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Neste trabalho, investigou-se o espalhamento elástico 16O+12C, considerando o efeito da troca de uma partícula alfa entre o projétil e o alvo que conduz aos mesmos núcleos do canal de entrada (transferência elástica). Foram analisadas distribuições angulares em uma faixa de energias que, no referencial de centro de massa, vai de 8,55 MeV até 56,57 MeV. A barreira coulombiana desse sistema está em torno de 11MeV. Foram realizadas medidas de distribuição angular das reações de transferência elástica e inelástica no sistema 16O+12C, em Elab = 46, 26 MeV. A análise dessas medidas forneceu os fatores espectroscópicos, 12C+_alfa _ 16O, do estado fundamental e dos estados excitados J_ = 2+ e J_ = 1, ambos logo abaixo do limiar de emissão alfa, em 7,16 MeV. A partir do valor da amplitude espectroscópica do estado J_ = 2+, determinou-se um valor confiável para o Coeficiente de Normalização Assintótica, 1,05± 0,13(105 fm1/2), este valor foi usado para calcular a largura reduzida desse estado e realizando um cálculo de matriz R determinou-se o fator S astrofísico em energias em torno do pico de Gamow, S(E2)=37keVb. / The 16O+12C elastic scattering was investigated considering the effect of exchange of an alpha particle between projectile and target leading to the same nuclei of the entrance channel (elastic transfer). Angular distributions were analyzed in an energy range from 8.55 MeV to 56.57 MeV in the center of mass frame. The Coulomb barrier is around 11MeV for this system. Measurements of angular distributions of elastic and inelastic transfer reactions to states of the 16O in the 16O+12C system were performed at Elab = 46, 26MeV. Those measurements provided the spectroscopic factors of 12C+_ 16O for the ground state and for J_ = 2+ and J_ = 1 16O excited states, both just below the _-threshold at 7.16 MeV. The Asymptotic Normalization Coefficient (ANC) for the J_ = 2+ state was obtained (1.05 ±0,13(105 fm1/2)) and used to calculate the reduced width of this state, with this value a R-matrix calculation was performed to determine the astrophysical S-factor in energies around the Gamow peak, S(E2)=37keVb.

In the presented thesis we study quantum reaction dynamics of H2O- using semiclassical method. Using ab initio quantum potential evaluated on a fine grid we derive analytical formula for potential energy surface, which is used for solving classical equations of motion. A reaction path is analyzed using contour plots with a focus on a saddle point area. Reaction dynamics analysis is focused on properties of interaction probability and cross section depending on impact parameter, collision energy and initial vibrational state of interacting molecule. Final results are compared with experimental data.

The current study addresses the stability of shock waves propagating through dissipative media, analogous to both granular media and molecular gases undergoing endothermic reactions. In order to investigate the stability, a simple molecular dynamics model was developed to observe shock waves and their structures with the inclusion of energy dissipation. For this, an Event Driven Molecular Dynamics model was implemented in a 2D environment, where a molecule is represented by a disk. The simulations addressed the formation of a shock wave in a gas by the sudden acceleration of a piston. Inelastic collisions were assumed to occur only if an impact velocity threshold is surpassed, representing the activation energy of the dissipative reactions. Parametric studies were conducted for this molecular model, by varying the strength of the shock wave, the activation threshold and the degree of inelasticity in the collisions. The resulting simulations showed that a shock structure does indeed become unstable with the presence of dissipative collisions. This instability manifests itself in the form of distinctive high density non-uniformities behind the shock wave, which take the form of convective rolls. The spacing and size of this ``finger-like" unstable pattern was shown to be dependent on the degree of inelasticity, the activation energy, and the strength of the driving piston. The mechanism responsible for the instability was addressed by studying the time evolution of the material undergoing the shock wave compression and further relaxation. It is found that the gas develops the instability on the same time scales as the clustering instability in homogeneous gases, first observed by Goldhirsch and Zanetti in granular gases. This confirmed that the clustering instability is the dominant mechanism.

