Exposure to aerosol particles can cause health issues such as respiratory and cardiovascular diseases. Nevertheless, aerosol particle exposure with size-resolved information was seldom investigated in real-life European houses in the long term, especially for the ultrafine size range. In this work, indoor and outdoor measurements were conducted from December 2016 to March 2019. A standard of high-quality indoor and outdoor particle measurements in multi-homes was established for the first time. For more than 500 days, measurement data were collected in 40 German homes, including particle mass concentrations (PMC) of PM10, PM2.5, and PM1, particle number concentration (PNC) and size distribution, equivalent black carbon (eBC) mass concentration, CO2 concentration, and the residents’ activity log. With such novel dataset, representative patterns of diurnal and seasonal variation of particle concentration and size distribution as well as eBC mass concentration have been captured. In the warm season, diurnal cycles of indoor PMC and PNC showed weaker variation and less intense peaks (around the time of breakfast, lunch and dinner) than in the cold season, due to ventilation reducing the effect of indoor sources. To better understand the key dynamic processes of indoor particles (i.e. ventilation, building shell penetration, particle losses and emission), two commonly used quantitation methods, single parameter approach (SPA) and Indoor Aerosol Model approach (IAM), were compared and evaluated for the first time. Correction factors were derived to adjust the emission rates calculated from the simplified SPA approach, making emission rates derived from different levels of analysis mutually comparable. Results show that indoor source was the major contributor (56%) to indoor particle number exposure in investigated German residences. For the contribution of outdoors, penetration through the building envelope (26%) was higher than infiltration through open windows (15%). Burning candles and opening of window(s) led to seasonal differences in the contributions of indoor sources to residential exposure (70% and 40% in the cold and warm season, respectively). Indoor sources should be taken into consideration in future epidemiological studies and risk assessment of exposure to particle air pollution. / Aerosolpartikel können gesundheitliche Probleme wie Atemwegs- und Herz-Kreislauf-Erkrankungen verursachen. Jedoch wurde die Aerosolpartikelexposition, insbesondere für ultrafeine Partikel, in realen Europäischen Haushalten bisher nicht langfristig untersucht. Für diese Arbeit wurden Messungen im Innen- und Außenbereich von Dezember 2016 bis März 2019 durchgeführt. Erstmals wurde ein Standard für qualitativ hochwertige Innen- und Außenmessungen von Aerosolpartikeln in Wohnhäusern etabliert. An mehr als 500 Tagen wurden Messdaten verteilt über 40 deutsche Haushalte gesammelt, darunter die Partikelmassekonzentration (PMC) von PM10, PM2,5 und PM1, die Partikelanzahlkonzentration (PNC) und deren Größenverteilung, die Massekonzentration des äquivalenter schwarzer Kohlenstoff (eBC – equivalent Black Carbon) und ein Aktivitätsprotokoll der Bewohner. Mit diesem neuartigen Datensatz wurden repräsentative Muster der tages- und jahreszeitlichen Variation der Partikelkonzentration und Partikelgrößenverteilung sowie der eBC-Konzentration erstellt. Im Sommerhalbjahr zeigen sich schwächere Variationen und weniger intensive Spitzen (während der Frühstücks-, Mittags- und Abendessenszeit) in den Tageszyklen von PMC und PNC als im Winterhalbjahr. Dies ist auf die die Belüftung zurückzuführen, die den Effekt von Innenraumquellen reduziert. Zwei häufig verwendete Quantifizierungsmethoden der Schlüsselprozesse, der Single-Parameter-Ansatz (SPA) und der Indoor-Aerosol-Modellansatz (IAM), wurden zum ersten Mal quantitativ verglichen und bewertet. Es wurden Korrekturfaktoren abgeleitet, um die mit dem vereinfachten SPA-Ansatz berechneten Emissionsraten anzupassen, so dass die aus verschiedenen Analyseebenen abgeleiteten Emissionsraten miteinander vergleichbar sind. Die Ergebnisse zeigen, dass Quellen in Innenräumen den größten Beitrag (56%) zur Partikelanzahlexposition der Bewohner der untersuchten deutschen Haushalte leisten. Der Beitrag des Außenbereichs durch das Eindringen durch die Gebäudehülle (26%) ist höher als der durch offene Fenster (15%). Brennende Kerzen und das Öffnen von Fenster(n) hatten den größten Einfluss auf die saisonalen Unterschiede in der Partikelexposition. Innenraumquellen sollten in zukünftigen epidemiologischen Studien und bei der Risikobewertung Aerosolpartikelexposition berücksichtigt werden.

