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工業製品の高機能化や低価格化実現のため，難削材と呼ばれる加工の困難な材料の高精度かつ高能率な加工方法の開発要求が増大している．そこで，本研究では難削材の難削性を，機械的・熱的特性によって分類したうえで，その難削材の適用分野を具体的に想定し，バインダレス超硬合金やCFRP，チタン合金，ステンレス合金などの難削材の高精度・高能率加工の実現に向けた新規加工工具および加工方法の開発に取り組んだ． / 博士(工学) / Doctor of Philosophy in Engineering / 同志社大学 / Doshisha University

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In turbomachines, rotors and stators differ by the rotation of the former. Hence, half of each stage is directly influenced by rotation effects. The influence of rotation on the flow structure and its impact on the performance is studied through wall-resolving large Eddy simulations of a rotor with large relative tip gap size. The simulations are performed in a rotating frame with rotation accounted for through a Coriolis force term. In a first step, experimental results are used to provide validation. The main part of the study is the comparison of the results from two simulations, one representing the rotating configuration and one with the Coriolis force removed, without any other change. This setup allows a very clean assessment of the influence of rotation. The turbulence-resolving approach ensures that the turbulent flow features are well represented. The results show a significant impact of rotation on the secondary flow. In the tip region, the tip leakage vortex is enlarged and destabilized. Inside the tip gap, the flow is altered as well, with uniformization in the rotating case. At the blade midspan, no significant effects are observed on the suction side, while an earlier transition to turbulence is found on the pressure side. Near the hub, rotation effects are shown to reduce the corner separation significantly.

Unmanned Air Vehicles (UAVs) have recently gained attention due to their increased ability to perform sophisticated missions with less cost and/or risk than their manned counterparts. This thesis develops approaches to the use of compliant mechanisms in the design of deployable wings for small UAVs. Although deployable wings with rigid-link mechanisms have been used in the past to maintain flight endurance while minimizing required storage volume, compliant mechanisms offer many advantages in manufacturability and potential space savings due to function sharing of components. A number of compliant, deployable wing concepts are generated and a classification system for them is formed. The pool of generated concepts serves as a basis for stimulating future concept ideas. A methodology is also proposed for evaluating concepts for a given application. The approach to developing compliant designs for certain applications is illustrated through two example designs, which demonstrate key portions of the proposed design process. Each is modeled and analyzed to demonstrate viability.

Global renewable energy requirements rapidly increase with the transition to a fossil-free society. As a result, intermittent energy resources, such as wind- and solar power, have become increasingly popular. However, their energy production varies over time, both in the short- and long term. Hydropower plants are therefore utilized as a regulating resource more frequently to maintain a balance between production and consumption on the electrical grid. This means that they must be operated away from the design point, also known as the best-efficiency-point (BEP), and often are operated at part-load (PL) with a lower power output. Moreover, some plants are expected to provide a spinning reserve, also referred to as speed-no-load (SNL), to respond rapidly to power shortages. During this operating condition, the turbine rotates without producing any power. During the above mentioned off-design operating conditions, the flow rate is restricted by the closure of the guide vanes. This changes the absolute velocity of the flow and increases the swirl, which is unfavorable. The flow field can be described as chaotic, with separated regions and recirculating fluid. Shear layer formation between stagnant- and rotating flow regions can be an origin for rotating flow structures. Examples are the rotating-vortex-rope (RVR) found during PL operation and the vortical flow structures in the vaneless space during SNL operation, which can cause the flow between the runner blades to stall, also referred to as rotating stall. The flow structures are associated with pressure pulsations throughout the turbine, which puts high stress on the runner and other critical parts and shortens the turbine's lifetime. Numerical models of hydraulic turbines are highly coveted to investigate the detrimental flow inside the hydraulic turbines' different sections at off-design operating conditions. They enable the detailed study of the flow and the origin of the instabilities. This knowledge eases the design and assessment of mitigation techniques that expand the turbines' operating range, ultimately enabling a wider implementation of intermittent energy resources on the electrical grid and a smoother transition to a fossil-free society. This thesis presents the numerical study of the Porjus U9 model, a scaled-down version of the 10 MW prototype Kaplan turbine located along the Luleå river in northern Sweden. The distributor contains 20 guide vanes, 18 stay vanes and the runner is 6-bladed. The numerical model is a geometrical representation of the model turbine located at Vattenfall Research and Development in Älvkarleby, Sweden. The commercial software ANSYS CFX 2020 R2 is used to perform the numerical simulations. Firstly, the draft tube cone section of the U9 model is numerically studied to investigate the sensitivity of a swirling flow to the GEKO (generalized kω) turbulence model. The GEKO model aims to consolidate different eddy viscosity turbulence models. Six free coefficients are changeable to tune the model to flow conditions and obtain results closer to an experimental reference without affecting the calibration of the turbulence model to basic flow test cases. Especially, the coefficients affecting wall-bounded flows are of interest. This study aims to analyze if the GEKO model can be used to obtain results closer to experimental measurements and better predict the swirling flow at PL operation compared to other eddy viscosity turbulence models. Results show that the near-wall- and separation coefficients predict a higher swirl and give results closer to experimentally obtained ones. Secondly, a simplified version of the U9 model is investigated at BEP and PL operating conditions and includes one distributor passage with periodic boundary conditions, the runner and the draft tube. The flow is assumed axisymmetric upstream of the runner, hence the single distributor passage. Previous studies of hydraulic turbines operating at PL show difficulties predicting the flow's tangential velocity component as it is often under predicted. Therefore, a parametric analysis is performed to investigate which parameters affect the prediction of the tangential velocity in the runner domain. Results show that the model predicts the flow relatively well at BEP but has problems at PL; the axial velocity is overpredicted while the tangential is underpredicted. Moreover, the torque is overpredicted. The root cause for the deviation is an underestimation of the head losses. Another contributing reason is that the runner extracts too much swirl from the flow, hence the low tangential velocity and the high torque. Sensitive parameters are the blade clearance, blade angle and mass flow. Finally, the full version of the U9 model is analyzed at SNL operation, including the spiral casing, full distributor, runner and draft tube. During this operating condition, the flow is not axisymmetric; vortical flow structures extend from the vaneless space to the draft tube and the flow stalls between the runner blades. A mitigation technique with independent control of each guide vane is presented and implemented in the model. The idea is to open some of the guidevanes to BEP angle while keeping the remaining ones closed. The aim is to reduce the swirl and prevent the vortical flow structures from developing. Results show that the flow structures are broken down upstream the runner and the rotating stall between the runner blades is reduced, which decreases the pressure- and velocity fluctuations. The flow down stream the runner remains mainly unchanged.

