In order to preserve groundwater as a viable source of drinking water, remedial measures must be applied where appropriate. The application of the various remedial technologies is site and contaminant dependent. Differing geology, subsurface soil, groundwater geochemistry, type of contaminant present, cost and even accessibility to the site are all considerations when selecting an appropriate remedial system. At many sites oxygen is a limiting factor for aerobic degradation of many organic compounds like methyl tert butyl ether (MTBE) and hydrocarbons found in diesel and fuel oil, etc. (Nyer et al, 2002). Mechanisms limiting the success of getting the oxygen out of the passive release well include: · Slow chemical diffusion of oxygen in water; · Limited cross section of the groundwater flowing into the well and advecting oxygenated water back into the aquifer; and · Generally weak transverse dispersion, both horizontal and vertical, during subsequent advection of the oxygenated water in the porous media. These issues must be recognized even in the design of a passive release well remediation system. For example, a typical remedial objective is to deliver dissolved oxygen across the width and vertical extent of a contaminant zone in an aquifer. The width of the oxygen plume around the injection well defines how many oxygen-release wells are required to create a curtain of oxygen. Cost-effective design dictates fewer wells, while effective coverage may dictate more wells placed closer together. Thus, understanding the transverse width over which significant oxygen is passively released to the aquifer (the “radius of influence”) is a critical design parameter and the focus of this thesis. Due to the difficulty in getting a passively released dissolved oxygen plume to transversely encompass the total width of a contaminant plume, other more efficient means of introducing oxygen into the subsurface are required. Injecting amended water directly into a release well would increase the transverse distance in which dissolved oxygen would spread. A series of experiments were conducted at CFB Borden to assess the efficacy of an oxygen releasing technology called the iSOC™. The experiments were all conducted in the same manner, by connecting a tank of oxygen to the iSOC™ unit, which then was placed in a release well and allowed to run in experiment 1 for 103 days, experiment 2 for 132 days and experiment 3 for 29 days. iv Dissolved oxygen concentrations were measured at varying time intervals throughout each experiment using an Orion dissolved oxygen probe. Results of each of the three experiments were very similar in that dissolved oxygen was only detected in a very narrow plume (10 cm to 25 cm in width) within 1 m of the release well. The presence of BTEX, BOD and COD within the groundwater and soil at the site were investigated to assess if presented a significant enough sink for the oxygen and thereby limiting the transverse growth of the dissolved oxygen plume. Groundwater results indicated that while dissolved oxygen was utilized for BTEX degradation and to overcome the natural oxygen demand (both BOD and COD) at the site, the amount of oxygen released into the aquifer would have satisfied both of these processes. The COD of the soil at the site presented a higher oxygen demand than the groundwater and presented a greater limiting factor to the transverse growth of the oxygen plume. By releasing oxygen passively with the iSOC™ only a small transverse portion of the Borden aquifer was likely influenced. This limitation has been noted in general for passive release technologies (Wilson & Mackay, 1995). While the iSOCÔ technology develops very high oxygen levels in the groundwater in the release well, it does not overcome the hydrogeological constraint of limited transverse dispersion. Thus, a high oxygen concentration is delivered to a very narrow segment of the aquifer. Overall, transverse dispersion has a minimal impact on a passively release oxygen plume, particularly in close proximity to the release well, but once the plume has migrated a distance away from the release well the effect of transverse dispersion increases. The oxygen demand of an aquifer can also limit the effect of transverse and longitudinal dispersion. If a site has a high chemical or biological oxygen demand the released gas will be consumed before dispersion can have an effect on the plume. By injecting nutrient rich water into a release well the water will forcibly overcome any influence transverse dispersion will have in and around a release well, thereby relying on longitudinal dispersion to create a larger area for contaminant degradation to occur.

