This thesis contributes to an increased understanding of the formation of dioxins and dioxin-like compounds in combustion processes. Although emissions to air from waste incineration facilities have been greatly reduced by the use of efficient air pollution control measures, the resulting residues (ashes and filters) are highly toxic and are classified as hazardous waste. The main objective of the work underlying this thesis was to elucidate the formation and chlorination pathways of dioxins and dioxin-like compounds in waste combustion flue gases in the temperature range 640-200°C in a representative, well-controlled laboratory-scale reactor using artificial municipal solid waste. This could contribute to the reduction of harmful emissions to air and also reduce the toxicity of waste incineration residues, thus reducing or even eliminating the need for costly and potentially hazardous after-treatment. A comparison of four different quenching profiles showed that the formation of polychlorinated dibenzo-p-dioxins (PCDD) and dibenzofurans (PCDF) was rapid and mainly occurred in the 640-400°C temperature region, with high dependency on sufficient residence time within a specific temperature region. Prolonged residence time at high temperatures (450/460°C) reduced the PCDD yields, even at lower temperatures along the post-combustion zone. PCDD, PCDF and PCN (polychlorinated naphthalene) isomer distribution patterns indicated contributions from chlorophenol condensation as well as chlorination reactions for all three classes of compounds. The formation of PCDDs was largely influenced by chlorophenol condensation and to some extent by chlorination reactions. For the PCDFs, chlorine substitution adjacent to the oxygen bridges was unfavoured, as demonstrated by the notably lower abundance of 1,9-substituted congeners. This was supported by bidirectional orthogonal partial least squares (O2PLS) modelling. The variable with the greatest influence on the distribution of PCDD congeners was the relative free energy (RΔGf). The O2PLS models displayed distinct clusters, dividing most of the homologues into two or three sub-groups of congeners which seemed to correspond to the probability of origination from chlorophenol condensation. The effects of injection of aromatic structures into the flue gas differed for each class of compounds. Injection of naphthalene increased the formation of monochlorinated naphthalene but the remaining homologues appeared to be unaffected. This was probably due to insufficient residence time at temperatures necessary for further chlorination. Injected dibenzo-p-dioxin was decomposed, chlorinated and re-condensated into PCDDs and PCDFs, whereas injection of dibenzofuran and fluorene reduced the PCDD levels in the flue gas. / Denna avhandling fokuserar på olika aspekter som kan bidra till en ökad förståelse av bildning av dioxiner och dioxin-lika föreningar i förbränningsprocesser. Även om utsläppen till luft från sopförbränningsanläggningar har minskat kraftigt tack vare effektiva rökgasreningsmetoder, så återstår problemet med mycket giftiga rökgasreningsprodukter (askor och filter), vilka klassificeras som farligt avfall. Det huvudsakliga syftet med arbetet bakom denna avhandling var att klarlägga bildnings- och kloreringsvägarna för dioxiner och dioxin-lika föreningar i temperaturintervallet 640-200°C i rökgaser från sopförbränning. Detta kan möjliggöra lösningar för ytterligare emissionsminskningar och en avgiftning av biprodukterna från avfallsförbränning, vilket minskar eller till och med eliminerar behovet av kostsam och riskfylld efterbehandling. Realistiska och välkontrollerade försök har utförts i en lab-skalereaktor där en artificiell hushållssopa har förbränts. En jämförelse av fyra olika temperatur- och uppehållstidsprofiler visade att bildning av polyklorerade dibenso-p-dioxiner (PCDD) och dibensofuraner (PCDF) sker snabbt och huvudsakligen inom temperaturintervallet 640-400°C. Bildningen var starkt beroende av en tillräckligt lång uppehållstid inom ett visst temperaturområde. En förlängd uppehållstid vid höga temperaturer (>450°C) resulterade i minskade halter av PCDD, vilka förhöll sig låga även senare i efterförbränningszonen. Isomermönstren av PCDD, PCDF och PCN (polyklorerade naftalener) visade alla tecken på att härröra från både klorfenolkondensation och kloreringsreaktioner. PCDD-mönstret visade tydliga indikationer på bildning från klorfenoler, och till mindre grad bildning via klorering. För PCDF var klorsubstitution i positioner angränsande till syrebryggan missgynnad, vilket bekräftades av multivariat modellering (O2PLS). Den variabel som starkast påverkade bildningen av PCDD var relativa fria energin (RΔGf). Modellerna visade på en distinkt gruppering av PCDD- och PCDF-kongenerna i två eller tre grupper för varje kloreringsgrad, och föreslås vara relaterad till sannolikheten för respektive kongen att bildas via klorfenolkondensation. Injektion av aromatiska kolstrukturer i rökgaskanalen gav upphov till skilda effekter. Injektion av naftalen ökade bildningen av monoklorerad naftalen medan resterande homologer inte verkade påverkas, sannolikt på grund av för kort uppehållstid för ytterligare klorering. Dibenso-p-dioxin spjälkades sannolikt till fenoliska fragment som klorerades och sedan återkondenserades till PCDD och PCDF, medan dibensofuran och fluoren kraftigt reducerade PCDD-koncentrationerna.

