This dissertation focuses on the global investigation of optically thin cirrus cloud optical thickness (tau) and microphysical properties, such as, effective particle size (D_(eff)) and ice crystal habits (shapes), based on the global satellite observations and fast radiative transfer models (RTMs). In the first part, we develop two computationally efficient RTMs simulating satellite observations under cloudy-sky conditions in the visible/shortwave infrared (VIS/SWIR) and thermal inferred (IR) spectral regions, respectively. To mitigate the computational burden associated with absorption, thermal emission and multiple scattering, we generate pre-computed lookup tables (LUTs) using two rigorous models, i.e., the line-by-line radiative transfer model (LBLRTM) and the discrete ordinates radiative transfer model (DISORT). The second part introduces two methods (i.e., VIS/SWIR- and IR-based methods) to retrieve tau and D_(eff) from satellite observations in corresponding spectral regions of the two RTMs. We discuss the advantages and weakness of the two methods by estimating the impacts from different error sources on the retrievals through sensitivity studies. Finally, we develop a new method to infer the scattering phase functions of optically thin cirrus clouds in a water vapor absorption channel (1.38-µm). We estimate the ice crystal habits and surface structures by comparing the inferred scattering phase functions and numerically simulated phase functions calculated using idealized habits.

Industry is heavily dependent on the process of combustion and with a projected rapid increase for the demand of combustion-derived energy it is imperative to expose a new age of engineering professionals to the discipline of combustion engineering. One purpose of this study was to modify an existing scaled-down industrial furnace and to retrofit it with the ability to interchange burners for academic application and combustion testing. A number of available industrial burners are presented and their qualities and drawbacks discussed. The modification of an existing scaled-down industrial tunnel furnace is proposed in this work with the objective of providing users with exposure to the control and safe operating strategies associated with industrial combustion. The furnace system simulates a square-shaped tunnel geometry commonly found in industrial applications. A single nozzle mix burner is mounted along the furnace axis and operated with supporting equipment such as a burner control safeguard, a gas train, and an air supply. Details of the furnace are provided in this work. The concept of radiative heat transfer within a combustion enclosure is demonstrated through furnace simulation with Hottel’s Zone Method. / Thesis (Master, Chemical Engineering) -- Queen's University, 2010-07-19 09:50:22.797

Mineral dust aerosols, the tiny soil particles in the atmosphere, play a key role in the atmospheric radiation budget through their radiative and cloud condensation nuclei effects. It is therefore important to evaluate the radiative forcing of mineral dust and subsequent changes in atmospheric dynamics. The Weather Research and Forecasting with Chemistry (WRF/Chem) regional model with the integrated dust modules and available observations have been used to investigate the three-dimensional distribution of mineral dust over Australia. Additionally, the WRF/Chem model was used to estimate the direct radiative forcing by mineral dust over Australia. Particular emphasize has been given to direct radiative feedback effect of mineral dust on boundary layer dynamics. Two dust emission schemes embedded within the WRF/Chem model have been utilized in this study: the dust transport (DUSTRAN) and the Goddard Global Ozone Chemistry Aerosol Radiation and Transport (GOCART) schemes. The refractive index of mineral dust depends on the mineralogy, size and composition of dust over a given region. The refractive index of mineral dust for shortwave radiation was considered to be wavelength independent and set based on previous mineralogical studies over North Africa and Australia. However, the refractive index of mineral dust for longwave radiation was considered to be wavelength dependent and to vary for 16 longwave spectral bands. Model results were compared with observations to validate the performance of the model, including satellite datasets from the Moderate Resolution Imaging Spectroradiometer (MODIS), Multi-angle Imaging SpectroRadiometer (MISR) and Cloud-Aerosol Lidar with Orthogonal Polarization (CALIOP), as well as ground-based measurements obtained from air quality monitoring sites over Australia. The major results can be summarized as follows: (1) Lake Eyre Basin is the most important source of dust in Australia, with a peak activity identified to be during austral spring and summer, and dust emission within the basin is often associated with the passage of dry cold fronts; (2) Mineral dust from Lake Eyre Basin can be transported long distances to southeastern Australia in association with eastward propagating frontal systems, reaching as far as New Zealand and beyond, and to northern tropical Australia by postfrontal southerly winds, and subsequently towards northwestern Australia and the Indian Ocean by southeasterly trade winds; (3) Australian dust plumes are mainly transported in the lower atmosphere, although variation of boundary layer depth during the passage of cold frontal systems, as well as ascending motion at the leading edge of these systems and descending motion where postfrontal anticyclonic circulation is dominant contribute to the vertical extent of mineral dust aerosols; (4) the shortwave direct radiative effect of mineral dust results in cooling of the atmosphere from the surface to near the boundary layer top, but warming of the boundary layer top and lower free atmosphere; (5) changes in the vertical profile of temperature result in an overall decrease of wind speed in the lower boundary layer and an increase within the upper boundary layer and lower free atmosphere; (6) the longwave warming effect of mineral dust partly offsets its shortwave cooling effect at the surface. This compensation is significantly larger over and immediately downwind of dust source regions where coarse particles are more abundant, as they have stronger interaction with longwave radiation emitted from the Earth’s surface; (7) both shortwave and longwave radiative forcing by mineral dust was found to have a diurnal variation in response to changes in solar zenith angle and in the intensity of longwave radiation, respectively; (8) the absorptive nature of dust was shown to be associated with the shortwave heating of the atmosphere; (9) on the other hand, longwave cooling of the atmosphere was identified because absorption of longwave radiation by dust is less than its emission to the surface and top of the atmosphere (TOA).

