Star-forming compact dwarf galaxies (CDGs) resemble the expected pristine conditions of the first galaxies in the Universe and are the best systems to test models on primordial galaxy formation and evolution. Here, we report on one of such CDGs, Tololo 1214-277, which presents a broad, single peaked, highly symmetric Ly alpha emission line that had evaded theoretical interpretation so far. In this paper, we reproduce for the first time these line features with two different physically motivated kinematic models: an interstellar medium composed by outflowing clumps with random motions and an homogeneous gaseous sphere undergoing solid body rotation. The multiphase model requires a clump velocity dispersion of 54.3 +/- 0.6 km s(-1) with outflows of 54.3 +/- 5.1 km s(-1), while the bulk rotation velocity is constrained to be 348(-48)(+75) km s(-1). We argue that the results from the multiphase model provide a correct interpretation of the data. In that case, the clump velocity dispersion implies a dynamical mass of 2 x 10(9) M-circle dot, 10 times its baryonic mass. If future kinematic maps of Tololo 1214-277 confirm the velocities suggested by the multiphase model, it would provide additional support to expect such kinematic state in primordial galaxies, opening the opportunity to use the models and methods presented in this paper to constrain the physics of star formation and feedback in the early generation of Ly alpha - emitting galaxies.

L'atmosphère de Saturne subit d'importantes variations saisonnières d'insolation, à cause de son obliquité, de son excentricité et de l'ombre de ses anneaux. Dans la stratosphère (de 20 hPa à 10-4 hPa), les échelles de temps photochimiques et radiatives sont du même ordre de grandeur que la période de révolution de Saturne (29,5 ans). On s'attend donc à mesurer des variations saisonnières et méridiennes significatives de la température et des espèces produites par la photochimie (en particulier C2H6, C2H2 et C3H8) dans cette région. Grâce à sa durée (2004-2017), la mission Cassini est l'occasion inédite de suivre l'évolution saisonnière de l'atmosphère de Saturne.Au cours de ma thèse, j'ai analysé des observations au limbe Cassini/CIRS car elles permettent de sonder à la fois la structure méridienne et verticale de la stratosphère de Saturne. Ainsi, j'ai mesuré les variations saisonnières de la température et des abondances de C2H6, C2H2 et C3H8. J'ai également contribué au développement d'un modèle radiatif-convectif et d'un GCM (Global Climate Model) de l'atmosphère de Saturne. Les prédictions de ces modèles sont comparées avec les températures mesurées avec CIRS, de façon à étudier les processus radiatifs et dynamiques qui contribuent à l'évolution saisonnière. Les simulations numériques réalisées avec ce GCM m'ont également permis d'étudier la propagation des ondes atmosphérique ainsi que les effets de l'ombre des anneaux sur l'atmosphère de Saturne. Par ailleurs, la comparaison entre les distributions de C2H6, C2H2 et C3H8 et des modèles photochimiques (Moses et Greathouse 2005, Hue et al. 2015) donne des indications sur le transport méridien. / Saturn's atmosphere undergoes important seasonal variations of insolation, due to its obliquity, its eccentricity and the shadow of its rings. In the stratosphere (from 20 hPa to 10-4 hPa), radiative and photochemical timescales are in the same order as Saturn's revolution period (29.5 ans). Hence, significative seasonal and meridional variations of temperature and photochemical by-products (especially C2H6, C2H2, and C3H8) are expected. Because of its duration (2004-2017), the Cassini mission is an unprecedented opportunity to monitor the seasonal evolution of Saturn's atmosphere. During my PhD, I analysed Cassini/CIRS limb observations as they probe the meridional and vertical structure of Saturn's stratosphere. Hence, I measured seasonal variations of temperature and abundances of C2H6, C2H2, and C3H8. I also contributed to the development of a radiative-convective model and a GCM (Global Climate Model) of Saturn's atmosphere. The predictions of these models are compared with the temperatures measured from CIRS observations, in order to study the radiative and dynamical processes which contribute to the seasonal evolution. Numerical simulations performed with the GCM also allowed me to study atmospheric waves propagation and the effects of rings shadowing in Saturn's atmosphere. Besides, comparison between C2H6, C2H2, and C3H8 distributions and photochemical models (Moses and Greathouse 2005, Hue et al., 2015) give insights on meridional transport.

