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Mapping and treatment optimization attempt of monocalcium phosphate monohydrate (MCPM) in bioceramic implant productionHunhammar, Martin January 2022 (has links)
The in vitro production of ceramic implants used for cranial defect repair can be challenging and complex. In this thesis, a raw material in such a production has been mapped in order to optimize the production process. The current production leaves variations in the handling properties of the calcium phosphate cement (CPC), such as the viscosity and setting performance. The problems originate from the in-house recrystallization of the raw material monocalcium phosphate monohydrate (MCPM) with a 70% ethanol solution. The treatment of MCPM is strongly dependent on the relative humidity and the current process is not reliable and leaves unwanted fluctuations in the quality of MCPM. Various material and process parameters were investigated to get a deeper knowledge of MCPM in the specific process. The mapping resulted in new information about how the MCPM recrystallizes and how it depends on the evaporation of the ethanol solution during the treatment. Other findings were that the particle size distribution of MCPM is not the only factor controlling the viscosity of the CPC; the density and shape of the MCPM particles may also influence the handling properties. The mapping led to a process optimization suggestion where the amount of ethanol solution is adjusted to the relative humidity during the recrystallization to neutralize the effect of the humidity. The adjustment of ethanol solution volume means the evaporation can be controlled and in theory, constant quality of MCPM can be maintained. Unfortunately, the new method needs additional data to be fully effective but shows great potential.
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SYNTHESIS, CRYSTAL STRUCTURE AND MAGNETISM OF PEROVSKITE-BASED TRANSITION METAL OXIDESRamezanipour, Farshid 10 1900 (has links)
<p>A series of layered perovskite-based compounds were synthesized and studied as follows.</p> <p>La<sub>5</sub>Mo<sub>2.76(4)</sub>V<sub>1.25(4)</sub>O<sub>16</sub> is a new pillared-perovskite synthesized by solid state chemistry method. It has layers of corner-sharing octahedra separated by dimers of edge-sharing octahedra, and is the first Mo-based pillared-perovskite whose magnetic structure was determined by neutron diffraction.</p> <p>Ca<sub>2</sub>FeMnO<sub>5</sub> is an oxygen-deficient-perovskite with a brownmillerite-type ordering of oxygen vacancies, resulting in layers of corner-sharing octahedra separated by chains of corner-sharing tetrahedra. The octahedral layer contains mostly (~87%) Mn, while the tetrahedral layer is mainly (~91%) occupied by Fe. Long-range G-type magnetic ordering is present, where the moment on each site is coupled antiferromagnetically relative to all nearest neighbors.</p> <p>Ca<sub>2</sub>FeCoO<sub>5</sub> has a brownmillerite superstructure with space group <em>Pcmb</em>, a rare space group for brownmillerites that requires doubling of one unit cell axis. Ca<sub>2</sub>FeCoO<sub>5 </sub>is the first brownmillerite to contain intra-layer cation ordering. It has a long-range G-type ordering, and is the first brownmillerite to show spin re-orientation as function of temperature.</p> <p>Sr<sub>2</sub>FeMnO<sub>5+y</sub> was synthesized in both air (y~0.5) and argon (y~0), both of which resulted in vacancy-disordered cubic structures. The argon compound has a local brownmillerite structure, i.e. local ordering of vacancies. It has a superparamagnetic state below ~55K, with domains of short range (50Å) G-type ordering at 4K. For the air synthesized compound, y~0.5, long range G-type ordering is observed in ~4% of the sample.</p> <p>Sr<sub>2</sub>Fe<sub>1.9</sub>M<sub>0.1</sub>O<sub>5+y</sub> (M=Mn, Cr, Co; y= 0, 0.5) were synthesized in both air(y~0.5), and argon(y~0). All argon materials are brownmillerites with G-type magnetic ordering, but T<sub>N</sub>’s are significantly different. The air-synthesized Co-material has long range vacancy ordering and magnetic ordering, while the Mn and Cr-materials (air) lack such orderings and both show spin-glass-like transitions.</p> <p>Sr<sub>2</sub>Fe<sub>1.5</sub>Cr<sub>0.5</sub>O<sub>5</sub> has a vacancy-disordered cubic structure, but contains long range G-type magnetic ordering, unlike the other vacancy-disordered materials studied.</p> / Doctor of Philosophy (PhD)
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Long term effects of ammonia on piston ring materials for maritime combustion enginesFirsching, Matilda January 2024 (has links)