In order to preserve groundwater as a viable source of drinking water, remedial measures must be applied where appropriate. The application of the various remedial technologies is site and contaminant dependent. Differing geology, subsurface soil, groundwater geochemistry, type of contaminant present, cost and even accessibility to the site are all considerations when selecting an appropriate remedial system. At many sites oxygen is a limiting factor for aerobic degradation of many organic compounds like methyl tert butyl ether (MTBE) and hydrocarbons found in diesel and fuel oil, etc. (Nyer et al, 2002). Mechanisms limiting the success of getting the oxygen out of the passive release well include: · Slow chemical diffusion of oxygen in water; · Limited cross section of the groundwater flowing into the well and advecting oxygenated water back into the aquifer; and · Generally weak transverse dispersion, both horizontal and vertical, during subsequent advection of the oxygenated water in the porous media. These issues must be recognized even in the design of a passive release well remediation system. For example, a typical remedial objective is to deliver dissolved oxygen across the width and vertical extent of a contaminant zone in an aquifer. The width of the oxygen plume around the injection well defines how many oxygen-release wells are required to create a curtain of oxygen. Cost-effective design dictates fewer wells, while effective coverage may dictate more wells placed closer together. Thus, understanding the transverse width over which significant oxygen is passively released to the aquifer (the “radius of influence”) is a critical design parameter and the focus of this thesis. Due to the difficulty in getting a passively released dissolved oxygen plume to transversely encompass the total width of a contaminant plume, other more efficient means of introducing oxygen into the subsurface are required. Injecting amended water directly into a release well would increase the transverse distance in which dissolved oxygen would spread. A series of experiments were conducted at CFB Borden to assess the efficacy of an oxygen releasing technology called the iSOC™. The experiments were all conducted in the same manner, by connecting a tank of oxygen to the iSOC™ unit, which then was placed in a release well and allowed to run in experiment 1 for 103 days, experiment 2 for 132 days and experiment 3 for 29 days. iv Dissolved oxygen concentrations were measured at varying time intervals throughout each experiment using an Orion dissolved oxygen probe. Results of each of the three experiments were very similar in that dissolved oxygen was only detected in a very narrow plume (10 cm to 25 cm in width) within 1 m of the release well. The presence of BTEX, BOD and COD within the groundwater and soil at the site were investigated to assess if presented a significant enough sink for the oxygen and thereby limiting the transverse growth of the dissolved oxygen plume. Groundwater results indicated that while dissolved oxygen was utilized for BTEX degradation and to overcome the natural oxygen demand (both BOD and COD) at the site, the amount of oxygen released into the aquifer would have satisfied both of these processes. The COD of the soil at the site presented a higher oxygen demand than the groundwater and presented a greater limiting factor to the transverse growth of the oxygen plume. By releasing oxygen passively with the iSOC™ only a small transverse portion of the Borden aquifer was likely influenced. This limitation has been noted in general for passive release technologies (Wilson & Mackay, 1995). While the iSOCÔ technology develops very high oxygen levels in the groundwater in the release well, it does not overcome the hydrogeological constraint of limited transverse dispersion. Thus, a high oxygen concentration is delivered to a very narrow segment of the aquifer. Overall, transverse dispersion has a minimal impact on a passively release oxygen plume, particularly in close proximity to the release well, but once the plume has migrated a distance away from the release well the effect of transverse dispersion increases. The oxygen demand of an aquifer can also limit the effect of transverse and longitudinal dispersion. If a site has a high chemical or biological oxygen demand the released gas will be consumed before dispersion can have an effect on the plume. By injecting nutrient rich water into a release well the water will forcibly overcome any influence transverse dispersion will have in and around a release well, thereby relying on longitudinal dispersion to create a larger area for contaminant degradation to occur.

