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  • About
  • The Global ETD Search service is a free service for researchers to find electronic theses and dissertations. This service is provided by the Networked Digital Library of Theses and Dissertations.
    Our metadata is collected from universities around the world. If you manage a university/consortium/country archive and want to be added, details can be found on the NDLTD website.
231

Contributions à la résolution du transport à la demande fondées sur les systèmes multi-agents / Contributions to on-demand transport resolution based on multi-agent systems

Malas, Anas 18 May 2017 (has links)
Cette thèse porte sur le problème du transport à la demande (TAD). Nous proposons trois approches décentralisées basées sur les systèmes multi-agents pour résoudre ce problème. La première approche multi-agent utilise l'algorithme A* afin de trouver une solution optimale dans un réseau routier caractérisé par des vitesses de voyage constantes. Des expérimentations sont effectuées sur le réseau routier d'une ville libanaise appelée Tripoli et de bons résultats sont obtenus. Cependant, dans une ville comme Tripoli, les vitesses de voyage dépendent fortement de la situation dynamique du trafic routier. Pour cette raison, la deuxième approche multi-agent massif vient remédier à la première en tenant compte de l'évolution du trafic. Le réseau routier est considéré comme dynamique déterministe. Il se caractérise par des vitesses de voyages dépendantes de la situation habituelle du trafic. Ces vitesses sont pré-calculées en se basant sur des connaissances historiques du trafic routier. Les résultats expérimentaux montrent que le nombre de clients insatisfaits est supérieur à 50 % si les vitesses sont considérées comme constantes. Or, les connaissances historiques ne suffisent pas pour refléter la situation réelle du trafic surtout en cas d'apparition d'un événement imprévu tel qu'un accident sur le réseau. Pour cela, une troisième approche multi-agent massif auto-organisé est proposée. Le réseau routier est considéré comme dynamique stochastique caractérisé par des vitesses de voyage dépendantes de la situation réelle du trafic. Cette approche représente l'organisation dynamique du trafic à son échelle en se basant sur des connaissances historiques du trafic et sur des informations du trafic en temps réel. Les trajectoires des véhicules et leurs durées sont calculées et recalculées en ligne à chaque fois qu'un événement imprévu perturbe la situation habituelle du trafic. Les résultats expérimentaux montrent que jusqu'à 39 % des clients seront insatisfaits si un accident routier n'est pas considéré durant le traitement de leurs demandes. Autrement, 50 % à 100 % de ces clients sont satisfaits. / This thesis addresses the problem of on-demand transport (ODT). We propose three decentralized approaches based on multi-agent systems to solve this problem. The first multi-agent approach uses the algorithm A* in order to find an optimal solution in a road network characterized by constant travel speeds. Experiments are carried out on the road network of a Lebanese city called Tripoli and good results are obtained. However, in a city like Tripoli, travel speeds depend heavily on the dynamic situation of road traffic. For this reason, the second multi-agent approach massif comes to remedy the first taking into account the evolution of traffic. The road network is considered as dynamic deterministic. It is characterized by travel speeds dependent on the usual traffic situation. These speeds are pre-calculated on the basis of historical knowledge of road traffic. The experimental results show that the number of dissatisfied customers is greater than 50 % if the speeds are considered to be constant. Nevertheless, historical knowledge is not sufficient to reflect the actual traffic situation, especially in case of an unexpected event (such as an accident) occurring on the network. For this, a self-organized massive multi-agent approach is proposed. The road network is considered as a dynamic stochastic characterized by travel speeds dependent on the actual traffic situation. This approach represents the dynamic organization of traffic on its scale based on historical traffic knowledge and real-time traffic information. Vehicle trajectories and their durations are calculated and recalculated online whenever an unexpected event disrupts the usual traffic situation. The experimental results show that up to 39 % of customers will be dissatisfied if a road accident is not considered during the processing of their demands. Otherwise, 50 % to 100 % of these customers are satisfied.
232