Business dynamics have generally been driven by the ability to create and provide value to customers. Value has evolved over time having meanings from merely price to something that actually creates a competitive advantage. Nevertheless, with the fast change in market conditions, it has become relevant to understand value, how it is originated, how customers perceive it and strategies to delineate it in order to fulfil customer needs in frontier technology environments. This thesis aims to research on how value is perceived in indoor air quality and heating, ventilating and air conditioning technologies, what customers look for and what the drivers are to originate value. The study is supported in empirical data obtained through four semi-structured interviews from customers with experience in these fields working in companies in Europe. After the research, the findings in terms of value entail several factors. Customers approach value by means of performance, however, at the same time this represents a constraint since it is important to balance performance over price. The value promise is also key to comply with customer expectations and current regulations in place. Moreover, due to the fact that locations are different and the type of buildings too, flexibility is another way to adopt value especially because these technologies are expected to have long lifespans and hence, it is important to consider changes in the future. The results also suggest that sustainable value can be found, improving people’s health, reducing environmental impacts and creating key partnerships corresponding to the triple bottom line of sustainability. Finally, some discussions are given in terms of barriers to create value such as the lack of incentives or low capital to invest, followed by a trend of energy saving systems to optimize and improve current conditions in this market.

Ce travail permet d'approfondir les connaissances sur l'exposition des voyageurs aux polluants de l'air dans les autobus via des mesures représentatives en fonction du matériel roulant (Agora Long, Agora Standard), le taux de renouvellement de l'air, de la qualité de l'air extérieur et des paramètres du trafic routier. Les expériences ont été réalisées en étudiant la répartition des polluants dans l'habitacle, un sujet peu abordé jusqu'à présent dans la littérature. Sont quantifiées certaines sources de pollution comme le relargage des nouveaux matériaux et le transfert des effluents du bus vers sa cabine (auto-pollution). Dans le cadre de cette démarche, une campagne inédite a été créée pour quantifier l'auto-pollution minimum et maximum pour ces deux types de bus. Dans des conditions réelles de circulation, les concentrations en polluants (NO2, PM2.5, concentration en nombre des particules entre 0,02-1µm) ont été plus élevées dans les habitacles des bus par rapport au fond urbain. De plus il a été constaté des concentrations en NO2 plus faibles à l'avant par rapport à l'arrière du bus, position du pot d'échappement et du moteur. Cette surexposition a été expliquée par une auto-pollution plus importante à l'arrière par rapport à l'avant (0,13% contre 0,05% dans des conditions défavorables). Enfin l'influence du relargage des matériaux, du trafic routier, des ouvertures des portes, de la vitesse du vent sur les concentrations des polluants dans les habitacles des bus a été démontrée / This study can increase knowledge about the travelers' exposure to air pollution inside buses through measures based representative of rolling stock (Agora Long, Agora Standard), the air change rate, air outdoor quality and traffic parameters. The experiments were performed by studying the distribution of pollutants in the cabin, a subject little discussed in the literature. Some sources of pollution such as the material emissions and the transfer of bus exhaust in the cabin are quantified (self-pollution). As part of this approach, an unprecedented campaign was conducted to quantify the maximum and minimum self-pollution for both types of bus. In real traffic conditions, the pollutant concentrations (NO2, PM2.5, particle number concentration between 0.02-1µm) are higher in the instrumented buses compared to outdoors. Moreover the lowest concentrations of NO2 have been measured in the front of the cabin compared to the rear, the localization of exhaust pipe and the engine. This overexposure was explained by a self-pollution higher in the rear of the cabin compared to the front (0.13% against 0.05% in adverse conditions). Finally the influence of the material emissions, traffic, door openings, the wind speed on the pollutant concentrations inside buses have been demonstrated

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<p>Clean indoor air is a necessity, in the past opening a window or supplying outdoor air would suffice for removing indoor contaminated air. As humans live in more dense neighborhoods or urban areas, the need for energy efficient clean indoor air is important. As outdoor air pollution increases, a Biowall is a device to improve aesthetics and clean indoor air by pulling air through the root zone of plants in a loosely packed growth media. The Biowall is a sustainable supplement to a single use air filter. For this research a small Biowall was designed, fabricated, tested, and installed in the Children’s wing of a public library. The airflow simulation and watering for the Biowall was explored using Autodesk CFD to simulate the airflow through growth media and identify a hole pattern to distribute airflow evenly through the plant trays. Various watering line designs were also tested until the rectangular design proved to be more balanced at distributing the water evenly to the growth media. Finally, the air cleaning ability of the Biowall was tested using a Clean Air Delivery Rate (CADR) test to quantify the cleaning rate. The Biowall provided 12 cfm of clean air, or about 2 cfm/sq ft of plant tray area.  </p>

