in our immediate surrounding environment. It also affects our perception of the thermal environment. In some offices however employees are expected to wear regulated clothing or uniforms, during the working day; for various corporate identity reasons. Field studies were undertaken in office spaces in Enugu involving the behavioural and environmental analysis of thermal comfort conditions in six typical case study office spaces, at the Federal Radio Corporation of Nigeria (FRCN) and Federal Road Safety Corps (FRSC). The thesis adopted a mixed‐mode methodological process; combining a quantitative and qualitative approach to data collection and analysis. The field research analysis found that all office spaces analysed were in compliance with the adaptive thermal comfort component of the ASHRAE Standard 55‐2013. The results however did not comply with the adaptive thermal comfort of CEN/EN 15251‐2007. The thermal sensation component of the results suggests a neutral temperature of 28.80C, with 80% thermal satisfaction, in a comfort range of between 25.40C and 32.20C. The thermal comfort vote indicates that approximately 85% of office workers with flexible clothing policy were comfortable at that comfort range, whilst only 55% of workers who had to adhere to a strict uniform policy voted that they were comfortable. The key research findings were: Firstly, the field observations and semi-structured interviews undertaken indicated that the strict uniform policy of FRSC office workers contributed substantially to the limited adaptation of staff to their workspace thermal conditions. Also, of all the thermal variables recorded during the field survey, clothing insulation had the strongest correlations to the thermal sensation of participants in the survey compared to indoor operative temperature, outdoor air temperature, relative humidity or metabolic rate. Furthermore, it is possible for workers in naturally ventilated office buildings in the hot humid climate zone of Enugu to achieve thermal comfort in higher temperature conditions through clothing adaptation.

Wave energy is one of the most promising renewable energy sources for future exploitation. This thesis focuses on thermodynamic effects within Oscillating Water Column (OWC) devices equipped withWells turbines, particularly humidity effects. Previous theoretical studies of the operation of OWCs have resulted in expressions for the oscillation of the water surface in the chamber of an OWC based on linear wave theory, and the air expansion{compression cycle inside the air chamber based on ideal gas theory. Although in practice high humidity levels occur in OWC devices open to the sea, the influence of atmospheric conditions such as temperature and moisture on the performance of Wells turbines has not yet been studied in the field of ocean energy. Researchers have reported substantial differences between predicted and measured power output, and performance rates of OWCs presently coming into operation. The effect of moisture in the air chamber of the OWC causes variations on the atmospheric conditions near the turbine, modifying its performance and efficiency. Discrepancies in available power to the turbine are believed to be due to the humid air conditions, which had not been modelled previously. This thesis presents a study of the influence of humid air on the performance of an idealised Wells turbine in the chamber of an OWC using a real gas model. A new formulation is presented, including a modified adiabatic index, and subsequent modified thermodynamic state variables such as enthalpy, entropy and specific heat. The formulation is validated against experimental data, and found to exhibit better agreement than the ideal approach. The analysis indicates that the real gas behaviour can be explained by a non{dimensional number which depends on the local pressure and temperature in the OWC chamber. A first approach to the OWC formulation through the calculation of real air flow in the OWC is given, which predicts a 6% decrease in efficiency with respect to the ideal case when it is tested with a hypothetical pulse of pressure. This is important because accurate prediction of efficiency is essential for the optimal design and management of OWC converters. A numerical model has also been developed using computational fluid dynamics (CFD) to simulate the OWC characteristics in open sea. The performance of an OWC turbine is studied through the implementation of an actuator disk model in Fluent®. A set of different regular wave tests is developed in a 2D numerical wave flume. The model is tested using information obtained from experimental tests on a Wells{type turbine located in a wind tunnel. Linear response is achieved in terms of pressure drop and air flow in all cases, proving effectively the applicability of the actuator disk model to OWC devices. The numerical model is applied first to an OWC chamber containing dry air, and then to an OWC chamber containing humid air. Results from both cases are compared, and it is found that the results are sensitive to the degree of humidity of the air. Power decreases when humidity increases. Finally, results from the analytical real gas and numerical ideal gas models are compared. Very satisfactory agreement is obtained between the analytical and the numerical models when humidity is inserted in the gaseous phase. Both analytical and numerical models with humid air show considerable differences with the numerical model when dry air is considered. However, at the resonance frequency, results are independent of the gas model used. At every other frequency analysed, the real gas model predicts reduced values of power that can fall to 50% of the ideal power value when coupled to the radiation-diffraction model for regular waves. It is recommended that real gas should be considered in future analyses of Wells turbines in order to calculate accurately the efficiency and expected power of OWC devices.

