Actualment estem entrant a una nova era de la informació amb gran demanda de sistemes de comunicació sense fils. Nous serveis com dades i video requereixen transmissions fiables d'alta velocitat, fins i tot en escenaris d'alta mobilitat. A més a més, la dificultat d'assignar el limitat espectre radioelèctric juntament amb la necessitat d'incrementar el temps de vida de les bateries dels terminals mòbils, requereix el diseny de transceptors que usin la potència i l'ampla de banda disponibles de manera eficient. Les comunicacions multiportadora basades en OFDM són capaces de satisfer la majoria d'aquests requeriments. Però, entre altres reptes, reduir la sensibilitat a la amplificació no-lineal és un factor clau durant el diseny. En aquesta tesi doctoral s'analitza la sensibilitat dels sistemes multiportadora basats en OFDM a l'amplificació no-lineal i es consideren formes eficients per superar aquest problema. La tesi s'enfoca principalment al problema de reduir les fluctuacions de l'envolupant del senyal transmès. En aquest sentit es presenta també un estudi de les mètriques de l'envolupant del senyal, PAPR i CM. A més a més, basant-nos en l'anàlisis presentat es proposen noves tècniques per sistemes OFDM i MC-SS. Per MC-SS, també es tracta el diseny d'una tècnica de postprocessament en forma de detector multiusuari per canals no-lineals. / Actualmente estamos entrando en una nueva era de la información donde se da una gran demanda de sistemas de comunicación inalámbricos. Nuevos servicios como datos y vídeo requieren transmisiones fiables de alta velocidad, incluso en escenarios de alta movilidad. Además, la dificultad de asignar el limitado espectro radioeléctrico junto con la necesidad de incrementar el tiempo de vida de las baterías de los terminales móviles, requiere el diseño de transceptores que usen eficientemente la potencia y el ancho de banda disponibles. Las comunicaciones multiportadora basadas en OFDM son capaces de satisfacer la mayoría de dichos requerimientos. Sin embargo, entre otros retos, reducir su sensibilidad a la amplificación no-lineal es un factor clave durante el diseño. En esta tesis se analiza la sensibilidad de los sistemas multiportadora basados en OFDM a la amplificación no-lineal y se consideran formas eficientes para superar dicho problema. La tesis se enfoca principalmente al problema de reducir las fluctuaciones de la envolvente. En este sentido también se presenta un estudio de las métricas de la señal, PAPR y CM. Además, basándonos en el análisis presentado se proponen nuevas técnicas para OFDM y MC-SS. Para MC-SS, también se trata el diseño de un detector multiusuario para canales no-lineales. / We are now facing a new information age with high demand of wireless communication systems. New services such as data and video require achieving reliable high-speed transmissions even in high mobility scenarios. Moreover, the difficulty to allocate so many wireless communication systems in the limited frequency band in addition to the demand for long battery life requires designing spectrum and power efficient transceivers. Multicarrier communications based on OFDM are known to fulfill most of the requirements of such systems. However, among other challenges, reducing the sensitivity to nonlinear amplification has become a design key. In this thesis the sensitivity of OFDM-based multicarrier systems to nonlinear amplification is analyzed and efficient ways to overcome this problem are considered. The focus is mainly on the problem of reducing the envelope fluctuations. Therefore, a study of the signal metrics, namely PAPR and CM, is also presented. From the presented analysis, several new techniques for OFDM and MC-SS are proposed. For MC-SS, the design of a post-processing technique in the form of a multiuser detector for nonlinearly distorted MC-SS symbols is also addressed.

