Energy harvesting and energy storage are two most important technologies in today's green and renewable energy science. As for energy harvesting, the fundamental science and practically applicable technologies are not only essential in realizing the self-powered electronic devices and systems, but also tremendously helpful in meeting the rapid-growing world-wide energy consumptions. Mechanical energy is one of the most universally-existing, diversely-presenting, but usually-wasted energies in the natural environment. Owing to the limitations of the traditional technologies for mechanical energy harvesting, it is highly desirable to develop new technology that can efficiently convert different types of mechanical energy into electricity. On the other hand, the electricity generated from environmental energy often needs to be stored before used to drive electronic devices. For the energy storage units such as Li-ion batteries as the power sources, the limited lifetime is the prominent problem. Hybridizing energy harvesting devices with energy storage units could not only provide new solution for this, but also lead to the realization of sustainable power sources. In this dissertation, the research efforts have led to several critical advances in a new technology for mechanical energy harvesting—triboelectric nanogenerators (TENGs). Previous to the research of this dissertation, the TENG only has one basic mode—the contact mode. Through rational structural design, we largely improved the output performance of the contact-mode TENG and systematically studied their characteristics as a power source. Beyond this, we have also established the second basic mode for TENG—the lateral sliding mode, and demonstrated sliding-based disk TENGs for harvesting rotational energy and wind-cup-based TENGs for harvesting wind energy. In order to expand the application and versatility of TENG by avoid the connection of the electrode on the moving part, we further developed another basic mode—freestanding-layer mode, which is capable of working with supreme stability in non-contact mode and harvesting energy from any free-moving object. Both the grating structured and disk-structured TENGs based on this mode also display much improved long-term stability and very high energy conversion efficiency. For the further improvement of the TENG’s output performance from the material aspect, we introduced the ion-injection method to study the maximum surface charge density of the TENG, and for the first time unraveled its dependence on the structural parameter—the thickness of the dielectric film. The above researches have largely propelled the development of TENGs for mechanical energy harvesting and brought a big potential of impacting people’s everyday life. Targeted at developing sustainable and independent power sources for electronic devices, efforts have been made in this dissertation to develop new fundamental science and new devices that hybridize the nanogenerator-based mechanical energy harvesting and the Li-ion-battery-based energy storage process into a single-step process or in a single device. Through hybridizing a piezoelectric nanogenerator with a Li-ion battery, a self-charging power cell has been demonstrated based on a fundamentally-new mechanical-to-electrochemcial process. The triboelectric nanogenerator as a powerful technology for mechanical energy harvesting has also been hybridized with a Li-ion battery into a self-charging power unit. This new concept of device can sustainably provide a constant voltage for the non-stop operation of electronic devices.

Vibration converters based on piezoelectric materials are currently becoming increasingly important for powering low-power wireless sensor nodes and wearable electronic devices. Piezoelectric materials generate variable electrical charges under mechanical stress, requiring an energy management interface to meet load requirements. Resonant interfaces like Parallel Synchronized Switch Harvesting on Inductor (P-SSHI) are highly efficient and robust to energy sources and loads variations. Nevertheless, SSHI circuits require synchronous switch control for efficient energy transfer. At irregular excitation, SSHI circuits may not perform optimally because the resonant frequency of the circuit is typically tuned to match the frequency of the energy source, which in the case of footsteps can be irregular and unpredictable. In addition, the circuit may also be susceptible to noise and interference from irregular excitations, which can further affect its performance. The aim is to design a self-powered energy management solution that can operate autonomously even at low frequencies and for irregular chock excitations, while at the same time allowing higher energy flow to the energy storage device and maintaining high levels of energy efficiency. To evaluate the performance of the proposed circuit, a piezoelectric shoe insole is designed and used for testing with different storage capacitance values and loads as a proof of the circuit’s adaptability to various loading conditions.:1 Introduction 2 Theoretical background 3 State of the art of piezoelectric energy harvesting interfaces 4 Novel approach of SP-PSSHI piezoelectric energy harvesting interface 5 Experimental investigations 6 Conclusions and Outlook

