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A frequency response tracer technique was used to study the hydraulic properties of a laboratory flow through reactor with variations in reactor size, flow rate and applied mixing. At any one set of conditions the reactor was studied over a range of input sine wave frequencies. Theoretical models consisting of in-series networks of completely mixed segments, plug flow segments, and dead space allowances were developed to approximate the experimental findings. / Thesis / Master of Engineering (ME)

Grouting is performed in order to decrease the permeability and increase the stiffness of the material, especially soil and rock. For tunnelling and underground constructions, permeation grouting is done where cement based materials are pumped inside drilled boreholes under a constant pressure, higher than the ground water pressure. The aim of permeation grouting is to reduce the water flow into tunnels and caverns and to limit the lowering of the surrounding groundwater table. Cement based materials are commonly used as grout due to their availability and lower costs. To obtain a proper water sealing and reduce the lowering of the ground water table, a desired spread of grout must be achieved and the rheology of the cement grout is the governing factor for estimating the required spread. Rheological properties of cement grout such as viscosity and yield stress are commonly measured off-line using laboratory instruments, and some simple tools are available to make field measurements. Although the rheological properties of the grout that is used play a fundamental role in design and execution, no method has yet been developed to measure these properties in-line in field work. In addition to the real time measurement, there is no standard method for determining the yield stress for grouting applications. Despite the common usage of Bingham model fitting to determine the yield stress, the range of shear rate is often not specified or is neglected.   In this work, an in-line rheometry method combining the Ultrasound Velocity Profiling (UVP) technique with Pressure Difference (PD) measurements, known as “UVP+PD”, was successfully tested for continuous in-line measurements of concentrated micro cement based grouts. A major obstacle of using the ultrasound based methodology was the transducers, which would be capable of emitting sufficient acoustic energy and can be used in field conditions. The transducer technology was developed in a parallel project and the Flow-Viz industrial rheometer was found to be capable of detail measurement of the velocity profiles of cement grout. The shape of the velocity profiles was visualized, and the change in the shape of the profiles with concentration and time was observed. The viscosity and yield stress of the grout were determined using rheological models, e.g. Bingham and Herschel-Bulkley. In addition, rheological properties were determined using the non-model approach (gradient method) and the tube viscometry concept and were compared with results obtained using the rheological models. The UVP+PD method was found to be capable of determining the rheological behavior of cement grout regardless of the rheological model. The yield stress of cement grout was investigated using off-line rheometry techniques and UVP+PD in-line measurements. Tests were performed applying different shear histories and it was found that two ranges of yield stress indeed exist. Therefore, the design value of yield stress should be chosen with respect to the prevailing shear rate at the grout front for the required spread of grout. In addition, an appropriate shear rate range should be used when a Bingham fitting is done to determine the yield stress. In order to estimate the shear rate, plug thickness and velocity for one dimensional and two dimensional geometry, a non- dimensional nomogram was developed. The advantage of using the nomogram is that it does not depend on the applied pressure and the rheological properties of the grout and can therefore, be used as a simple design tool. Analytical approaches were used for the estimation and good agreements were found with numerical calculations and experimental results. In conclusion, in this work, it was found that it is possible to continuously measure the velocity profiles and determine the change of the rheological properties of cement grout using the ultrasound based UVP+PD method under field conditions. The yield stress was also investigated and it was found that two range of yield stress exist depending on the prevailing shear rate of the grout, which should be used for designing the grouting time at different conditions. In order to decide the design value of yield stress for grouting applications, a non-dimensional nomogram was developed that can be used to estimate the plug thickness, shear rate and velocity of the grout. / <p>Funding for the project was provided by the Swedish Rock Engineering Research Foundation (BeFo), The Swedish Research Council (FORMAS) and The Development Fund of the Swedish Construction Industry (SBUF), who are gratefully acknowledged. QC 20151112</p>

This experimental study explores the heat transfer from heated bare and finned tubular surfaces to particulates in packed bed cross flow. The results from this experiment will be used to help select the type of particulates that will be used. Additionally, these results will assist in estimating heat transfer in prototype and commercial particle to fluid heat exchangers (PFHX). This research is part of larger effort in the use of particulates in concentrating solar power technology. These solid particles are heated by concentrated sunlight to very high temperatures at which they are a suitable heat source for various thermal power and thermochemical cycles. Furthermore, one of the advantages of this concept is the ability to store thermal energy in the solid particles at relatively low cost. However, an important feature of any Particle Heat Receiver (PHR) system is the PFHX, which is the interface between the solar energy system and the thermal power or chemical system. In order to create this system material data is needed for the design and optimization of this PFHX. The paper focuses on the heat transfer properties of particulates to solid surfaces under plug flow conditions. The particulates will be evaluated for three grain sizes of sand and two grain sizes of proppants. These two materials will be tested at one, five and ten millimeters per second in order to see how the various flow rates, which will be required for different loads, will affect the heat transfer coefficient. Finally the heat transfer coefficient will also be evaluated for both finned and non-finned heat exchangers to see the effect that changes in the surface geometry and surface area have on the heat transfer coefficient. The heat transfer coefficient will help determine the appropriate material that will be used in the PHR system.