[pt] Acidentes com influxo descontrolado de hidrocarbonetos em um poço de petróleo (blowouts) são eventos com baixa probabilidade de ocorrência na indústria, porém têm impactos catastróficos. O evento de Macondo, com uma sonda afretada pela British Petroleum (BP) no Golfo do México (GoM), mostrou que um acidente dessa proporção tem um impacto significativo nas pessoas, no meio ambiente, nos ativos e na imagem da empresa. Portanto, uma resposta rápida e definitiva para o problema se mostra necessária. Dentre as possibilidades de se conter um derramamento de óleo ocasionado por um blowout, a mais efetiva para cessar o vazamento com segurança e abandonar definitivamente o poço em descontrole é o poço de alívio. Trata-se de um poço direcional perfurado a uma determinada distância do poço em blowout, respeitando-se critérios mínimos de segurança, com o objetivo de interceptar este no ponto estabelecido em projeto. Após a interceptação, injeta-se fluido de alta densidade que, quando preenche o poço que estava em blowout, gera uma contra-pressão capaz de cessar o influxo de hidrocarbonetos do reservatório. Quando é feita essa contra-pressão e o poço que estava em blowout estiver estável e sem influxo, injeta-se cimento pelo poço de alívio para que seja tamponado o reservatório e o poço possa ser abandonado de forma definitiva. No presente trabalho o enfoque é no amortecimento do poço em blowout através do poço de alívio e, portanto, parte-se do pressuposto que a detecção e interceptação do poço em influxo foi feita com sucesso no ponto desejado. A detecção, a interceptação e o abandono no poço em blowout não são estudados com detalhes. O trabalho é desenvolvido tomando como base um poço exploratório de gás a ser simulado, trabalhando os requisitos de pressão e vazão que melhor se adequam ao proposto. O objetivo do amortecimento do poço em blowout pelo poço de alívio é cessar o influxo descontrolado de forma eficaz, otimizando os parâmetros de pressão, vazão e volume de fluido às capacidades de sondas e embarcações disponíveis no mercado. Caso não seja possível o amortecimento variando a densidade do fluido injetado e a pressão nas bombas de injeção, parte-se para mudanças na estratégia de amortecimento como, por exemplo, variação no número de poços de alívio a serem perfurados para amortecer o poço em blowout ao mesmo tempo. Não será objetivo do presente trabalho a modificação no projeto do poço com o objetivo de facilitar o amortecimento. / [en] Accidents with uncontrolled influx of hydrocarbons into an oil well (blowouts) are events with a low probability of occurrence in the industry. Although, if they occur, the impact may be catastrophic. The Macondo event, with British Petroleum s rig (BP) in the Gulf of Mexico (GoM), showed that an accident of this proportion has a significant impact on people, environment and an image of the company. Therefore, a quick and definitive response for the problem is necessary. There are several possibilities to contain an oil spill caused by a blowout. However, the most effective way to safely plug and abandon (P and A) the blowout well is the relief well. This technique consists of the construction of a directional well at a certain distance from the blowout well, respecting minimum safety criteria, in order to intercept this at the point established in the project. After the interception, kill mud is pumped at high rates what makes a backpressure capable of killing the blowout well. When this backpressure is enough to kill the blowout well, cement is pumped through the relief well to plug and abandon permanently the well. In the present work, the objective is to kill the blowout well and we consider that detection and interception of the blowout well was successfully been made at the target point. Detection, interception and P and A of the blowout well are not covered in detail. This work is developed based on an exploratory gas well to be simulated, working the pump rate and pump pressure requirements that best fit in the proposed one. The purpose of well killing is to kill the well optimizing the parameters of pressure, flow and volume of fluid considering the rig and vessels available in the market. If well killing is not possible by varying the density of the kill mud and pump pressure it will be tried new strategies like changing the number of relief wells at the same time to be drilled killing the blowout well. It s not a purpose of this study to change the well design.