Active Galactic Nuclei (AGN) are compact regions in the centers of some galaxies. They emit significantly in the whole range of the electromagnetic spectrum and show variability at different timescales. Observational evidence suggests the presence of a dusty torus obscuring the central radiation source of AGN. According to the Unified Model the observed general properties of AGN emission can be understood on the basis of orientation of this torus toward an observer. Two main types of AGN are distinguished: Type 1, with detected emission from the inner torus cavity viewed pole-on, and Type 2, viewed through the obscuring torus. There are numerous attempts in the past decade to model the emission from the torus, considering a homogeneous distribution of dust. However, important problems in explaining the observations still remain unsolved: it is hard to suppress the 10 m emission feature of silicate dust for a pole-on view and at the same time produce an absorption feature for an edge-on viewed torus; despite the huge optical depths inferred from X-ray observations of Type 2 sources, the observed absorption feature is shallow. Unlike observations, models of homogeneous tori with large optical depths always produce deep absorption feature. While it is realized that dust contained in clumps would resolve these issues, modeling of a clumpy medium poses a serious computational challenge. We are the first to incorporate clumps in our model of a dusty torus and to successfully explain the infrared emission from AGN. We model two types of clouds: directly illuminated by the AGN and diffusely heated by other clouds. We calculate the emission of the first type as angle-averaged emission from a dusty slab. The second type of clouds is modeled as dusty spheres embedded in the radiation field of the directly heated clouds. The radiative transfer problem for a dusty slab and externally heated sphere is solved exactly with our code DUSTY. The overall emission of the torus is found by integration over the spatial distribution of clouds. We find a very good agreement of our model results with observations. Comparison with them can constrain the physical conditions in the AGN dusty tori.

The current capabilities of SASKTRAN – a radiative transfer model at the University of Saskatchewan in Saskatoon, Canada – are to accurately model the scattering of solar radiation within the earth’s atmosphere for the ultraviolet-visible (UV-Vis) and near infra-red (NIR) regions of the electromagnetic spectrum. However, the current model does not account for the radiation emitted by the ground and atmosphere, approximated by the blackbody spectrum. In the UV-Vis, this contribution is unimportant, but when transitioning to wavelengths longer than 2.5 μm, the solar spectrum decreases in intensity while radiation of terrestrial and atmospheric origin increases along the blackbody curve. At wavelengths longer than 5 μm in the far infra-red (FIR), the blackbody radiation is the dominant source in the atmosphere. A modification to the source code of SASKTRAN was made in order to include the additional effect of this “thermal” radiation – with the help of the spectral line database HITRAN – while still maintaining scattering capabilities of solar radiation. This would make SASKTRAN one of the first radiative transfer models with the ability to model radiation in the difficult region between 3 and 5 μm – the mid infra-red (MIR) region – where the solar and thermal radiation sources are equally diminished and are the same order of magnitude. An introduction is given to atmospheric physics with a focus on the science of infra-red active molecules like H2O, CO2, CH4, N2O, O3, and CO – the so-called “greenhouse gases” – and the measurement techniques used to determine their atmospheric distribution. A theoretical basis is then provided for general radiative transfer, and the physics of molecular absorption and emission is examined in detail. A summary of the implementation of thermal radiation within the SASKTRAN framework is given, followed by verification studies where the model’s radiative transfer calculations in the infra-red are compared against measurements, including those made by the ground-based instrument E-AERI, the space-borne instruments IASI and GOSAT, and against model results from the LBLRTM, another well-verified radiative transfer model.