The present thesis is focused on calculation prediction of characteristic parameters of combustion process in combustion chamber which is installed at burners testing laboratory. In the thesis basic theoretical knowledge needed for description of heat transfer in process combustion equipment are given. The Plug Flow Furnace Model is based on this knowledge. This model is used to evaluation of specific heat flux in tube furnaces. In the next step the Plug – Flow model is modified and adapted on the combustion chamber. Obtained results are compared with a measured data. By this comparison quality of this model is assessed.

Fjärrvärme i dagens Sverige är ett väletablerat sätt att leverera värme för både industriell och privat användning. Med nästa generations fjärrvärmesystem vid horisonten kan förändringar av existerande fjärrvärmenät komma att bli vanligt förekommande. Trots att det inte är fullt aktuellt med den typen av renoveringar ännu så måste fjärrvärmenät ibland byggas ut för att hantera nya situationer som kan uppstå. För att få en god uppskattning om vad de nya situationerna kommer kräva, och potentiellt kosta, så är simuleringsmodeller ett användbart verktyg. Den här studien har granskat en kommande ökning av effektbehovet och en konsekvent ökning av den producerade värmen angående fjärrvärmesystemet lokaliserat i Malå. Granskningen genomfördes via etablering av en simuleringsmodell som baserats på metoder från tillgänglig litteratur. Empiriska värden användes både som indata till modellen och för feluppskattning. Två hypotetiska scenarier undersöktes där effektbehovet hos en industrikund antas dubbleras, ett som systemet ser ut idag och det andra med ett termiskt energilager i form av en ackumulatortank inkluderat. Simuleringssvaren gav en uppskattning av hur mycket effekt en ny produktionsenhet behöver kunna producera för att nå ett eftersökt mål. Dessa visade på att en ny produktionsenhet med en effekt av minst 10.50 MW är nödvändigt. Vidare så indikerade resultaten att installation av ett sådant energilager med den valda styrningen inte reducerar effektmagnituden hos en ny produktionsenhet. De visade dock på att införande av energilagret kan medföra en reduktion i antalet effektsvängningar som förekommer i systemet. Beroende på övrig konfiguration så minskades förekomsten av antalet effektsvängningar mellan 0.2 till 25.5 procent med ett energilager av den minsta undersökta volymen infört. / District heating in Sweden is a well established way of delivering heat for both industrial and private applications. With the next generation of district heating on the doorstep, changes of existing district heating networks may become a regular occurrence. Despite the fact that these kinds of reconstructions are not quite applicable yet, refurbishments of existing district heating networks are still sometimes necessary in order to deal with new prerequisites that may appear. In order to achieve a good estimation of what these new prerequisites will require and possibly cost, the usage of tools such as models for simulation are valuable. This study has evaluated a future increase of power demand and the subsequent expansion of the produced heat concerning the district heating network located in the city of Malå. The evaluation was carried forth by establishment of a simulation model which was based on present literature. Empirical data was used both as input and for error estimation. Two hypothetical scenarios were examined in which the power demand of an industrial customer is assumed to be doubled. The first represented the system as it is defined presently, while the other introduced a tank thermal energy storage to the system. The results of the simulation yielded an estimate of how much heat a new plant needs to produce in order to attain a set goal. These suggested that the necessary heat production in the new plant needs to be at least 10.50 MW. Furthermore, the results indicated that the inclusion of a thermal energy storage of this kind and with the defined priorities will not reduce the required size of a new production plant. However, they did indicate that the defined thermal energy storage may contribute to a reduction in the number of power fluctuations occurring in the system. Depending on other configurations, the frequency of the power fluctuations were reduced between 0.2 to 25.5 percent with the inlcusion of the smallest examined thermal energy storage.