Rekonfigurierbare Schnittstellen

Ihmor, Stefan, Flade, Marcel 02 March 2006 (has links)
Die neu ins Leben gerufene Schriftenreihe EINGEBETTETE, SELBSTORGANISIERENDE SYSTEME (ESS) widmet sich einer sehr aktuellen Thematik der Technischen Informatik. Seit Jahren durchdringen eingebettete Systeme unseren Alltag in fast allen Lebensbereichen. Angefangen von automatisierten Türöffnungssystemen, über komplex gesteuerte Servicemaschinen, z.B. Waschmaschinen, bis hin zu mobilen, persönlich zugeordneten Systemen wie Mobiltelefone und Handheld-Computer sind eingebettete Systeme zur Selbstverständlichkeit geworden. Der Aspekt der rekonfigurierbaren Schnittstellen zwischen einzelnen Komponenten eingebetteter Systeme wird in diesem ersten Band aufgegriffen. Der erste Beitrag befasst sich mit der systematischen Modellierung von Schnittstellen. Zunächst werden aktive Tasks und Kommunikationsmedien unterschieden sowie die Parameter der Zielarchitektur in den Entwurfsprozess für Schnittstellen eingebracht. Darauf aufbauend wird eine systematische Konzeption von Schnittstellen vorgestellt und bewertet. Der zweite Beitrag betrachtet das Problem der Rekonfigurierung von Schnittstellen zur Gewährleistung von sicherer Funktionalität, auch im Fehlerfall. Die Fehlererkennung und –behandlung werden von der erweiterten Schnittstelle implementiert. In dem dritten Beitrag untersucht Marcel Flade Schnittstellen in Hardware/Software-Systemen. Dabei stellt sich das Problem, die Kontrolle über die Funktionalität der Schnittstelle auf den Software- und Hardwareteil aufzuteilen. Die Beiträge werden durch eine vollständige Implementierung eines Beispiels und eines Werkzeugs zur automatisierten Generierung der VHDL-Implementierung abgerundet. Mit diesen ausgewählten Arbeiten, die in den ersten Band dieser wissenschaftlichen Schriftenreihe aufgenommen sind, werden dem Leser grundlegende Aspekte rekonfigurierbarer Schnittstellen für eingebettete, selbstorganisierende Systeme vorgestellt.
233

Role náhody v novo-mediálním umění na příkladu tvorby Zdeňka Sýkory / The role of randomness in new media art on the example of Zdeněk Sýkora

Poliaková, Karolína January 2018 (has links)
The paper maps the use of the principle of randomness in artistic activity with a focus on visual art and the placement of Czech art into the world context. It examines the hypothesis whether randomness in the hands of the artist becomes an instrument to objectify his or her work and to approach the general principles of the natural world, which, according to the assumption, add novelty and consequently increases its artistic value. The text begins with an etymological interpretation of the concept of randomness, further observes the randomness as phenomenon in various social spheres, and eventually presents the artistic movements and artworks that systematically use randomness. An overview of avant-garde art and abstraction of the first half of the 20th century will allow the author to interpret the principles of randomness used in computer art. The work concludes with a detailed analysis of Zdeněk Sýkora's work, in which, according to the author, the development line of precomputational art is mirrored, along with a breakthrough to digital tools. The conclusion of the work reveals the diversity of the application of the principle of randomness in the art world and finds a common divisor in the objectivizing function, respectively the rising aesthetic value. Through this interpretation, Zdeněk...
234

A theoretical study of dispersion-to-aggregation of nanoparticles in adsorbing polymers using molecular dynamics simulations

Cao, Xue-Zheng, Merlitz, Holger, Wu, Chen-Xu, Ungar, Goran, Sommer, Jens-Uwe 16 December 2019 (has links)
The properties of polymer–nanoparticle (NP) mixtures significantly depend on the dispersion of the NPs. Using molecular dynamics simulations, we demonstrate that, in the presence of polymer–NP attraction, the dispersion of NPs in semidilute and concentrated polymers can be stabilized by increasing the polymer concentration. A lower polymer concentration facilitates the aggregation of NPs bridged by polymer chains, as well as a further increase of the polymer–NP attraction. Evaluating the binding of NPs through shared polymer segments in an adsorption blob, we derive a linear relationship between the polymer concentration and the polymer–NP attraction at the phase boundary between dispersed and aggregated NPs. Our theoretical findings are directly relevant for understanding and controlling many self-assembly processes that use either dispersion or aggregation of NPs to yield the desired materials.
235

Ion beam processing of surfaces and interfaces – Modeling and atomistic simulations