The graphene-polymer SA thin film using solution blending method and atomic layer graphene as saturable absorber (SA) used to generate femtosecond laser pulse were measured. Stable soliton-like pulses with the pulsewidth of 403 fs and 432 fs, the spectral linewidth of 6.32 nm and 6.16 nm, and the time-bandwidth product of 0.315 and 0.329 using graphene-PVA film and atomic layer graphene as SA were achieved, respectively, in mode-locked Er-doped fiber ring laser. The graphene-PVA SA suffered from larger loss caused by graphene flake aggregating, while the atomic layer graphene had smaller nonsaturable loss which exhibited lower mode locking threshold power. Atomic layer graphene also had stable fabricated process and controllable modulation depth depended on its layer numbers. To compare the mode locking performance of single wall carbon nanotubes (SWCNTs) and graphene SA, the same solution blending fabricated sample was used. Under similar nonsaturable loss and modulation depth, the SWCNTs SA with optimized concentration of 0.5wt% and thickness of 188£gm had shortest pulsewidth of 440 fs and 3-dB spectral linewidth of 6 nm. The shortest pulsewidth of 403 fs and broad spectral linewidth of 6.32 nm was obtained using graphene SA with concentration of 6.25wt% and thickness of 18£gm. Graphene has broad band absorbance and larger modulation depth, the experimental result indicates that graphene SA can generate shorter pulse and has chance to become the potential candidate of SA.

The dependence of single-wall carbon nanotubes-based saturable absorber (SWCNTs SA) on concentration and thickness for mode-locked laser pulse formation is comprehensively investigated. The peak absorption wavelength of SWCNTs SA is engineered within the gain band-width of erbium-doped fiber centered near 1550 nm. The optima full-width half-maximum (FWHM) of pulses was obtained as the concentrations of SWCNTs SA was 0.05 wt%. This indicates that the laser pulse become shorter as the concentration of SWCNTs SA increases. The result also showed that the FWHM of pulses from 3.43 to 1.85 ps were found as the thickness of SWCNTs SA increased from 8 to 100 um. This also indicates that the laser pulse become shorter as the thickness of SWCNTs SA increases. However, the pulse width significantly broadened as concentration increased to 0.1 wt% and became stable as thickness of SWCNTs SA increased from 100 to 264 um for passively mode-locked lasers. An in-depth study on the optimum fabrication of concentration and thickness of SWCNTs SA for laser pulse formation may allow developing a cost-effective mode-locked laser with high performance as well as broadly benefit to the utilization of many other low-cost nanodevices.

Compared with Nd:YAG, the traditional high power solid state laser gain medium, Yb:YAG has less quantum defect, no excited state absorption, and longer fluorescence lifetime, which makes it suitable for Q-switched laser. In addition, concentration quenching is absent in Yb:YAG, higher concentration of active ion makes the thickness of gain medium thinner. For ring cavities, the necessity of symmetrical beam path is important, a thinner Yb:YAG crystal can reduce the shift of optical beam path and avoids cavity unstability. Thus, Yb:YAG is suitable for the two-mirror ring cavity. In this study, a compact and efficient Yb:YAG ring laser with 50.3% slope efficiency was demonstrated. And the Yb:YAG ring laser performances influenced by thermal effect was analyzed and compared to that of Nd:YAG ring laser. The polarization of ring lasers with different configurations were also discussed. In manufacturing process, the coating design on gain medium and laser mirrors were introduced. The advantages of passively Q-switched laser are efficient, compact, simple setup and no complicated driving circuits. They make passively Q-switched laser suitable for various applications, such as nonlinear optics, medical treatment, micromachining, material processing, and range finder. Due to spontaneous noise from the gain medium, conventional passively Q-switched laser has large timing jitter. This study is to build up a passively Q-switched Yb:YAG/Cr4+:YAG ring laser with lower timing jitter. At present, a Q-switched ring laser with a peak power of 208 W and a pulse width of 33 ns, was developed. Its slope efficiency is 18.1% with a timing jitter of 11.9%. To our knowledge, this is the first passively Q-switched Yb:YAG/Cr4+:YAG ring laser.