The Infrared Atmospheric Sounding Interferometer (IASI) provides atmospheric observations with high spectral resolution and its data have been shown to have a significant positive impact on global Numerical Weather Prediction (NWP) and trace gas retrievals. A fundamental component of the retrieval of atmospheric composition is the radiative transfer model used to simulate the observations. An accurate representation of the expected emission spectrum measured by the satellite is essential given that differences in the reproduced atmospheric spectra propagate through a retrieval procedure and produce an altered estimate of the atmospheric state. The importance of the assumptions within the forward model are discussed and it is established that in the simulation of spectra from satellite-borne instruments the choice of the model parameters can have a large impact upon the resulting output. These assumptions are explored in the context of the Reference Forward Model (RFM), which is further configured to optimise its output for simulating the IASI spectrum in the troposphere. In order to ascertain the consistency of different radiative transfer models, comparisons are carried out between the RFM and the Radiative Transfer model for TOVS (RTTOV) in order to quantify any discrepancies in the reproduction of IASI measurements. Good agreement is shown across the majority of the spectrum, with exceptions caused by CO₂ line mixing effects and the H₂O continuum. Alongside model comparisons, the RFM is validated against real IASI measurements. Being a Fourier Transform Spectrometer, there are a large number of channels available from the IASI instrument, which leads to a very large quantity of data. However, this can lead to problems within retrievals and data assimilation. Choosing an optimal subset of the channels is an established method to reduce the amount of data; maintaining the information contained within it whilst eliminating spectral regions with large uncertainties. The method currently used at the UK Met Office to select their spectral channels is re-assessed and a modified method is presented that improves upon the modelling of spectrally correlated errors.

Les travaux présentés dans ce manuscrit sont consacrés à l'étudie du un petit instrument sophistiqué de mesure d'épaisseur optique : ODS (Optical Depth Sensor) a été conçu pour étudier l'atmosphère martienne et terrestre. L'une de ses principales missions consiste à fournir des mesures journalières de l'épaisseur optique des aérosols (AOD: Aerosol Optical Depth) et de détecter et caractériser les nuages optiquement minces à l'aube et au crépuscule. Les méthodes d'analyses sont basées sur l'utilisation de tables d'intensité reproduisant les signaux observés ODS en fonction de différents paramètres clés. Ces tables ont été réalisées à l'aide d'un code de transfert radiatif dans une géométrie en plans parallèles pour l'estimation de l'opacité des poussières, tandis que les propriétés des nuages sont issues d'un modèle de type Monte-Carlo en géométrie sphérique. Le premier objectif de ce travail a consisté à développer les algorithmes d'analyses nécessaires à l'étude du signal d'ODS. / The work presented in this manuscript is devoted to the development of reliable retrieval procedures for a lightweight and sophisticated optical depth sensor (ODS) which measures alternatively scattered flux at zenith and the sum of the direct flux and the scattered flux in the blue and red wavelength ranges. The ODS sensor is dedicated to Mars and Earth atmosphere and its principal goals are perform measurements of the daily mean aerosol optical depth (AOD) and retrieve the altitude and optical depth of high altitude clouds at twilight. The retrieval procedure is based on the use of look-up tables of intensities reproducing the signals that should be observed by ODS, as a function of different key parameters. For the estimation of AOD, the look-up tables are obtained by using a plane-parallel radiative transfer code, while for the study of cloud properties a Monte-Carlo radiative transfer code in spherical geometry is used.

The work conducted in this thesis examines the nature of circumstellar discs by investigating irradiance and polarization of scattered light. Two circumstellar discs are investigated. Firstly, H-band high contrast imaging data on the transitional disc of the Herbig Ae/Be star HD169142 are presented. The images were obtained through the polarimetric differential imaging (PDI) technique on the Very Large Telescope (VLT) using the adaptive optics system NACO. Our observations use longer exposure times, allowing us to examine the edges of the disc. Analysis of the observations shows distinct signs of polarization due to circumstellar material, but due to excessive saturation and adaptive optics errors further information on the disc could not be inferred. The HD169142 disc is then modelled using the 3D radiative transfer code Hyperion. Initial models were constructed using a two disc structure, however recent PDI has shown the existence of an annular gap. In addition to this, the annular gap is found not to be devoid of dust. This then led to the construction of a four-component disc structure. Estimates of the mass of dust in the gap (2:10x10⁻⁶ M⊙) are made as well as for the planet (≈1:53 x 10⁻⁵ M⊙ (0.016MJupiter)) suspected to be responsible for causing the gap. The predicted polarization was also estimated for the disc, peaking at 14 percent. The use of realistic dust grains (ballistic aggregate particles) in Monte Carlo code is also examined. The fortran code DDSCAT is used to calculate the scattering properties for aggregates which are used to replace the spherical grain models used by the radiative transfer code Hyperion. Currently, Hyperion uses four independent elements to de ne the scattering matrix, therefore the use of rotational averaging and a 50/50 percent population of grains and their enantiomers were explored to reduce the number of contributing scattering elements from DDSCAT. A python script was created to extract the scattering data from the DDSCAT output les and to apply a size distribution to the data. The second circumstellar disc investigated is the debris disc of the M dwarf star AU Mic. The disc was modelled, using the radiative transfer code Hyperion, based on F606W (HST) and JHK0-band (Keck II) scattered light observations and F606Wband polarized light observations. Initially, the disc is modelled as a two component structure using two grain types: compact silicate grains and porous dirty ice water. Both models are able to reproduce the observed SED and the F606W and H-band surface brightness pro les, but are unable to t the observed F606W degree of polarization. Therefore, a more complex/realistic grain model was examined (ballistic aggregate particles). In addition, recent millimetre observations suggest the existence of a planetesimal belt < 3 AU from the central star. This belt is included in the BAM2 model and was successful in fitting the observed SED, F606W and H-band surface brightness and F606W polarization. These results demonstrate the limitations of spherical grain models and indicate the importance of modelling more realistic dust grains.