This research seeks to find a design solution for reducing the energy usage in high-rise office buildings in Singapore. There are numerous methods and techniques that could be employed to achieve the purpose of designing energy efficient buildings. The Thesis explores the viability of double-skin fa??ades (DSF) to provide natural ventilation as an energy efficient solution for office buildings in hot and humid environment by using computational fluid dynamic (CFD) simulations and case study methodologies. CFD simulations were used to examine various types of DSF used in office buildings and the behaviour of airflow and thermal transfer through the DSF; the internal thermal comfort levels of each office spaces were analyzed and compared; and an optimization methodology was developed to explore the best DSF configuration to be used in high-rise office buildings in the tropics. The correlation between the fa??ade configurations, the thermal comfort parameters, and the internal office space energy consumption through the DSF is studied and presented. The research outcome of the Thesis has found that significant energy saving is possible if natural ventilation strategies could be exploited with the use of DSF. A prototype DSF configuration which will be best suited for the tropical environment in terms of its energy efficiency through cross ventilation strategy is proposed in this Thesis. A series of comprehensive and user-friendly nomograms for design optimization in selecting the most appropriate double-skin fa??ade configurations with considerations of various orientations for the use in high-rise office buildings in the tropics were also presented.

An energy analysis was performed on the Texas A & M University at Qatar building in Doha, Qatar. The building and its HVAC systems were modeled using EnergyPlus. Building chilled water and electrical data were collected to validate the computer simulation. The simulated monthly electricity consumption was within plus/minus 5 percent of the metered building data. Ninety-five percent of simulated hourly electricity data in a day were within plus/minus 10 percent of metered data. Monthly chilled water demand was within plus/minus 18 percent of measurements, and simulated monthly demand was correlated to metered monthly values with an R-squared correlation coefficient of 0.95. Once the simulation was verified with the metered data, an optimization of the building's HVAC systems was performed. Better utilizing the building's variable speed fans at part loads showed potential annual electricity savings of 16 percent over the base case, with another 22 percent savings in chilled water energy. After converting chilled water savings to equivalent chiller electricity savings, the potential utility cost savings over the base case were found to be $90,000/yr at local utility rates. Reducing outdoor air intake to ASHRAE indoor air quality minimums yielded an additional 17 percent in potential chilled water savings and brought total monetary savings over the base case to $110,000/yr. Using a dedicated outside air system to precisely control individual zone ventilation showed potential for an additional 12 percent chilled water savings and $14,000 in yearly utility savings, while also eliminating cases of under-ventilation. A hypothetical retrofit of fan powered terminal units (FPTU's) resulted in energy savings only at very low minimum flow rates, below ventilation standards. Savings were never more than 20 percent over the no-fan case. Series FPTU's showed no savings at any flow setting and negligible difference was found between ECM and SCR motor control. Finally, the dependence on climate of each improvement was studied. Simulations were run in the relatively milder climates of Houston and Phoenix and compared to those found for Doha. It was found that variable speed fan operation is a more cost effective option for milder climates, while outside air control is more cost effective in extreme hot and humid climates such as Doha. Future study is needed to make the FPTU model valid for different climates and flow ranges.

As building codes and green building programs require tighter home construction, the need for outdoor air ventilation to improve indoor air quality increases. Major improvements in building envelopes and duct systems have led to decreases in heating and cooling loads causing fewer HVAC system run-time hours, and increasing the probability for air stagnation within homes with poor outdoor air ventilation. ASHRAE Standard 62.2 quantifies the amount of whole-house ventilation required based on the number of occupants and the square footage of conditioned space, but leaves the design of the ventilation system up to the mechanical engineer or HVAC contractor. In 2010, ASHRAE began requiring flow testing for confirmation of outdoor air ventilation rates, yet few municipalities and green building programs have adopted the new standard. Builders in mixed-humid climates are forced to balance the need for outdoor air ventilation with the upfront costs for mechanical ventilation systems, and the potential for increased humidity loads and energy costs associated with mechanical ventilation strategies. One common solution employed in the southeastern United States involves a central fan integrated supply (CFIS) ventilation system controlled with an air-cycler for minimum run-time to meet ASHRAE Standard 62.2. While this system has been tested and proven to meet design ventilation rates, those tests were often conducted on homes constructed by well trained builders receiving strong oversight from building scientists and the design ventilation rates were not always ASHRAE compliant. The following report analyzes whether the CFIS ventilation system with air-cycler controller provides ventilation meeting ASHRAE Standard 62.2 when employed by builders with minimal training and support.