Due to climate changes and an increasing global temperature, the maritime transport sector has taken upon a mission to reduce their share of greenhouse gas emissions by 50% until 2050. Combustion engines used in ships mainly run on carbon-based fuels, but to achieve the reduction of emissions it is crucial to investigate the possibility of alternative fuels. Ammonia is an alternative fuel with a carbon free chemical composition that shows big potential, with several initiatives to put ammonia driven ship engines on the market in the near future. For ships to be able to run on ammonia fuel, the engine materials have to withstand the corrosive effect of ammonia whilst still ensuring that the motor runs properly. In this study, two piston ring materials are investigated with regards to long-term effects of exposure to ammonia solution. The piston ring materials investigated were comprised of a cast iron substrate covered with either a chromium ceramic coating or a with a cermet coating, the latter also coated with an aluminium-bronze based running in layer on top. The materials were submerged in 25% ammonia solution for different time intervals up to 12 weeks, with a solution change every fourth week. After exposure to ammonia, the materials were tribologically tested in a reciprocal sliding test rig. The surfaces, both inside and outside of the wear tracks, were analysed with SEM and EDS, as well as with CSI. The chromium ceramic coating did not seem to get affected by, or interact chemically, with the ammonia solution. Exposing the material to ammonia did not seemingly affect the tribological properties. However, two different behaviours were observed when analysing the cermet coated samples with a running-in layer of aluminium-bronze. These samples reacted with the ammonia solution in two different ways, resulting in the series being split into two. In both cases precipitates were formed, but the colour changes of the solutions differed for the series. The coatings were also worn differently, as in one case a flattening effect was observed throughout all time intervals, whereas in the other case the worn volume and track depth seemed to increase with exposure to ammonia solution.
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UNDERSTANDING ELECTRICAL CONDUCTION IN LITHIUM ION BATTERIES THROUGH MULTI-SCALE MODELINGPan, Jie 01 January 2016 (has links)
Silicon (Si) has been considered as a promising negative electrode material for lithium ion batteries (LIBs) because of its high theoretical capacity, low discharge voltage, and low cost. However, the utilization of Si electrode has been hampered by problems such as slow ionic transport, large stress/strain generation, and unstable solid electrolyte interphase (SEI). These problems severely influence the performance and cycle life of Si electrodes. In general, ionic conduction determines the rate performance of the electrode, while electron leakage through the SEI causes electrolyte decomposition and, thus, causes capacity loss. The goal of this thesis research is to design Si electrodes with high current efficiency and durability through a fundamental understanding of the ionic and electronic conduction in Si and its SEI.
Multi-scale physical and chemical processes occur in the electrode during charging and discharging. This thesis, thus, focuses on multi-scale modeling, including developing new methods, to help understand these coupled physical and chemical processes. For example, we developed a new method based on ab initio molecular dynamics to study the effects of stress/strain on Li ion transport in amorphous lithiated Si electrodes. This method not only quantitatively shows the effect of stress on ionic transport in amorphous materials, but also uncovers the underlying atomistic mechanisms. However, the origin of ionic conduction in the inorganic components in SEI is different from that in the amorphous Si electrode. To tackle this problem, we developed a model by separating the problem into two scales: 1) atomistic scale: defect physics and transport in individual SEI components with consideration of the environment, e.g., LiF in equilibrium with Si electrode; 2) mesoscopic scale: defect distribution near the heterogeneous interface based on a space charge model. In addition, to help design better artificial SEI, we further demonstrated a theoretical design of multicomponent SEIs by utilizing the synergetic effect found in the natural SEI. We show that the electrical conduction can be optimized by varying the grain size and volume fraction of two phases in the artificial multicomponent SEI.