All classes of Active Galactic Nuclei (AGN) are fundamentally powered by accretion of gas onto a supermassive black hole. The process converts the potential energy of the infalling matter to X-ray and ultraviolet (UV) radiation, releasing up to several 1012 solar luminosities. Observations show that the accreting "central engines" in AGN are surrounded by dusty matter. The dust occupies a "torus" around the AGN which is comprised of discrete clumps. If the AGN radiation is propagating through the torus on its way to an observer, it will be heavily re-processed by the dust, i.e. converted from UV to infrared (IR) wavelengths. Much of the information about the input radiation is lost in this conversion process while an imprint of the dusty torus is left in the released IR photons. Our group was the first to formulate a consistent treatment of radiative transfer in a clumpy medium an important improvement over simpler models with smooth dust distributions previously used by researchers. Our code CLUMPY computes spectral energy distributions (SED) for any set of model parameters values. Fitting these models to observed AGN SEDs allows us to determine important quantities, such as the torus size, the spatial distribution of clumps, the torus covering factor, or the intrinsic AGN luminosity. Detailed modeling also permits us to study the complex behavior of certain spectral features. IR radiative transfer introduces degeneracies to the solution space: different parameter values can yield similar SEDs. The geometry of the torus further exacerbates the problem. Knowing the amount of parameter degeneracy present in our models is important for quantifying the confidence in data fits. When matching the models to observed SEDs we must employ modern statistical methods. In my research I use Bayesian statistics to determine the likely ranges of parameter values. I have developed all tools required for fitting observed SEDs with our large model database: the latest implementation of CLUMPY, the fit algorithms, the Markov Chain Monte Carlo sampler, and the Bayesian estimator. In collaboration with observing groups we have applied our methods to a multitude of real-life AGN.

CP violation is an important condition to explain the preponderance of baryons in our universe, yet the available CP violation in the Standard Model (SM) via the so-called Cabibbo-Kobayashi-Maskawa mechanism seems to not provide enough CP violation. Thus searching for new sources of CP violation is one of the central tasks of modern physics. In this thesis, we focus on a new possible source of CP violation which generates triple-product correlations in momenta which can appear in neutron and nuclear radiative β decay. We show that at low energies such a CP violating correlation may arise from the exotic coupling of nucleon, photon and neutrino that was proposed by Harvey, Hill, and Hill (HHH). One specialty of such an exotic HHH coupling is that it does not generate the well-known CP-violating terms such as ``D-term'', ``R-term'', and neutron electric dipole moment, in which particle's spins play critical role. We show that such a new HHH-induced CP violating effect is proportional to the imaginary part of c5gv, where gv is the vector coupling constant in neutron and nuclear β decay, and c5 is the phenomenological coupling constant that appears in chiral perturbation theory at O(M-2) with M referring to the nucleon or nuclear mass. We consider a possible non-Abelian hidden sector model, which is beyond the SM and may yield a nontrivial Im(c5). The available bounds on both Im(c5) and Im(gv) are considered, and a better limit on Im(c5) can come from a direct measurement in radiative beta decay. We calculate the competitive effect that arises from the general parameterization of the weak interaction that was proposed by Lee and Yang in 1956. We also show that in the proposed measurements, the CP-violating effect can be mimicked by the SM via final-state interactions (FSI). For a better determination of the bound of Im(c5), we consider the FSI-induced mimicking effect in full detail in O(α) as well as in leading recoil order. To face ongoing precision measurements of neutron radiative β decay of up to 1% relative error, we sharpen our calculations of the CP conserving pieces of neutron radiative β decay by considering the largest contributions in O(α2): the final-state Coulomb corrections as well as the contributions from two-photon radiation.