Conselho Nacional do Desenvolvimento Científico e Tecnológico (CNPq) / O principal objetivo deste estudo é desenvolver um compósito cerâmico e uma tecnologia de laboratório para a produção de materiais de construção com maior percentual de lodo galvânico, lodo de anodização do alumínio, areia de fundição e argila taguá. Os corpos de prova foram confeccionados com 20 g e 16 g em molde de 20 x 60 mm e prensados utilizando-se uma uniaxial de 10 MPa. Os corpos de prova foram sinterizados a temperaturas de 900, 950, 1000, 1050, 1100, 1150, 1200 e 1250°C durante 6 horas. Foram realizadas análises de densidade, perda ao fogo, FRX, DRX, MEV/EDS, TGA/DSC, retração linear após queima, absorção de água, resistência de ruptura à flexão e lixiviação, a fim de caracterizar as matérias primas e o material cerâmico desenvolvido. A concentração destes resíduos, utilizados como matérias-primas, variou nos seguintes limites: lodo galvânico 0-10%, lodo de anodização do alumínio 0- 75%, areia de fundição de 0-20% e a argila Taguá de 0-80%. Os valores de resistência de ruptura à flexão na composição 1 a 900 °C alcançaram 5,87 MPa e a 1250 °C alcançaram 12,99 MPa, na composição 7 a 900 °C – 1,40 MPa, e a 1250 °C – 26,82 MPa. Através de métodos de MEV, observou-se que a temperatura de 900 °C a interação das particulas é mecânica e a temperatura de 1250 °C esta interação tornou-se coesa e a argila funde-se transforma-se em um material semelhante ao vidro. Os resultados do ensaio de lixiviação apontaram que os materiais cerâmicos após a sinterização apresentaram traços de Pb, Cu, Al e Fe, tendo imobilizado apenas parte dos metais pesados analisados, o que os classifica como resíduos perigosos. Em comparação com as normas brasileiras, no quesito resistência, as cerâmicas atenderam aos parâmetros para uso em blocos cerâmicos para alvenaria estrutural nas categorias A, B e C e tijolos maciços comuns para alvenaria, respectivamente, no entanto, a imobilização de metais pesados carece de ajustes para que se alcance um material cerâmico ambientalmente amigável. / The main objective of this study is to develop a ceramic composite and laboratory technology for the production of building materials with higher percentage of galvanic sludge, aluminium anodizing sludge, foundry sand and clay Taguá. The bodies of proof (CPs) were made with 20 g and 16 g in 20 x 60 mm mould and with uniaxial press of 10 MPa. The CPs were sintered at temperatures of 900, 950, 1000, 1050, 1100, 1150, 1200 and 1250° C for 6 hours. Density analyses were performed, fire loss, FRX, DRX, SEM/EDS, TGA/DSC, linear firing shrinkage, water absorption, flexural strength and leaching in order to characterize raw materials and developed ceramic material. The concentration of these residues, that were used as raw materials, varied in the following boundaries: galvanic sludge 0-10%, aluminium anodizing sludge 0- 75%, 0-20% foundry sand and clay Taguá of 0-80%. The values of flexural strength in composition 1 were 900 °C reached 5.87 MPa and 1250 °C reached 12.99 MPa, and composition 7 to 900 °C – 1.40 MPa, and 1250 °C – 26.82 MPa. SEM to the temperature of 900 °C showed the interaction of particles is mechanical and to the one of 1250 °C exhibited the cohesive interaction and clay fusion produced a material similar to glass. The results of the leaching indicated that the ceramic materials after sintering showed traces of Pb, Cu, Al and Fe, having immobilised just part of heavy metals present in the composition, which classifies it as hazardous waste. In comparison with the Brazilian standards, resistance aspect met the requirement for use in ceramic blocks for structural masonry in categories A, B and C, and solid bricks for masonry, respectively, however, the immobilization of heavy metals requires adjustments to achieve an environmentally friendly ceramic material.

A utilização de resíduos industriais na produção de materiais pode mitigar os impactos gerados pelo agente gerador. A utilização na costrução civil de materiais gerados a partir de resíduos, minimizaria também os impactos gerados pela extração de recursos naturais para este setor. Os resíduos industriais utilizados nesta pesquisa são classificados como resíduos perigosos e, sendo a pesquisa sustentada na hipótese de que é possível produzir um material cerâmico para utilização na construção civil a partir de lodo de indústria de placa de circuito impresso, lama vermelha do processamento de bauxita e escória siderúrgica, foram produzidas composições cerâmicas utilizando estes resíduos como matéria prima. Os corpos de prova (CPs) foram confeccionados com 20g em molde de 20x60 mm e com prensa uniaxial de 5 MPa. Os CPs foram sinterizados à temperaturas de 800, 900, 1000, 1050, 1100 e 1150°C durante 6 horas. Foram realizadas análises de umidade, granulometria, densidade, perda ao fogo, FRX, DRX, MEV/EDS, retração linear de queima, absorção de água, resistência à flexão e lixiviação, a fim de caracterizar as matérias primas e o material cerâmico desenvolvido. Os resultados demonstram que houve fusão dos elementos que compõem as matérias primas. A composição que apresentou o melhor resultado alcançou 5,48 MPa de resistência à flexão, 4,57% de retração linear de queima, 2,06 de densidade e 19,94% de absorção de água. O resultado do ensaio de lixiviação aponta que o material