Целью диссертационного исследования является изучение процессов восстановления нитрогруппы в препаратах азоло-азинового ряда с применением электрохимических методов и ЭПР-спектроскопии. Для достижения стабильных и воспроизводимых данных была разработана методика эксперимента. Рассмотрены вопросы электровосстановления фармпрепаратов содержащих нитрогруппу в своем строении и применение ЭПР – спектроскопии и электрохимических методов анализа, в частности вольтамперометрии, для установления механизма восстановления лекарственных веществ в теле человека. В ходе экспериментальной части установлена природа происходящих процессов, в том числе, природа лимитирующей стадии, проведен расчет количества электронов, принимающих участие в процессах электровосстановления основного вещества препаратов TRIAZAVIRIN® и TRIAZID®. Предложены вероятные механизмы протекания исследуемого процессов восстановления нитрогруппы исследуемых соединений. / The main substances of the newest Russian antiviral drugs, the aziolo-azine series TRIAZAVIRIN® and TRIAZID®, served as the research subjects. Objective: to study the processes of reduction of the nitro group in these compounds using electrochemical methods and EPR spectroscopy. An analysis of the literature data showed that the pharmaceutical activity of preparations containing a nitro group is due to its reduction. Electrochemical methods of analysis make it possible to study the in vitro transformation of the preparation as close as possible to the processes taking place with the drug in vivo. The method of EPR-spectroscopy allows obtaining reliable data on the free radical formed during the reaction, which can be a determining factor of the biological activity of the preparation. These methods were taken as a basis for studying the processes of nitro group reduction, which is a part of the basic substances of TRIAZAVIRIN® (TRZ) and TRIAZID® (TZ) preparations. The processes of nitro group reduction in TRZ and TZ molecules were studied using voltammetry and EPR spectroscopy. It has been established that the rate of reduction of the nitro group TRZ is controlled by diffusion, the process of reduction of the nitro group of the preparation is stepwise, irreversible and proceeds at a potential of -0.35 V through the formation of an anion radical with addition of 4e. It is shown that the rate of reduction of the nitro group of TZ is controlled by diffusion. The single-wave reduction process of the nitro group TZ at a potential of 6 -0.65 V is irreversible, goes through the formation of an anion radical with addition of 6e. Possible schemes for the recovery of the nitro group of the basic substances of TRIAZAVIRIN® and TRIAZID® preparations are proposed.

<p dir="ltr">Burst-mode lasers and burst-mode optical parametric oscillators (OPOs) are applied and developed for planar laser induced fluorescence (PLIF) measurements of key species for high-speed combustion measurements. OH-PLIF in the rotating detonation engine was performed for the first time at wave structure visualization in two different planes and was 10 times faster than any other burst mode OH-PLIF measurements at the time. The same system was used to perform another OH-PLIF experiment at 1 MHz for ~200 pulses to compare key features of the detonation wave structure with computational fluid dynamic simulations and a fundamental detonation tube experiment. The system was also used for seedless velocity measurements in the exhaust by tracking a pocket of OH with a technique called FLASH. A similar OPO was built, aligned, and tuned to perform 1 MHz NO PLIF in a Mach 10 hypersonic tunnel to visualize second mode instabilities and calculate the frequency in the boundary layer transition of a 7-degree cone. A high-efficiency OPO was developed and characterized utilizing the KTP crystal to provide narrow bandwidth pulses for the fluorescence of multiple species. The OPO was pumped at repetition rates up to 1 MHz and was calculated to have a 1.9% UV efficiency from the fundamental 1064 nm output. This is 3 – 5 times increase in efficiency from previous custom and commercial built OPOs. The OPO was applied to the RDC for OH PLIF in the combustor channel and NO PLIF for injector dynamics and response studies. Lastly, a burst-mode laser was used to perform LII on the post detonation blast flow field to measure explosively generated soot. The data was taken at 1 MHz and compared and corrected with a separate set of experiments and computational simulations.</p>

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