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  • About
  • The Global ETD Search service is a free service for researchers to find electronic theses and dissertations. This service is provided by the Networked Digital Library of Theses and Dissertations.
    Our metadata is collected from universities around the world. If you manage a university/consortium/country archive and want to be added, details can be found on the NDLTD website.
491

Design and Implementation of a UWB Radar Sensor for Non-Destructive Application

Ahajjam, Younes 22 July 2019 (has links)
[ES] Debido a la importancia de los campos de aplicación del sensor de radar de banda ultraancha, y también a los requisitos de cada aplicación específica, existe una demanda creciente de diseño compacto, de bajo coste y alta precisión del sensor de radar de banda ultraancha. Para responder a estas exigencias, esta tesis pretende proponer un sensor de radar UWB avanzado. Este trabajo de investigación se centra en el diseño del sensor de radar de banda ultraancha (UWB) para aplicaciones no destructivas (END). Los detalles de diseño incluyen el diseño de un generador de pulsos ultracorto, de alta potencia con un timbre mínimo. El radar desarrollado fue construido con una configuración biestática. El objetivo de este trabajo es medir el rango de distancia y las propiedades eléctricas de un objetivo, por ejemplo, metales y materiales dieléctricos, como el cloruro de polivinilo (PV C). Para lograr este objetivo, se ha desarrollado un novedoso generador de pulsos de alta potencia ultra-corto (pulsador de radar). El nuevo generador de pulsos consiste en un transistor que funciona en modo de avalancha y un circuito de afilado de pulsos que utiliza un nuevo modelo de diodo de recuperación de paso (SRD). Para convertir el pulso gaussiano en un monociclo, se ha añadido una red de formación de monociclo (MFN). El generador de impulsos desarrollado produce un impulso eléctrico con una amplitud de 12 V, un tiempo de subida de 112 ps y un ancho de impulso (FWHM) de 155 ps. Con el fin de aumentar la amplitud de los pulsos, se han propuesto dos técnicas útiles en este trabajo. El primero consiste en agregar dos generadores en paralelo, en este diseño propuesto se tuvo en cuenta alguna especificación para hacer que este circuito funcione. Sin embargo, la segunda técnica adoptada en este trabajo consiste en dos etapas de generadores, ambas técnicas dan lugar a un buen rendimiento; en lugar de un solo módulo de un generador de impulsos, las técnicas propuestas en este trabajo aumentan la amplitud en torno al doble. Ambas técnicas han sido investigadas en detalle. Para transmitir y recibir los impulsos ultracortos generados, se utilizaron dos tipos diferentes de antenas UWB. En primer lugar, una antena Vivaldi con un ancho de banda de unos 5,5 GHz de 600 MHz a 6 GHz. La segunda es una antena Vivaldi con un ancho de banda de 6 GHz de 400 Mhz a 6,2 GHz. Utilizando el sensor de radar de banda ultraancha desarrollado, se realizaron mediciones de prueba. Esto incluye las propiedades eléctricas, así como la medición de la distancia a las placas de metal, madera y PVC. La incertidumbre del sensor de radar es de 14 mm (datos medidos asustados a + 14 mm para un blanco fijo). El diseño y la implementación real que conduce a lograr un excelente prototipo de rendimiento para una aplicación no destructiva. / [CA] A causa de la rellevància dels camps d'aplicació del sensor de radar d'ultra banda ampla, i també l'exigència de cada aplicació específica, hi ha una demanda creixent de disseny compacte, de baix cost i alta precisió del sensor de radar d'ultra banda ampla. Amb la intenció d'atendre aquestes demandes, aquesta tesi pretén proposar un sensor avançat de radar UWB. Aquest treball de recerca tracta del disseny del sensor de radar d'ultra-banda ampla (UWB) per a aplicacions no destructives (NDT). Els detalls del disseny inclouen el disseny d'un pols de monocicle amb pols de potència d'alta potència i amb un mínim de timbre. El radar desenvolupat va ser construït en configuració bi-estàtica. L'objectiu d'aquest treball és mesurar el rang de distància i les propietats elèctriques d'un objectiu, per exemple, materials metàl·lics i dielèctrics, com el clorur de polivinil (PV C). Per assolir aquest objectiu, s'ha desenvolupat un nou ultrasò, generador de pols d'alta potència (polsador de radar). El nou generador de pols està format per un transistor que funciona en