Indoor air quality is a critical determinant of physical and mental health. Despite evidence linking poor indoor air quality to adverse health outcomes, this issue is understudied in the context of First Nations children and youth health and wellbeing. The objectives of this study were to (1) characterize indoor air quality, housing conditions, and respiratory health of children living in the Kanesatake First Nation and (2) evaluate the feasibility of using remote community-based participatory methods in the context of First Nations health research. Community-assisted data collection occurred between June 2021 and February 2022 in the Kanesatake First Nation, Quebec. Indoor air data were collected from 31 randomly selected houses. Results showed elevated levels of contaminants, including particulate matter, benzene, toluene, and xylene, compared to the Canadian averages. Houses generally lacked adequate ventilation, and over one-quarter were reported to be in need of major repairs. We developed instruction tools for air sampling and house inspection to facilitate off-site data collection. High rates of participant completion (95%) and low attrition rates (5%) indicated the feasibility of remote community-based participatory research methods. Lessons learnt are summarized and important recommendations are made for adaptation to improve future data collection. This research served as a pilot project for a multi-year, cross-Nation study, as well as the first study to evaluate the indoor air environment in the Kanesatake First Nation.

More than 50 % of EU’s yearly energy demand is spent on heating and cooling systems with which most of its source is generated from non-renewable fossil fuel [1]. Furthermore, half of the EU buildings are heated with a non-efficient boiler of about 60% or less efficiency [1]. The report released by EU from 1990 to 2007 revealed that fuel combustion and fugitive emission contribute to about 79.3% of total greenhouse gas emissions in CO2 equivalents [1]. The EU-EBPD long-term renovation strategy is to improve the energy performance of all residential and non-residential buildings in its member countries through supporting the renovation of the existing buildings into highly energy efficient and decarbonised buildings [2]. Despite all these EU policies and efforts to replace these non-efficient heating systems, the main challenge is price comparison of different solutions and their efficiency in retrofitting of the heating old systems together with the lack of information about the functioning of those old systems [1]. Thus, the development of an easy to install heating system in retrofitting with low exergy heat supply is a significant contribution to a sustainable solution in minimizing energy resources depletion and environmental emission. Furthermore, efficient system control of these easy to install heating systems, hybrids combinations solution for retrofitting building could be a sustainable solution for the preservation of the existing building. The main objective of this work was to design an easy to install hybrid low-temperature floor heating system in retrofitting buildings and compare its results on energy performance, thermal comfort and indoor air quality with other conventional heating mainly used in the Mediterranean climate. This study was performed in two existing radiators heated buildings located in Sant Cugat del vallès in Catalonia, Spain.The results showed that the hybrid low-temperature heating system has the highest energy performance and energy saving of 48 % and 52% compared to that of existing radiator heating and all air heating, respectively. However, hybrid low-temperature floor heating showed a slow heating response, and consequently, it showed lower operative temperature compared to others even though it was within the recommended standards limits. The hybrid low-temperature heating system with demand-controlled ventilation also showed a better indoor air quality, while as existing radiator with its natural ventilation showed the worst indoor air quality. All three compared heating systems showed a better coefficient of performance with low-temperature heat supply and were able to operate with low-temperature heat supply. / Mer än 50% av EU:s årliga energibehov spenderas på värme- och kylsystem där de flesta av deras källor genereras från icke-förnybart fossilt bränsle [1]. Dessutom värms hälften av EU:s byggnader upp med en ineffektiv panna med cirka 60% eller mindre effektivitet [1]. EU:s rapport från 1990 till 2007 avslöjade att bränsleförbränning och flyktiga utsläpp bidrar till cirka 79% av de totala utsläppen av växthusgaser i koldioxidekvivalenter [1]. EU:s och EBPD:s långsiktiga renoveringsstrategi är att förbättra energiprestanda för alla bostäder och andra byggnader i dess medlemsländer genom att stödja renovering av befintliga byggnader till mycket energieffektiva byggnader [2].Trots alla dessa EU-policyer och ansträngningar för att ersätta dessa ineffektiva värmesystem, är den största utmaningen prisjämförelse av olika lösningar och deras effektivitet i renovering av de gamla värmesystemen tillsammans med bristen på information om hur de gamla systemen fungerar [1]. Därför är utvecklingen av ett installationsenkelt värmesystem med låg värmeförsörjning av exergi ett viktigt bidrag till en hållbar lösning för att minimera energiresurser och miljöutsläpp. Dessutom kan effektiv systemkontroll av dessa värmesystem med olika kombinationslösningar för renovering av byggnaden vara en hållbar lösning för att bevara den befintliga byggnaden.Huvudsyftet med detta arbete var att utforma ett lågtemperaturgolvvärmesystem att använda vid renovering av byggnader och jämföra dess resultat på energiprestanda, termisk komfort och inomhusluftkvalitet med annan konventionell uppvärmning som huvudsakligen används i medelhavsklimat. Denna studie utfördes i två befintliga radiatoruppvärmda byggnadet i Sant Cugat del vallès i Katalonien, Spanien. Resultaten visade att hybridsystemet med låg temperatur har den högsta energiprestandan och energibesparingen på 48% och 52% för den befintliga radiatorvärme respektive luftvärme. Emellertid visade lågtemperaturgolvvärme ett långsamt uppvärmningssvar, och följaktligen visade det lägre driftstemperatur jämfört med de andra systemen trots att det låg inom de rekommenderade standardgränserna. Lågtemperaturvärmesystem med efterfrågningsstyrd ventilation visade också en bättre inomhusluftkvalitet, medan befintliga radiatorer med sin naturliga ventilation visade den sämsta inomhusluftkvaliteten. Alla tre jämförda värmesystemen visade bättre prestanda med lågtemperaturvärmeförsörjning och kunde fungera med lågtemperaturvärmeförsörjning.