<i>Staphylococcus aureus</i> is a ubiquitous organism causing world-wide morbidity and mortality. This species readily develops resistance to antimicrobial agents. Current dosing strategies are based, in part, on minimum inhibitory concentrations (MICs). This susceptibility test fails to detect the presence of first-step resistant mutants often present in large heterogeneous populations of infecting bacteria. Dosing strategies based on MIC results may, in fact, allow for the selective proliferation of resistant subpopulations. The mutant-prevention concentration (MPC) is the drug concentration at which all first-step resistant mutants will be eradicated along with the susceptible cells. Determination of the mutant-selection window (MSW) is possible using MIC and MPC data. When considered together with achievable drug concentrations in human bodily sites, the MSW helps determine which antimicrobials are likely to select for resistance. MIC and MPC testing on clinical isolates of methicillin-susceptible (MSSA) and -resistant (MRSA) S. aureus was performed. Characterization via the polymerase chain reaction, sequencing, and electron microscopy (EM) was done on selected organisms recovered from MPC studies (MPC-recovered). MIC and MPC testing was performed on organisms isolated sequentially from patients with recurring S. aureus infections. Pulsed field gel electrophoresis was performed on these sequential isolates. Based on the MIC and the MPC values, the most potent agents for systemic MSSA and MRSA infections are gemifloxacin and vancomycin, respectively. Re-testing MPC-recovered populations by the MIC showed increased MIC results compared to the parent populations. Macrolide-resistance genes were discovered in S. aureus MPC-recovered populations; in contrast, parental isolates lacked these resistance determinants. EM revealed an increase in cell wall thickness of a vancomycin MPC-recovered population compared to its parental population. Moxifloxacin and vancomycin had the lowest and narrowest MSWs for systemic MSSA and MRSA infections, respectively, compared to the other agents tested. Sequential isolates showed no change in MIC and MPC values. The data presented provides evidence for the application of the MPC test to S. aureus organisms. The MPC data is significant when determining appropriate dosing strategies aimed at preventing resistance.

<i>Staphylococcus aureus</i> is a ubiquitous organism causing world-wide morbidity and mortality. This species readily develops resistance to antimicrobial agents. Current dosing strategies are based, in part, on minimum inhibitory concentrations (MICs). This susceptibility test fails to detect the presence of first-step resistant mutants often present in large heterogeneous populations of infecting bacteria. Dosing strategies based on MIC results may, in fact, allow for the selective proliferation of resistant subpopulations. The mutant-prevention concentration (MPC) is the drug concentration at which all first-step resistant mutants will be eradicated along with the susceptible cells. Determination of the mutant-selection window (MSW) is possible using MIC and MPC data. When considered together with achievable drug concentrations in human bodily sites, the MSW helps determine which antimicrobials are likely to select for resistance. MIC and MPC testing on clinical isolates of methicillin-susceptible (MSSA) and -resistant (MRSA) S. aureus was performed. Characterization via the polymerase chain reaction, sequencing, and electron microscopy (EM) was done on selected organisms recovered from MPC studies (MPC-recovered). MIC and MPC testing was performed on organisms isolated sequentially from patients with recurring S. aureus infections. Pulsed field gel electrophoresis was performed on these sequential isolates. Based on the MIC and the MPC values, the most potent agents for systemic MSSA and MRSA infections are gemifloxacin and vancomycin, respectively. Re-testing MPC-recovered populations by the MIC showed increased MIC results compared to the parent populations. Macrolide-resistance genes were discovered in S. aureus MPC-recovered populations; in contrast, parental isolates lacked these resistance determinants. EM revealed an increase in cell wall thickness of a vancomycin MPC-recovered population compared to its parental population. Moxifloxacin and vancomycin had the lowest and narrowest MSWs for systemic MSSA and MRSA infections, respectively, compared to the other agents tested. Sequential isolates showed no change in MIC and MPC values. The data presented provides evidence for the application of the MPC test to S. aureus organisms. The MPC data is significant when determining appropriate dosing strategies aimed at preventing resistance.