Passive loading of a specimen is a relatively cheap method to use in fracture mechanical testing compared to an actively loaded specimen. For stress corrosion cracking testing it is easier to use a passively loaded specimen since the specimen easily can be placed in a specific corrosive environment. The passive method lacks information about the crack growth over time and the load can not be regulated during the test to ensure crack growth. This thesis work was mainly about finding a specimen with a region of constant KI to ensure crack growth without the need of controlling the load and to find a way to estimate the crack growth over time. The work is based on Linear Elastic Fracture Mechanics and the Finite Element Method. The thesis work resulted in a specimen with constant KI in the region 23/50 ≤ a/W ≤ 33/50 of crack growth and an equation was found to describe the relation between the crack propagation and the strain measured on the specimens back face. / Passiv belastning av en provstav är en relativt billig metod att använda för brottmekanisk provning jämfört med en aktivt belastad provstav. En passivt belastad provstav är enklare att använda vid provning av spänningskorrosion då provstaven enkelt kan placeras i en specifik korrosiv miljö. Den passiva metoden är bristande i information om spricktillväxen över tid och belastningen på provstaven kan inte justeras för att upprätthålla fortsatt spricktillväxt under provningens gång. Detta examensarbete syftade till att ta fram en provstav med ett spricktillväxtomrade med konstant KI för fortsatt spricktillväxt vid konstant belastning samt att hitta en metod för att uppskatta spricktillväxten över tid. Arbetet är baserat på linjärelastisk brottmekanik och finita elementmetoden. Arbetet resulterade i en provstav med konstant KI i spricktillväxtområdet 23/50 ≤ a/W ≤ 33/50 och en relation mellan spricktillväxt och töjningen som mäts på provstavens baksida.

The research presented in this thesis regards walking of quadruped robots, and particularly the walking of the Warp1 robot. The motivation for the robot is to provide a platform for autonomous walking in rough terrain. The thesis contains six papers ranging from development tools to actuation of robot legs. The first paper describes the methods and tools made for control development. These tools feature: programming of the robot without low level coding (C-code); that the controller has to be built only once for simulation and experiments; and that names of variables and constants are unchanged through the chain of software Maple -- Matlab -- Simulink -- Real~Time~Workshop -- xPC--Target. Three controllers, each making the robot walk are presented. The first controller makes the robot walk using the crawl gait. The method uses static stability as method for keeping balance and the instantaneous trunk motions are given by a concept using the so called weight ratios. A method for planning new footholds based on the positions of the existing footholds is also proposed and the controller experimentally verified. The second walking controller shows that the robot also can walk dynamically using the trot gait. The method proposed uses information from ground contact sensors on the feet as input to control balance, instead of, which is common, inertial sensors. It is experimentally verified that Warp1 can trot from level ground onto a slope and turn around while staying balanced. The main ideas of these two walking controllers are fused in the third which enables smooth transitions between crawl and trot. The idea of using the ground contact sensors from the first controller is here used to estimate the position of the center of mass. This controller uses weight ratios in the gait crawl as well as in the dynamic gait trot. Hence, the method of using weight ratios is not only useful for static stability for which it was originally intended. The controller is experimentally verified on Warp1. The Warp1 robot weighs about 60 kg, has 0.6 m long legs with three actuated joints on each. The speed and strength is sufficient only for slow walking, even though the installed power indicates that it should be enough for faster walking. The reason is that a walking robot often needs to be strong but slow when the feet are on the ground and the opposite when in the air. This can not be achieved with the motors and transmissions currently used. A transmission called the passively variable transmission (PVT) is proposed which enhance motor capabilities of robot joints. It is elastic, nonlinear and conservative. Some general properties for elastic transmissions are derived such that they can be compared with conventional transmissions. The PVT gives strong actuation at large loads and fast actuation at small loads. The proposed transmission is compared to a conventional transmission for a specific task, and the result is that a smaller motor can be used. / QC 20100831