In the case of cold accretion disk, coupling between charge neutral gas and magnetic field is too weak such that the magneto-rotational instability will be less effective or even stop working. In such a situation it is of prime interest to investigate the pure hydrodynamic turbulence and transport phenomenon. As the Reynolds number increases, the relative importance of the non-linear term in the hydrodynamic equation increases and in the case of accretion disk where molecular viscosity is too small the Reynolds number is large enough for the non-linear term to bring new effects. We investigate a scenario, the ‘weakly non-linear’ evolution of amplitude of linear mode when the flow is bounded by two parallel walls. The unperturbed flow is similar to plane Couette flow but with Coriolis force included in the hydrodynamic equation. Although there is no exponentially growing eigenmode, due to self-interaction the least stable eigenmode will grow in an intermediate phase. Later on this will lead to higher order non-linearity and plausible turbulence. Although the non-linear term in the hydrodynamic equation is energy conserving, within the weakly non-linear analysis it is possible to define a lower bound of the energy needed for flow to transform to turbulent phase. Such an unstable phase is possible only if the Reynolds number ≥ 103−4. In Chapter-2 we set up equation of amplitude for the hydrodynamic perturbation and study the effect of weak non-linear evolution of linear mode for general angular momentum distribution, where Keplerian disk is obtained as a special case. As we know that to explain observed hard X-rays the choice of Keplerian angular momentum profile is not adequate, we consider the sub-Keplerian regime of the disk. In Chapter-3 we assume that the cooling mechanism is dominated by bremsstrahlung process (without any strict knowledge of the magnetic field structure).We show that in a range of Shakura-Sunyaev viscosity 0.2 ≥ α ≥ 0.0005, flow behavior varies widely, particularly by means of the size of disk, efficiency of cooling and corresponding temperatures of ions and electrons. We also show that the disk around a rotating black hole is hotter compared to that around a Schwarzschild black hole, rendering a larger difference between ion and electron temperatures in the former case. We finally reproduce the observed luminosities(L) of two extreme cases—the under-fed AGNs and quasars and ultra-luminous X-ray sources at different combinations of mass accretion rate, ratio of specific heats, Shakura-Sunyaev viscosity parameter and Kerr parameter. In Chapter-4 we investigate the viscous two temperature accretion disk flows around rotating blackholes. We describe the global solution of accretion flows, unlike that in Chapter-3, with a sub-Keplerian angular momentum profile, by solving the underlying conservation equations including explicit cooling processes self-consistently. Bremsstrahlung, synchrotron and inverse comptonization of soft photons are considered as possible cooling mechanisms. We focus on the set of solutions for sub-Eddington, Eddington and super-Eddington mass accretion rates around Schwarzschild and Kerr black holes with a Kerr parameter 0.998. We analyse various phases of advection–general advective paradigm to radiatively inefficient paradigm. The solution may potentially explain the hard X-rays and γ-rays emitted from AGNs and X-ray binaries. We also compare the solutions for two different regimes of viscosity. We finally reproduce the observed luminosities of the under-fed AGNs and quasars, ultra-luminous X-ray sources at different combinations of input parameters such as mass accretion rate and ratio of specific heats.