The objective of this study is to illustrate that phase separation improves the efficiency of an anaerobic system which digests semi-solid organic wastes. Organic fraction of municipal solid waste (OFMSW) was the semi-solid organic waste investigated. In the first part of the study, the optimum operational conditions for acidified reactor were determined by considering the volatile solid (VS) reductions and average acidification percentages at the end of two experimental sets conducted. Organic loading rate (OLR) of 15 g VS/L.day, pH value of 5.5 and hydraulic retention time (HRT) of 2 days were determined to be the optimum operational conditions for the acidification step. Maximum total volatile fatty acid and average acidification percentage were determined as 12405 mg as HAc/L and 28%, respectively in the reactor operated at optimum conditions. In the second part, an acidification reactor was operated at the optimum conditions determined in the first part. The effluents taken from this reactor as well as the waste stock used to feed this reactor were used as substrate in the biochemical methane potential (BMP) test. The results of BMP test revealed that the reactors fed by acidified samples indicated higher total chemical oxygen demand (tCOD) removals (39%), VS reductions (67%) and cumulative gas productions (265 mL). The result of this study indicated that the separation of the reactors could lead efficiency enhancement in the systems providing that effective control was achieved on acidified reactors.

Este trabalho apresenta a caracterização in situ de propriedades de interesse geotécnico de maciços de resíduos sólidos urbanos (RSU) e o estudo das propriedades de resistência ao cisalhamento de RSU com diferentes idades. Foram realizadas investigações por sondagens e com métodos geofísicos sísmicos no Aterro Sanitário de São Carlos (ASSC) e ensaios de cisalhamento direto de grandes dimensões (50x50 cm2) com amostras de diferentes idades de aterramento coletadas no ASSC, no Lixão Desativado de São Carlos e em Aterro Experimental construído nas proximidades do Lixão. As investigações realizadas no ASSC revelaram que as diferentes fases de operação do maciço (aterro controlado e aterro sanitário) produziram dois estratos com diferentes propriedades geotécnicas. A umidade, as velocidades de propagação de ondas sísmicas e o peso específico in situ dos dois estratos são distintos, sendo sempre menores e menos dispersos no estrato mais raso (operado como aterro sanitário) e maiores e mais dispersos no estrato mais profundo (operado como aterro controlado). Realizaram-se tentativas de determinação do peso específico in situ dos RSU com medição dos volumes escavados por substituição de volume. Notou-se que os furos tendiam a diminuir de diâmetro assim que a composição de sondagem era retirada e que o método adotado para avanço dos furos, com trado helicoidal de haste oca, promovia segregação dos componentes atravessados, realizando uma amostragem parcial dos mesmos. Foram calculados valores médios de peso específico in situ para o maciço investigado (9 a 15 kN/m3) e identificadas as principais limitações da aplicação deste método a aterros sanitários. A aplicação de métodos geofísicos sísmicos foi fundamental para a diferenciação dos dois estratos e permitiu que se calculasse o módulo de cisalhamento máximo (Go) dos resíduos, que variou significativamente de um estrato para outro. Foi possível comparar os resultados obtidos com a aplicação do método crosshole e do método multichannel analysis of surface waves (MASW) no mesmo aterro sanitário. A caracterização das seis amostras utilizadas nos ensaios de cisalhamento direto revelou que, apesar de elas representarem idades distintas de disposição dos resíduos (2 a 25 anos) e condições de aterramento variadas (formas de operação dos depósitos, ambientes de decomposição e condições de confinamento), a maioria delas se encontrava em estágio avançado de degradação (fase metanogênica) e apenas a mais recente (2 anos de aterramento) encontrava-se em estágio um pouco menos avançado de degradação (início da fase metanogênica). Todas elas exibiram curvas tensão-deslocamento semelhantes, sem pico ou valor de máxima resistência bem caracterizados. Os parâmetros de resistência ao cisalhamento foram obtidos a partir de níveis específicos de deslocamento. Avaliou-se a influência da amostragem, dos procedimentos de preparação das amostras e da composição gravimétrica de cada uma delas sobre os valores calculados para coesão