Valet mellan aktiv respektive passiv fondförvaltning har sedan länge varit en omdiskuterad fråga inom privata fondsparandet. På senare tid har frågan kommit att återaktualiserat efter att de aktivt förvaltade storfonderna Allemansfond komplett och Kapitalinvest anklagats för vilseledande marknadsföring, då de inte har generat en högre avkastning än den generella marknaden. Inom den akademiska världen har erkända forskare och sedermera pristagare av Sveriges Riksbanks pris i ekonomisk vetenskap till Alfred Nobels minne, påvisat att aktivt förvaltade fonder inte kan generera en högre avkastning med hänsyn till förvaltningsavgifterna. Utifrån förvaltningsavgifterna påvisade betydelse har vi valt att studera effekten av de rabatterade förvaltningsavgifterna, inom Premiepensionssystemet. Studiens syfte är således att under tidsperioden, 1 januari 2004 till 31 december 2013, analysera om aktiv förvaltade fonder har genererat en högre riskjusterad avkastning än passivt förvaltade fonder, då hänsyn tagits till de rabatterade förvaltningsavgifterna. Studien baserades på dagliga marknadsnoteringar av 174 aktivt förvaltade premiepensionsfonder och årliga förvaltningsavgifter.  Vidare använde vi oss av ett globalt aktiemarknadsindex, MSCI World, som utifrån definitionen av passivt förvaltade fonder var synonymt med studiens jämförelseindex. I enlighet med studiens syfte använde vi oss av det riskjusterade avkastningsmåttet Sharpekvot för att kunna besvara studiens frågeställning.  Resultatet av studien påvisade att aktivt förvaltade fonder har genererat en högre avkastning än passivt förvaltade fonder då hänsyn tagits till förvaltningsavgifter. Då även fondernas risktagande togs i anspråk blev resultatet det motsatta och vi kan därigenom konstatera att aktivt förvaltade fonder har generat en lägre riskjusterad avkastning är passivt förvaltade fonder. Vidare har vi även kunnat konstatera att aktivt förvaltade fonder med låga förvaltningsavgifter har generat en högre såväl avkastning som riskjusterad avkastning än aktivt förvaltade fonder med höga förvaltningsavgifter. / The choice between active and passive fund management has long been a contentious issue within the private mutual fund investments. Lately, the issue has been widely discussed since the actively managed funds Allemansfond komplett and Kapitalinvest was accused of misleading marketing, since their performance has not overachieved the return of the general market. In the academic world, recognized scholars and later Laureate of the Sveriges Riksbank Prize in Economic Sciences in Memory of Alfred Nobel, has demonstrated that actively managed funds cannot generate a higher return with regard to management fees. Based on the importance of the management fees, we have chosen to study the effect of the discount management fees, within the Premiepensionssystemet. Therefore the study's objective is to analyse whether active managed funds have generated higher risk-adjusted returns than passively managed funds, reduced for the discounted management fees. The study will be limited to analyse the period between the 1st January 2004 to 31th December 20103 The study was based on daily market quotations of 174 actively managed Premiepensionsfonder and annual management fees. Furthermore, we used a global stock market index, MSCI World, by the definition of passively managed funds that was synonymous with the study's benchmark. In accordance with the study’s purpose, we used the risk-adjusted performance measure Sharpe ratio in order to answer the research question. The results of this study demonstrated that actively managed funds have generated higher returns than passively managed funds, reduced for the discounted management fees. When the funds' risk taking was committed, the result is the opposite, and we can thus conclude that actively managed funds have yield a lower risk-adjusted returns than passively managed funds. Furthermore, we also noted that actively managed funds with low management fees has generated higher returns as well as risk-adjusted returns than actively managed funds with high management fees.

