Dans le cadre du stockage de Gaz Naturel Liquéfié (GNL) dans des réservoirs flottants, tels que les méthaniers, les contraintes imposées à la cuve par le ballotement de la cargaison doivent être quantifiées. La plupart des études expérimentales ou numériques actuelles ne prennent pas en compte la possibilité de changement de phase entre le GNL et sa vapeur lors d'un impact du liquide sur la paroi. L'objectif de cette thèse est l'ajout de ce phénomène physique dans un code de mécanique des fluides numérique pour la simulation de l'impact d'une vague déferlante sur une paroi.Dans ce but, un état de l'art des différentes modélisations possibles du changement de phase en mécanique des fluides est présenté. Il a été choisi de modéliser le changement de phase entre le liquide et le gaz à une interface franche sans hypothèse d'équilibre thermodynamique à l'interface. Un système hyperbolique de lois de conservation incluant le changement de phase interfacial hors-équilibre est présenté.Deux approches sont utilisées pour la résolution numérique de ce système. La première utilise un modèle de mélange pour décrire les mailles contenant l'interface liquide-vapeur. Dans la seconde méthode, l'interface est reconstruite et évolue de manière lagrangienne. Les deux approches sont basées sur un schéma volume fini de type Roe.L'enjeu de la simulation numérique du changement de phase interfacial est la capacité du code à gérer un rapport de densité loin de 1 et une chaleur latente élevée, qui entrainent respectivement de fortes variations de pression et de température à l'interface. L'aspect thermique est le phénomène limitant dans le cadre de la simulation d'impacts de vagues avec changement de phase. Seule une fine couche limite thermique autour de l'interface tend à revenir à l'équilibre thermodynamique liquide vapeur, ce qui limite l'effet quantitatif du changement de phase. / In the context of Liquefied Natural Gas (LNG) transportation in floating tanks, such as in LNG carriers, the constraints imposed by the sloshing of the liquid cargo on the tank have to be estimated. Most experimental and numerical studies until now do not take into account the possibility of phase change between the LNG and its vapor during the impact of liquid on the wall. The goal of this thesis is to include this physical phenomenon into a CFD code for the simulation of a breaking wave impact on a wall.A state of the art of the different modelisations of phase change in fluid mechanics is thus presented. This work focus on the modeling of phase change between the liquid and the gas at a sharp interface, without any equilibrium hypothesis. An hyperbolic system of balance laws including non-equilibrium interfacial phase change is presented.Two approaches are used to solve numerically this system. The first one relies on a mixture model for the description of the finite volume cells containing the interface, whereas in the second approach the interface is reconstructed and evolves in a lagrangian way. Both methods are based on a Roe-type finite volume scheme.The challenge of the numerical simulation of interfacial phase change is the capacity of the code to deal with density ratio far from 1 and high latent heat, as the lead to high temperature and pressure variations at the interface. The thermal aspect is the limiting phenomenon in the frame of wave impact simulation with phase change. Only a thin boundary layer around the interface tends to return to thermodynamical equilibrium, thus limiting the quantitative effect of phase change.

In this research thermal properties enhancement of phase change material (PCM) using boron nitride nanomaterials such as nanoparticles and nanotubes is studied through experimental measurements, finite element method (FEM) through COMSOL 5.3 package and molecular dynamics simulations via equilibrium molecular dynamics simulation (EMD) with the Materials and Process Simulations (MAPS 4.3). This study includes two sections: thermal properties enhancement of inorganic salt hydrate (CaCl2∙6H2O) as the phase change material by mixing boron nitride nanoparticles (BNNPs), and thermal properties enhancement of organic phase change material (paraffin wax) as the phase change material via encapsulation into boron nitride nanotubes (BNNTs). The results of the proposed research will contribute to enhance the thermal transport properties of inorganic and organic phase change material applying nanotechnology for increasing energy efficiency of systems including electronic devices, vehicles in cold areas to overcome the cold start problem, thermal interface materials for efficient heat conduction and spacecraft in planetary missions for efficient thermal managements.

The topic of presented master’s thesis was study of passive stabilization of building materials temperature. The main goal of this thesis was measuring and characterization of the thermal properties of building materials, which are used to PCM technology. PCM technology is based on utilization of latent heat of phase change. At the beginning of this thesis it was needed to define physical principle of phase change, then the most usable PCM chemicals (e.g. paraffin, Glauber’s salt, hexahydrate calcium chloride) and their basic physical properties (especially thermo-physical), background research of building materials with PCM and also the methods of thermo-physical properties measurement. It was also needed to characterize measured building materials and define theirs thermal parameters; because the values of thermal parameters of measured samples were compared to these values. In the experimental part of my thesis are measurements of material thermal analysis, which are methods, where the properties of materials are studied as they change with temperature. I had used to differential scanning calorimetry, transient pulse method and other methods, which are usable for thermo-physical properties measuring and characterization. I have been much interested in properties of measured material, which were specific heat capacity, temperature diffusivity, heat conductivity and phase change temperature (the melting point of PCM). At the end of my thesis the findings of all methods were finally summarized, compared and commented.