Research on the electrocoagulation (EC) of hexane extractable materials (HEM) has been conducted at the University of New Orleans using a proprietary bench-scale EC reactor. The original reactor configuration forced the fluid to follow a vertical upward-downward path. An alternate electrode arrangement was introduced so that the path of flow became horizontal. Both configurations were evaluated by comparing the residence time distribution (RTD) data generated in each case. These data produced indication of internal recirculation and stagnant water when the fluid followed a vertical path. These anomalies were attenuated when the fluid flowed horizontally and at a velocity higher than 0.032 m s-1 . A series of EC experiments were performed using a synthetic emulsion with a HEM concentration of approximately 700 mg l-1. It was confirmed that EC of HEM follows first-order kinetics, and kinetic constants of 0.0441 s-1 and 0.0443 s-1 were obtained from applying both the dispersion and tanks-in-series (TIS) models, respectively. In both cases R2 was 0.97. Also, the TIS model indicated that each cell of the EC behaves as an independent continuous-stirred-tank reactor.

The loss of efficiency and performance of bioprocesses on scale-up is well known, but not fully understood. This work addresses this problem, by studying the effect of some fermentation gradients (pH, glucose and oxygen) at a larger scale in a bench-scale two compartment reactor (PFR + STR) using the cadaverine-producing recombinant bacterium, Corynebacterium glutamicum DM1945 Δact3 Ptuf-ldcC_OPT. The initial scale down strategy increased the magnitude of these gradients by only increasing the mean cell residence time in the plug flow reactor (τ_PFR). The cell growth and product related rate constants were compared as the τ_PFR was increased; differences were significant in some cases, but only up to 2 min residence time. For example, losses in cadaverine productivity when compared to the control fed-batch fermentation on average for the τ_PFR of 1 min, 2 min and 5 min were 25 %, 42 % and 46 % respectively. This indicated that the increasing the τ_PFR alone does not necessarily increase the magnitude of fermentation gradients. The new scale-down strategy developed here, increased the magnitude of fermentation gradients by not only increasing the τ_PFR, but also considering the mean frequency at which the bacterial cells entered the PFR section (f_m). The f_m was kept constant by reducing the broth volume in the STR. Hence, the bacterial cells also spent shorter times in the well mixed STR, as the τ_PFR was increased (hypothesised as giving the bacterial cells less time to recover the non-ideal PFR section of the SDR). On adoption of this strategy cadaverine productivity decreases for the τ_PFR of 1 min, 2 min and 5 min were 25 %, 32 % and 53 % respectively. Thus, highlighting that loss in performance is most likely to occur as the magnitude of heterogeneity within the fermentation environment increases. However, Corynebacterium glutamicum DM1945 Δact3 Ptuf-ldcC_OPT did show some resilience in its biomass productivity. It was only marginally affected in the harshest of conditions simulated here.