Liedke, B. January 2011 (has links)
Self-organization of regular surface pattern under ion beam erosion was described in detail by Navez in 1962. Several years later in 1986 Bradley and Harper (BH) published the first self-consistent theory on this phenomenon based on the competition of surface roughening described by Sigmund’s sputter theory and surface smoothing by Mullins-Herring diffusion. Many papers that followed BH theory introduced other processes responsible for the surface patterning e.g. viscous flow, redeposition, phase separation, preferential sputtering, etc. The present understanding is still not sufficient to specify the dominant driving forces responsible for self-organization. 3D atomistic simulations can improve the understanding by reproducing the pattern formation with the detailed microscopic description of the driving forces. 2D simulations published so far can contribute to this understanding only partially. A novel program package for 3D atomistic simulations called trider (TRansport of Ions in matter with DEfect Relaxation), which unifies full collision cascade simulation with atomistic relaxation processes, has been developed. The collision cascades are provided by simulations based on the Binary Collision Approximation, and the relaxation processes are simulated with the 3D lattice kinetic Monte-Carlo method. This allows, without any phenomenological model, a full 3D atomistic description on experimental spatiotemporal scales. Recently discussed new mechanisms of surface patterning like ballistic mass drift or the dependence of the local morphology on sputtering yield are inherently included in our atomistic approach. The atomistic 3D simulations do not depend so much on experimental assumptions like reported 2D simulations or continuum theories. The 3D computer experiments can even be considered as ’cleanest’ possible experiments for checking continuum theories. This work aims mainly at the methodology of a novel atomistic approach, showing that: (i) In general, sputtering is not the dominant driving force responsible for the ripple formation. Processes like bulk and surface defect kinetics dominate the surface morphology evolution. Only at grazing incidence the sputtering has been found to be a direct cause of the ripple formation. Bradley and Harper theory fails in explaining the ripple dynamics because it is based on the second-order-effect ‘sputtering’. However, taking into account the new mechanisms, a ‘Bradley-Harper equation’ with redefined parameters can be derived, which describes pattern formation satisfactorily. (ii) Kinetics of (bulk) defects has been revealed as the dominating driving force of pattern formation. Constantly created defects within the collision cascade, are responsible for local surface topography fluctuation and cause surface mass currents. The mass currents smooth the surface at normal and close to normal ion incidence angles, while ripples appear first at θ ≥ 40°. The evolution of bimetallic interfaces under ion irradiation is another application of trider described in this thesis. The collisional mixing is in competition with diffusion and phase separation. The irradiation with He+ ions is studied for two extreme cases of bimetals: (i) Irradiation of interfaces formed by immiscible elements, here Al and Pb. Ballistic interface mixing is accompanied by phase separation. Al and Pb nanoclusters show a self-ordering (banding) parallel to the interface. (ii) Irradiation of interfaces by intermetallics forming species, here Pt and Co. Well-ordered layers of phases of intermetallics appear in the sequence Pt/Pt3Co/PtCo/PtCo3/Co. The trider program package has been proven to be an appropriate technique providing a complete picture of mixing mechanisms.
236