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Effect of charged species on the gradient propertiesAshraf, Kayesh 01 January 2017 (has links)
Surface chemical gradients are materials that exhibit continuous, gradually varying chemical or physical properties along and across the length of a substrate. As a result, each point on the gradient surface can represent an individual sample. They are broadly classified as chemical and physical gradients depending upon the properties that the gradient exhibits. A physical gradient involves a continuous variation of physical properties such as surface roughness and film porosity on the micrometer scale. Chemical gradients involve a gradual variation of chemical properties such as polarity, acidity and basicity, etc. Such gradients have found various applications in cell adhesion, nanoparticle absorption, etc. Because of the multitude of potential applications of acid-base gradient materials in separation science and biological applications, the main work of this dissertation work is focused on the preparation and fundamental, molecular level investigation of acid-base gradients on siloxane surfaces. In this work, we focused on the preparation and characterization of surface charge gradients. Charged gradients are gradients that contain charged functional groups that are spatially distributed along the length of the substrate. They can interact with each other or with other species in solution by electrostatic interactions. They can also play a key role in governing the interaction of macromolecules and bacteria on surfaces, the wetting of surfaces, the layer-by-layer (LBL) assembly of thin films, reactions in catalysis, and the separation of charged species in chromatography. Therefore, understanding localized interactions between surface functional groups and charged species in solution are particularly relevant to the development of surfaces resistant to biofouling, antimicrobial surfaces, catalytic surfaces, multi-layered composite thin films, and imprinted surfaces for chemical sensing and separations. Thus, it is of great of interest to develop methodologies to create and study heterogeneous and homogeneous charged surfaces with well-defined properties. There have been several different methods developed for the preparation of charged gradients. First a chemical gradient is prepared and then the chemical gradient is converted to charged gradient by a chemical approach. Silane-based methods for the preparation of chemical gradients are among those that are widely used because of the straightforwardness of the chemistry involved and also the availability of silanes with various chemical functionalities. A few of these silane based approaches such as the vapor-diffusion method and liquid diffusion method have been used for various applications so far. Most of these methods are only able to prepare surface chemical gradients for a specific application mainly because of their limitations in terms of gradient-length scale and chemistry involved. In this work, we used a procedure already developed in our lab to prepare chemical gradients from different functionalized alkoxysilanes; we call this procedure the ‘controlled-rate infusion method (CRI)’. This method can be adapted to different substrates and can form gradients at various length-scales, such as few hundred microns to tens of centimeters. The CRI method involves the infusion of an organoalkoxysilane solution into a container with a substrate mounted vertically so that time-dependent exposure along the substrate forms a gradient in chemical functionality from bottom to the top. The most important attribute of this method is that the local steepness of the gradient can be systematically controlled by simply changing the rate of infusion. The steepness of the gradient can also be changed at predefined positions along its length by programming the rate of infusion. CRI can also be used to prepare gradients containing multiple functionalities, termed multicomponent chemical gradients. The different chemical functionalities can be oriented in different directions to produce gradients where functionalities can be oriented along the same or opposed directions producing aligned and opposed multicomponent chemical gradients, respectively. In this work, the multicomponent gradients were converted to charge gradients via chemical reaction with 30% H2O2. Using controlled rate infusion and this technique, aligned or opposed multicomponent charge gradients containing NH3+, SO3- and SiO- groups were prepared. By infusing 3-aminopropyltriethoxysilane (APTEOS) and 3-mercaptopropyltriethoxysilane (MPTMOS) in the same or opposed direction, gradients containing charged species in different locations relative to each other along the length of the substrate were made. The gradient properties in each case were different and correlated to the way they were prepared i.e., where the gradients were oriented in an aligned or opposed fashion. Surface wettability and local surface charge, etc were found to be entirely different depending on the type of charge gradients (aligned and opposed). In another example, SiO- and NH3+ opposed gradients were prepared by infusing APTEOS on different base layers prepared from tetramethoxysilane (TMOS), phenyltrimethoxysilane (PTMOS), dimethyldimethoxysilane (DMDMOS) or octyltrimethoxysilane (OTMOS) followed by protonation of the surface amines. The gradient profiles and surface wettability were found to be independent of each other and dependent of the type of the base layer. In summary, this dissertation work focuses mainly on the preparation of multicomponent charge gradients and their molecular level characterization by a multitude of different analytical methods including XPS spectroscopy, tapping mode atomic force microscopy (TM-AFM), zeta potential measurement, and SCA and DCA measurements. CRI has incredible flexibility and adaptability, which was confirmed by extending it to different siloxane base films and creating gradients with different functionalities. Multicomponent charge gradients containing acid and base functionalities can be prepared and optimized for and acid base catalysis reactions such Michael addition as well as aldol, Henry, and Knoevenagel condensations.