Stars on the asymptotic giant branch (AGB) lose a significant fraction of their mass to their surroundings through stellar winds. As a result, they are surrounded by circumstellar shells of gas and dust. This stellar mass loss replenishes and enriches the interstellar medium (ISM) with the products of stellar nucleosynthesis, progressively increasing its metallicity and thereby driving galactic chemical evolution. In this thesis I present a comprehensive study of oxygen-rich (O-rich) AGB stars and red supergiants (RSG) observed with the Spitzer Infrared Spectrograph and Infrared Space Observatory Short Wavelength Spectrometer in the Milky Way, the Large and Small Magellanic Clouds, and Galactic globular clusters; focusing on the composition of the dust in the circumstellar envelopes surrounding these stars. Combining spectroscopic and photometric observations with the GRAMS grid of radiative transfer models to derive (dust) mass-loss rates, I detect crystalline silicates in stars with dust mass-loss rates which span over a factor of 1000, down to rates of ~10^{-9} Msun/yr. Detections of crystalline silicates are more prevalent in higher mass-loss rate objects, and our results indicate that the dust mass-loss rate has a greater influence on the crystalline fraction than the gas mass-loss rate, suggesting that thermal annealing of amorphous silicate grains is the primary formation mechanism of crystalline silicates in such environments rather than the direct condensation of crystalline silicates from the gas phase. I also find that metallicity influences the composition of crystalline silicates, with enstatite seen increasingly at low metallicity, while forsterite becomes depleted at these metallicities due to the different chemical composition of the gas. To trace the evolution of alumina and silicate dust along the AGB, I present an alternative grid of MODUST radiative transfer-models for a range of dust compositions, mass-loss rates, dust shell inner radii and stellar parameters. Our analysis shows that the AKARI [11]-[15] versus [3.2]-[7] colour is a robust indicator of the fractional abundance of alumina in O-rich AGB stars. From the modelling, I show that a grain mixture consisting primarily of amorphous silicates, with contributions from amorphous alumina and metallic iron provides a good fit to the observed spectra of O-rich AGB stars in the LMC. In agreement with previous studies, we find a correlation between the dust composition and mass-loss rate; the lower the mass-loss rate the higher the percentage of alumina in the shell. Finally, I present mid-infrared observations of the Local Group dwarf elliptical galaxy M32; where I find a large population of dust-enshrouded stars. These observations will act as a pathfinder for future observations with the JWST and SPICA.

Evolved stars and planetary nebulae are rich and varied sites of molecule and dust formation. These objects undergo dramatic mass loss which ultimately enriches the interstellar medium. In this thesis, a number of studies, outlined below, have been undertaken to better understand the chemical and physical properties of these diverse objects. A molecular line survey of a sample of evolved stars and planetary nebulae has been carried out using the Mopra radio telescope, Australia. Transitions with hyperfine structure have been fitted to constrain optical depths. The population diagram method was applied to determine the rotation temperatures of molecules which had multiple transitions available. Column densities have been calculated for all detected species and isotopic ratios measured where possible. The results include the corroboration of the classification of II Lup as a J-type star. The 89.087 GHz HCN maser was detected in IRAS 15082-4808 for the first time from the aforementioned survey, bringing the total number of detections of this maser to ten. The velocity shift of this maser has been measured at −2.0+/-0.9 km/s. Drawing on literature data in addition to the survey data, the variation of maser intensity with pulsation phase has been investigated across all sources for the first time. Comparing these masers with model atmospheres constrains the formation region to between 2 and 4 stellar radii. CO in the circumstellar envelope of II Lup has been modelled using the radiative transfer codes GASTRoNOoM, and ComboCode. The models have demonstrated that a ‘standard’ smooth model does not satisfactorily reproduce the combined CO observations of PACS, JCMT, Mopra and APEX. Two potential solutions are proposed: a discontinuous temperature model, requiring the presence of an efficient cooling molecule that is most effective in the region 75-200 R*, or a variable mass loss model that requires a factor of ten increase inmass loss in the same region. Zinc abundances, a proxy for iron abundances, have been determined for a sample of Galactic planetary nebulae using the [Zn IV] 3.625 μm line. O++/O has been shown to be a reliable ionisation correction factor for Zn3+ from Cloudy photoionisation models. The majority of the sample are sub-solar in [Zn/H] and enriched in [O/Zn]. Zinc abundances as functions of Galactocentric distance have also been investigated and no evidence for a trend has been found.