Le biodiesel est un biocarburant, composé d'un mélange de mono-esters d'acide gras saturés et insaturés avec une longue chaîne carbonée. Ce travail de thèse présente les données de la littérature sur l'origine du biodiesel et son procédé de fabrication ; sont présentées aussi les performances et les émissions des moteurs diesel fonctionnant au biodiesel et la cinétique d'oxydation du biodiesel. Des efforts ont été faits pour mettre en évidence les principales différences entre les esters méthyliques et éthyliques tout en montrant que d'autres recherches sont encore à développer. Pour ces raisons, les délais d'auto-inflammation de cinq esters méthyliques et éthyliques ont été mesurés dans un tube à onde de choc : l'acrylate d'éthyle, l'acrylate de méthyle, le crotonate d'éthyle, le crotonate de méthyle et le butanoate d'éthyle. Les mécanismes cinétiques détaillés d'oxydation des cinq esters étudiés ont été générés automatiquement en utilisant le logiciel EXGAS. L'oxydation du butanoate d'éthyle, molécule modèle d'esters éthyliques d'huiles végétales (EEHV) a été étudiée dans un réacteur piston à pression atmosphérique pour une gamme de température allant de 500 à 1200 K. Les résultats représentent les profils de concentration des réactifs, les intermédiaires stables et les produits finaux. Le modèle cinétique a été validé de façon satisfaisante par une comparaison entre les résultats simulés et expérimentaux / An increasingly popular biofuel is biodiesel, composed of a mixture of saturated and unsaturated fatty acid methyl or ethyl esters, with a long aliphatic main chain. This PhD dissertation provides a literature review concerning the origin of biodiesel, its manufacturing process, performance and emissions of diesel engines fueled with biodiesel, and the kinetics of oxidation of biodiesel. Efforts were made to highlight the main differences between methyl and ethyl esters while showing where further research needs to be developed or pursued. For these reasons, the autoignition of five esters were measured behind reflected shock tube: ethyl acrylate, methyl acrylate, ethyl crotonate, methyl crotonate, and ethyl butanoate. Detailed mechanisms for the oxidation of the five studied esters were automatically generated using the version of EXGAS software. In addition, the oxidation of ethyl butanoate as a model compound for Fatty Acid Ethyl Esters (FAEE) has been investigated in tubular plug flow reactor at atmospheric pressure over wide range of temperature (500-1200 K). The results consist of concentration profiles of the reactants, stable intermediates, and final products. The model was again validated satisfactorily by comparison between computed results and the generated experimental data

Användningen av kommunalt avfall för att producera förnybar energi, huvudsaklig biogas, uppfyller 8 av Sveriges 16 miljökvalitetsmål. Två typer av rötningsprocesser som används är kontinuerligt omrörda tankreaktorer (CSTR) och pluggflödesreaktorer (PFR). Rapportens syfte är att direkt jämföra de två reaktorkonfigurationerna, PFR och CSTR, med samma substratblandning. Båda reaktortyperna drevs med samma belastning (5,2 g VS/L dag), hydraulisk retentionstid (30 dagar) och driftstemperatur (520C). Två PFR-reaktorer drevs med återcirkulation av rötrester. Under projektets gång mättes olika parametrar, vilka var: pH, total gasvolym och gassammansättning, FOS/TAC (organiska syror/alkalinitet), flyktiga fettsyror (VFA), ammonium-kvävekoncentration och TS (torrsubstanshalt) och VS (organiska ämnen). Studieresultatet var uppdelat i två sektioner. Avsnitt 1 sammanfattar uppstartsperioden, där alla tre CSTR (D1-R, D2-NR och C1-NR) kördes i icke-återcirkulerande läge. Uppstartsperioden gjordes för att säkerställa reaktorernas stabilitet och det gällde att uppnå en liknande baslinje för detektion. Inom studien accepterades avvikelser för baslinjen inom intervallet 0-5%. För uppstartsperioden varierade den specifika metanproduktionen med 2 % mellan D1-NR och D2-R, D1-R och C1-NR med 6 %, och D2-NR och C1-NR med 8 %. För ammoniak-koncentrationen var skillnaden mellan D1-R och D2-NR 2 % och