Kinetics of hydrate formation and decomposition of methane hydrate formed in silica sand particles were studied in detail at three temperatures of 7.0, 4.0 and 1.0°C, respectively. A new apparatus was setup to study the decomposition behavior of the methane hydrate formed in the bed of silica sand particles. Six thermocouples are placed in different locations to study the temperature profiles during hydrate formation and decomposition experiments. Gas uptake measurement curves for the formation experiments and the gas release measurement curves for the decomposition experiment were determined from the experimental data. Percent conversion of water to hydrates was significantly higher for the experiments conducted at 4.0 and 1.0°C compared to 7.0°C. Recovery of methane occurred in two stages during the decomposition experiments carried out with a thermal stimulation approach at constant pressure. Methane recovery in the range of 95 to 98% was achieved.

Raman spectroscopic observations of the characteristics and dissociation of methane hydrate were carried out on hydrates synthesized in silica sands with particle sizes of 53-75 μm, 90-106 μm, 106-150 μm, and 150-180 μm. The results obtained indicate that methane hydrates formed in silica sands had similar characteristics regarding cage occupancy and hydration number (5.99) to bulk hydrate, indicative of no influence of particle size on hydrate composition. During hydrate dissociation, the change in average intensity ratio of large to small cages were generally consistent with that of bulk hydrate but dropped dramatically after a certain time, and this turning point seems to be related to the particle size of silica sands.

A gas hydrate production test using the depressurization method was conducted in early April 2007 as part of the JOGMEC/NRCan/Aurora Mallik production research program. The results of the production test were analyzed using a numerical simulator (MH21-HYDRES) coded especially for gas hydrate reservoirs. This paper evaluates the test results based on analyses of production test data, numerical modeling and a series of history matching simulations. Methane gas and water was produced from a 12 m perforation interval within one of the major methane hydrate (MH) reservoirs at the Mallik MH field, by reducing the bottomhole pressure down to about 7 MPa. The measured gas production rate was far higher than that expected for a comparatively small pressure drawdown. However, irregular (on-off) pumping operations, probably related to excessive sand production, resulted in unstable fluid flow within the wellbore, which made the analysis of test performance extremely complicated. A numerical reservoir model was constructed as a series of grid blocks, including those mimicking the wellbore, to enable rigorous simulation of fluid flow patterns in the vicinity of the wellbore. The model was then tuned through history matching, not by simply adjusting reservoir parameters, but by introducing the concept that sand production might have dramatically increased the near-wellbore permeability. The good agreement between observed and simulated performances suggests the mechanism of MH dissociation/production during the test. The history matched reservoir model was employed to predict the second-year production test performance, in order to examine the gas production potential of the Mallik MH reservoir, and to provide insight into future exploration and development planning for MH reservoirs.

The 19th century French novel has a well-know model called Bildung Novel. The inspiration for this name comes from Wilhem Meister by Goethe published in 1795. In this type of writing we witness the education (Bildung) of a hero or a heroin who has to face and overcome a series of difficulties. / In this memoire we will analyze the theme of education in the works of two authors Stendhal and George Sand. We have chosen two novels from each author, one dating back to the beginning of their career, and the other to the end. For Stendhal we have selected Le Rouge et le Noir (1830) and Lucien Leuwen (posthume publication 1894); Mauprat (1837) and La Ville Noire (1861) by Sand. / In each novel we will analyze family education, intellectual and moral training, life experience and sentimental education successively in the same way the heros experience them. / To do this we use thematic method which, as Jean Starobinski puts it, considers the theme as a unit of meaning of the novel. / In the conclusion we will compare the results of our analyses in the works of Stendhal and George Sand.

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The impact of development on coastal ecological processes within the coastal zone is often noted as being of ecological concern, due to the suggested destabilization of dune systems as a result of construction activities and post construction impacts such as stormwater disposal, trampling and other artificial influences on, in particular, the plant ecology of the frontal dune systems. Given that the stability of frontal dune systems along the Kwa Zulu Natal north coast is often attributed to the maintenance of vegetation and seral progression on such systems, the identification of changes in dune plant communities that may arise from the influence of proximal or adjacent activities was sought to be identified. Utilising data collected from a number of sites in the Kwa Dukuza Municipal area, the classification and ordination of environmental and botanical species information collated over approximately 6 months was undertaken. The results of this investigation indicate that: Species composition differs in terms of richness and abundance in the three frontal dune vegetation zones sampled. 2 3 4 5 Some species occur in all three zones and others are confined to one zone only. Bearing and the associated influence of wind, the slope and length of the beach, and the steepness ofthe dune face all influence the species composition at any particular site The influence of anthropogenic activities on dune synusia is such that human influence on one species may disrupt associations between species and may result in attenuation or '" reversal of seral movement. Anthropogenic impacts influences species composition at different sites by causing some species to decline abundance or disappear from a site and others to invade or oust established species. In Zone I the species that appears to be most affected by human activity is Gazania rigens, which appears to dominate in sites of high human activity, at the expense of Sporobolus virginicus. In Zone IT under high human activity species such as Cynanchum obtusifolium, Rhoicissus digitata and Sporobolus virginicus dominate, while the woody species Mimusops caffra and Eugenia capensis, as well as the liane Gloriosa superba appear to decline or be ousted from this Zone. In Zone Ill, Asystasia gangetica, is a dominant species where low to moderate human impacts are encountered, while where human impacts are high, species common to Zone I, such as G rigens may become prevalent, ousting A gangetica and grasses such as S virginicus may be ousted by more competitive species such as Stenotaphrum secundatum. It is thus concluded that human activities in and around the frontal dune system may be influential in re-inforcing aeolian impacts on sites with bearings affected by strong prevailing winds. / Thesis (M.Sc.)-University of KwaZulu- Natal,Durban, 2004.