e ângulo de atrito. Para deslocamentos de 100 mm o resíduo aterrado há dois anos apresentou coesão de 13,7 kPa e ângulo de atrito de 22º. Os resíduos mais degradados, com idades de disposição entre 5 e 25 anos, apresentaram coesão de 4,4 kPa e ângulo de atrito de 30º. Utilizaram-se tensões normais de 50, 150 e 250 kPa. Realizaram-se ainda ensaios de cisalhamento direto de grandes dimensões em uma das amostras com corpos de prova em duas posições: paralela e perpendicular à direção de compactação. Os resultados confirmaram que os RSU têm comportamento anisotrópico, sendo que os corpos de prova ensaiados com os componentes alinhados preferencialmente na posição vertical (rotacionados) têm comportamento de endurecimento ainda mais pronunciado que aqueles ensaiados com os componentes orientados preferencialmente no plano horizontal. / Field and laboratory tests were combined to characterize some in-place geotechnical properties of the waste body in the São Carlos Sanitary Landfill (SCSL). The investigation was carried out using hollow stem auger soundings and seismic geophysical methods in the field, and large-scale direct shear testing in the laboratory. The field investigation revealed two strata with different geotechnical properties and they could be related to the different operational phases of the landfill (controlled landfill and sanitary landfill). Moisture content, seismic wave velocities and in-place unit weight were systematically lower and less scattered in the upper stratum than in the lower stratum. The upper stratum was operated as a sanitary landfill and the lower stratum was operated as a controlled landfill. The investigations with geophysical seismic methods were essential for identifying the two strata and allowed for the calculation of the Poisson ratio and the small strain shear modulus (Go) of the waste body. The Poisson ratio showed no sensibility to the waste stratigraphy, but Go values were significantly higher in the lower stratum. Moreover, the results of two different geophysical methods, namely crosshole and multichannel analysis of surface waves (MASW), could be compared. An attempt was made to estimate overboring using a volume substitution method by filling the boreholes with gravel. This aimed at incorporating this aspect in the calculations of the MSW in-place unit weight. Nevertheless, the borings tended to cave in as soon as the augers were removed and this prevented the evaluation of the overboring. Moreover, the hollow stem auger tended to segregate the larger components of the waste and to bring only the smaller ones to the surface. Despite all these difficulties, average values for the MSW inplace unit weight were be calculated (9 to 15 kN/m3). In the laboratory, large-scale direct shear tests (500 x 500 mm2) were performed to provide an insight on the shear strength response of municipal solid waste (MSW) of different landfilling ages. The test samples were collected from the SCSL, a dumpsite and an experimental landfill. Their landfilling ages ranged from 2 to 25 years. Physico-chemical characterization of the samples revealed that most of them were subjected to the metanogenesis degradation phase, in spite of their different landfilling ages and burial conditions (operational characteristics of the deposits, decomposition environment and confining pressures). Only the newest one (2 years old sample) was subjected to an earlier stage of degradation. In the direct shear tests, all samples showed similar stress-strain curves, with continuous strain hardening and no identifiable maximum stress, despite the large displacements. The influence of sampling method, sample preparation and sample gravimetric composition on the calculated shear resistance parameters is discussed. For a 100-mm displacement the shear resistance of the less degraded waste (2 years of landfilling) is best characterized by cohesion = 13.7 kPa and friction angle = 22º. The more degraded wastes (5 to 25 years old samples) are best characterized by cohesion = 4.4 kPa and friction angle = 30º. The tests were performed with initial normal stresses of 50, 150 and 250 kPa. Specific large direct shear tests were performed to evaluate anisotropy in the MSW shear response. The test samples had the fibrous materials oriented perpendicular or parallel to the horizontal shear surface. Results confirmed the expected anisotropy by showing a hardening behaviour that was more pronounced when the fibrous materials were oriented perpendicular to the shear plan.