mode d'allaus i un circuit d'afilat de pols mitjançant un nou model de díode de recuperació de pas (SRD). Per a convertir el pols gaussiano en un monocicle, s'ha afegit una xarxa de formació de monocicles (MFN). El generador de polsos desenvolupat produeix un pols elèctric amb una amplitud de 12 V, un temps d'augment de 112 ps i un ample de pols (FWHM) de 155 ps. Amb l'objectiu d'augmentar l'amplitud dels polsos, s'han proposat dues tècniques útils en aquest treball. El primer consisteix a afegir dos generadors de forma paral·lela, en aquest disseny proposat, cal tenir en compte algunes especificacions per a fer la viabilitat d'aquest circuit. No obstant això, la segona tècnica adoptada en aquest treball consisteix en una doble etapa de generadors, ambdues tècniques donen lloc a una bona actuació; en lloc d'un únic mòdul d'un generador de pols, les tècniques proposades en aquest treball augmenten l'amplitud al voltant del doble. Per transmetre i rebre polsos ultra-curts generats, s'han utilitzat dos tipus diferents d'antenes UWB. En primer lloc, una antena de Vivaldi amb un ample de banda d'uns 5,5 GHz de 600 MHz a 6 GHz. Mentre que la segona és una antena Vivaldi amb un ample de banda de 6 GHz de 400 MHz a 6.2 GHz. Mitjançant el sensor de radar ultra-ampla desenvolupat, es va realitzar la mesura de la prova. Incloïen propietats elèctriques i mesures de distància a les plaques metàl·liques, fusta i PVC. S'ha trobat que la incertesa del sensor de radar és de 14 mm (dades mesurades espantades entre + 14 mm per a un objectiu fix). El disseny i la implementació real condueixen a aconseguir un excel·lent prototip de rendiment per a una aplicació no destructiva. / [EN] Due to the relevance of application fields of ultra-wideband radar sensor, and also the requirement of each specific application, there is an increasing demand of compact, low cost and high accuracy design of ultra-wideband radar sensor. With a view to addressing these demands, this thesis aims to propose an advanced UWB radar sensor. This research work deals with the design of the ultra-wideband (UWB) radar sensor for non-destructive (NDT) application. The design details include the design of ultra-short, high power pulse generator monocycle pulse with a minimum of ringing. The developed radar was build in bi-static configuration. The goal of this work is to measure the distance range and electrical properties of a target e.g, metal and dielectric materials, such as Polyvinyl chloride (PV C). To achieve this goal, a novel ultrashort, high power pulse generator (radar pulser) has been developed. The new pulse generator consists of a transistor operating in avalanche mode and a pulse sharpening circuit using a new model of step recovery diode (SRD). In order to converts the Gaussian pulse to a monocycle, a monocycle forming network (MFN) has been added. The developed pulse generator produces an electrical pulse with an amplitude of 12 V, a rise-time of 112 ps and pulse width (FWHM) of 155 ps. For the purpose to increase the amplitude of the pulses, two useful techniques have been proposed in this work. The first one consist of adding two generators in parallel, in this proposed design some specification was be taking into account to making the workability of this circuit. However, the second technic adopted in this work consists of a two-stage of generators, both technics give rise to a good performance; instead of a single module of a pulse generator, the techniques proposed in this work increase the amplitude around the double. In order to transmit and receive the generated ultra-short pulses, two different types of UWB antennas have been used. First, a Vivaldi antenna with a bandwidth of about 5.5 GHz from 600 MHz to 6 GHz. While the second is a Vivaldi antenna with a bandwidth of 6 GHz from 400 Mhz to 6,2 GHz. Using the developed ultra-wideband radar sensor, test measurement was performed. These included electrical properties as well as distance measurement towards metal plates, wood, and PVC. The uncertainty of the radar sensor has been found to be 14 mm (measured data scared within + 14 mm for a fixed target). The design and real implementation leading to achieve excellent performance prototype for a non-destructive application. / Ahajjam, Y. (2019). Design and Implementation of a UWB Radar Sensor for Non-Destructive Application [Tesis doctoral]. Universitat Politècnica de València. https://doi.org/10.4995/Thesis/10251/124057
492

