Passive samplers can be used to determine time-integrated patterns of water chemistry at one or many locations throughout a stream network while minimizing cost and sampling time. A passive flux meter (PFM) simultaneously estimates time-averaged water and solute mass fluxes in flowing water. PFMs have been used in groundwater to quantify contaminant flux but have been used only very recently in streams. In this study, PFMs were deployed in the surface and subsurface of headwater stream channels to examine the efficacy of the device to quantify mean concentrations of calcium, aluminum, and sulfur in streams of the Hubbard Brook Experimental Forest in New Hampshire, USA. In general, the PFM estimates of surface and subsurface stream chemistry were more accurate when flow rates were higher and more water passed through the PFM. During the lowest flows, PFMs overpredicted concentrations by 50 to 800%. In estimating calcium concentrations, 5 PFMs were within 10% of grab sample concentrations and 7 PFMs were within 30% of grab sample concentrations out of a total of 35 comparisons. Likewise, for sulfur concentrations, 4 PFMs were within 10% of grab sample concentrations and 7 PFMs were within 30% of grab sample concentrations out of 35 comparisons. Concentrations of aluminum were too low to be quantified above 90% confidence. PFMs calculated a lower cumulative discharge through the surface water PFMs than through the subsurface which may be explained by flow divergence around the sampler. Changes to PFM design and shorter deployment times are proposed to increase the efficacy of the PFM. / Master of Science / Passive sampling of headwater streams has advantages over traditional water sampling in quantifying stream water chemistry over time and space, while minimizing cost and sampling time. A passive flux meter (PFM) is a sampler that estimates local time-averaged discharge of water and time-averaged solute amount in flowing water without the need for constant monitoring, maintenance, or power sources. PFMs have been used in groundwater systems to quantify contaminant concentrations but have only been used very recently in streams or in the sediments below streams. In this study, PFMs were installed in headwater streams and the shallow sediments below the streams to examine the ability of the device to quantify the natural water chemistry. Concentrations of calcium, aluminum, and sulfate were evaluated in streams of the Hubbard Brook watershed in New Hampshire, USA. Concentrations of aluminum were too low to be quantified. In general, the PFM estimates of surface and subsurface stream chemistry were more accurate when flow rates were higher and more water passed through the PFM. During the lowest flows, PFMs overestimated stream concentrations. PFMs installed in small streams measured more total volume through the device than PFMs installed in sediments below the streams. PFM design may have had an impact on these results. Changes to PFM design and shorter deployment times are proposed to increase the efficacy of the PFM

Dichloro-diphenyl-trichlorethane (DDT) is a chemical used in malaria control through indoor residual spraying (IRS) and has saved numerous lives in the past six decades. DDT use is restricted/banned under the Stockholm Convention on Persistent Organic Pollutants. Passive air sampling using polyurethane foam was conducted in South Africa to evaluate the presence and trends of DDT and its metabolites. Three sampling sites were used, namely, Barberspan Nature Reserve (rural agricultural), Vanderbijlpark (urban industrial) and Molopo Nature Reserve (isolated nature reserve). Sampling was conducted for a period of one year in 2008. Back trajectories from the three sampling sites were generated using HYSPILT to determine the sources of DDT metabolites to the sampling areas. Forward trajectories were also generated to determine the movement, distribution, and fate of DDT from the areas under Indoor residual spray of DDT for malaria control in South Africa and Swaziland. Chemical analysis was conducted by the RECETOX (Mazaryk University) in the Czech Republic. DDT metabolites (o,p’-DDE, p’p’-DDE, o.p’-DDD, p,p’-DDD, o,p’-DDT p,p’-DDT) were analysed using a GC-ECD (HP 5890). Vanderbijlpark had the highest concentrations of DDT metabolites throughout the year. Barberspan had the second highest concentration and Molopo the least. Seasonal changes in concentration were much the same at the three sites. %p,p’-DDT of ΣDDT is consistent with IRS spraying months in South Africa and Swaziland. A combinations of backward and forward trajectories, together with the temporal pattern of change of the %p,p’-DDT of ΣDDT support the deduction that DDT sampled from the three study sites (to some degree) came from IRS areas in South Africa and Swaziland. The presence of DDT in Molopo Nature Reserve and Barberspan is evidence of long-range transportation over dry semi-desert areas. Back-trajectories indicate the possible source of DDT were the IRS areas in the provinces of Limpopo, Mpumalanga, and KwaZulu-Natal. Some air masses to the sampling sites came from the sprayed areas. The forward trajectories also revealed that the DDT sprayed during IRS could undergo LRT. The DDT metabolites were able to travel to neighbouring countries such as Mozambique, Namibia, Zimbabwe and Botswana. / MSc (Environmental Sciences), North-West University, Potchefstroom Campus, 2013