Indoor air quality (IAQ) has a direct impact on our health, as more than half the air we inhale throughout our lifetimes is indoor air. With an increasing trend in dampness in modern buildings due to urban expansion into wetland environments and increased use of gypsum board in construction, hydrolysis in indoor surface films has been suggested to be an important chemical process in the indoor environment. Several synthetic esters (SEs) found in building materials, electronics, and consumer products may undergo hydrolysis to produce harmful volatile organic compounds (VOCs) to which building occupants may be exposed. In this dissertation, the impact of hydrolysis on indoor air quality is explored by experiments on alkaline hydrolysis kinetics and ventilation, followed by simulations of VOC production from hydrolysis. Alkaline hydrolysis kinetics of four SEs, 2,2,4-trimethyl-1,3-pentanediol monoisobutyrate (TMPD-MIB), butylparaben (BP), bis (2-ethylhexyl) adipate (DEHA), and butyl benzyl phthalate (BBzP), in bulk solutions are investigated in chapter 2. With concentration decay profiles following pseudo first-order kinetics, the second order-rate constants were determined from measured pH values. The determined rate constants of the aforementioned SEs are compared with those of respective ester categories (e.g., parabens, phthalates), and the steric/polar effects of the ester substituents are discussed in detail. The results of this study contributed to the completion of the indoor chemistry box model GAMMA-CIE which was used for simulation studies in chapter 4. Room-level ventilation measurements in educational spaces across different US regions (e.g., Northeastern, Southeastern, Western) are presented in chapter 3. In the wake of COVID-19 pandemic, ventilation data on a room-by-room basis were critical in planning a safe reopening in schools and universities. Three major approaches to ventilation measurements are outlined in this chapter: direct flow measurement, controlled release, and passive/in-situ monitoring. The application of these approaches is presented in case studies across various educational institutions, showcasing their advantages and disadvantages. The frequently observed range of 0.5-5.5 ACH in this study is taken into account in simulation conditions in chapter 4. The predicted indoor generation of VOCs from alkaline hydrolysis of SEs occurring in surface aqueous films is discussed in chapter 4. Simulations were performed using GAMMA-CIE, which considers aqueous hydrolysis kinetics, interphase mass transport, and loss by ventilation. Three different scenarios were studied: (1) installation of PVC flooring on concrete; (2) coating of latex paint on concrete; and (3) uptake of airborne SEs by surface aqueous films. The simulation results suggested that: (1) the rate of hydrolysis of DEHA and DEHP from PVC flooring is not fast enough to generate high concentrations of 2-ethylhexanol observed during episodes of sick building syndrome (SBS); (2) fresh application of latex paint may cause acute exposure to 2,2,4-trimethyl-1,3-pentanediol (TMPD); and (3) hydrolysis of SEs diffused from indoor air is unlikely to produce significant amounts of alcohols associated with SBS.

No description available.

No description available.