Du fait de leur compacité, leur robustesse et leur faible coût, les microlasers impulsionnels nanosecondes constituent des sources particulièrement attractives pour de nombreux systèmes de détection et d'analyse, en particulier les cytomètres en flux ou les dispositifs pour la spectroscopie CARS (Coherent Raman Anti Stokes Scattering). Cependant, ces applications nécessitent des performances améliorées en ce qui concerne la gigue temporelle et la cadence de répétition accessible. Dans sa première partie, cette thèse propose des solutions originales pour atteindre les performances requises à partir de microlasers passivement déclenchés, grâce à la mise en oeuvre d'une cavité hybride couplée, pompée par une onde modulée en intensité. Une cadence de répétition supérieure à 30 kHz avec une gigue demeurant inférieure à 200 ns est atteinte. Le potentiel de microlasers à fibres déclenchés par modulation du gain pour monter en cadence est aussi évalué, montrant que des impulsions à faible gigue, à une cadence de plus de 2 MHz peuvent être produites. Enfin, la dernière partie est consacrée à la mise au point et à l'exploitation d'un nouveau système de spectroscopie CARS assisté par une excitation électrique haute tension. Ce dispositif, réalisé à partir d'un microlaser amplifié, permet de s'affranchir du bruit de fond non résonnant des mesures et de réaliser une analyse spectroscopique fine de la réponse de différents milieux d'intérêt sous champ continu ou impulsionnel, pouvant conduire à une nouvelle méthode de microdosimétrie de champ. Diverses applications, dont la granulométrie à l'échelle micro ou nanométrique ou l'identification de marqueurs pour la biologie, sont démontrées. / Thanks to their compactness, robustness and low cost, pulsed nanosecond microlasers are particularly attractive sources for different detection and analysis systems, particularly flow cytometers or devices for CARS (Coherent Anti Raman Stokes Scattering) spectroscopy. However, these applications require reduced time jitter and increased repetition rate. The first part of this thesis proposes novel solutions to achieve the required performance from passively Q-switched microlasers, which are based on an hybrid coupled-cavity and intensitymodulated pump wave. A repetition rate greater than 30 kHz with jitter remaining lower than 200 ns is reached. Pulsed fiber microlasers operating by gain switching are also studied, showing that pulses with low timing jitter, at a repetition rate of more than 2 MHz can be obtained. The last part is devoted to the development and the implementation of a new system of CARS spectroscopy assisted by a high-voltage electrical stimulation. This device, based on an amplified microlaser, allows to substract the non-resonant background noise in the measurements. Thus, a fine spectroscopic analysis of the response of different environments of interest in continuous or pulsed field can be achieved. It may lead to a new method for field microdosimetry. Various applications, including granulometry at the micro or nanometric scale and the identification of markers for biology, are shown.

The Spanish slug (Arion vulgaris) is one of the most problematic invasive species in Europe and a serious pest species in agriculture and gardens, and it can have negative effects on native slug species. In this study, we used passively intergraded transponder (PIT) telemetry to determine the movement behavior of 57 Spanish slugs during autumn in two different habitats: a private garden and a deciduous forest, located in Karlstad municipality, Sweden. The slugs generally moved within relatively small areas. There was a difference between the movements between the two habitats, with slugs moving longer distances per day (2.0 m day‑1) and over larger areas in the forest than in the garden (1.1 m day-1). Local control measures are therefore potentially effective in gardens and in agricultural landscapes, since the Spanish slug there concentrate within patches of habitat. To develop control methods to mitigate the impact of this problematic slug, we need more basic ecological knowledge, and this study provides such knowledge. / Den spanska skogssnigeln (Arion vulgaris) är en av Europas mest problematiska invasiva arter och ett allvarligt skadedjur för jordbruk och trädgårdar. Den kan också ha negativa effekter på inhemska snigelarter. I den här studien använde vi telemetri baserat på passivt integrerade transpondrar (PIT) för att bestämma rörelsemönstret hos 57 spanska skogssniglar under hösten i två olika habitat: en villaträdgård och en lövskog, i Karlstads kommun, Sverige. Sniglarna rörde sig inom små områden. Det var en skillnad mellan rörelserna i de två habitaten, sniglarna förflyttade sig längre distanser per dag (2,0 m dag-1) och över större områden i skogen än i trädgården (1,1 m day-1). Lokala kontrollåtgärder är därför potentiellt effektiva i trädgårdar och jordbrukslandskap, då den spanska skogssnigeln där koncentrerar sig inom fläckar av habitat. För att utveckla kontrollmetoder för att minska påverkan av den här problematiska snigeln, så behöver vi mer grundläggande ekologisk kunskap, och den här studien förser oss med sådan kunskap.