abstract: Gallium-based liquid metals are of interest for a variety of applications including flexible electronics, soft robotics, and biomedical devices. Still, nano- to microscale device fabrication with these materials is challenging because of their strong adhesion to a majority of substrates. This unusual high adhesion is attributed to the formation of a thin oxide shell; however, its role in the adhesion process has not yet been established. In the first part of the thesis, we described a multiscale study aiming at understanding the fundamental mechanisms governing wetting and adhesion of gallium-based liquid metals. In particular, macroscale dynamic contact angle measurements were coupled with Scanning Electron Microscope (SEM) imaging to relate macroscopic drop adhesion to morphology of the liquid metal-surface interface. In addition, room temperature liquid-metal microfluidic devices are also attractive systems for hyperelastic strain sensing. Currently two types of liquid metal-based strain sensors exist for inplane measurements: single-microchannel resistive and two-microchannel capacitive devices. However, with a winding serpentine channel geometry, these sensors typically have a footprint of about a square centimeter, limiting the number of sensors that can be embedded into. In the second part of the thesis, firstly, simulations and an experimental setup consisting of two GaInSn filled tubes submerged within a dielectric liquid bath are used to quantify the effects of the cylindrical electrode geometry including diameter, spacing, and meniscus shape as well as dielectric constant of the insulating liquid and the presence of tubing on the overall system's capacitance. Furthermore, a procedure for fabricating the two-liquid capacitor within a single straight polydiemethylsiloxane channel is developed. Lastly, capacitance and response of this compact device to strain and operational issues arising from complex hydrodynamics near liquid-liquid and liquid-elastomer interfaces are described. / Dissertation/Thesis / Masters Thesis Materials Science and Engineering 2015

abstract: Advancements in thermal interface materials (TIMs) allows for the creation of new and more powerful electronics as they increase the heat transfer from the component to the heat sink. Current industrial options provide decent heat transfer, but the creation of TIMs with higher thermal conductivities is needed. In addition, if these TIMs are elastic in nature, their effectiveness can greatly increase as they can deal with changing interfaces without degradation of their properties. The research performed delves into this idea, creating elastic TIMs using liquid metal (LM), in this case galinstan, along with other matrix particles embedded in Polydimethylsiloxane (PDMS) to create an easy to use, relatively inexpensive, thermally conductive, but electrically insulative, pad with increased thermal conductivity from industrial solutions. The pads were created using varying amounts of LM and matrix materials ranging from copper microspheres to diamond powder mixed into PDMS using a high-speed mixer. The material was then cast into molds and cured to create the pads. Once the pads were created, the difficulty came in quantifying their thermal properties. A stepped bar apparatus (SBA) following ASTM D5470 was created to measure the thermal resistance of the pads but it was determined that thermal conductivity was a more usable metric of the pads’ performance. This meant that the pad’s in-situ thickness was needed during testing, prompting the installation of a linear encoder to measure the thickness. The design and analysis of the necessary modification and proposed future design is further detailed in the following paper. / Dissertation/Thesis / Masters Thesis Mechanical Engineering 2017

Progress in the fields of wearable computing, soft robotics and bio hybrid engineering depend on new classes of soft multifunctional materials that match the mechanical properties of soft biological tissue and possess high toughness, while having metal-like electrical and thermal properties.

Reconfigurable radio frequency (RF) devices are attractive for miniaturization of wireless components and systems by handling functionality of multiple distinct devices. Existing reconfiguration techniques rely on device loadings with semiconductor diodes, ferrite/ferroelectric materials, and microelectromechanical system (MEMS) switches and capacitors. However, it is well-recognized that these techniques cannot fully address important system metrics such as high efficiency, wide frequency tuning range, high power handling capability and cost. Therefore, novel alternative techniques are highly desirable to advance the state of the art in reconfigurable RF devices. The aim of this dissertation is to investigate the novel concept of microfluidically loaded reconfigurability within the context of RF antennas and imaging systems. The proposed devices operate based on continuously movable microfluidic loads consisting of metal (liquid/solid) and dielectric solutions. Microfluidics and microfabrication techniques are utilized with flexible/rigid multilayered substrates to maximize the reconfigurable loading effect on the devices and enable highly reconfigurable antennas and imaging array realizations. Specifically, a wideband frequency tunable monopole antenna is introduced by utilizing continuously movable liquid metal within the microfluidic channel as a length varying conductor. By resorting to ultra-thin channel walls, the liquid metal volume overlapping with the microstrip line feed is utilized as a non-radiating capacitive excitation point to achieve the realized 4:1 (1.29GHz – 5.17GHz) frequency tuning range. Subsequently, an alternative design that replaces liquid metal volume with a microfluidically movable metallized plate is introduced. This novel liquid-metal-free implementation alleviates the liquid metal associated drawbacks of reliability, long-term device operation, and efficiency. The antenna is shown to provide 2:1 (1.6GHz – 3.5GHz) frequency tuning range with > 87 % radiation efficient. Due to the high radiation efficiency, the antenna is also capable of handling 15 W of RF power which is 10 W more than its liquid metal counterpart. This metallized plate approach is also suitable for reconfiguration of miniature antennas, and this is demonstrated with the design/implementation of a microfluidically reconfigurable top loaded monopole antenna. It is also suitable for reconfiguration of other structures such as textile antennas – and this is demonstrated with a 0.8GHz to 1.4GHz frequency reconfigurable textile antenna realization. The last section of the dissertation introduces a novel surface imaging array realization by utilizing the microfluidically reconfigurable metallized plate as an RF read-out circuit component. Specifically, a 24 element imaging array is designed and validated to operate within 6 – 12 GHz band with subwavelength resonators to demonstrate the possibility of constructing low-cost high-resolution microwave surface imaging arrays by utilizing the microfluidics based reconfiguration techniques. The presented work emphasizes system level implementation of the proposed devices by integrating them with micropump units, controller boards, and investigating their reliability performances under higher power RF excitations.