Nuclear reactors with improved safety concepts are currently being studied within the nuclear engineering community, with a focus on passive safety features. One of these reactor concepts is the Very High Temperature gas-cooled Reactor (VHTR) of which the Reactor Cavity Cooling Systems (RCCS) is seen as an integral and crucial part of the passive safety concept. Considerable validation and development of the necessary software tools is required to perform analysis and designs of these future reactor concepts. The primary objective of this study is to establish a methodology for the creation of an integrated system level process model of a typical air-cooled RCCS in Flownex®, and to illustrate its applicability by simulating different scenarios that illustrate the operational characteristics of such a system. For this purpose, the existing RCCS conceptual design that is being studied by the KAERI was used as the case study. As a start, selected case studies were performed to verify that the Flownex® models were set up correctly to perform natural circulation flows, both in steady and transient conditions, and with radiation, convection and conduction taking part. These are the major typical physical phenomena in the RCCS. The models were compared with EES (Engineering Equation Solver) models of the same geometries and specifications. There was a good agreement between Flownex® and EES model results. After this verification, a simulation model of the integrated RCCS system was developed. The Flownex® models were applied to model selected possible operational scenarios. The major observations from the results are that: - The RCCS carries with it enough heat to the ambient such that the concrete wall temperature is maintained below the benchmark value of 65°C for the different boundary conditions imposed. - The RCCS maintains its functionality even with three quarters of the risers blocked or in the event that there is a break in one of the chimney pipes. / MIng (Nuclear Engineering), North-West University, Potchefstroom Campus, 2015

Dichloro-diphenyl-trichlorethane (DDT) is a chemical used in malaria control through indoor residual spraying (IRS) and has saved numerous lives in the past six decades. DDT use is restricted/banned under the Stockholm Convention on Persistent Organic Pollutants. Passive air sampling using polyurethane foam was conducted in South Africa to evaluate the presence and trends of DDT and its metabolites. Three sampling sites were used, namely, Barberspan Nature Reserve (rural agricultural), Vanderbijlpark (urban industrial) and Molopo Nature Reserve (isolated nature reserve). Sampling was conducted for a period of one year in 2008. Back trajectories from the three sampling sites were generated using HYSPILT to determine the sources of DDT metabolites to the sampling areas. Forward trajectories were also generated to determine the movement, distribution, and fate of DDT from the areas under Indoor residual spray of DDT for malaria control in South Africa and Swaziland. Chemical analysis was conducted by the RECETOX (Mazaryk University) in the Czech Republic. DDT metabolites (o,p’-DDE, p’p’-DDE, o.p’-DDD, p,p’-DDD, o,p’-DDT p,p’-DDT) were analysed using a GC-ECD (HP 5890). Vanderbijlpark had the highest concentrations of DDT metabolites throughout the year. Barberspan had the second highest concentration and Molopo the least. Seasonal changes in concentration were much the same at the three sites. %p,p’-DDT of ΣDDT is consistent with IRS spraying months in South Africa and Swaziland. A combinations of backward and forward trajectories, together with the temporal pattern of change of the %p,p’-DDT of ΣDDT support the deduction that DDT sampled from the three study sites (to some degree) came from IRS areas in South Africa and Swaziland. The presence of DDT in Molopo Nature Reserve and Barberspan is evidence of long-range transportation over dry semi-desert areas. Back-trajectories indicate the possible source of DDT were the IRS areas in the provinces of Limpopo, Mpumalanga, and KwaZulu-Natal. Some air masses to the sampling sites came from the sprayed areas. The forward trajectories also revealed that the DDT sprayed during IRS could undergo LRT. The DDT metabolites were able to travel to neighbouring countries such as Mozambique, Namibia, Zimbabwe and Botswana. / MSc (Environmental Sciences), North-West University, Potchefstroom Campus, 2013