The thesis deals with the integration of phase change materials (PCMs) into building structures. The basic requirement is improved thermal stability during the summer season without using an air conditioner. This can be achieved by increasing the thermal storage capacity of the building structures. If the thermal capacity cannot be increased on the level of weight, phase change materials can be used. These materials are capable of storing latent heat and thus increasing the thermal storage capacity of the building. In the thesis the phase change materials were investigated in a thermal incubator by thermal analysis and, above all, in full-scale experiments using comparative measurements. The comparative measurements were carried out in two attic rooms at the Faculty of Civil Engineering, Brno University of Technology, where in one was used as a reference and the other for the experiment. Manufactured heat storage panels were installed in the experimental room. These panels are composed of a base plate; the capillary tubes placed on it are coated with modified plaster. The gypsum plaster is modified with micro-capsules paraffin for improving the thermal storage capacity. This system is connected to a thermal air-water pump, by which the storage panels can be additionally cooled or heated. In the experimental measurements, different operating modes were investigated and their effect on the indoor environment was evaluated. Thermal storage in PCMs dampens the temperature amplitude in the building during the summer season and, at the same time, allows the stored heat to be discharged during the night. Moreover, the time interval of withdrawing electric energy from the supply mains is much shorter than in the case of air conditioning. A conventional air conditioner must operate simultaneously with the thermal load, i.e. at the time of peak consumption of electric energy. Thanks to the set regimes, the installed system is capable of responding to external thermal condit

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To uilize the shallow geothermal energy, heat pumps are often coupled with borehole heat exchangers (BHE) for heating and cooling buildings. In cold regions, soil freezing around the BHE is a potential problem which can seriously influence the underground soil temperature distribution, inlet and outlet fluid temperature of the BHE, and thus the efficiency of the whole GSHP system. The influence of the freezing process on the overall system performance is investigated by comparing different BHE configuration with and without latent heat effect from the frozen groundwater. The coefficient of performance (COP) of the heat pump will alter when freezing process in taken into account and lead to various electricity consumption. Except for the efficiency aspect, the freezing behavior can also lead to the redistribution of pore pressure and fluid flow, and in some extreme cases can even result in frost damage to the BHEs. A fully coupled thermohydro-mechanical model is required for advanced system design and scenario analyses. Based on the framework of the Theory of Porous Media, a triphasic freezing model is derived and solved with the finite element method. Ice formation in the porous medium results from a coupled heat and mass transfer problem with phase transition and is accompanied by volume expansion. The model is able to capture various coupled physical phenomena through the freezing process including the latent heat effect, groundwater flow with porosity change and mechanical deformation. With this kind of THM freezing model, we are also able to solve different kinds of engineering problem, e.g. geotechnics, construction engineering and material engineering.

<p>To reduce greenhouse gas emissions, shifting the energy sources used in buildings, transportation, industry, etc., from fossil fuels to clean electricity is a trend. The increasing electricity demand stresses the existing electric grids. Buildings consume 73% of all U.S. electricity and are responsible for 30% of U.S. greenhouse gas emissions.  Residential and commercial buildings' space heating/cooling system consumes considerable electricity. Integrating thermal energy storage (TES) in building heating/cooling systems can mitigate the challenge of electric grids. Applying TES to existing air-source heat pump (ASHP) systems is the most studied for residential buildings. However, the high-quality thermal energy requirement for charging the TES tank results in low thermal performance of the ASHP system. Moreover, the failure of ASHP in cold climates requires a supplemental electric heater that significantly reduces the system efficiency and may lead to a higher annual peak for the grids.</p> <p>This study proposes integrating TES with ground-source heat pump (GSHP) systems as a more effective solution for building decarbonization due to the high efficiency of renewable-energy-based GSHPs year-round. This study focuses on proving the effectiveness of TES-integrated GSHPs for building decarbonization.  A dual-source heat pump (DSHP) with a hybrid TES and ground heat exchanger (GHE) named dual-purpose underground thermal battery (DPUTB) is investigated. The study uses modeling and experiments to verify the system's energy efficiency, decarbonization potential, and demand response capability. The modeling process involves developing various models, from component-level to system-level, and investigating advanced control strategies. A first-of-this-kind dynamic model of the DPUTB is developed to enable high-resolution system simulation for the GSHP system. The simulation is conducted using Modelica with rule-based control (RBC). A model predictive control (MPC) is also developed based on dynamic building envelope and heating, ventilation, and air conditioning (HVAC) system models. A cutting-edge co-simulation testbed integrates Modelica physical models with a MATLAB MPC controller model for advanced control evaluation. A prototype system of the DPUTB+DSHP is tested in a flexible research platform (FRP) at Oak Ridge National Laboratory (ORNL), which allows for component and system-level testing and remote automation controls. </p> <p>The study highlights the importance of proper insulation in the performance of the DPUTB, which consists of a TES tank enclosed by an outer tank functioning as a GHE. With appropriate insulation, a full-size DPUTB can store 1-ton cooling (3.5 kW) for four hours after eight hours of charging. Simulation results suggest that decoupling the TES with the GHE could reduce energy consumption by 27%.  System-level simulations confirm that the DSHP+DPUTB system, with a customized RBC, outperforms the conventional ASHP. The proposed system can reduce the annual HVAC electricity cost by up to 50% while saving 45% on electricity consumption. In the Northern areas of the United States, the annual peak load of the HVAC system can be reduced by 60%.  However, this reduction is less in the Southern parts of the as the system's higher efficiency in winter dominates the overall decrease. The application of MPC can further reduce the cost and energy consumption of the system by 35% theoretically. However, the accuracy of model prediction affects its performance in practical applications, which can be mitigated by employing technologies such as machine learning and reinforcement learning. Further research is required to verify these technologies.</p> <p>The DSHP+DPUTB system, a type of TES-integrated GSHP, has been well-designed and demonstrated superior performance to conventional systems, with greater flexibility and thermal efficiency. As a result, this system can enable electrification in the space heating sector without requiring an escalation in the grid. Moreover, alternative controls can be utilized to exploit its decarbonization potential fully.</p>