Min-Protein Waves on Geometrically Structured Artificial Membranes

Schweizer, Jakob 06 February 2013 (has links)
Das stäbchenförmige Bakterium Escherichia coli teilt sich in zwei gleich große Tochterzellen. Dies ist nur möglich, wenn sich die Zelle in der Mitte teilt. Bei E. coli wird die Zellteilung durch den Zusammenschluss der FtsZ-Proteine an der Membran zum Z-Ring eingeleitet. Topologische Regulierung des Z-Ringes erfolgt durch räumlich-zeitliche Oszillationen von Min-Proteinen zwischen den beiden Zellpolen. MinC, MinD und MinE binden an und lösen sich von der Membran unter Hydrolyse von ATP und in antagonistischer Art und Weise, was zu einer alternierenden Ansammlung von MinC und MinD an den Zellpolen führt. Gemittelt über die Zeit ergibt sich somit ein MinD-Verteilungsprofil, das maximale Konzentration an den Zellpolen und ein Minimum in der Zellmitte aufweist. MinC bindet an MinD und folgt somit seiner Verteilung. Der Zusammenschluss von FtsZ-Proteinen wird durch MinC unterbunden, und somit kann sich der Z-ring nur an einer Position herausbilden, die ein Minimum an MinC aufweist - der Zellmitte. Das Min-system wurde in der Vergangenheit auch mit einem in-vitro-Ansatz untersucht, indem Min-Proteine in künstliche, aufliegende Lipiddoppelschichten (supported lipid bilayers, SLB) rekonstitutiert wurden. Dabei bildeten die Min-Proteine kein oszillierendes Muster aus, sondern organisierten sich vielmehr in parallelen und propagierenden Wellen (Loose, 2008, Science, 320). In diesen in-vitro-Experimenten war das Membransubstrat wesentlich größer als die Wellenlänge der Min-Proteinwellen. In vivo hingegen ist die Länge der Zelle in der gleichen Größenordnung wie die charakteristische Länge des Oszillationsmusters der Min-Proteine. Daher war es das Ziel dieser Arbeit, den Einfluß einer beschränkten Fläche und geometrischer Formgebung der künstlichen Lipiddoppelschichten auf die Wellenpropagation der Min-Protein zu untersuchen. Flächige Beschränkung künstlicher Membranen erfolgte durch Mikrostrukturtechnologie. Deckglässchen wurden mit einer Goldschicht und mikroskopischen Aussparungen unterschiedlicher geometrischer Formen strukturiert. Funktionale SLBs bildeten sich nur auf Glasflächen ohne Goldbeschichtung aus. Nach der Rekonstitution der Min-Proteine, organisierten sich diese auf den Membranstücken in parallele Wellen. Dabei bestimmte die flächige Beschränkung der künstlichen Membranen die Ausbreitungsrichtung der Min-Proteinwellen. Min-Proteinwellen konnten entlang gekrümmter Membranstreifen, in Ring- und sogar in Slalomstrukturen geleitet werden. In geraden, länglichen Strukturen richteten sich die Wellen entlang der längsten Achse aus. Kopplung von Proteinwellen auf räumlich getrennten Membranstücken in Abhängigkeit des Abstandes und des sogenannten Molecular Crowdings in der wässrigen Lösung konnte ebenfalls beobachtet werden. Diese Kopplung ist ein Indiz für inhomogene Proteinverteilungen in der Lösung oberhalb der Membran. Desweiteren konnten Min-Proteinwellen auch in diversen dreidimensionalen künstlichen Membranen rekonstitituiert werden. Im Wildtyp von E. coli ähneln die Min-Proteindynamiken der einer Oszillation mit einer charakteristischen Länge von 5 µm. Auf SLBs, bilden Min-Proteine Wellen mit einer Wellenlänge aus, die ca. zehnmal größer ist als in vivo. Dieser Unterschied zwischen der in-vivo- und der in-vitro-Welt wurde untersucht und diskutiert. In vitro konnte die Wellenlänge um 50 % durch Erhöhung des Molecular Crowding in der Lösung sowie um 33 % durch Temperaturerhöhung verkleinert werden. Das oszillierende Muster könnte dahingegen eine Folge der Kompartimentierung sein. Erste Versuche, das Min-System in geschlossene Membrankompartimente zu rekonstitutieren, wurden getestet. / Escherichia coli, a rod-like bacterium, divides by binary fission. Cell division into two daughter cells of equal size requires that fission takes place at a midcell position. In E. coli, cell division is initiated by assembly of the FtsZ-proteins at the inner membrane to the Z-ring. Topological regulation of the Z-ring is achieved by spatiotemporal pole-to-pole oscillations of Min-proteins. MinC, MinD and MinE bind to and detach from - under hydrolysis of ATP - the membrane in an antagonistic manner leading to an alternating accumulation of MinC and MinD at the cell poles. Averaged over time, the distribution profile of MinD exhibits maximal concentration at the cell poles and a minimum at the cell center. MinC binds to MinD and thus follows its distribution. FtsZ assembly is inhibited by MinC and therefore the Z-ring can only form at a cell position low in MinC - at the cell center. In the past, the Min-system was also investigated in an in vitro approach by reconstitution of Min-proteins into a supported lipid bilayer (SLB). Here, Min-proteins did not self-organize into an oscillatory pattern but into parallel and propagating waves (Loose, 2008, Science, 320). In this in vitro assay, the membrane substrate was infinitely large compared to the wavelength. However, in vivo, the cell length is on the same order of magnitude as the respective length scale of the oscillatory pattern of Min-proteins. Therefore, we wished to investigate the effect of lateral confinement and geometric structuring of artificial lipid bilayers on the Min-protein wave propagation. Lateral confinement of artificial membranes was achieved by microfabrication technology. Glass slides were patterned by a gold coating with microscopic windows of different geometries, and functional SLBs were only formed on uncoated areas. Upon reconstitution, Min-proteins organized into parallel waves on the geometric membrane patches. Confinement of the artificial membranes determined the direction of propagation of Min-protein waves. Min-protein waves could be guided along curved membrane stripes, in rings and even along slalom-geometries. In elongated membrane structures, the protein waves always propagate along the longest axis. Coupling of protein waves across spatially separated membrane patches was observed, dependent on gap size and level of molecular crowding of the aqueous media above the bilayer. This indicates the existence of an inhomogeneous and dynamic protein gradient in the solution above the membrane. Furthermore, reconstitution of Min-protein waves in various three-dimensional artificial membranes was achieved. In wild-type E. coli, Min-protein dynamics resemble that of an oscillation with a characteristic length scale of 5 µm. On supported lipid bilayers, Min-proteins self-organize into waves with a wavelength approximately 10-fold larger than in vivo. These discrepancies between the in vivo and in vitro world were investigated and discussed. In vitro, the wavelength could be decreased by a factor of 50 % by increase of the molecular crowding in solution and by 33 % through temperature increase. The oscillatory pattern is thought to be a consequence of compartmentalization and first attempts to encapsulate the Min-system in closed bilayer compartments are presented.
237