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Microwave-Assisted Topochemical Manipulation of Layered Oxide Perovskites: From Inorganic Layered Oxides to Inorganic-Organic Hybrid Perovskites and Functionalized Metal-Oxide NanosheetsAkbarian-Tefaghi, Sara 19 May 2017 (has links)
Developing new materials with desired properties is a vital component of emerging technologies. Functional hybrid compounds make an important class of advanced materials that let us synergistically utilize the key features of the organic and inorganic counterparts in a single composite, providing a very strong tool to develop new materials with ”engineered” properties. The research presented here, summarizes efforts in the development of facile and efficient methods for the fabrication of three- and two-dimensional inorganic-organic hybrids based on layered oxide perovskites. Microwave radiation was exploited to rapidly fabricate and modify new and known materials. Despite the extensive utilization of microwaves in organic syntheses as well as the fabrication of the inorganic solids, the work herein was among the first reported that used microwaves in topochemical modification of the layered oxide perovskites. Our group specifically was the first to perform rapid microwave-assisted reactions in all of the modification steps including proton exchange, grafting, intercalation, and exfoliation, which decreased the duration of multi-step modification procedures from weeks to only a few hours. Microwave-assisted grafting and intercalation reactions with n-alkyl alcohols and n-alkylamines, respectively, were successfully applied on double-layered Dion-Jacobson and Ruddlesden-Popper phases (HLaNb2O7, HPrNb2O7, and H2CaTa2O7), and with somewhat more limited reactivity, applied to triple-layered perovskites (HCa2Nb3O10 and H2La2Ti3O10). Performing neutron diffraction on n-propoxy-LaNb2O7, structure refinement of a layered hybrid oxide perovskite was then tried for the first time. Furthermore, two-dimensional hybrid oxides were efficiently prepared from HLnNb2O7 (Ln = La, Pr), HCa2Nb3O10, HCa2Nb2FeO9, and HLaCaNb2MnO10, employing facile microwave-assisted exfoliation and post-exfoliation surface-modification reactions for the first time. A variety of surface groups, saturated or unsaturated linear and cyclic organics, were successfully anchored onto these oxide nanosheets. Properties of various functionalized metal-oxide nanosheets, as well as the polymerization of some monomer-grafted nanosheets, were then investigated for the two-dimensional hybrid systems.
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Modified Seed Growth of Iron Oxide Nanoparticles in Benzyl Alcohol: Magnetic Nanoparticles for Radio Frequency Hyperthermia Treatment of CancerGilliland, Stanley E, III 01 January 2014 (has links)
Iron oxide nanoparticles have received sustained interest for biomedical applications as synthetic approaches are continually developed for precise control of nanoparticle properties. This thesis presents an investigation of parameters in the benzyl alcohol synthesis of iron oxide nanoparticles. A modified seed growth method was designed for obtaining optimal nanoparticle properties for magnetic fluid hyperthermia. With a one or two addition process, iron oxide nanoparticles were produced with crystallite sizes ranging from 5-20 nm using only benzyl alcohol and iron precursor. The effects of reaction environment, temperature, concentration, and modified seed growth parameters were investigated to obtain precise control over properties affecting radiofrequency heat generation. The reaction A2-24(205)_B2-24(205) produced monodispersed (PDI=0.265) nanoparticles with a crystallite size of 19.5±1.06 nm and the highest radiofrequency heating rate of 4.48 (°C/min)/mg (SAR=1,175.56 W/g, ILP=3.1127 nHm2/kg) for the reactions investigated. The benzyl alcohol modified seed growth method offers great potential for synthesizing iron oxide nanoparticles for radiofrequency hyperthermia.
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Non-Conventional Approaches to Syntheses of Ferromagnetic NanomaterialsClifford, Dustin M 01 January 2016 (has links)
The work of this dissertation is centered on two non-conventional synthetic approaches to ferromagnetic nanomaterials: high-throughput experimentation (HTE) (polyol process) and continuous flow (CF) synthesis (aqueous reduction and the polyol process). HTE was performed to investigate phase control between FexCo1-x and Co3-xFexOy. Exploration of synthesis limitations based on magnetic properties was achieved by reproducing Ms=210 emu/g. Morphological control of FexCo1-x alloy was achieved by formation of linear chains using an Hext. The final study of the FexCo1-x chains used DoE to determine factors to control FexCo1-x, diameter, crystallite size and morphology. [Ag] with [Metal] provide statistically significant control of crystallite size. [OH]/[Metal] predict 100 % FexCo1-x at > 30. To conclude section 1, a morphological study was performed on synthesis of Co3-xFexOy using the polyol process. Co3-xFexOy micropillars were synthesized at various sizes. The close proximity of the particles in the nanostructure produced an optical anisotropy and was magnetically induced which is evidence for the magneto-birefringence effect.
The second non-conventional synthetic approach involves continuous flow (CF) chemistry. Co nanoparticles (Ms=125 emu/g) were newly synthesized by aqueous reduction in a microreactor and had 30 ±10 nm diameter and were produced at >1g/hr, a marker of industrial-scale up viability. The final work was the CF synthesis of FexCo1-x. The FexCo1-x was synthesized with limitation to the composition. The maximum FexCo1-x phase composition at 20 % resulted from the aqueous carrier solvent triggering oxide formation over FexCo1-x.