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<p dir="ltr">Ice thermal energy storage (ITES) systems have long been an economic way to slash cooling costs in the commercial sector since the 1980s. An ITES system generates cooling in the formation of ice within a storage tank. This occurs during periods of the day when the cost of electricity is low, normally at night. This ice is then melted to absorb the energy within the conditioned space. While ITES systems have been prosperous in the commercial sector, they have yet to take root in the residential sector.</p><p dir="ltr">The U.S. Department of Energy (DoE) has published guidelines for TES. The DoE guidelines include providing a minimum of four hours of cooling, shifting 30-50% of a space’s cooling load to non-peak hours, minimizing the weight, volume, complexity, and cost of the system, creating a system than operates for over 10,000 cycles, enacting predictive control measures, and being modular to increase scale for larger single-family and multi-family homes [1]. The purpose of this research is to develop a model that meets these guidelines.</p><p dir="ltr">After extensive research in both experimental data, technical specifications, existing models, and best practices taken from the works of others a MATLAB model was generated. The modeled ITES system is comprised of a 1m diameter tank by 1m tall. Ice was selected as the PCM. A baseline model was constructed with parameters deemed to be ideal. This model generated an ITES system that can be charged in under four hours and is capable of providing a total of 22.18 kWh of cooling for a single-family home over a four-hour time period. This model was then validated with experimental data and found to have a root mean squared error of 0.0959 for the system state of charge. During the validation both the experimental and model estimation for the water/ice within the tank converged at the HTF supply temperature of -5.2°C.</p><p dir="ltr">With the model established, a parametric analysis was conducted to learn how adjusting a few of the system parameters impact it. The first parameter, reducing the pipe radius, has the potential to lead to a 152.6-minute reduction in charge time. The second parameter, varying the heat transfer fluid (HTF) within the prescribed zone of 0.7 kg/s to 1.2 kg/s, experienced a 4.8-minute increase in charge time for the former and a decrease in charge time by 5.4 minutes for the latter. The third parameter, increasing the pipe spacing and consequently increasing the ratio of mass of water to mass of HTF, yielded a negative impact. A 7.1mm increase in pipe spacing produced a 16.6-minute increase in charge time. Meanwhile, a 14.2mm increase in pipe spacing created a 93.3-minute increase in charge time and exceeded the charging time limit of five hours.</p><p dir="ltr">This functioning model establishes the foundation of creating a residential-scale ITES system. The adjustability and scalability of the code enable it to be modified to user specifications. Thus, allowing for various prototypes to be generated based on it. The model also lays the groundwork to synthesize a code containing an ITES system and a heat pump operating as one. This will aid in the understanding of residential-scale ITES systems and their energy effects.</p>

<p>With the advent of increasingly complex radio systems at higher frequencies and the slowing of traditional CMOS process scaling with power concerns, there has been an increased focus on integration, architectural, and material innovations as a continued path forward in MEMS and logic. This work presents the first comprehensive experimental study of resonant body transistors in a commercial 14nm FinFET process, demonstrating differential radio frequency transduction as a function of transistor biasing through electrostatic, piezoresistive, and threshold voltage modulation. The impact of device design changes on unreleased resonator performance are further explored, highlighting the importance of phononic confinement in achieving an f*Q product of 8.2*10¹¹ at 11.73 GHz. Also shown are initial efforts towards the understanding of coupled oscillator architectures and a perovskite nickelate material system. Finally, development of resonators based on two-dimensional materials, whose scale is particularly attractive for high-frequency nano-mechanical resonators and acoustic devices, is discussed. Experiments towards dry transfer of tellurene flakes using geometries printed via two photon polymerization are presented along with optimization of a fabrication process for gated RF devices, presenting new opportunities for high-frequency electro-mechanical interactions in this topological material. </p>