With the global deployment of renewable energy generation at record rates, clean energy is steadily becoming competitive with its fossil-fuel counterparts. However, further expansion is limited by the inherent intermittency of renewable energy sources (solar, wind, wave, etc.), which typically do not match with daily and seasonal variations of global (and local) energy demand. Thermochemical energy storage (TCES) has demonstrated strong potential in being a technological pathway to provide on-demand process heat and handle the intrinsic variations in renewable energy generation and energy demand. TCES works on the premise of excess renewable heat driving an endothermic reduction reaction, in which thermal energy is converted to chemical potential energy. The reversed exothermic oxidation reaction is subsequently triggered (on-demand) to recover thermal energy which can be used as process heat. While the benefits of TCES have been demonstrated experimentally at the lab-scale, accurate numerical modeling of TCES reactors is key for future development, optimization, and implementation of large industrial-scale energy storage systems. This dissertation focuses on the development of continuum-scale models to accurately simulate and predict performance of high temperature (up to 1500 °C) moving-bed reactors for TCES. The efficacy of present volume- averaging approaches is briefly reviewed, with the major focus of the work on the development of multi-dimensional multi-physics models of increasing complexity for moving-bed TCES reduction and oxidation reactors.

No description available.

No description available.

No description available.

No description available.

No description available.

This dissertation describes the simulation and optimization of adsorptive and chromatographic separation processes. The first part focus on the simulation and comparison of operational modes in simulated moving bed (SMB) chromatography for separation and purification in bioprocesses. The second part includes the simulation of gas-phase adsorptive processes by pressure swing adsorption and temperature swing adsorption technologies. The applications of SMB chromatography are popular in separating and purifying enantiomers, petrochemicals, pharmaceuticals and biochemicals with higher yield and lower solvent consumption. We simulate and compare several operational modes of simulated moving bed (SMB) for a binary and a ternary bioprocess using Aspen Chromatography. These operational modes are able to improve the separation efficiency of the basic SMB process by our simulation and optimization. We compare their separation performances and identify heuristics that will guide the selection of operational modes across a variety of systems. Pressure swing adsorption (PSA) and temperature swing adsorption (TSA) are two of the main technologies for gas-phase adsorption separation processes. We simulate and demonstrate a PSA model for air separation system and a TSA model for CO2 capture system in Aspen Adsorption. We present their separation performance plots to provide the physical insights of these two systems. / Ph. D.

A conventional membrane bioreactor (MBR) and two moving bed bioreactors coupled with ultrafiltration membrane filtration were operated for close to six months to investigate biological nutrient removal and potential fouling inducing parameter mitigation. Unique to one of the moving bed membrane bioreactors (MBMBR) was a newly designed media that incorporated a hydrodynamic exterior carrier with a highly porous interior packing. Preliminary investigation indicates that nitrogen compounds were superiorly removed in the two MBMBRs when compared with the MBR. This is a result of denitrification processes occurring in anoxic micro-zones found within the depths of the biofilm affixed to media. Fouling propensity was found to be increased by over four times in the MBMBR systems as compared to the MBR. Mixed liquor, permeate and filtrate analysis, membrane fibre examination and permeability tests indicated that colloidal organic carbon, as well as soluble microbial products were the dominant fouling inducing compounds. / Manuscript format / The Natural Sciences and Engineering Research Council of Canada