[en] FIOT: AN AGENT-BASED FRAMEWORK FOR SELF-ADAPTIVE AND SELF-ORGANIZING INTERNET OF THINGS APPLICATIONS / [pt] FIOT: UM FRAMEWORK BASEADO EM AGENTES PARA APLICAÇÕES AUTO-ORGANIZÁVEIS E AUTOADAPTATIVAS DE INTERNET DAS COISAS

NATHALIA MORAES DO NASCIMENTO 01 June 2016 (has links)
[pt] A ideia principal da Internet das Coisas (IoT) é conectar bilhões de coisas à Internet nos próximos anos, a exemplo de carros, roupas e comidas. Entretanto, muitos problemas precisam ser resolvidos antes que essa ideia possa ser concretizada. Alguns desses problemas estão relacionados à necessidade de construir sistemas para IoT que sejam auto-organizáveis e autoadaptativos. Este trabalho, portanto, apresenta a elaboração do Framework para Internet das Coisas (FIoT), que oferece suporte ao desenvolvimento de aplicações para IoT com essas características. Ele é baseado nos paradigmas de Sistemas Multiagente (SMA) e algumas técnicas abordadas em Aprendizado de Máquina, a exemplo de redes neurais e algoritmos evolutivos. Um agente pode ter algumas características, como autonomia e sociabilidade, que tornam SMAs compatíveis com sistemas que requerem auto-organização. Redes neurais e algoritmos de evolução vêm sendo comumente usados nos estudos de robótica, no intuito de prover autonomia e adaptação à agentes físicos (ex.: robôs, sensores). Para demonstrar o uso do FIoT, dois grupos de problemas em IoT serão instanciados: (i) Cidades Inteligentes e (ii) Quantificação de Coisas. / [en] The agreed fact about the Internet of Things (IoT) is that, within the coming years, billions of resources, such as cars, clothes and foods will be connected to the Internet. However, several challenging issues need to be addressed before the IoT vision becomes a reality. Some open problems are related to the need of building self-organizing and self-adaptive IoT systems. To create IoT applications with these features, this work presents a Framework for Internet of Things (FIoT). Our approach is based on concepts from Multi-Agent Systems (MAS) and Machine Learning Techniques, such as a neural network and evolutionary algorithms. An agent could have characteristics, such as autonomy and social ability, which makes MAS suitable for systems requiring self-organization (SO). Neural networks and algorithms of evolution have been commonly used in robotic studies to provide embodied agents (as robots and sensors) with autonomy and adaptive capabilities. To illustrate the use of FIoT, we derived two different instances from IoT applications: (i) Quantified Things and (ii) Smart Cities. We show how exible points of our framework are instantiated to generate an application.
238