Flood pulse influences on exploited fish populations of the Central Amazon

Olsen, Jesse Eric Burle 10 January 2017 (has links)
Seasonally fluctuating water levels, known as flood pulses, influence the population dynamics and catches of fishes from river-floodplains. Although different measures of flood pulses, here called flood pulse variables, have been correlated to changes in catches of river-floodplain fishes, the flood pulse variables that have the strongest relationships to catches have not been identified. Furthermore, it is unclear if flood pulses influence catches of river-floodplain fishes with different life history strategies in different ways. Catches of 21 taxa from approximately 18,000 fishing trips were modeled as a function of fishing effort, gear type, seasonal flood pulse variables, and interannual flood pulse variables. These models were analyzed to understand which flood pulse variables had the strongest relationships to catches, and evaluate different flood pulse influences among taxa with different life history strategies. High water flood pulse variables generally had positive influences on catches in future years, while low water flood pulse variables generally had negative influences on catches in future years. Flood pulses generally had stronger influences on the catches of fishes with high fecundities and smaller eggs than on catches of fishes with low fecundities and larger eggs. Variation was observed in strengths and directions of flood pulse influences on catches of fishes with similar and different life history strategies. While my results were generally consistent with prevailing knowledge of how flood pulses influence catches of fishes, other biological factors of specific fish populations may further explain population responses to flood pulses. / Master of Science / Seasonally fluctuating water levels, known as flood pulses, influence the population dynamics and catches of fishes from river-floodplains. Although different measures of flood pulses, here called flood pulse variables, have been related to changes in catches of riverfloodplain fishes, the flood pulse variables that have the strongest relationships to catches have not been identified. Furthermore, it is unclear if flood pulses influence catches of riverfloodplain fishes with different life history strategies in different ways. Catches of 21 taxa from approximately 18,000 fishing trips were modeled as a function of fishing effort, gear type, seasonal flood pulse variables, and interannual flood pulse variables. These models were analyzed to understand which flood pulse variables had the strongest relationships to catches, and evaluate different flood pulse influences among taxa with different life history strategies. High water flood pulse variables generally had positive influences on catches in future years, while low water flood pulse variables generally had negative influences on catches in future years. Flood pulses generally had stronger influences on the catches of fishes that produce many smaller eggs than on catches of fishes that produce fewer and larger eggs. Variation was observed in strengths and types of flood pulse influences on catches of fishes with similar and different life history strategies. While my results were generally consistent with prevailing knowledge of how flood pulses influence catches of fishes, other biological factors of specific fish populations may further explain population responses to flood pulses.
493

From few-cycle femtosecond pulse to single attosecond pulse-controlling and tracking electron dynamics with attosecond precision