Water is the most important resource on Earth. Climate and land cover changes are two important factors that directly influenced water resources. This research provides important information for water resources management and contributes on understanding of the responses of water resources to climate and land cover changes in two different climates. The Neches River watershed located in a humid subtropical climate had a 0.7 °C increase in temperature and a 16.3 % increase in precipitation. Developed and crop land covers increased whereas vegetation cover decreased, as a result of human activities. Hydrologic responses to climate and land cover changes resulted in the increases of surface runoff (15.0 %), soil water content (2.7 %), evapotranspiration (20.1 %), and a decrease of groundwater discharge (9.2 %). Surface runoff had an increasing trend with precipitation whereas soil water content was sensitive to changes in land cover, especially human intervention. The Canadian River watershed, a semi-arid watershed, experienced a 0.9 °C increase in temperature and a 10.9 % decrease in precipitation. Land cover was converted from developed and crop lands into barren land and grass covers, as a result of the decrease in human activity. The change of grass and forest covers into bush/shrub cover is thought to be linked to climate change. Surface runoff, groundwater discharge, soil water content, and evapotranspiration were all decreased by 10.2 %, 10.0 %, 7.7 %, and 9.4%, respectively. Hydrologic parameters generally follow similar patterns to that of precipitation. The trend in water resources followed a similar trend of precipitation for the two watersheds with different climates; a humid watershed and a semi-arid watershed. The humid climate watershed, the Neches River watershed, experienced increasing trends in temperature and precipitation. Groundwater discharge was sensitive to changes in land cover caused by human activities. The semi-arid watershed, the Canadian River watershed, had an increase in precipitation and a decrease in precipitation. Conversion of developed and crop land covers into barren and grass land covers was thought to be the result of the decrease in human activity. The volume of soil water was relatively offset by a combination of precipitation changes and land-cover changes.

This research seeks to find a design solution for reducing the energy usage in high-rise office buildings in Singapore. There are numerous methods and techniques that could be employed to achieve the purpose of designing energy efficient buildings. The Thesis explores the viability of double-skin fa??ades (DSF) to provide natural ventilation as an energy efficient solution for office buildings in hot and humid environment by using computational fluid dynamic (CFD) simulations and case study methodologies. CFD simulations were used to examine various types of DSF used in office buildings and the behaviour of airflow and thermal transfer through the DSF; the internal thermal comfort levels of each office spaces were analyzed and compared; and an optimization methodology was developed to explore the best DSF configuration to be used in high-rise office buildings in the tropics. The correlation between the fa??ade configurations, the thermal comfort parameters, and the internal office space energy consumption through the DSF is studied and presented. The research outcome of the Thesis has found that significant energy saving is possible if natural ventilation strategies could be exploited with the use of DSF. A prototype DSF configuration which will be best suited for the tropical environment in terms of its energy efficiency through cross ventilation strategy is proposed in this Thesis. A series of comprehensive and user-friendly nomograms for design optimization in selecting the most appropriate double-skin fa??ade configurations with considerations of various orientations for the use in high-rise office buildings in the tropics were also presented.

We all take for granted that if we press the switch, the lights turn on; that to charge our phone we just need to plug-in the charger and that food is always safely stored in our fridge. but what would happen in the event of a blackout? are we really conscious of how much we rely on electricity? could we survive without it, even for a few days?The current electricity network is strongly centralised, with electricity generated in large power plants and distributed through transmission networks to the final consumers. With increasing energy demand and renewable energies entering the scene, centralised systems have proven to be very stiff: lacking the flexibility to adapt to sudden demand fluctuations and being unable to deal with strong peaks, with the consequent risk of blackouts.Small, decentralised energy systems can be placed closed to the consumers, avoiding distribution losses and adding flexibility to the network. In particular, small cogeneration units can simultaneously generate heat and electricity; thus, also fulfilling our heating requirements and increasing energy efficiency. However, when there is no or little heat demand (e.g. during the summer), the heat produced by the cogeneration engines cannot be utilised and they need to be shut down. This is the reason why small-scale cogeneration cycles are rarely seen and have not been widely adopted yet.This PhD focuses on the injection of water in a specific small-scale cogeneration technology, the micro gas turbine (mGT) cycle. Thanks to water injection, the production of heat and electricity is decoupled; therefore, the operation of the units is not anymore dependant on the heating demand and they can be used any time during the year. The objective of this thesis is to analyse the numerical, experimental and economic aspects of the so-known micro Humid Air Turbine cycle. The aim is to bring mGTs closer to the market so as to contribute to a more secure, future energy network, where blackouts are avoided at all times. / Doctorat en Sciences de l'ingénieur et technologie / info:eu-repo/semantics/nonPublished

We begin by explaining the general terms of the Colocasia esculenta’s chemical properties, agricultural practices and food value as well as its geographic and taxonomic distribution. Thetaro’s starch provides an alternative for pharmaceutical use and even a possible industrialization of its grains by two ways: the moist by water flowing of the starch grains and allowing sedimentation, and by sun drying where the grains lose much of its water, near 60% of its raw weight. Next, we make a list of possible technologies for its use and possible competition with other traditional starches. / Empezamos explicando lo referente a las generalidades de sus características químicas agrícolas y alimenticias, así como su distribución geográfica y taxonomía. Se da una alternativa de uso farmacéutico al almidón de pituca (Colocasia esculenta) para una posible industrialización de sus granos de almidón por medio de dos vías, la húmeda en presencia de arrastre de los gránulos con agua por el método de la sedimentación y el otro método por el secado al sol en el cual perdió un gran porcentaje de agua de casi el 60% de contenido de peso bruto. Luego elaboramos una lista de posibles tecnologías en su utilización y posible competencia frente al uso de otros almidones tradicionales