A new Content Distribution Network architecture - PlentyCast

Cao, Wei Qiu January 2004 (has links)
Content Distribution Networks have existed for some years. They involve the following problem domains and have attracted attention both in academic research and industry: content replica placement, content location and routing, swarm intelligence, and overlay network self-organization for this type of distributed system. In this project, we propose a novel Content Distribution Network architecture – PlentyCast. This study focuses on improving access latency, network scalability, high content availability, low bandwidth consumption, and improving infrastructure performance for Content Distribution Networks. Outstanding problems such as: Flash crowd, DoS, and difficulty of traffic engineering due to Peer-to-Peer are addressed. / Mediadistributionsnätverk har funnits några år. De har fått uppmärksamhet i både akademisk forskning och i industrin och kännetecknas av följande frågor: placering av innehållskopior, lokalisering av innehåll och routing, svärm intelligens, överlagrade nätverks självorganisering för denna typ av fördelade system. I denna rapport studeras en ny nätverksarkitektur för innehållsfördelning - PlentyCast. Denna studie fokuserar på tillgångslatens, nätverksskalbarhet, hög innehållstillgång, låg bandbreddskonsumtion, och förbättrad infrastrukturprestanda för Innehållsfördelningsnätverk.
239

Une approche autonome pour la gestion logicielle des espaces intelligents / An autonomic approach for the software management of smart spaces

Gouin-Vallerand, Charles 23 June 2011 (has links)
Depuis une vingtaine d'années, les développements dans les technologies de l'information ont fait évoluer les paradigmes de l'informatique. L'arrivée d'approches telles que l'informatique diffuse ont fait émerger de nouvelles technologies permettant d'améliorer la qualité des interactions avec les systèmes informatisés. Toutefois, la démocratisation de l'informatique diffuse et la mise en place des espaces intelligents rencontrent un bon nombre de problèmes. Le nombre important de composantes matérielles et logicielles et leurs natures hétérogènes contribuent à la complexité de déploiement et de gestion de ces milieux, entraînant des coûts élevés. Cette thèse vise à contribuer à la gestion logicielle des espaces intelligents par la réduction de la complexité des tâches de gestion. Notre proposition consiste en une approche autonome de la gestion logicielle, fondée sur l'approche de l'informatique diffuse autonome. Dans le cadre de ce travail, nous proposons une solution utilisant les informations contextuelles des milieux, afin de déterminer quelle répartition des logiciels parmi les appareils des milieux correspond le mieux au besoin des applications, des caractéristiques propres des environnements et, non le moindre, des modalités et préférences d’interaction des utilisateurs de ces milieux. La solution proposée a été implémentée et évaluée à l’aide d’une série de tests et de mises en situation d’organisation logicielle / Since two decades, the developments in the information technologies have changed the computer science paradigms. The arrival of new approaches such as the pervasive computing create new technologies, which improved the quality of the interactions with the I.T. systems, However, the broad utilization of the pervasive computing and the development of smart spaces are facing several challenges. The large number of hardware and software components and their heterogeneous natures, contributes to the complexity of deploying and managing these environments, resulting in high costs. This thesis contributes to the software management of the smart spaces by reducing the complexity of the management tasks. Our proposal consists of an autonomic approach to software management based on the autonomic pervasive computing. As part of this work, we propose a solution using the environment’s contextual information to determine the software distribution among the environment’s devices, which best fits the needs of the software, environments and the interaction modalities and preferences of the environment’s users. The proposed solution was implemented and evaluated using a series of tests and software organization scenarios
240

Etude par microscopie optique des comportements spatio-temporels thermo- et photo-induits et de l’auto-organisation dans les monocristaux à transition de spin / Optical microscopy studies of thermo- and photo-induced spatiotemporal behaviors and self-organization in switchable spin crossover single crystal