mellan D1-R och C1-NR 9 %, mellan D2-NR och C1-NR, 7%. Med dessa variationer togs beslutet att utesluta reaktor C1-NR från den experimentella perioden för projektet. Avsnitt 2 jämför PFR och CSTR återcirkulerat/icke återcirkulerat läge. En CSTR drevs med 30 % återcirkulation av rötrest och en CSTR drevs i icke-återcirkulationsläge. Att jämföra PFR och CSTR återcirkulerat/icke återcirkulerat läge visade att PFR:erna övervann båda CSTR:erna när det gäller den specifika metanproduktionen. Där PFR producerade 395±93 NL/KgVS och 372±42 (N)L/KgVS CSTR med återcirkulation 280±10 (N)L/KgVS och den icke-återcirkulerade CSTR producerade 250±7 (N)L/KgVS. NH4+-N-nivåerna mellan PFR och CSTR visade en skillnad på 1 g/L, där PFR var den med högre NH4+-N (2,53±0,39 g/L för PFR-A och 2,73±0,43 g/L för PFR-T). En av skillnaderna mellan de återcirkulerade och de icke-återcirkulerade CSTR:erna var VFA-koncentrationen. VFA-koncentrationen i de återcirkulerade var 1,05±0,90 g/L och 0,43±0,25 g/L i de icke-återcirkulerade. VFA-koncentrationen för PFR var i genomsnitt 0,28±0,12 g/L och 0,40 ±0,16 g/L. Graden av nedbrytning i CSTRs var 90-91%, och 63-65% i PFR. Den är möjligen felberäknad och visar en inkonsekvens mellan reaktorernas prestanda och specifik metanproduktion. / The use of municipal waste to produce renewable energy, in the form of biogas, fulfils eight of Sweden's sixteen environmental quality objectives. The most common technology to produce biogas is anaerobic digestion (AD). Two common types of AD processes are continuously stirred reactors (CSTR) and plug flow reactors (PFR). The thesis aims at directly comparing the two reactor configurations using the same substrate mix. For this, two PFRs (PFR-T and PFR-A) and three CSTRs (D1-R, D2-NR and C1-NR) were setup. All reactors were operated at the same organic loading rate (5.2 g VS/L-day), hydraulic retention time (30 days) and operational temperature (52°C). During the project, various parameters were measured to evaluate the reactor performance, such as pH, total gas volume and gas composition, FOS/TAC (organic acids/alkalinity), volatile fatty acids (VFA), ammonium-nitrogen concentration, and solid and volatile solid of digestate.   The study result was divided into two sections. Section 1 summarises the start-up period (42 days), where the CSTRs and the PFRs were operated under non-recirculation mode. The start-up period was done to ensure the stability of the reactors and was concerned with achieving a similar baseline for performance. For the start-up period, the specific methane production between D1-R and D2-NR varied by 2% while the variation between C1-NR and D2-NR was 8%. Likewise, for the ammonia concentration, the difference between D1-R and D2-NR was 2%, while C1-NR differed by 9% from D2-NR. Based on these findings, the decision was taken to exclude reactor C1-NR from the experimental period of the project.  Section 2 compares the PFR and CSTR. One CSTR was operated with 30% recirculation of digest, while the other CSTR was operated in non-recirculation mode. The two PFRs were operated with recirculation of digestate. The experiments showed that the PFRs outperformed both CSTRs regarding the specific methane production. The PFRs produced 395±93 (N)L/kg-VS and 372±42 (N)L/kg-VS. In contrast, the CSTR with recirculation reached 280±10 (N)L/kg-VS and the non-recirculated CSTR produced 250±7 (N)L/kg-VS. The NH4+-N levels for the PFRs and CSTRs showed a 1 g/L difference, with a higher value for the PFRs (2.53±0.39 g/L for PFR-A, and 2.73±0.43 g/L for PFR-T). One of the significant differences between the recirculated and the non-recirculated CSTRs was the VFA concentration. The VFA concentration in the recirculated and non-recirculated reactor was 1.05±0.90 g/L and 0.43±0.25 g/L, respectively. The VFA concentration for the two PFRs was on average 0.28±0.12 g/L and 0.40 ±0.16 g/L. The degree of degradation in the CSTRs was 90-91% compared to 63-65% in the PFRs. The degree of degradation is possibly miscalculated and shows an inconsistency between the reactor performance in terms of specific methane production.