Made available in DSpace on 2015-05-14T12:09:31Z (GMT). No. of bitstreams: 1 arquivototal.pdf: 4535021 bytes, checksum: 6a466a19576e3fff542d984d0c14fecd (MD5) Previous issue date: 2012-12-14 / Coordenação de Aperfeiçoamento de Pessoal de Nível Superior - CAPES / The study of biological conversion for energy purposes in landfills of municipal solid waste is a major breakthrough to the society and it is considered having an extremely environmental and economic importance. Given this ostentation a study was conducted in the João Pessoa's metropolitan landfill , in order to estimate the production of biogas and its main component, methane. There is no an official protocol of the Biochemical Methane Potential Test (BMP) for the prediction of gas generated for this reason literature searches were conducted and a methodology was adapted based on the characterization and monitoring of the main factors involved in the degradation process. The steps of the study were as following: waste's gravimetric characterization, physicochemical characterization and acclimatization of inoculum and the BMP test, which includes the inoculation of the reaction ways , the monitoring of the biogas' volume produced, the quantitative and qualitative control of the generation of gases comprising the biogas and consequently the estimate of the generation of biogas in the landfill. The results has showed that the gravimetric characterization of the municipal solid waste, which used the French method MODECOM brought data definitions more precise, giving reliability to the composition of the waste. The proposed methodology for the BMP test was effective in obtaining the results, as it has produced a volume of accumulated biogas 282.66 NL.kg-1MS in 90 days in the biodegradable waste, consistent with the literature, providing a favorable production of biogas in the João Pessoa's metropolitan landfill. As it was considered an excellent experimental tool for determining the potential for the biogas generation in MSW, the BMP test enables the preparation for the official procedure. / O estudo da conversão biológica com fins energéticos em aterros de resíduos sólidos urbanos representa um grande avanço para a sociedade, sendo considerada de extrema importância ambiental e econômica. Diante dessa ostentação foi realizado um estudo no aterro sanitário metropolitano de João Pessoa, visando estimar a produção de biogás e do seu principal componente, o metano. Por não existir um protocolo oficial do Teste do Potencial Bioquímico de Metano (Teste BMP) para a previsão dos gases gerados, foram realizadas pesquisas bibliográficas e adaptada uma metodologia fundamentada nas caracterizações e monitoramentos dos principais fatores envolvidos no processo de degradação. As etapas do trabalho foram as seguintes: caracterização gravimétrica dos resíduos, caracterização físico-química e aclimatação do inóculo e o Teste BMP, o qual inclui a inoculação dos meios de reação, o monitoramento do volume de biogás produzido, o controle quantitativo e qualitativo da geração dos gases que compõem o biogás e consequentemente a estimativa de geração do biogás no aterro. Os resultados mostraram que a caracterização gravimétrica dos resíduos sólidos urbanos, a qual utilizou o método francês MODECOM, trouxe definições de dados mais precisos, dando confiabilidade à composição dos resíduos. A metodologia proposta para o teste BMP mostrou-se eficiente na obtenção dos resultados, pois produziu no resíduo biodegradável um volume acumulado de biogás de 282,66 NL.kg-1MS em 90 dias, condizente com a bibliografia, possibilitando uma produção favorável de biogás no aterro sanitário metropolitano de João Pessoa. Por ter sido considerado uma excelente ferramenta experimental para determinação do potencial de geração de biogás nos RSU, o teste BMP, viabiliza a elaboração para um procedimento oficial.