cerâmico após a sinterização apresenta traços de Pb, tendo imobilizado apenas parte dos metais pesados analisados presentes na composição dos corpos de prova, o que o classifica como resíduo perigoso. Em comparação com as normas brasileiras, os aspectos de absorção de água e resistência atenderam aos requisitos para uso em blocos cerâmicos para alvenaria estrutural e nas categorias A, B e C de tijolos maciços comuns para alvenaria, respectivamente, no entanto, a imobilização de metais pesados carece de ajustes para que se alcance um material cerâmico inerte. / The use of industrial waste in the production of materials can mitigate the impacts generated by the generating agent. The use in civil construction of materials generated from waste, would also minimize the impacts generated by the extraction of natural resources for this sector. The industrial waste used in this research is classified as hazardous waste and the research is based on the hypothesis that it is possible to produce a ceramic material for use in civil construction from printed circuit board industry sludge, bauxite red processing sludge and steel slag, ceramic compositions using these residues as raw material were produced. The sample were made with 20g in mold 20x60 mm and with uniaxial press 5 MPa. The sample were sintered at temperatures of 800, 900, 1000, 1050, 1100 and 1150°C for 6 hours. Moisture tests were carried out, density, granulometry, loss on ignition, XRF, XRD, SEM/EDS, linear firing shrinkage, water absorption, flexural strength and leaching in order to characterize the materials and the ceramic material developed. The results show that there has been fusion of the components of the raw materials. The composition showed the best result achieved flexural strength 5.48 MPa, 4.57% of linear firing decrease, 2.06 density and 19.94% water absorption. The results of the leaching test indicate that the ceramic material after sintering presents traces of Pb, having immobilized only part of the analyzed heavy metals present in the composition of the test specimens, which classifies it as hazardous waste. In comparison with the Brazilian standards, the water absorption and resistance aspects met the requirements for use in ceramic blocks for structural masonry and in categories A, B and C of solid bricks common for masonry, respectively, however, the immobilization of metals is required to achieve an inert ceramic material.

Fundação Carlos Chagas Filho de Amparo a Pesquisa do Estado do Rio de Janeiro / The Amazon river, located in northernBrazil, discharges between 80,000 and 250,000 m3s-1 of water onto the adjacent shelf, creating a plume of brackish water that extends hundreds of kilometers away from the river mouth. This river also carries a large amount of fine sediments to the ocean where fluid mud has been found in the topset and upper foreset layers of the subaqueous delta formed on the mid-shelf. One of the main goals of this dissertation is to describe how turbulence and suspended sediment concentration vary along the Northern Channel of the Amazon river. Water column measurements were carried out in October 2008 at six anchor stations (P1, P3, P5, P6, P8 e P9) located seaward of the river mouth; P1 and P9 were 125 km apart. Each station was occupied during 13 hours during which current speed and direction were continuously sampled with a 600 kHz Teledyne-RDI ADCP; hourly profiles of temperature, salinity, turbidity and depth were also obtained. Water samples were collected for determination of Suspended Particulate Matter (SPM) concentration and calibration of the turbidity sensor. Current speed reached values above 1.5 m s1 in the along-channel direction (NE-SW); a remarkable ebb-flood asymmetry was observed and flows were strongly ebb-dominated. Throughout the water column, SPM concentration at stations P1 and P3 varied between 100 and 300 mg L1 in association with the presence of freshwater. In contrast, a strong salinity gradient was observed between stations P6 and P9, coinciding with the occurrence of concentrations of SPM above 10 g L-1 (fluid mud). At stations P3, P5 and P6, interface between freshwater from the Amazon river and salt water from the continental shelf, shear stresses wereestimated through four diferents methods: Reynolds, Turbulent Kinetic Energy (TKE), modified TKE and Quadratic Law; in the nearbed region (3 mab) the computed values varied between 0 and 3 Pa. At the three stations (P3, P5 and P6) the lowest and the highest shear stress values were obtained through, respectively, the Reynolds and the TKE methods. Over the whole water column turbulence intensity was estimated through the standard deviation of the turbulent component of the along-channel current velocity (root-mean square of u); from these values, it was estimated the turbulent dissipation of energy (G), whose values at 3 mab varied between zero and 20 s1.