In this thesis spectral solar zenith radiances are analyzed which were obtained from ship-based measurements over the Atlantic ocean. In combination with high-resolution lidar and microwave remote sensing optical and microphysical cloud properties were retrieved using spectral radiation data. To overcome problems of existing transmissivity-based cloud retrievals, a new retrieval algorithm is introduced which circumvents retrieval ambiguities and reduces the influence of measurement uncertainties. The method matches radiation measurements of ratios of spectral transmissivity at six wavelengths with modeled transmissivities. The new retrieval method is fast and accurate, and thus suitable for operational purposes. It is applied to homogeneous and inhomogeneous liquid water and cirrus clouds. The results from the new algorithm are compared to observations of liquid water path obtained from a microwave radiometer, yielding an overestimation for thick liquid water clouds but a slight underestimation for thin clouds. A statistical analysis of retrieved cloud properties during three Atlantic transects is introduced. Similar characteristics of cloud properties are found in the mid latitudes and northern subtropics but the large variability of meridional distribution in the remaining regions imply the prevailing influence of weather systems compared to typical cloud distributions. With about 63% homogeneous stratocumulus clouds are found to be the prevailing cloud type over ocean, while scattered and inhomogeneous liquid water clouds amount to 16% and 21%, respectively. All analyzed distributions are affected by an increased frequency of small values of cloud properties caused by 3D radiative effects. The comparison with satellite-based and ship-based cloud retrievals along the cruise track show comparable results for the cloud optical thickness with limitations for thick liquid water clouds. The meridional distribution of effective radius agreed within the uncertainties of both methods, however, the satellite-derived values are biased toward larger mean values.

This dissertation deals with spectral measurements of solar radiation in the visible and near infrared wavelength range. The data were collected during a field campaign on the Cape Verde Islands in January / February 2008 within the DFG research group SAMUM 2 (Saharan Mineral Dust Experiment). During this campaign airborne measurements of upward radiances and irradiances were performed over aerosol layers. Since the Cape Verde Islands are in the advection area of air masses from the Sahara region northeast of the islands and from regions with bush fires from the southeast, the sampled aerosol mainly consists of mineral dust, biomass burning smoke or a mixture of both. These radiation measurements and airborne lidar measurements of aerosol extinction coefficients were used to calculate the dust radiative forcing at the top of atmosphere with an one-dimensional radiative transfer model. This required the spectral surface albedo and aerosol optical properties, determined by model retrievals. The dependence of the calculated dust radiative forcing on the aerosol optical thickness was used to distinguish between aerosol distributions with mineral dust only or mixed with biomass burning smoke. This mainly model-based method was compared with another mainly measurement-based method, which requires the net radiation at the flight altitude and its dependence on the aerosol optical thickness to distinguish between the different aerosol distributions. The mainly model-based method shows no differences between the calculated radiative forcings of aerosols mainly consisting of mineral dust and those mixed with biomass burning smoke due to high uncertainties. In contrast to the mainly model-based method, the mainly measurement-based method shows clear differences between aerosols with and without biomass burning smoke. Thus the mainly measurement-based method is the preferred method, because it omits the retrieval of the aerosol optical properties, which leads to high uncertainties, in contrast to the mainly model-based method.

The production of three gauge bosons in high-energy collisions - in particular in view of a next-linear collider with center of mass energies in the TeV range - offers an unique opportunity to probe the Standard Model (SM) of today's particle physics. In this thesis we pay particular attention to the electroweak sector of the theory. We investigate the gauge structure {i. e. possible deviations from the SM predictions of gauge boson self-interactions manifest e. g. in anomalous quartic gauge boson couplings and Radiation zeros) as well as electroweak radiative corrections in order to improve theoretical predictions for SM processes. Quartic gauge boson couplings can be regarded as a direct window on the sector of electroweak symmetry breaking. We have studied the impact of three such anomalous couplings on the processes e+e(^-) → WWγ, ZZγ and Zγγ at LEP2 and a future linear collider. In certain high-energy scattering processes involving charged particles and the emission of one or more photons, the scattering amplitude vanishes for particular configurations of the final state particles. The fact that gauge symmetry is a vital ingredient for the cancellation to occur means that radiation zeros can be used to probe physics beyond the standard model. For example anomalous electroweak gauge boson couplings destroy the delicate cancellation necessary for the zero to occur. We have studied the process qq → WWγ. To match the expected experimental precision at future linear colliders, improved theoretical predictions beyond next-to-leading order are required. By choosing an appropriate gauge, we have developed a formalism to calculate such corrections for arbitrary electroweak processes. As an example we consider here the processes e(^+)e → f f and e(^+)e(^-) → W(^+)(_T)W(^-)(_T), W(^+)(_L)W(^-)(_L) and study the perturbative structure of the electroweak Sudakov logarithms by means of an explicit two-loop calculation. In this way we investigate how the Standard Model, with its mass gap between the photon and Z boson in the neutral sector, compares to unbroken theories like QED and QCD. We observe that the two-loop corrections are consistent with an exponentiation of the one-loop corrections. In this sense the Standard Model behaves like an unbroken theory at high energies.