Smart sensors have become and will continue to constitute an enabling technology to wirelessly connect platforms and systems and enable improved and autonomous performance. Automobiles have about two hundred sensors. Airplanes have about eight thousand sensors. With technology advancements in autonomous vehicles or fly-by-wireless, the numbers of these sensors is expected to increase significantly. The need to conserve water and energy has led to the development of advanced metering infrastructure (AMI) as a concept to support smart energy and water grid systems that would respond to emergency shut-offs or electric blackouts. Through the Internet of things (IoT) smart sensors and other network devices will be connected to enable exchange and control procedure toward reducing the operational cost and improving the efficiency of residential and commercial buildings in terms of their function or energy and water use. Powering these smart sensors with batteries or wires poses great challenges in terms of replacing the batteries and connecting the wires especially in remote and difficult-to-reach locations. Harvesting free ambient energy provides a solution to develop self-powered smart sensors that can support different platforms and systems and integrate their functionality. In this dissertation, we develop and experimentally assess the performance of harvesters that draw their energy from air or water flows. These harvesters include centimeter-scale micro wind turbines, piezo aeroelastic harvesters, and micro hydro generators. The performance of these different harvesters is determined by their capability to support wireless sensing and transmission, the level of generated power, and power density. We also develop and demonstrate the capability of multifunctional systems that can harvest energy to replenish a battery and use the harvested energy to sense speed, flow rate or temperature, and to transmit the data wirelessly to a remote location. / PHD

Low-frequency vibrations typically occur in many practical structures and systems when in use, for example, in aerospaces and industrial machines. Piezoelectric materials feature compactness, lightweight, high integration potential, and permit to transduce mechanical energy from vibrations into electrical energy. Because of their properties, piezoelectric materials have been receiving growing interest during the last decades as potential vibration- harvested energy generators for the proliferating number of embeddable wireless sensor systems in applications such as structural health monitoring (SHM). The basic idea behind piezoelectric energy harvesting (PEH) powered architectures, or energy harvesting (EH) more in general, is to develop truly “fit and forget” solutions that allow reducing physical installations and burdens to maintenance over battery-powered systems. However, due to the low mechanical energy available under low-frequency conditions and the relatively high power consumption of wireless sensor nodes, PEH from low-frequency vibrations is a challenge that needs to be addressed for the majority of the practical cases. Simply saying, the energy harvested from low-frequency vibrations is not high enough to power wireless sensor nodes or the power consumption of the wireless sensor nodes is higher than the harvested energy. This represents a main barrier to the widespread use of PEH technology at the current state of the development, despite the advantages it may offer. The main contribution of this research work concerns the proposal of a novel EH circuitry, which is based on a whole-system approach, in order to develop enhanced PEH powered wireless sensor nodes, hence to compensate the existing mismatch between harvested and demanded energy. By whole-system approach, it is meant that this work develops an integrated system-of-systems rather than a single EH unit, thus getting closer to the industrial need of a ready- to-use energy-autonomous solution for wireless sensor applications such as SHM. To achieve so, this work introduces: Novel passive interfaces in connection with the piezoelectric harvester that permit to extract more energy from it (i.e., a complex conjugate impedance matching (CCIM) interface, which uses a PC permalloy toroidal coil to achieve a large inductive reactance with a centimetre- scaled size at low frequency; and interfaces for resonant PEH applications, which exploit the harvester‟s displacement to achieve a mechanical amplification of the input force, a magnetic and a mechanical activation of a synchronised switching harvesting on inductor (SSHI) mechanism). A novel power management approach, which permits to minimise the power consumption for conditioning the transduced signal and optimises the flow of the harvested energy towards a custom-developed wireless sensor communication node (WSCN) through a dedicated energy-aware interface (EAI); where the EAI is based on a voltage sensing device across a capacitive energy storage. Theoretical and experimental analyses of the developed systems are carried in connection with resistive loads and the WSCN under excitations of low frequency and strain/acceleration levels typical of two potential energy- autonomous applications, that are: 1) wireless condition monitoring of commercial aircraft wings through non-resonant PEH based on Macro-Fibre Composite (MFC) material bonded to aluminium and composite substrates; and wireless condition monitoring of large industrial machinery through resonant PEH based on a cantilever structure. shown that under similar testing conditions the developed systems feature a performance in comparison with other architectures reported in the literature or currently available on the market. Power levels up to 12.16 mW and 116.6 µW were respectively measured across an optimal resistive load of 66 277 kΩ for an implemented non-resonant MFC energy harvester on aluminium substrate and a resonant cantilever-based structure when no interfaces were added into the circuits. When the WSCN was connected to the harvesters in place of the resistive loads, data transmissions as fast as 0.4 and s were also respectively measured. By use of the implemented passive interfaces, a maximum power enhancement of around 95% and 452% was achieved in the two tested cases and faster data transmissions obtained with a maximum percentage improvement around 36% and 73%, respectively. By the use of the EAI in connection with the WSCN, results have also shown that the overall system‟s power consumption is as low as a few microwatts during non- active modes of operation (i.e., before the WSCN starts data acquisition and transmission to a base station). Through the introduction of the developed interfaces, this research work takes a whole-system approach and brings about the capability to continuously power wireless sensor nodes entirely from vibration-harvested energy in time intervals of a few seconds or fractions of a second once they have been firstly activated. Therefore, such an approach has potential to be used for real-world energy- autonomous applications of SHM.