En Nouvelle-Calédonie il y a une forte volonté politique pour diversifier l'aquaculture qui repose encore aujourd'hui sur la crevetticulture. Dans ce contexte le crabe de palétuvier est considéré comme une espèce à fort potentiel. Un des principaux verrous au développement de la carcinoculture en Nouvelle-Calédonie est la disponibilité d'un aliment granulé commercial. Ainsi le principal objectif de cette thèse est d'améliorer notre connaissance des besoins nutritionnels du crabe de palétuvier afin d'être en mesure de formuler un aliment équilibré pour son élevage. Cependant avant d'aborder les études nutritionnelles nous avons vérifié le nombre d'espèces de crabes de palétuvier présentes en Nouvelle-Calédonie.Nos résultats d'études morphologiques et génétiques de 63 individus provenant de 9 sites des côtes Ouest et Nord-Est de la Nouvelle-Calédonie ont confirmé l'existence d'une unique espèce commercialisée: Scylla serrata. C'est donc sur cette espèce que nous avons travaillé en nutrition avec deux séries expérimentales ayant pour objectifs: i) d'évaluer le concentré protéique de soja (CPS) en comparaison avec la farine de poisson comme principale source en protéines et ii) de déterminer le taux optimum d'incorporation du CPS pour la mue et la croissance tissulaire des animaux. Nous avons ainsi observé deux phases de croissance tissulaire au cours d'un cycle de mue (CM): une phase rapide (CTR) qui démarre après la mue et dure jusqu'au début de l'intermue (elle représente 30% du CM) suivi d'une phase de croissance lente (CTL) sur toute la durée de l'intermue et jusqu'à la mue suivante (elle représente 70% du CM). L'accumulation des protéines et des lipides au cours du CM a suivi le même profil de croissance tissulaire contrairement aux cendres qui ont augmenté de façon rapide durant 5 jours suivant l'ecdysis pour atteindre un plateau jusqu'à la prochaine mue. Les deux phases de croissance étaient corrélées avec une prise de l'aliment par les animaux maximale pendant les deux premières semaines suivant la mue. Elle a diminué de moitié sur les 5 semaines suivantes et s'est maintenue ensuite à un niveau de base jusqu'à la prochaine mue. L'énergie ingérée était allouée principalement à la croissance et à l'entretient respectivement durant les périodes CTR et CTL. Durant la phase de croissance lente, 28% de l'énergie ingérée étaient mise en réserve en prévision de la prochaine mue. Le remplacement de la farine de poisson par la CPS n'a pas modifié la croissance tissulaire,l'efficience de l'aliment et le bilan énergétique des animaux quelque soit la phase de croissance considérée. Le taux d'incorporation dans l'aliment de 42% de CPS a permis la meilleure croissance (fréquence de mue et croissance tissulaire, efficience de l'aliment et la rétention de l'énergie des protéines et des lipides. L'hypothèse d'une toxicité de l'ammonium issu de la dégradation des protéines en excès ou des facteurs antinutritionnels du soja est avancée pour expliquer les effets négatifs observés avec les aliments renfermant des taux d'incorporation élevés en CPS. En conclusion, nos travaux apportent des informations originales sur la croissance tissulaire et les dépenses énergétiques durant un cycle de mue et la capacité du crabe juvénile d'utiliser le CPS comme principale source de protéines. Sur ces bases nous somme en mesure de préconiser des contraintes nutritionnelles permettant de formuler un aliment équilibré sans farine de poissons pour l'élevage du crabe de palétuvier S.serrata. / In New Caledonia, there is the strong political will to diversify aquaculture which is mainly based on shrimp farming. In this context, mud crabs have been considered as a potential species for aquaculture development. One of the main constraints to develop crab farming is the availability of formulated feed. Thus, the main purpose of this thesis is to get information on the crab nutritional requirements in order to formulate a balanced diet. However, we had to clarify first how many species of mud crab were present in New-Caledonia. The result of our morphological and genetic investigations carried out on 63 specimens from 9 areas of the west and northeast coast of New-Caledonia confirmed that only one species, Scylla serrata, is commercialized in this country. Consequently, S. serrata was used in our nutritional study based on two experiments to: i) evaluate the soy protein concentrate (SPC) compared with the fishmeal as the main protein source and ii) determine the optimum level of SPC in the diet for molting and tissue growth. We observed two tissue growth phases within one molt cycle (MC): a fast tissue growth (FTG) occurred after ecdysis until early intermolt stage (30% of MC) which is followed by a slow tissue growth (STG) period from intermolt to ecdysis (70% of MC). Protein and lipid deposition followed the same trend than tissue growth while ash level increased quickly during five days after molt and then remained stable until the next molt. The two growth phases were correlated with the voluntary feed intakes (VFI) which was maximum during 2 weeks after ecdysis and then decreased by 50% over the five following weeks to reach a baseline until the next molt. Intake energy was allocated mainly for growth during FTG period and for maintenance during STG period. During STG, 28% of the ingested energy was accumulated for the next ecdysis. Replacement of fishmeal by SPC as main protein source did not affect tissue growth, efficiency of feed utilization and energy budget of crabs whatever the tissue growth period considered. The dietary SPC inclusion of 42% in the diet promoted growth (molt frequency and tissue growth), feed efficiency and retention of energy, protein and lipid. Hypothesis related to ammonia toxicity from catabolism of proteins in excess or anti-nutritional factors from soybean could explain the negative effects of higher inclusion of SPC in the diet for juvenile crabs. In conclusion, our work brings novel information on tissue growth, energy budget during a molt cycle and the ability of juvenile crab to use SPC as a main source of protein. On this basis we suggest to formulate nutritionally balanced diet without fishmeal to farm juvenile mud crabs S. serrata.