Wang, He January 1900 (has links)
Doctor of Philosophy / Department of Physics / Zenghu Chang / The few-cycle femtosecond laser pulse has proved itself to be a powerful tool for controlling the electron dynamics inside atoms and molecules. By applying such few-cycle pulses as a driving field, single isolated attosecond pulses can be produced through the high-order harmonic generation process, which provide a novel tool for capturing the real time electron motion. The first part of the thesis is devoted to the state of the art few-cycle near infrared (NIR) laser pulse development, which includes absolute phase control (carrier-envelope phase stabilization), amplitude control (power stabilization), and relative phase control (pulse compression and shaping). Then the double optical gating (DOG) method for generating single attosecond pulses and the attosecond streaking experiment for characterizing such pulses are presented. Various experimental limitations in the attosecond streaking measurement are illustrated through simulation. Finally by using the single attosecond pulses generated by DOG, an attosecond transient absorption experiment is performed to study the autoionization process of argon. When the delay between a few-cycle NIR pulse and a single attosecond XUV pulse is scanned, the Fano resonance shapes of the argon autoionizing states are modified by the NIR pulse, which shows the direct observation and control of electron-electron correlation in the temporal domain.
494

A detailed analysis of the imperfections of pulsewidth modulated waveforms on the output stage of a class D audio amplifier

Koeslag, Francois 03 1900 (has links)
Thesis (PhD (Electrical and Electronic Engineering))--University of Stellenbosch, 2009. / Although the Class D topology offers several advantages, its use in audio amplification has previously been limited by the lack of competitiveness in fidelity compared to its linear counterparts. During the past decade, technological advances in semiconductor technology have awakened new interest since competitive levels of distortion could now be achieved. The output stage of such an amplifier is the primary limiting factor in its performance. In this dissertation, four non-ideal effects existing in this stage are identified and mathematically analysed. The analytical analysis makes use of a well-established mathematical model, based on the double Fourier series method, to model the imperfections introduced into a naturally sampled pulsewidth modulated waveform. The analysis is complemented by simulation using a strategy based on Newton’s numerical method. The theory is verified by a comparison between the analytical-, simulated- and experimental results.
495

Design and Validation of an Arterial Pulse Wave Analysis Device

Salter, Geoffrey Douglas 17 November 2006 (has links)
Student Number :9900127Y - MSc (Eng) dissertation - Faculty of Engineering and the Built Environment / Arterial pulse wave analysis studies the wave shape of the blood pressure pulse. The pulse wave provides more information than the extreme systolic and dia- stolic pressures, measured with a cuff sphygmomanometer. The aim of the research is to investigate the design issues in a pulse wave analysis system, and to compare these to a commercially available system. The system was compared and validated by measuring the pulse wave at the radial artery (wrist) using the non-invasive technique of arterial tonometry. The design conformed to the IEC-601 safety standard to ensure patient safety. The data was compared against the data from the commercial system and analysis was performed in the time and frequency domain. The performance of the design suggests that, in some respects, the design was comparable to the commer- cial system, however, a number of performance characteristics fell short of the commercial system. Suggestions have been made to address these problems in further research.
496

Wearable Forehead Pulse Oximetry: Minimization of Motion and Pressure Artifacts

Dresher, Russell Paul 03 May 2006 (has links)
Although steady progress has been made towards the development of a wearable pulse oximeter to aid in remote physiological status monitoring (RPSM) and triage operations, the ability to extract accurate physiological data from a forehead pulse oximeter during extended periods of activity and in the presence of pressure disturbances acting on the sensor remains a significant challenge. This research was undertaken to assess whether the attachment method used to secure a pulse oximeter sensor affects arterial oxygen saturation (SpO2) and heart rate (HR) accuracy during motion. Additionally, two sensor housings were prototyped to assess whether isolating the sensor from external pressure disturbances could improve SpO2 and HR accuracy. The research revealed that measurement accuracy during walking is significantly affected by the choice of an attachment method. Specifically, the research indicated that an elastic band providing a contact pressure of 60 mmHg can result in decreased measurement error and improved reliability. Furthermore, the research validated that the two isolating housings we have investigated improve SpO2 and HR errors significantly at pressures as high as 1200 mmHg (160 kPa) compared to current commercial housings. This information may be helpful in the design of a more robust pulse oximeter sensor for use in RPSM.
497