Reinforced concrete frame buildings designed and built prior to the enactment of modern seismic codes of the pre-1970’s era are considered seismically vulnerable, particularly when they are subjected to strong ground motions. It is the objective of this research to develop a new and innovative seismic retrofit technology for seismic upgrading of nonductile or limited ductility reinforced concrete frame buildings involving the implementation of buckling restrained braces. To achieve this objective, combined experimental and analytical research was conducted. The experimental research involved tests of large-scales reinforced concrete frames under slowly applied lateral deformation reversals, and the analytical research involved design and nonlinear analysis of laboratory specimens, as well as design and dynamic inelastic response history analysis of selected prototype buildings in eastern and western Canada. The research project started with a comprehensive review of the building code development in Canada to assess the progression of seismic design requirements over the years, and to select a representative period within which a significant number of engineered buildings were designed and constructed with seismic deficiencies. A similar review of seismic design and detailing provisions of the Canadian Standard Association (CSA) Standard A23.3 on Design of Concrete Structures was also conducted for the same purpose. Six-storey and ten-storey prototype buildings were designed for Ottawa and Vancouver, using the seismic provisions of the 1965 National Building Code of Canada, representative of buildings in eastern and western Canadian. Preliminary static and dynamic linear elastic analyses were performed to assess the effectiveness of upgrading the ten-storey reinforced concrete building designed for Ottawa. The retrofit methods studied consisted of lateral bracing by adding reinforced concrete shear walls, diagonal steel braces, or diagonal steel cable strands. The results indicated that the retrofit techniques are effective in limiting deformations in non-ductile frame elements to the elastic range. The numerical analyses were used to demonstrate the effectiveness of Buckling Restrained Braces (BRBs) as a retrofit method for seismically deficient reinforced concrete frame buildings. The experimental phase of research consisted of two, 2/3rd scale, single bay and single storey reinforced concrete frames, designed and constructed based on a prototype sixstorey moment resisting frame building located in Ottawa and Vancouver, following the requirements of the 1965 edition of the NBCC. One test specimen served as a bare control frame (BCF) that was first tested, repaired and retrofitted (RRF) to evaluate the effectiveness of the proposed retrofit methodology for buildings subjected to earthquakes in the City of Ottawa. The control frame was assessed to be seismically deficient. The second frame served as a companion non-damaged frame (RF) that was retrofitted with a similar retrofit concept but for buildings subjected to earthquakes in the City of Vancouver. A new buckling restrained brace (BRB) was conceived and developed to retrofit existing sub-standard reinforced concrete frames against seismic actions. The new BRB consists of a ductile inner steel core and an outer circular sleeve that encompasses two circular steel sections of different diameters to provide lateral restraint against buckling in compression of inner steel core. Mortar is placed between the two circular sections to provide additional buckling resistance. The inner core is connected to novel end units that allow extension and contraction during tension-compression cycles under seismic loading while providing lateral restraint against buckling within the end zones. The end units constitute an original contribution to the design of Buckling Restrained Braces (BRBs), providing continuous lateral restraint along the core bar. The new technique has been verified experimentally by testing four BRBs on the two test structures under simulated seismic loading. The test results of the BRB retrofitted frames indicate promising seismic performance, with substantial increases in the lateral load and displacement ductility capacities by factors of up to 3.9 and 2.6, respectively. In addition, the test results demonstrate that the BRB technology can provide excellent drift control, increased stiffness, and significant energy dissipation, while the reinforced concrete frames continue fulfilling their function as gravity load carrying frames. The above development was further verified by an exhaustive analytical study using SAP2000. At the onset, analyses were conducted to calibrate and verify the analytical models. Two-dimensional, one-bay, one-storey models, simulating the BCF and RRF test frames, were created. The models were subjected to incrementally increasing lateral displacement reversals in nonlinear static pushover analyses, and the results were compared with those obtained in the test program. Material nonlinearity was modeled using “Links” to incorporate all lumped linear and nonlinear properties that were defined with moment-rotation properties for flexural frame members and with force-displacement properties for the diagonal buckling restrained braces. Comparison with test data demonstrated good agreement of the frame behaviour in the elastic and post-elastic ranges, and the loading and unloading stiffness. The research program was further augmented with nonlinear dynamic time history analyses to verify the feasibility of the new retrofit technique in multi-storey reinforced concrete frame buildings located in Canada and their performances relative to the performance-based design objectives stated in current codes. Prior to conducting the analyses, 450 artificial earthquake records were studied to select the best matches to the Uniform Hazard Spectra (UHS) according to the 2010 edition of the NBCC for Ottawa and Vancouver. Furthermore, additional analyses were conducted on buildings for the City of Ottawa based on amplified Uniform Hazard Spectrum compatible earthquake records. The nonlinear time-history response analyses were conducted using a model that permits inelasticity in both the frame elements and the BRBs.The results indicated that reinforced concrete buildings built before the 1970’s in the City of Ottawa do not require seismic retrofitting; they remain within the elastic range under current code-compatible earthquake records. The structural building performance is within the Immediate Occupancy level, and all structural elements have capacities greater than the force demands. In the City of Vancouver, buildings in their virgin state experienced maximum interstorey drifts of 2.3%, which is within the Collapse Prevention structural performance level. Improved building performance was realized by retrofitting the exterior frames with multiple uses of the BRB developed in this research project. The seismic shear demands were reduced in the columns, while limiting the deformations in the non-ductile frame elements to the elastic range. The lateral interstorey drift was limited to 0.92%, which lies within the Life Safety structural performance level.

A collection of studies are reported that focus on the examination of exchange interactions in complexes containing paramagnetic ions with a large magnetic anisotropy. A number of complementary techniques are used to analyse the complicated systems that arise, including high-field high-frequency electron paramagnetic resonance, inelastic neutron scattering, SQUID magnetometry, and ab initio calculations. The nuclearity of the complexes ranges from dimetallic, to trimetallic, to octametallic. A family of five water- and carboxylate-bridged nickel(II) dimetallics are the focus of a magneto-structural correlation study that succeeds in measuring the magnitude of the exchange interaction despite dominating effects from large zero-field splitting effects. Similar work is reported for four cobalt(II) analogues of these compounds, with the relationship between exchange interactions and geometry also being probed by pressure INS. Charge density studies that combine high resolution X-ray and neutron diffraction studies are reported on cobalt and nickel analogues from the same family of dimetallics, revealing strong evidence for non-direct exchange. A family of four trimetallic triangle complexes containing two nickel(II) ions and one chromium(III) ion bridged by a central fluoride and a total of six carboxylates are reported, and the exchange interactions are elucidated from a global model that accounts for the low-field magnetic, heat capacity, and EPR data. Two new octametallic vanadium(III) wheels—where each pair of adjacent metals are bridged by a fluoride and two carboxylates—are reported along with preliminary results from magnetic measurements and solid state proton NMR spectra, which reveal significant field-dependent effects arising from level crossings at high fields.

京都大学 / 0048 / 新制・課程博士 / 博士(理学) / 甲第22240号 / 理博第4554号 / 新制||理||1654(附属図書館) / 京都大学大学院理学研究科物理学・宇宙物理学専攻 / (主査)准教授 松田 和博, 教授 田中 耕一郎, 教授 佐々 真一 / 学位規則第4条第1項該当 / Doctor of Science / Kyoto University / DFAM