Cette thèse est dédié à l’étude de la problématique des interférences multi utilisateurs dans le système Argos et à la proposition des diverses techniques pour réduire les effets de ces interférences. Le système Argos est un système mondial de localisation et de collecte de données géo positionnées par satellite. Il permet à l’échelle mondiale de collecter et de traiter les données émises par des émetteurs installés sur la surface de terre. Ces émetteurs sont connus sous le nom de balises. Ces balises sont installées sur des voiliers, des stations météo, des bouées, ainsi que sur quelques animaux (phoques, penguins, etc.…). Le système Argos a été créé en 1978 par le Centre National des Études spatiales (CNES), l’agence spatiale américaine (NASA) et l’agence américaine d’étude de l’atmosphère et de l’océan (NOAA). Depuis sa création, le nombre de balises Argos n’a cessé d’augmenter afin de couvrir au mieux la couverture mondiale. Nous sommes orientés ainsi à la saturation de la bande d’émission et à la présence des interférences multi utilisateurs (MUI) provenant de la réception simultanée de plusieurs signaux émis par les balises. Cette MUI limite la capacité du système Argos et dégrade les performances en termes de Taux Erreur Bit (TEB). Actuellement, le système Argos n’est capable de traiter qu’un seul signal reçu à un instant donné. D’où, l’intérêt d’implanter des techniques au niveau du récepteur capable de réduire les effets des interférences et de traiter les signaux émis par toutes les balises. Plusieurs techniques de détection multi utilisateurs (MUD) ont été développées dans le cadre de cette problématique. Ces techniques sont principalement implantées dans les systèmes CDMA où des codes d’étalement sont utilisés afin de différencier entre les différents signaux. Ceci n’est pas le cas du système Argos où les signaux ne présentent pas des séquences d’étalement et que les bandes de fréquences pour ces différents signaux ne sont pas disjointes à cause de l’effet Doppler et donc, un recouvrement spectral au niveau du récepteur est très probable. Dans ce contexte, l’objectif du travail présenté dans cette thèse est d’étudier différentes techniques MUD appliquées au système Argos et d’évaluer ces techniques au niveau des performances en termes de TEB et de complexité d’implantation. Dans ce travail, nous présentons les différentes composantes du système Argos ainsi que son mode de fonctionnement. Ensuite, nous présentons la problématique dans le système Argos ainsi que les différentes solutions proposées. Parmi ces solutions, nous montrons celle basant sur l’implantation des techniques MUD au niveau du récepteur. Ces différentes techniques MUD sont alors présentées ainsi que les avantages et les inconvénients de chacune d’elles. Parmi les techniques possédant un bon compromis entre les performances d’une part et la complexité d’autre part, nous notons la technique d’annulation par série d’interférence (SIC). Dans cette technique, les signaux sont démodulés successivement suivant l’ordre décroissant des puissances. Cette technique nécessite une étape d’estimation des paramètres des signaux à chaque étape. L’impact d’une estimation imparfaite des différents paramètres est aussi étudié. Après l’étude des impacts des erreurs d’estimation, nous proposons des estimateurs adaptables au système Argos. Les performances de ces estimateurs sont obtenues en comparant les variances de leurs erreurs aux bornes de Cramer Rao (CRB). Enfin, nous terminons le travail par une conclusion générale des résultats obtenus et nous envisageons les perspectives des prochains travaux. / In our thesis, we investigate the application of multi user detection techniques to a Low Polar Orbit (LPO) satellite used in the Argos system. Argos is a global satellite-based location and data collection system dedicated for studying and protecting the environment. User platforms, each equipped with a Platform Transmitter Terminal (PTT), transmit data messages to a 850 km LPO satellite. An ARGOS satellite receives, decodes, and forwards the signals to ground stations. All PTTs transmit at random times in a 100 kHz bandwidth using different carrier frequencies. The central carrier frequency f0 is 401.65 MHz. Due to the relative motion between the satellite and the platforms, signals transmitted by PTTs are affected by both a different Doppler shift and a different propagation delay. Thus, the Argos satellite receives overlapping signals in both frequency and time domains inducing Multiple Access Interference (MAI). One common approach to mitigate the MAI problem is to implement Multi User Detection (MUD) techniques at the receiver. To tackle this problem, several MUD techniques have been proposed for the reception of synchronous and asynchronous