Waste can be considered as an urban burden or as a valuable resource depending on how it ismanaged. Different waste treatment technologies are available at present to manage municipal solidwaste (MSW). Various actors are involved to develop waste treatment technology for certain area.The aim of this study is to analyze the driving forces in technical development in waste sector inSweden. The study is also done to identify emerging waste management technology in Sweden.Moreover, a comparative study of existing and emerging technologies is done by Life CycleAssessment (LCA) model. An extensive literature review and pilot questionnaire survey among thewaste management professionals’ is done for the study. LCA model is developed by SimaProsoftware CML2 baseline method is used for identifying environmental burden from the wastetechnologies.Dry composting, Pyrolysis-Gasification (P-G), Plasma-Arc are identified as potential emergingtechnologies for waste management system in Sweden. Technical developments of thesetechnologies are influenced by indigenous people’s behavior, waste characteristics, regulations, healthor environmental impact and global climate change. Comparative LCA model of P-G andIncineration shows that, P-G is a favorable waste treatment technology than Incineration for MSW,especially in acidification, global warming and aquatic eco-toxicity impact categories.

Nowadays, municipal solid waste (MSW) has got great attention from world-wide decision makers in the field of waste management. When they are making a MSW management decision, there are lots of factors that may influence their final decision for picking up an optimal alternative. In order to find out the influence factors in municipal solid waste management decision-making, incineration and anaerobic fermentation techniques are selected as example for comparison. Literature study and interview are used for collecting theoretical and practical information respectively. A list of theoretical influence factors is created, which integrates environmental, social and financial aspects of incineration and anaerobic fermentation. This list can help the decision-maker to have a better choice when they are choosing an alternative from MSW management methods. Practical information is achieved by interviewing the City of Stockholm Waste Management Administration. Differences are revealed between theory and the Stockholm case. The priority of each influence factor is discussed in this paper. Base on the decision between theoretical factors and the Stockholm case, the result shows that the theoretical factors are not completely sufficient for the practical use in the city of Stockholm. The list of theoretical influence factors should be extended by integrating more factors and more MSW management alternatives to meet different requirements in practical cases. There is no clear definition on which factor has the highest degree of influence for the decision-maker. The priority of influence factors is depended on the local condition and subjective choice of decision-maker. / www.ima.kth.se

"Les dioxines" (PCDD/F : polychlorodibenzodioxines/furanes) sont des polluants organiques persistants émis dans l'atmosphère, provenant de combustions incomplètes. Cette étude concerne l'oxydation et la pyrolyse du dibenzofurane (DBF) choisie comme molécule modèle des PCDF. La réaction est étudiée dans un réacteur parfaitement agité entre 500 et 950°C, pour un temps de passage de 3 à 5s et à très faible concentration de DBF (~2 ppm) pour se rapprocher des conditions des incinérateurs (UIOM). Les espèces intermédiaires, formées lors de la décomposition du DBF, sont identifiées par GC/MS puis quantifiées par TD/GC/FID. Ces produits sont des dérivés du benzofurane, des composés aromatiques et poly-aromatiques. A partir de ces résultats, un mécanisme cinétique détaillé a pu être développé et validé. Ce mécanisme est ensuite utilisé pour simuler d'autres conditions opératoires et optimiser la zone de postcombustion des UIOM / "Dioxins" (PCDD/F) are persistent organic pollutants which are emitted in the atmosphere by several combustion and thermal processes. The present study concerns the oxidation and the pyrolysis of dibenzofuran which is chosen as a model molecule of polychrorodibenzofurans. The reaction is studied at very low concentration of dibenzofuran (~2 ppm) in a continuous perfectly stirred reactor between 3s and 5s, whereas temperature is ranging from 500°C to 950°C. During dibenzofuran decomposition, several intermediary species are formed; they are identified by GC/MS and then quantified by TD/GC/FID. The main products are derivatives of benzofuran, polyaromatic hydrocarbons and other volatile organic compounds. Taking into account our experimental results and the literature data, we have proposed and validated a detailed mechanism of DBF reaction. This mechanism is used to model the abatement of dioxins by total oxidation in the postcombustion area of a municipal waste incinerator