This thesis investigates how well the Alexandria (WBK) force-field can predict themelting point for multi-cation chloride salts with molecular dynamic (MD) simulationsin Gromacs 4.6.7. Researched is the eutectic ternary salt LiCl-NaCl-KCl(53.5-8.6-37.9 mol%) and its binary eutectic constituents(NaCl-LiCl: 22.5-77.5, KCl-NaCl: 50-50, LiCl-KCl: 58.5-41.5 mol%). The choosen salt mixtures are all promising candidates for use as electrolyte in liquidmetal batteries, a potential future power grid storage system. Simulation of the ternary salt's bulk at 298 K over 100 simulations with its ionsdifferently arranged within the crystal lattice for each simulation all resulted in stablecrystalline structures. This indicates that the WBK force-field properly andconsistently can produce stable crystalline structures not just for pure salts, but alsowithin multi-component ones. The melting point for the ternary and first binary combination was determined to550 K (12.9 % lower than experimental) and 950 K (12.6 % higher than experimental). No melting point could be determined for the last two binary combinations, as theymelted in their entire simulated temperature intervals. The ternary salt showcased acrystalline/amorphous mixture at solid phase temperatures when simulating with thesolid/liquid coexistence method. These simulation anomalies show that modeling ofmulti-cation chloride salts may not be as straight forward as it is with pure salts,despite using a force-field parameterized specifically for alkali halides.

abstract: Deformable heat exchangers could provide a multitude of previously untapped advantages ranging from adaptable performance via macroscale, dynamic shape change (akin to dilation/constriction seen in blood vessels) to enhanced heat transfer at thermal interfaces through microscale, surface deformations. So far, making deformable, ‘soft heat exchangers’ (SHXs) has been limited by the low thermal conductivity of materials with suitable mechanical properties. The recent introduction of liquid-metal embedded elastomers by Bartlett et al1 has addressed this need. Specifically, by remaining soft and stretchable despite the addition of filler, these thermally conductive composites provide an ideal material for the new class of “soft thermal systems”, which is introduced in this work. Understanding such thermal systems will be a key element in enabling technology that require high levels of stretchability, such as thermoregulatory garments, soft electronics, wearable electronics, and high-powered robotics. Shape change inherent to SHX operation has the potential to violate many conventional assumptions used in HX design and thus requires the development of new theoretical approaches to predict performance. To create a basis for understanding these devices, this work highlights two sequential studies. First, the effects of transitioning to a surface deformable, SHX under steady state static conditions in the setting of a liquid cooling device for thermoregulation, electronics and robotics applications was explored. In this study, a thermomechanical model was built and validated to predict the thermal performance and a system wide analysis to optimize such devices was carried out. Second, from a more fundamental perspective, the effects of SHXs undergoing transient shape deformation during operation was explored. A phase shift phenomenon in cooling performance dependent on stretch rate, stretch extent and thermal diffusivity was discovered and explained. With the use of a time scale analysis, the extent of quasi-static assumption viability in modeling such systems was quantified and multiple shape modulation regime limits were defined. Finally, nuance considerations and future work of using liquid metal-silicone composites in SHXs were discussed. / Dissertation/Thesis / Doctoral Dissertation Engineering 2020

京都大学 / 0048 / 新制・課程博士 / 博士(理学) / 甲第22240号 / 理博第4554号 / 新制||理||1654(附属図書館) / 京都大学大学院理学研究科物理学・宇宙物理学専攻 / (主査)准教授 松田 和博, 教授 田中 耕一郎, 教授 佐々 真一 / 学位規則第4条第1項該当 / Doctor of Science / Kyoto University / DFAM