Sy, Mouhamadou 15 June 2016 (has links)
Ce travail de thèse est dédié à la visualisation par microscopie optique des transitions de phases, thermo- et photo-induites dans des monocristaux à transition de spin. L’étude des cristaux du composé [{Fe(NCSe)(py)2}2(m-bpypz)] a permis de montrer la possibilité de contrôler la dynamique de l’interface HS/BS (haut spin/bas spin) par une irradiation lumineuse appliquée sur toute la surface du cristal ou de manière localisée. Les investigations expérimentales menées sur l’effet de l’intensité de la lumière sur la température de transition ont mis en évidence d’une part l’importance du couplage entre le cristal et le bain thermique, et d’autre part le rôle de la diffusion de la chaleur dans le monocristal. En parallèle, un modèle basé sur une description de type Ginzburg-Landau, a permis de mettre sur pied une description de type réaction diffusion des effets spatio-temporels accompagnant la transition de spin dans un monocristal. Celui-ci a permis d’identifier et de comprendre le rôle des paramètres pertinents entrant en jeu dans le contrôle du mouvement de l’interface HS/BS. Les résultats obtenus sont très encourageants et reproduisent avec une grande fidélité les données expérimentales. Cependant l’origine de l’orientation de l’interface HS/BS observée par microscopie optique dans les cristaux du composé [{Fe(NCSe)(py)2}2(m-bpypz)] était restée mystérieuse. Pour résoudre cette question, nous avons développé un modèle électro-élastique qui tient compte du changement de volume au cours de la transition de spin. Ce dernier nous a conduits à analyser l’effet de la symétrie du réseau cristallin et de la forme du cristal sur l’orientation de l’interface élastique. En l’appliquant au composé [{Fe(NCSe)(py)2}2(m-bpypz)], en tenant compte du caractère anisotrope du changement de la maille élémentaire lors du passage HSBS, nous avons réussi à retrouver quantitativement l’orientation du front observée expérimentalement en microscopie optique. Ceci confirme bien le rôle primordial de l’élasticité dans le comportement des matériaux à transition de spin. Des études sous lumière à très basse température nous ont donné la possibilité de suivre en temps réel, l’effet LIESST (Light Induced Excited Spin State Trapping), la re-laxation coopérative du cristal ainsi que l’instabilité photo-induite LITH (Light Induced Thermal Hysteresis). Un monde fascinant est apparu autour de cette dernière, avec la présence de comportements totalement inédits. Ainsi, et pour la première fois, nous avons mis en évidence l’existence de phénomènes d’auto-organisation et de comportements autocatalytiques du front de transition. Cette physique non-linéaire dénote un comportement actif du cristal, par suite d’une subtile préparation autour d’un état instable. Ces comportements rappellent les structures dissipatives de Turing et ouvrent des perspectives fascinantes pour cette thématique, tant sur le plan expérimental que théorique. / This thesis work is devoted to visualization by optical microscopy of thermo- and photo-induced phase transitions, in switchable spin transition single crystals. The study of crystals of the compound [{Fe (NCSe) (py) 2} 2 (m-bpypz)] showed the possibility to control reversibly the dynamics of the HS/LS interface through a photo-thermal effect generated by an irradiation of the whole crystal or using a spatially localized light spot on the crystal surface. The investigations of the effect of the light intensity on the transition temperature have highlighted the importance of the coupling between the crystal and the thermal bath in these experiments. Concomitantly, we developped a reaction diffusion model allowing to describe and iden-tify the relevant physical parameters involved in the control of the movement of HS/LS interface. The obtained results are very encouraging and reproduce the main features of the experimental data. However the origin of the interface orientation observed by the optical microscopy in the crystal of the compound [{Fe (NCSe) (py) 2} 2 (m-bpypz)] re-mained mysterious, and needed an elastic approach to be handled. At this end, an electro-elastic model including the volume change at the spin transition was developed. By taking into account for the anisotropy of the unit cell deformation at the transition, we were able to reproduce quantitatively the experimental HS/LS interface orientation. This result confirms the crucial role of the lattice symmetry and its elastic properties in the emergence of a stable interface orientation. The last part of the thesis is devoted to the investigation of photo-induced effects at very low temperatures (~10K). There, we visualized for the first time the real time transformation of a single crystal under LIESST (Light Induced Excited Spin State Trapping) effect as well as its subsequent relaxation at higher temperatures. We have also studied the light induced instabilities through investigation on the LITH (Light Induced Thermal Hysteresis) loops. Around the latter, a fascinating world made of nonlinear effects, and patterns formation emerged, recalled the well known Turing structures. These results lead to new horizons that will give access to new theories and original experimental observations that will enrich the topics opening the new avenues to study of nonlinear phenomena in spin crossover solids.

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