users. In particular, the Successive Interference Cancelation (SIC) detector has been shown to offer a good optimality-complexity trade-off compared to other common approaches such as the Maximum Likelihood (ML) receiver. In an Argos SIC receiver, users are decoded in a successive manner, and the signals of successfully decoded users are subtracted from the waveform before decoding the next user. This procedure involves a parameter estimation step and the impact of erroneous parameter estimates on the performance of Argos SIC receiver has been studied. Argos SIC receiver has been shown to be both robust to imperfect amplitude and phase estimation and sensitive to imperfect time delay estimation. The last part of our work focuses on the implementation of digital estimators for the Argos system. In particular, we propose a time delay estimator, a frequency estimator, a phase estimator and an amplitude estimator. These estimators are derived from the ML principle and they have been already derived for the single user transmission. In our work, we adapt successfully these estimators for the multi user detector case. These estimators use the Non Data Aided (NDA) cases in which no a priori information for the transmitted bits is required. The performance of these different estimators are compared to the Cramer Rao Bound (CRB) values. Finally, we conclude in our work by showing the different results obtained during this dissertation. Also, we give some perspectives for future work on Argos system.

No description available.

Hydraulic fracturing operations utilized for shale gas production result in the generation of a large volume of flowback and produced water that contain suspended material, salts, hydrocarbons, metals, chemical additives, and naturally-occurring radioactive material. The water is impounded at drilling sites or treated off-site, resulting in significant generation of residual solids. These are either buried on site or are disposed in lined landfills. The objective of this study was to determine the levels of heavy metals and other elements of concern that will leach from these residual solids when placed in typical disposal environments. For this purpose, laboratory leaching experiments were employed wherein representative samples were brought into contact with a liquid to determine the constituents that would be leached by the liquid and potentially released into the environment. The samples used included sludge resulting from the physicochemical treatment of process water (TS), sludge solidified with cement kiln dust (SS), raw solids obtained by gravity separation of process water (RS), and drilling mud (DM). The samples were subjected to both single extraction (i.e. Shake Extraction Test, SET) and multiple extraction (i.e. Immersion Test, IT) leaching tests. For the shake extraction test, samples were mixed with a specific amount of leaching solution without renewal over a short time period. In the immersion test, samples were immersed in a specific amount of leaching solution that was periodically renewed over a longer period of time. For both these tests, analyses were performed on the filtered eluate. The tests were performed as per standards with modifications. Distilled de-ionized water, synthetic acid rain (pH ~ 4.2), weak acetic acid (pH ~ 2.88), and synthetic landfill leachate were used as leaching solutions to mimic specific disposal environments. Alkali metals (Li, K, Na), alkaline earth metals (Ba, Ca, Mg, Sr) and a halide (Br), which are typically associated with Marcellus shale and produced waters, leached at high concentrations from most of the residual solids sample. The SS sample, due to its stabilization with CKD, had a lower extraction efficiency as compared to the unconsolidated TS and RS samples. In EF 2.9 and EF SLL, the leaching took place under acidic conditions, while for EF DDI and EF 4.2, the leaching occurred in alkaline conditions. EF 2.9 and EF SLL were determined to be the most aggressive leaching solutions, causing the maximum solubility of most inorganic elements. Thus, high amounts of most EOCs may leach from these residual solids in MSW landfills disposed under co-disposal conditions. Agitation, pH and composition of the leaching solution were determined to be important variables in evaluating the leaching potential of a sample. The results of this study should help with the design of further research experiments being undertaken to develop environmentally responsible management/disposal strategies for these residual solids and also prove useful for regulatory authorities in their efforts to develop specific guidelines for the disposal of residuals from shale gas production operations. / Master of Science

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