AnÃlise NumÃrica do Acoplador Duplo NÃo-Linear Baseado em Fibras de Cristais FotÃnicos (NLDC-PCF) Operando com PAM e PWM para ObtenÃÃo de Portas LÃgicas / Numerical Analysis of Nonlinear Dual Core Coupler Based on Photonic Crystal Fibers (PCF-NLDC) Operating with PAM and PWM for Obtaining Logic Gates

Marcos Benedito Caldas Costa 01 January 2013 (has links)
CoordenaÃÃo de AperfeiÃoamento de Pessoal de NÃvel Superior / Neste trabalho, apresentamos uma anÃlise numÃrica para a obtenÃÃo de portas lÃgicas totalmente Ãptica baseada em um acoplador direcional nÃo-linear simÃtrico (NLDC) em fibras de cristal fotÃnico (PCF). O projeto mais comumente usado para o NLDC-PCF à uma fibra holey, utilizada neste trabalho, em que a seÃÃo transversal à uma matriz periÃdica de buracos de ar que se prolonga por todo o comprimento da fibra, operando com dois pulsos de luz ultracurtos na forma de sÃlitons, de duraÃÃo mÃnima de 100fs (femtosegundos). Investigamos dois formatos de modulaÃÃo por pulsos, a modulaÃÃo por amplitude de pulso (PAM) na modalidade de chaveamento de mudanÃa de amplitude (ASK) e a modulaÃÃo por largura de pulso (PWM) para obter portas lÃgicas no NLDC-PCF duplo simÃtrico. Avaliamos o efeito resultante de um incremento no parÃmetro codificaÃÃo PAM (ε) e PWM (w), considerando a dispersÃo de segunda ordem (β2), a dispersÃo de terceira ordem (β3) e efeitos nÃo-lineares, tais como: SPM (Self Phase Modulation), SS (Self-Steepening) e IRS (lntrapulse Raman Scattering) em uma configuraÃÃo sem perdas. Os nossos resultados indicam que à possÃvel obter operaÃÃes lÃgicas utilizando um controle de fase entre os pulsos de entrada. / We present a numerical analysis for obtaining all-optical logic gates based on a nonlinear directional coupler symmetric (NLDC) based on photonic crystal fibers (PCF). The most commonly used to project the NLDC-PCF is a holey fiber, used here in cross section which is a periodic array of air holes extending through the length of the fiber, using two ultrashort light pulses in form of solitons, the minimum duration of 100fs (femtoseconds). We investigated two forms of modulation pulse, pulse amplitude modulation (PAM) in the form of amplitude shift keying (ASK) modulation and pulse width modulation (PWM) for logic gate NLDC-PCF symmetrical double. We evaluated the effect resulting from an increase in the offset parameter encoding PAM (ε) and PWM (w), considering the second order dispersion (β2), the third order dispersion (β3) and non-linear modulation effects SPM (Self Phase Modulation), SS (Self-Steepening) and IRS (lntrapulse Raman Scattering) in a configuration without loss. Our results indicate that logical operations can be obtained using a phase control between the input pulses.
498

Neue Methoden der Charakterisierung und Kompression intensiver ultrakurzer optischer Impulse

