No / This paper aims to establish the acid concentration of finely dispersed droplets in hydrocarbon oils. Small quantities of aqueous sulphuric acid (H2SO4) were found to be trapped within hydrocarbon shells, making them inaccessible for concentration evaluation by titration. Fourier transform infrared spectroscopy (FTIR) used in the attenuated total reflection mode (ATR; FTIR-ATR) was applied to study the reaction products of squalane, C30H62, and an API Group I base oil with various concentrations of aqueous H2SO4. The absorbance comparison usually used for estimating acid concentrations was found to fail when small quantities of acid are trapped in the reaction product. It was found that the peak shift and changes in absorbance found for various pure aqueous acid concentrations were useful to establish the remaining concentration of the trapped H2SO4. This paper fulfils the identified need to study acid dissociation-dependent peak shifts of H2SO4 to find the acid concentration of finely dispersed droplets in hydrocarbon oils.

Följande studie är gjord på uppdrag av Sjöfartsverket. I studien undersöktes hur en installation av ett Common Rail-system ombord på isbrytaren Ymer påverkat bränsleförbrukningen samt utsläppen av kväveoxider. Rådata som loggats ombord på Ymer har analyserat och bearbetat. Material och information från tillverkare, besättning samt teknisk chef på Sjöfartsverket, Albert Hagander har använts under studien. Tillsammans med uppmätta mätdata och tidigare gjord litteraturstudie stöds resultaten i studien. Det är ingen slump att system av Common Rail-typ redan är tillämpat inom de flesta branscher så som transport, personbilsindustri och jordbruk. Huvudsyftet med Common Rail är att minska bränsleåtgången samt minska utsläppen genom en renare och mer effektiv förbränning av bränslet.  Huvudsakligen undersöktes hur det nyinstallerade systemet påverkat bränsleförbrukningen och hur bränslebesparingen varierar med belastningen av maskinen. Vidare granskades hur utsläppen av kvävedioxider påverkats efter installationen. Problematiken med ökad NOx-produktion till följd av en högre förbränningstemperatur som Common Railsystemet medför diskuteras i rapporten. De resultat vi kommit fram till att en bränslebesparing kan göras ombord på Ymer genom att ersätta det gamla bränslesystemet med ett bränslesystem av Common Rail-typ. Vidare har installationen medfört andra förbättringar så som fartygsmaskinens reaktion på de många lastväxlingar som förekommer under isbrytning. / The following study has been carried out on behalf of Sjöfartsverket. The study examines how the installation of a common rail system on board the icebreaker Ymer affected fuel consumption and emissions of nitrogen oxides. The raw data logged on board Ymer was analyzed and processed. Materials and information from manufacturers, crew and the technical manager at the Swedish Maritime Administration, Albert Hagander have been used during the study. Together with measured data and previously made research study the findings of the study are supported. It is no coincidence that the system of the common rail type is already applied in most industries such as transport, car industry and agriculture. The main purpose of the Common Rail is to reduce fuel consumption and reduce emissions through cleaner and more efficient combustion of the fuel. We primarily examined how the newly installed system affected fuel consumption and the fuel savings will vary with the load of the machine. Furthermore, we examined how emissions of nitrogen oxides were affected after installation. The problem of increased NOx production due to a higher combustion temperature as the common rail system entails are discussed in the report. The result that was concluded was that fuel savings can be made on board Ymer by replacing the old fuel system with a common rail fuel type. Furthermore, the installation has brought other improvements such as ship machine's reaction to the many load changes that occur during icebreaking.