Nuclear reactors with improved safety concepts are currently being studied within the nuclear engineering community, with a focus on passive safety features. One of these reactor concepts is the Very High Temperature gas-cooled Reactor (VHTR) of which the Reactor Cavity Cooling Systems (RCCS) is seen as an integral and crucial part of the passive safety concept. Considerable validation and development of the necessary software tools is required to perform analysis and designs of these future reactor concepts. The primary objective of this study is to establish a methodology for the creation of an integrated system level process model of a typical air-cooled RCCS in Flownex®, and to illustrate its applicability by simulating different scenarios that illustrate the operational characteristics of such a system. For this purpose, the existing RCCS conceptual design that is being studied by the KAERI was used as the case study. As a start, selected case studies were performed to verify that the Flownex® models were set up correctly to perform natural circulation flows, both in steady and transient conditions, and with radiation, convection and conduction taking part. These are the major typical physical phenomena in the RCCS. The models were compared with EES (Engineering Equation Solver) models of the same geometries and specifications. There was a good agreement between Flownex® and EES model results. After this verification, a simulation model of the integrated RCCS system was developed. The Flownex® models were applied to model selected possible operational scenarios. The major observations from the results are that: - The RCCS carries with it enough heat to the ambient such that the concrete wall temperature is maintained below the benchmark value of 65°C for the different boundary conditions imposed. - The RCCS maintains its functionality even with three quarters of the risers blocked or in the event that there is a break in one of the chimney pipes. / MIng (Nuclear Engineering), North-West University, Potchefstroom Campus, 2015

Published Article / The paper presents a critique of passive and active thermal comfort strategies. Extensive review of literature on passive thermal comfort energy efficiency interventions and their benefits was under taken. The paper explains the correlation between climatic comfort and energy efficiency. The applicability of the energy management process in ensuring energy efficiency is presented. Passive thermal comfort energy efficiency interventions have been seen to provide thermal comfort as well as energy efficiency. Their major shortcoming is their disability to work in all kinds of weather, heating in the winter and cooling in the summer. There is need to optimize passive thermal comfort energy efficiency interventions so that they provide heating in the winter and cooling in the summer.

No description available.

published_or_final_version / Community Medicine / Master / Master of Public Health

This thesis investigates the improvements that can be made to Bayesian passive sonar tracking in the context of active-passive sonar data fusion. Performance improvements are achieved by exploiting the prior information available within a typical Bayesian data fusion framework. The algorithms developed are tested against both simulated data and data measured during the SEABAR 07 sea trial. Results show that the proposed approaches achieve improved detection, decreased estimation error, and the ability to track quiet targets in the presence of loud interferers. / text

This thesis summarizes ongoing work to develop low-cost, wireless, resonant sensor array that can be used to monitor corrosion in infrastructure systems. A magnetically coupled sensor array is presented and analyzed using circuit model. The array acts as a magneto-inductive waveguide and the impedance discontinuities caused by corrosion (or other defects) lead to reflection. The relationship between the relative position of defects and pass band characteristics is investigated, providing a technique to determine the location of targets. A configuration for increased sensitivity and a method for defect localization are presented. / text