Stibenz, Gero 06 October 2008 (has links)
Die Erzeugung immer kürzerer und energiereicherer Laserimpulse ist eine der wichtigsten Aufgaben der Laserphysik, um physikalische Phänomene in bisher unerreichten elektrischen Feldstärkebereichen zugängig zu machen und Beobachtungen auf kleinster Zeitskala zu ermöglichen. Mit Hilfe der Nachkompression verstärkter, in edelgasgefüllten Hohlfasern selbstphasenmodulierter Ti:Saphir-Laserimpulse werden die momentan kürzesten Impulse des sichtbaren Spektralbereiches erzeugt, die nur noch wenige Schwingungszyklen des elektrischen Feldes umfassen. Ebenso notwendig wie ein solcher Schritt der Impulskompression ist der verlässliche Nachweis seines Ergebnisses. Allerdings wächst auch die physikalische und technische Herausforderung einer präzisen und vollständigen Messung des ultrakurzen Laserimpulses mit zunehmender Komplexität und Breite des Impulsspektrums. Die vorliegende Arbeit stellt sowohl auf dem Gebiet der Kompression von Sub-10-fs Impulsen als auch auf dem der vollständigen Charakterisierung solcher Impulse optimierte aber auch neue Verfahrenstechniken vor. In Experimenten an einem zweistufigen Hohlfaserkompressor wird die Erzeugung der momentan kürzesten, nicht adaptiv komprimierten Impulse mit einer Dauer von lediglich 3,8 fs demonstriert. Eine elegante Alternative zu bisherigen Kompressionsmethoden zeigt der Nachweis effektiver Selbstkompression von mJ-Impulsen auf unter 8 fs in einem selbstführenden Edelgasfilament auf. Zur Kontrolle erfolgreicher Impulskompression und für eine phasenempfindliche Untersuchung des Prozesses der Dispersionskompensation über spektrale Bandbreiten von bis zu einer Oktave mussten etablierte Impulsmesstechniken wie das SPIDER- (Spectral Phase Interferometry for Direct Electric-field Reconstruction) und das FROG- (Frequency-Resolved Optical Gating) Verfahren weiterentwickelt werden. So wird mit der Realisierung und vollständigen Analyse interferometrischer FROG-Messungen ein neues phasenempfindliches Impulsmessverfahren vorgestellt. / One challenge of today’s laser physics is the stable compression of more and more intense laser pulses to the shortest possible pulse duration to enable new high-field laser experiments and to investigate fast atomic or molecular dynamics. At present, the shortest laser pulses of the visible spectral region envelop only a few cycles of the electric field. The state of the art method to generate such short pulses behind a Ti:sapphire amplifier laser system is by means of successive steps of spectral broadening inside a gas-filled hollow fibre and dispersion compensation. However, a reliable pulse characterization is as important as the pulse compression. The more spectral bandwidth the pulse covers the more technically challenging is the measurement of the pulse’s electric field structure. In this work, new concepts of compression and characterization of pulses down to durations below 10 fs are demonstrated as well as further optimization of established techniques. Due to modern, chirped-mirror based dispersion compensation pulses as short as 3.8 fs were generated with a two-stage hollow fibre compressor. At present, these are the shortest pulses of the visible spectral region, compressed without adaptive means for dispersion compensation. For the first time the effect of self-compression of mJ-pulses to below 8 fs in a self-guiding noble gas filament is demonstrated experimentally and determined by numerical simulations. Advanced pulse characterization schemes were needed for a phase-sensitive investigation of dispersion compensation and pulse compression of white light pulses. An optimized design of the SPIDER (Spectral Phase Interferometry for Direct Electric-field Reconstruction) technique is demonstrated that facilitates the measurement of the pulse’s spectral phase in case of broadband structured spectra. With the implementation of an interferometric FROG (Frequency-Resolved Optical Gating) a new phase-sensitive pulse characterization method is introduced.
499

A Novel Process for Fabricating Membrane-electrode Assemblies with Low Platinum Loading for Use in Proton Exchange Membrane Fuel Cells

