Mafic magma is the most common magma erupted at the surface of the earth. It is generated from partial melting of the mantle, which has been subdivided into end-members based on unique geochemical signatures. One reason these end members, or heterogeneities, exist is subduction of lithospheric plates back into the mantle. The amount of elements, such as Cl and K, removed during subduction and recycled into the deep mantle, is poorly constrained. Additionally, the amount of volatiles, such as Cl, that are recycled into the deep mantle will strongly affect the behavior of the system. I have looked at Cl and K in HIMU source melts to see how it varies. Cl/Nb and K/Nb suggest that elevated Cl/K ratios are the result of depletion of K rather than increased Cl recycled into the deep mantle. After the mantle has partially melted and mafic melt has migrated to the surface, it usually erupts effusively or with low explosivity because of its low viscosity, but it is possible for larger eruptions to occur. These larger, Plinian eruptions, are not well understood in mafic systems. It is generally thought that basalt has a viscosity that is too low to allow for such an eruption to occur. Plinian eruptions require fragmentation to occur, which means the melt must undergo brittle failure. This may occur if the melt ascends rapidly enough to allow pressure to build in bubbles without the bubbles expanding. To test this, I have done decompression experiments to try to bracket the ascent rate for two Plinian eruptions. One eruption has a fast ascent, faster than those seen in more silicic melts, whereas the other eruption is unable to be reproduced in the lab, however it began with a increased viscosity in the partly crystallized magma. After fragmentation and eruption, it is generally thought that tephra do not continue to crystallize. We have found that crystallinity increases from rim to core in two basaltic pumice. Textural data along with a cooling model has allowed us to estimate growth rates in a natural system, which are similar to experimental data. / text

Over the last fifty years, our knowledge of the Solar System has increased exponentially. Many planetary surfaces were seen for the first time through spacecraft observations. Yet the interiors of most planetary bodies remain poorly studied. This dissertation focuses on two main topics: the formation of central pit craters and what this reveals about the subsurface volatile content of the target material, and the mantle dynamics of Io and how they relate to the extensive volcanism on its surface. Central pit craters are seen on icy satellites, Mars, the Moon, and Mercury. They have terraced rims, flat floors, and a pit at or near their center. Several formation mechanisms have been suggested. This dissertation assesses the feasibility of central pit crater formation via drainage of impact melt through impact-generated fractures. For impacts on Ganymede, the expected volume of melt and volume of fracture space generated during the impact and the volume of melt able to drain before fractures freeze shut all exceed the observed central pit volumes on Ganymede. This suggests that drainage of impact melt could contribute to central pit crater formation on Ganymede. Molten rock draining through solid rock fractures will freeze shut more rapidly, so this work suggests that impact melt drainage is unlikely to be a significant factor in the formation of central pit craters on rocky bodies unless a significant amount of volatiles are present in the target. Io is the most volcanically active body in the Solar System. While volcanoes are most often associated with plate tectonics on Earth, Io shows no signs of plate tectonics. Previous work has suggested that Io could lose a significant fraction of its internal heat through volcanic eruptions. In this dissertation, I investigate the relationship between mantle convection and magma generation, migration by porous flow, and eruptions on Io. I couple convective scaling laws to a model solving the two-phase flow equations applied to a rising column of mantle. I show that Io has a partially molten upper mantle and loses the majority of its internal heat through volcanic eruption. Next, I present two-dimensional numerical simulations that self-consistently solve the two-phase flow equations including mantle convection and magma generation, migration by porous flow, and eruption. These simulations produce a high heat flux due to volcanic eruption, a thick lithosphere, a partially molten upper mantle, and a high eruption rate—all consistent with observations of Io. This model also reveals the eruption rate oscillates around the statistical steady state average eruption rate suggesting that the eruption rate and total heat flux measurements from the past 35 years may not be representative of Io's long term behavior.

No description available.

No description available.

No description available.

Although much progress has been made in determining the three dimensional distribution of seismic wave velocities in the Earth, substantially less is known about the three dimensional distribution of intrinsic attenuation. In this study variations in attenuation and shear velocity of the Earth's mantle are constrained using measurements of differential travel time and attenuation. The data are broadband displacement SH seismograms filtered to have energy in the period range 8 to 20 s. Broadband data are used as they should allow a more accurate estimation of body wave attenuation to be made. The seismograms are obtained from over 600 globally distributed earthquakes of magnitude, Mw, 5.5 or greater. Two new methods for determining differential travel times and differential t* values from multiple S phases are presented. The first of these, referred to as the "waveform fitting method" is used to analyse approximately 4300 SS and S waveforms and around 1000 SSS and SS waveforms resulting in differential SS-S and SSS-SS travel times, and corresponding values of differential attenuation represented by t*. The second method, referred to as the "spectral ratio method" is used to analyse approximately 3200 SS and S and around 900 SSS and SS waveforms. The differential travel times and t* values are inverted to obtain models of the lateral variation of shear velocity and lateral variation of q(mu) where q(mu) =1/Q(mu). The models explain the data well but have limited depth resolution. The velocity models show good correlation with previous studies, in particular, low velocities are observed underlying spreading ridges and convergent margins and high velocities are observed under continental regions. The q(mu) model shows shield regions to be less attenuating than PREM, with ridges appearing as highly attenuating features. Models of shear velocity and attenuation are also obtained by combining the body wave dataset of this study with the surface wave datasets of Van Heijst (1997) and Selby (1998).