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Fabrication of Multifunctional Nanostructured Porous MaterialsFarghaly, Ahmed A. 01 January 2016 (has links)
Nanostructured porous materials generally, and nanoporous noble metals specifically, have received considerable attention due to their superior chemical and physical properties over nanoparticles and bulk counterparts. This dissertation work aims to develop well-established strategies for the preparation of multifunctional nanostructured porous materials based on the combination of inorganic-chemistry, organic-chemistry and electrochemistry. The preparation strategies involved one or more of the following processes: sol-gel synthesis, co-electrodeposition, metal ions reduction, electropolymerization and dealloying or chemical etching. The study did not stop at the preparation limits but extended to investigate the reaction mechanism behind the formation of these multifunctional nanoporous structures in order to determine the different factors controlling the nanoporous structures formation. First, gold-silica nanocomposites were prepared and used as a building blocks for the fabrication of high surface area gold coral electrodes. Well-controlled surface area enhancement, film thickness and morphology were achieved. An enhancement in the electrode’s surface area up to 57 times relative to the geometric area was achieved. A critical sol-gel monomer concentration was also noted at which the deposited silica around the gold coral was able to stabilize the gold corals and below which the deposited coral structures are not stable. Second, free-standing and transferable strata-like 3D porous polypyrrole nanostructures were obtained from chemical etching of the electrodeposited polypyrrole-silica nanocomposite films. A new reaction mechanism was developed and a new structural directing factor has been discovered for the first time. Finally, silver-rich platinum alloys were prepared and dealloyed in acidic medium to produce 3D bicontinuous nanoporous platinum nanorods and films with a nanoporous gold-like structure. The 3D-BC-NP-Pt displayed high surface area, typical electrochemical sensing properties in an aqueous medium, and exceptional electrochemical sensing capability in a complex biofouling environment containing fibrinogen. The 3D-BC-NP-Pt displayed high catalytic activity toward the methanol electro-oxidation that is 30 times higher that of planar platinum and high volumetric capacitance of 400 F/cm3. These findings will pave the way toward the development of high performance and reliable electrodes for catalysis, sensing, high power outputs fuel cells, battery-like supercapacitors and miniaturized device applications.
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SYSTEMATIC POSTSYNTHETIC MODIFICATION OF NANOPOROUS ORGANIC FRAMEWORKS AND THEIR PERFORMANCE EVALUATION FOR SELECTIVE CO2 CAPTUREIslamoglu, Timur 01 January 2016 (has links)
Porous organic polymers (POPs) with high physicochemical stability have attracted significant attention from the scientific community as promising platforms for small gas separation adsorbents. Although POPs have amorphous morphology in general, with the help of organic chemistry toolbox, ultrahigh surface area materials can be synthesized. In particular, nitrogen-rich POPs have been studied intensively due to their enhanced framework-CO2 interactions. Postsynthetic modification (PSM) of POPs has been instrumental for incorporating different functional groups into the pores of POPs which would increase the CO2 capture properties. We have shown that functionalizing the surface of POPs with nitro and amine groups increases the CO/N2 and CO2/CH4 selectivity significantly due to selective polarization of CO2 molecule. In addition, controlled postsynthetic nitration of NPOF-1, a nanoporous organic framework constructed by nickel(0)-catalyzed Yamamoto coupling of 1,3,5-tris(4-bromophenyl)benzene, has been performed and is proven to be a promising route to introduce nitro groups and to convert mesopores to micropores without compromising surface area. Reduction of the nitro groups yields aniline-like amine-functionalized NPOF-1-NH2. Adequate basicity of the amine functionalities leads to modest isosteric heats of adsorption for CO2, which allow for high regenerability. The unique combination of high surface area, microporous structure, and amine-functionalized pore walls enables NPOF-1-NH2 to have remarkable CO2 working capacity values for removal from landfill gas and flue gas. Benzimidazole-linked polymers have also been shown to have promising CO2 capture properties. Here, an amine functionalized benzimidazole-linked polymer (BILP-6-NH2) was synthesized via a combination of pre- and postsynthetic modification techniques in two steps. Experimental studies confirm enhanced CO2 uptake in BILP-6-NH2 compared to BILP-6, and DFT calculations were used to understand the interaction modes of CO2 with BILP-6-NH2. Using BILP-6-NH2, higher CO2 uptake and CO2/CH4 selectivity was achieved compared to BILP-6 showing that this material has a very promising working capacity and sorbent selection parameter for landfill gas separation under VSA settings. Additionally, the sorbent evaluation criteria of different classes of organic polymers have been compared in order to reveal structure-property relationships in those materials as solid CO2 adsorbents.
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