Klädindustrin är idag en stor bidragande orsak till negativa miljöpåverkningar. Om avtrycket från den industrin ska minska behöver det ”fast fashion” fasas ut och ett nytt sätt att se på kläder implementeras. De enklaste sätten att minska avtrycket är att återanvända eller återvinna kläder. Renewcell återvinner textilier och bryter ner bomullen och återvinner den som nytt material - Circulose®. Det materialet skickas vidare för att bli nya kläder och på så sätt stängs loopen för textilindustrin. Av produktionen av Circulose® tillkommer ett nytt slags processavlopp som inte hunnits forskas mycket på. Paralleller till textilindustrin kan visserligen dras och där är processavloppen av heterogen karaktär. Renewcell vill se om det går att reducera det organiska materialet i avloppet till en nivå på 10 mg/l. Den här studien vill hjälpa till att fylla det forskningsgap som finns för reningsteknik inom textilåtervinningsindustrin idag. Med en ny marknad i uppstart är det viktigt att avlopp hanteras på ett bra och ansvarsfullt sätt. Syftet med studien var att undersöka experimentellt och litterärt om det går att reducera ner BOD7 i Renewcells processavloppet till 10 mg/l. En MBBR har efterforskats och jämförts med en MBR, där en MBBR ansågs vara mer resistent mot variationer och farliga ämnen. Det byggdes en MBBR i laborationsskala kopplat till processavloppet för att analysera reduktionen av BOD7 och för att göra en experimentell undersökning hur den kemiska fällningen påverkas om vattnet behandlades biologiskt först. Studien resulterade i att Renewcells karaktär på processavlopp är heterogent och är hanterbart av mikroorganismer. Dock, på grund av att ingen fullt utvecklad biofilm nåddes samt variationer i processen är det fortfarande osäkert om det fungerar att implementera en MBBR hos Renewcell. Processförändringar som ett produktionsstopp är inga problem för en fullt utvecklad MBBR att hantera. Processavloppet innehåller en stor mängd organiskt material, men saknar tillräckligt med näringsämnen. För detta projekt var 58 % reduktion av BOD7 den högsta som redovisades och det nåddes inte heller en fullt utvecklad biofilm. Att biologiskt behandla avloppet innan en kemisk fällning gav positiva resultat då reduktionen av metalljoner förbättrades. Allt som allt anses det vara möjligt att implementera en MBBR hos Renewcell om rätt förutsättningar finns och det ges en möjlighet att utveckla en biofilm fullt ut. Förhoppningsvis kan denna förstudie visa vägen för vidare studier inom området. / The clothing industry is one of the major causes for negative environmental impacts. The “fast-fashion” needs to be phased out and a more climate-friendly way of using clothes implemented. The easiest ways to do this is to reuse or recycle clothes. Renewcell recycles used textiles and dissolve the cotton into pulp and makes a new material of it - Circulose®, which is sent to become new clothes and, in that way, helps to close the loop for textile industry. With the production of Circulose® a new kind of wastewater is produced which has not yet been thoroughly researched. A parallel to the textile industry’s wastewater can be drawn, and that is of heterogeneous nature and can change quickly from day to day. It is in Renewcell’s interest to reduce the organic matter in the wastewater, more than they do today with their current chemical and mechanic wastewater treatment plant does. This study wants to help fill the research gap that exists for purification technology in the textile recycling industry today. Since it is a new field of technology, it is of importance to thoroughly invest in how to treat the wastewater responsibly. The purpose of this study was to investigate, both experimentally and literary, whether the possibility to reduce BOD7 to 10 mg/l in the wastewater treatment plant. With an investigation of MBBR and by compare it with an MBR it was concluded that a MBBRis a better fit for Renewcell since it is considered to be more resistant to variations and hazardous substances. To strengthen that conclusion a MBBR in laboratory scale was built and wastewater directly from the recycling process treated. The reduction of BOD7 and how it would come to affect the chemical precipitation was analyzed. The results of the study concluded that Renewcells wastewater is heterogenous and manageable for microorganisms. However, the due to the variations in the process such as dosing of biologically harmful substances it might not be possible for Renewcell to implement a MBBR. Process variations as a stop in production of wastewater for a shorter time period is manageable. The wastewater contains enough organic matter, but an extra addition of nutrients is needed. For this project the MBBR-process fluctuated in reduction of organic matter and the highest amount achieved was 58 %. No fully developed biofilm was achieved either. Biologically treating the process effluent before the chemical precipitation gave positive results as the reduction of metal ions was improved. All in all, it is believed to be possible to implement a MBBR at Renewcell if the process is given the required conditions from the beginning and a biofilm can be fully developed. Hopefully, this pilot study can show the way for future research within the field.

Adsorption separation processes are extremely important to the chemical industry, especially in the manufacturing of food, pharmaceutical, and fine chemical products. This work addresses three main topics: first, systematic decision-making between rival gas phase adsorption processes for the same separation problem; second, process development for liquid phase simulated moving bed chromatography (SMB); third, accelerated startup for SMB units. All of the work in this thesis uses model-based optimization to answer complicated questions about process selection, process development, and control of transient operation. It is shown in this thesis that there is a trade-off between productivity and product recovery in the gaseous separation of enantiomers using SMB and pressure swing adsorption (PSA). These processes are considered as rivals for the same separation problem and it is found that each process has a particular advantage that may be exploited depending on the production goals and economics. The processes are compared on a fair basis of equal capitol investment and the same multi-objective optimization problem is solved with equal constraints on the operating parameters. Secondly, this thesis demonstrates by experiment a systematic algorithm for SMB process development that utilizes dynamic optimization, transient experimental data, and parameter estimation to arrive at optimal operating conditions for a new separation problem in a matter of hours. Comparatively, the conventional process development for SMB relies on careful system characterization using single-column experiments, and manual tuning of operating parameters, that may take days and weeks. The optimal operating conditions that are found by this new method ensure both high purity constraints and optimal productivity are satisfied. The proposed algorithm proceeds until the SMB process is optimized without manual tuning. In some case studies, it is shown with both linear and nonlinear isotherm systems that the optimal performance can be reached in only two changes of operating conditions following the proposed algorithm. Finally, it is shown experimentally that the startup time for a real SMB unit is significantly reduced by solving model-based startup optimization problems using the SMB model developed from the proposed algorithm. The startup acceleration with purity constraints is shown to be successful at reducing the startup time by about 44%, and it is confirmed that the product purities are maintained during the operation. Significant cost savings in terms of decreased processing time and increased average product concentration can be attained using a relatively simple startup acceleration strategy.