Curitiba is a city of two million inhabitants located in the South of Brazil. It is a pioneer in waste management in the country, and is famous for its programs promoting recycling and organic waste collection. The city is now willing to take waste management one step further by investigating new solutions to treat and recover energy from organic municipal solid waste. This report is the fruit of a collaboration between two departments of the municipality of Curitiba, four local universities, the Swedish environment protection agency and the Royal Institute of Technology – KTH. The purpose of this report is to assess the potential for the development of anaerobic digestion as a solution to treat the organic municipal solid waste generated in Curitiba. The report offers an overview of the current waste treatment and of the main sources of organic waste in Curitiba. The annual amount of organic waste generated in the city is estimated to 144,350 tons, of which 913 tons come from food markets supervised by SMAB, the secretary of food supply. Three different scenarios, corresponding to three ranges of waste sources, have been considered. In the first one, the organic wastes generated by one of the two public markets of Curitiba are treated on-site. In the second one, all the organic wastes from food markets, street markets and popular restaurants are treated together in a medium-scale anaerobic digester. In the third one, all the sources of organic municipal solid waste identified in Curitiba are considered, including residential, institutional and small commercial waste. The annual methane production is estimated to 5,400 m3, 86,000 m3 and 12,600,000 m3 respectively for the three scenarios. In the last two scenarios, the methane could be converted into electricity, resulting in an annual electricity production of 257 MWh and 37,600 MWh. The first scenario does not consider a post-treatment of the digestate remaining at the end of the digestion. Between 46 and 50 tons of digestate could be used as a liquid fertilizer on-site and the surplus could be sold. For the two other scenarios, the digestate would be dewatered and composted to be sold as a dry fertilizer. The dry fertilizer production is estimated to 386 tons and 63,000 tons respectively every year. Each of the scenario considered would be financially viable, with a discounted payback period varying from 8 months for the small-scale scenario, to over 15 years for the second scenario. The third scenario would be the most lucrative, with a net present value of about 150 million reals. / Curitiba i Södra Brasilien är en stad med två miljoner invånare som har positionerat sig som pionjär inom avfallshantering. Staden är känd i landet med sin främjande strategi för återvinning och organisk avfallshantering. Curitiba planerar att undersöka och experimentera med nya metoder för behandling av avfall kombinerad med energiåtervinning från kommunalt organiskt avfall. Denna rapport är resultat av ett samarbete mellan två avdelningar inom Curitibas kommun, fyra lokala universitet, Sveriges miljöskyddsmyndighet och den Kungliga Tekniska Högskolan. Syftet med denna rapport är att utvärdera den potentialen som den anaeroba nedbrytningen har som medel för behandling av det kommunala fasta avfallet som genereras i Curitiba. Rapporten går även igenom hur avfallshanteringen ser ut i staden i dagsläget samt sammanfattar de största källorna för organiskt avfall i Curitiba. Den årliga mängden organiskt avfall som produceras i staden uppskattas till 144 350 ton, varav 913 ton kommer från livsmedelsaktiviteter som övervakas av det brasilianska livsmedelsverket SMAB. Tre olika scenarier representeras i denna rapport och omfattar tre områden av avfallskällor. I det första scenariot behandlas det organiska avfallet som genereras av en av de två köpmarknaderna i Staden direkt på plats. I det andra behandlas allt organiskt avfall från livsmedelsmarknader, gatumarknader och populära restauranger tillsammans i en medelstor anaerob kokare. I det tredje beaktas alla källor till organiskt kommunalt avfall som identifierats i Curitiba, inklusive bostads-, institutionellt och litet kommersiellt avfall. Den årliga metanproduktionen uppskattas till 5 400 m3, 86 000 m3 respektive 12 600 000 m3 för de tre scenarierna. I det andra och tredje scenariot kunde metan omvandlas till el, vilket resulterade i en årlig elproduktion på 257 MWh respektive 37 600 MWh. I det första scenariot anses inte en efterbehandling av digestatet kvar vid slutet av matsmältningen. Mellan 46 och 50 ton digestat kan användas som flytande gödselmedel på plats och överskottet kan säljas. För de två andra scenarierna skulle digestatet avvattnas och komposteras för att senare säljas som torr gödsel vars produktion beräknas uppgå till 386 ton respektive 63 000 ton varje år. Alla tre scenario som presenteras i denna rapport anses vara ekonomiskt genomförbara med en diskonterad återbetalningstid som varierar mellan 8 månader för det första scenariot till över 15 år för det andra scenariot. Det tredje scenariot anses vara det mest lukrativa med ett nuvärde på ca 150 miljoner realer.