京都大学 / 新制・課程博士 / 博士(理学) / 甲第23713号 / 理博第4803号 / 新制||理||1687(附属図書館) / 京都大学大学院理学研究科地球惑星科学専攻 / (主査)准教授 河上 哲生, 教授 田上 高広, 教授 下林 典正 / 学位規則第4条第1項該当 / Doctor of Science / Kyoto University / DFAM

Biomineralization is a process encompassing all mineral containing tissues produced within an organism. The most dynamic example of this process is the formation of the mollusk shell, comprising a variety of crystal phases and microstructures. The organic component incorporated within the shell is said to dictate this remarkable architecture. Subsequently, for the past decade considerable research have been undertaken to identify and characterize the protein components involved in biomineralization. Despite these efforts the general understanding of the process remains ambiguous. This study employs a novel molecular approach to further the elucidation of the shell biomineralization. A microarray platform has been custom generated (PmaxArray 1.0) from the pearl oyster Pinctada maxima. PmaxArray 1.0 consists of 4992 expressed sequence tags (ESTs) originating from the mantle, an organ involved in shell formation. This microarray has been used as the primary tool for three separate investigations in an effort to associate transcriptional gene expression from P. maxima to the process of shell biomineralization. The first investigation analyzes the spatial expression of ESTs throughout the mantle organ. The mantle was dissected into five discrete regions and each analyzed for gene expression with PmaxArray 1.0. Over 2000 ESTs were differentially expressed among the tissue sections, identifying five major expression regions. Three of these regions have been proposed to have shell formation functions belonging to nacre, prismatic calcite and periostracum. The spatial gene expression map was confirmed by in situ hybridization, localizing a subset of ESTs from each expression region to the same mantle area. Comparative sequence analysis of ESTs expressed in the proposed shell formation regions with the BLAST tool, revealed a number of the transcripts were novel while others showed significant sequence similarities to previously characterized shell formation genes. The second investigation correlates temporal EST expression during P. maxima larval ontogeny with transitions in shell mineralization during the same period. A timeline documenting the morphologicat microstructural and mineralogical shell characteristics of P. maxima throughout larval ontogeny has been established. Three different shell types were noted based on the physical characters and termed, prodissoconch I, prodissoconch 11 and dissoconch. PmaxArray 1.0 analyzed ESTs expression of animals throughout the larval development of P. maxima, noting up-regulation of 359 ESTs in association with the shell transitions from prodissoconch 1 to prodissoconch 11 to dissoconch. Comparative sequence analysis of these ESTs indicates a number of the transcripts are novel as well as showing significant sequence similarities between ESTs and known shell matrix associated genes and proteins. These ESTs are discussed in relation to the shell characters associated with their temporal expression. The third investigation uses PmaxArray 1.0 to analyze gene expression in the mantle tissue of P. maxima specimens exposed to sub-lethal concentrations of a shell-deforming toxin, tributyltin (TBT). The shell specific effects of TBT are used in this investigation to interpret differential expression of ESTs with respect to shell formation functions. A lethal and sublethal TBT concentration range was established for P. maxima, noting a concentration of 50 ng L- 1 TBT as sub-lethal over a 21 day period. Mantle tissue from P. maxima animals treated with 50 ng L- 1 TBT was assessed for differential EST expression with untreated control animals. A total of 102 ESTs were identified as differentially expressed in association with TBT exposure, comparative sequence identities included an up-regulation of immunity and detoxification related genes and down-regulation of several shell matrix genes. A number of transcripts encoding novel peptides were additionally identified. The potential actions of these genes are discussed with reference to TBT toxicity and shell biomineralization. This thesis has used a microarray platform to analyze gene expression in spatial, temporal and toxicity investigations, revealing the involvement of numerous gene transcripts in specific shell formation functions. Investigation of thousands of transcripts simultaneously has provided a holistic interpretation of the organic components regulating shell biomineralization.

Diss. (sammanfattning) Stockholm : Karolinska institutet, 2005. / Härtill 4 uppsatser.

Diss. (sammanfattning) Stockholm : Karolinska institutet, 2007. / Härtill 4 uppsatser.