Karimi, Shahram 31 August 2011 (has links)
A novel method based on pulse current electrodeposition (PCE) employing four different waveforms was developed and utilized for fabricating membrane-electrode assemblies (MEAs) with low platinum loading for use in low-temperature proton exchange membrane fuel cells. It was found that both peak deposition current density and duty cycle control the nucleation rate and the growth of platinum crystallites. Based on the combination of parameters used in this study, the optimum conditions for PCE were found to be a peak deposition current density of 400 mA cm-2, a duty cycle of 4%, and a pulse generated and delivered in the microsecond range utilizing a ramp-down waveform. MEAs prepared by PCE using the ramp-down waveform show performance comparable with commercial MEAs that employ ten times the loading of platinum catalyst. The thickness of the pulse electrodeposited catalyst layer is about 5-7 µm, which is ten times thinner than that of commercial state-of-the-art electrodes. MEAs prepared by PCE outperformed commercial MEAs when subjected to a series of steady-state and transient lifetime tests. In steady-state lifetime tests, the average cell voltage over a 3000-h period at a constant current density of 619 mA cm-2 for the in-house and the state-of-the-art MEAs were 564 mV and 505 mV, respectively. In addition, the influence of substrate and carbon powder type, hydrophobic polymer content in the gas diffusion layer, microporous layer loading, and the through-plane gas permeability of different gas diffusion layers on fuel cell performance were investigated and optimized. Finally, two mathematical models based on the microhardness model developed by Molina et al. [J. Molina, B. A. Hoyos, Electrochim. Acta, 54 (2009) 1784-1790] and Milchev [A. Milchev, “Electrocrystallization: Fundamentals of Nucleation And Growth” 2002, Kluwer Academic Publishers, 189-215] were refined and further developed, one based on pure diffusion control and another based on joint diffusion, ohmic and charge transfer control developed by Milchev [A. Milchev, J. Electroanal. Chem., 312 (1991) 267-275 & A. Milchev, Electrochim. Acta, 37 (12) (1992) 2229-2232]. Experimental results validated the above models and a strong correlation between the microhardness and the particle size of the deposited layer was established.
500

A Novel Process for Fabricating Membrane-electrode Assemblies with Low Platinum Loading for Use in Proton Exchange Membrane Fuel Cells

Karimi, Shahram 31 August 2011 (has links)
A novel method based on pulse current electrodeposition (PCE) employing four different waveforms was developed and utilized for fabricating membrane-electrode assemblies (MEAs) with low platinum loading for use in low-temperature proton exchange membrane fuel cells. It was found that both peak deposition current density and duty cycle control the nucleation rate and the growth of platinum crystallites. Based on the combination of parameters used in this study, the optimum conditions for PCE were found to be a peak deposition current density of 400 mA cm-2, a duty cycle of 4%, and a pulse generated and delivered in the microsecond range utilizing a ramp-down waveform. MEAs prepared by PCE using the ramp-down waveform show performance comparable with commercial MEAs that employ ten times the loading of platinum catalyst. The thickness of the pulse electrodeposited catalyst layer is about 5-7 µm, which is ten times thinner than that of commercial state-of-the-art electrodes. MEAs prepared by PCE outperformed commercial MEAs when subjected to a series of steady-state and transient lifetime tests. In steady-state lifetime tests, the average cell voltage over a 3000-h period at a constant current density of 619 mA cm-2 for the in-house and the state-of-the-art MEAs were 564 mV and 505 mV, respectively. In addition, the influence of substrate and carbon powder type, hydrophobic polymer content in the gas diffusion layer, microporous layer loading, and the through-plane gas permeability of different gas diffusion layers on fuel cell performance were investigated and optimized. Finally, two mathematical models based on the microhardness model developed by Molina et al. [J. Molina, B. A. Hoyos, Electrochim. Acta, 54 (2009) 1784-1790] and Milchev [A. Milchev, “Electrocrystallization: Fundamentals of Nucleation And Growth” 2002, Kluwer Academic Publishers, 189-215] were refined and further developed, one based on pure diffusion control and another based on joint diffusion, ohmic and charge transfer control developed by Milchev [A. Milchev, J. Electroanal. Chem., 312 (1991) 267-275 & A. Milchev, Electrochim. Acta, 37 (12) (1992) 2229-2232]. Experimental results validated the above models and a strong correlation between the microhardness and the particle size of the deposited layer was established.

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