Nous avons développé un détecteur intégré à base d'une diode pour être embarqué dans un ballon stratosphérique afin de caractériser l'environnement radiatif atmosphérique. Le détecteur a été calibré avec une source Californium, et il a été pleinement caractérisé lors de tests sous faisceaux de neutrons qui produisent diverses particules ionisantes secondaires. Les sections efficaces différentielles de détection pour différentes énergies de faisceaux de neutrons sont avérées être en bon accord avec les simulations effectuées avec le code MC-Oracle. Nous avons effectué un certain nombre de vols en ballon stratosphériques (avec l'ESA et le CNES) et confirmé la corrélation entre le taux de comptage et de l'altitude. En outre, nous avons observé que l'environnement radiatif n'est pas isotrope et démontré le potentiel de notre outil pour étudier l'environnement radiatif atmosphérique. Ces résultats sont utiles pour estimer le flux de particules qui affecte appareils et systèmes électroniques à bord des appareils. / We developed an integrated silicon detector to be embedded in a stratospheric balloon in order to investigate the radiative atmospheric environment. The detector was calibrated with a Californium source, and it was fully characterized under neutron beams which produced various secondary ionizing particles. Differential detection cross sections for different neutron beam energies were shown to be in good agreement with simulations performed with the MC-Oracle code. We performed four stratospheric balloon flights (with ESA and CNES) and confirmed the correlation between the count rate and the altitude. Moreover, we observed that the radiative environment is not isotropic and demonstrated the potential of our tool for investigating the radiative atmospheric environment. These results are useful for estimating the particle flux that affects electronic devices and onboard aircraft systems.

Aerosols are important atmospheric constituents that impact the Earth's radiative balance and climate. The detailed knowledge of the aerosol optical properties is required for a comprehensive analysis of the impacts of aerosols on climate. Mie theory is often used in satellite and ground-based retrieval algorithms to account for atmospheric mineral dust. However, the approximations used in Mie theory are often not appropriate for mineral dust and can lead to errors in the optical properties modeling. Analytic models based on Rayleigh theory that account for particle shapes can offer significant advantages when used to model infrared (IR) extinction of mineral dust. Here, the IR optical properties of some components of mineral dust, authentic dust samples and minerals processed with organic acids were investigated. Detailed characterization of the particles through online and offline methods of analysis that include IR extinction spectroscopy, micro-Raman spectroscopy and scanning electron microscopy was performed. Analysis of the IR extinction spectra and spectral simulations showed that the positions of the peaks and the shapes of the bands of the IR characteristic features are not well simulated by Mie theory in any of the samples studied. The resonance peaks were consistently shifted relative to the experimental spectrum in the Mie simulation. Rayleigh model solutions derived for different particle shapes better predicted the peak positions and band shapes of experimental spectra. To fill the gaps in the refractive index data for atmospherically relevant organic compounds in the IR region optical properties of atmospherically relevant carboxylic acids and humic-like substances using the IR extinction spectra and size distributions measured in the laboratory were determined. In addition to properties of mineral dust this dissertation focuses on properties of sea spray aerosol. Chemical and elemental composition of individual sea spray aerosol particles were studies using micro-Raman spectroscopy, mass-spectrometry and X-ray spectroscopy to provide insights into the biochemical processes that give rise to classes of organic molecules that make up these aerosol particles. The results suggested that degradation of biota (bacteria and diatoms) present in sea water led to lipopolysaccharides and extracellular polymeric substances that further degraded down to carbohydrates and fatty acids. Solubility of the resulting organic species seemed to play a role in their transfer to the aerosol phase. Furthermore, water uptake and hygroscopic growth of multi-component particles were studied. Understanding the interactions of water with atmospheric aerosols is crucial for determining their size, physical state, reactivity, and therefore for aerosol interactions with electromagnetic radiation and clouds. It was determined that particles composed of ammonium sulfate with succinic acid and of mixture of chlorides typical for marine environment show size dependent hygroscopic behavior. Microscopic analysis of the distribution of components within the aerosol particles showed that the observed size dependence is due to the differences in the mixing state. The composition and water uptake properties of sea spray aerosol particles were also measured during a phytoplankton bloom. The results showed that water uptake properties were directly related to the chemical composition of the particles and hygroscopicity decreased with increase in the fraction of water insoluble organic matter emitted during phytoplankton bloom. Finally, multiple methods of particle size, phase and shape analysis were compared and the results showed that the techniques that operate under ambient conditions provide the most relevant and robust measurement of particle size. Additionally, several storage methods for substrate deposited aerosol particles were evaluated and it was determined that storing samples at low relative humidity led to irreversible changes due to sample dehydration while sample freezing and thawing leads to irreversible changes due to phase changes and water condensation. Therefore it is suggested that samples used for single-particles analysis should be stored at ambient laboratory conditions, or near conditions which they were collected, in order to preserve the sample phase and hydration state. The results presented in this dissertation provide insight into physicochemical properties of atmospheric aerosols and help us better understand the role of aerosol particles in the Earth's atmosphere.