Thesis: Ph. D., Massachusetts Institute of Technology, Department of Nuclear Engineering, 1978 / Includes bibliographical references. / Ph. D. / Ph. D. Massachusetts Institute of Technology, Department of Nuclear Engineering

Aujourd’hui l’électronique fait partie intégrante de nos vies. En effet, de plus en plus d’objets intègrent de l’électronique permettant de les connecter, on appelle cela l’internet des objets (IoT). Tous ces dispositifs disposent d’une connectivité sans fil, rendant ainsi indispensable l’intégration d’une ou plusieurs antennes. De plus, l’électronique devant s’adapter à des objets de plus en plus petits et flexibles embarquant de plus en plus de capteurs tout en consommant de moins en moins d’énergie, il est intéressant de se pencher sur l’étude de nouveaux matériaux pour la réalisation d’antennes devant s’adapter à ces nouvelles contraintes. Dans ce cadre, nous nous sommes attachés dans ce travail de recherche, à la conception de structures antennaires à base de métaux liquides à température ambiante dans le but de réaliser des antennes conformables de formes complexes associant l’impression 3D, des antennes reconfigurables et des structures rayonnantes ayant la capacité de capteur. Dans ce manuscrit des prototypes d’antenne comportant ces caractéristiques ont été simulés, réalisés et mesurés. / Today, electronic is an integral part of our lives. Indeed, more and more objects integrate electronics to connect each other, this is the Internet of Things (IoT). All of these wireless devices need one or more antennas. Furthermore, It’s useful to develop new materials to realize new antennas that fit with new constraints: smaller and flexible objects, more and more sensors and less and less consuming.In this context, we have focused this research on antenna structures based on metals which are liquid at room temperature to realize conformable antennas of complex shapes combining 3D printing, reconfigurable antennas and radiant structures with the ability to sensor. In this manuscript, antenna prototypes with these characteristics have been simulated, realized and measured.

Introduction Low melting point metals are often encapsulated in a hermetic container, irradiated and the container transferred to hot-cell for material removal and processing. An important process of this kind is the production of 82Sr from rubidium (melting point: 39.5 °C.) This new concept departures completely form the encapsulated targets approach and allows an almost continues production by the irradiation of the bulk metal. As well, eliminated is the target transfer. By placing the target material dissolution chamber right in the target station, only the dissolution product is pumped to the hotcell for further processing. Material and Methods Some of the disadvantages of the encapsulated target are: 1. Complicated transfer system that is ex-pensive to install, slow and prone to failures. 2. Complex and expensive encapsulation procedure. 3. Loss of production time during the lengthy target changing. 4. Capsule geometry is constrained by the encapsulating process and transfer demands compromising heat transfer and beam power. To avoid the difficulties of liquid metal handling, metal salts are often used instead (rubidium chloride is one example). This creates other problems and limits the beam currents and production yields. In the system described, the liquid metal is transferred (by gravity) from a bulk container to an irradiation chamber. The chamber, made out of nickel-plated silver, holds the correct quantity of rubidium for one irradiation run. Because of the geometry of the chamber and the efficient cooling, up to 40KW of beam power can be delivered to the target. The chamber is equipped with thermocouples and a liquid-metal level detector and is entirely of welded/brazed construction. The alloy foil that forms the beam window is electron-beam welded to the chamber front ring. At the end of irradiation the irradiated liquid metal is gravity fed into a reaction chamber situ-ated below the irradiation chamber, and a new load of fresh rubidium released into the irradia-tion chamber. The liquid-metal transfer and the irradiation components are shown on FIG. 1, and the sectional view on FIG. 2. Appropriate chemicals (n-butanol in the case of rubidium) are delivered to the reaction chamber and the irradiated metal dissolved. The liquid dissolution product is transferred back to the hotcell. Since all steps of the reaction involve liquids, only small diameter tubes connect the target station with the hotcell. The transfer is fast and simple. The bulk liquid-metal storage container can be constructed to hold enough material for 10 or more runs. When empty, it is replaced with a pre-loaded one. The container is connected to the target system with one coupling and the exchange takes a short time. A robotic bottle exchange can be implemented if desired. The station is equipped with its own vacuum system, beam diagnostic (consisting of a four-sector mask) and a collimation. The target chamber and each of the beam intercepting components are electrically insulated to allow beam current monitoring. Constructed entirely out of metal and ceramic the target core assembly does not suffer from radiation damage. The use of aluminum, silver and alumina reduce component activation. Results and Conclusion A large part of the station design is based on the well proven construction of high current solid target system and is using the same, or similar components. Test was performed to optimize the liquid-metal transfer and the chamber filling with the correct volume, while leaving some room for expansion. A process for niobium coating of sliver is investi-gated. Niobium is known to provide good corro-sion resistance against liquid metals. Thermal modelling of the target and flow analysis of the cooling geometry is under way.