Le développement d’architectures nanostructurées originales composées de matériaux abondants et non-toxiques fait l’objet d’un fort intérêt de la communauté scientifique pour la fabrication de dispositifs fonctionnels efficaces et à bas coût suivant des méthodes d’élaborations faciles à mettre en œuvre. Les réseaux de nanofils de ZnO élaborés par dépôt en bain chimique sont, à ce titre, extrêmement prometteurs. L’étude des propriétés de ces réseaux de nanofils et leur intégration efficace au sein de dispositifs nécessitent toutefois un contrôle avancé de leurs propriétés structurales et physiques, notamment en terme de polarité, à l’aide de techniques de lithographies avancées.Le dépôt en bain chimique des nanofils de ZnO est d’abord effectué sur des monocristaux de ZnO de polarité O et Zn préparés par lithographie assistée par faisceau d’électrons. Par cette approche de croissance localisée, un effet significatif de la polarité des nanofils de ZnO est mis en évidence sur le mécanisme de croissance des nanofils, ainsi que sur leurs propriétés électriques et optiques. La possibilité de former des nanofils de ZnO sur des monocristaux de ZnO semipolaires nous a de plus permis d’affiner la compréhension de leurs mécanismes de croissance sur les couches d’amorces polycristallines de ZnO. Par la suite, le dépôt des nanofils de ZnO en bain chimique est développé sur des couches d’amorces polycristallines de ZnO préparés à l’aide de la lithographie assistée par nano-impression. Suivant cette approche, des réseaux de nanofils de ZnO localisés sont formées sur de grandes surfaces, ce qui permet d’envisager leur intégration future au sein de dispositifs fonctionnels.Les nanofils de ZnO sont ensuite combinés avec des coquilles semiconductrices de type p par des méthodes de dépôt chimique en phase liquide ou en phase vapeur afin de fabriquer des hétérostructures cœurs-coquilles originales. Le dépôt de couches successives par adsorption et réaction (SILAR) d’une coquille absorbante de SnS de phase cubique est optimisé sur des nanofils de ZnO recouverts d’une fine couche protectrice de TiO2, ouvrant la voie à la fabrication de cellules solaires à absorbeur extrêmement mince. Enfin, un photo-détecteur UV autoalimenté prometteur, présentant d’excellentes performances en termes de réponse spectrale et de temps de réponse, est réalisé par le dépôt chimique en phase vapeur d’une coquille de CuCrO2 sur les nanofils de ZnO. / Over the past decade, the development of novel nanostructured architectures has raised increasing interest within the scientific community in order to meet the demand for low-cost and efficient functional devices composed of abundant and non-toxic materials. A promising path is to use ZnO nanowires grown by chemical bath deposition as building blocks for these next generation functional devices. However, the precise control of the ZnO nanowires structural uniformity and the investigation of their physical properties, particularly in terms of polarity, remain key technological challenges for their efficient integration into functional devices.During this PhD, the chemical bath deposition of ZnO nanowires is combined with electron beam lithography prepared ZnO single crystal substrates of O- and Zn-polarity following the selective area growth approach. The significant effects of polarity on the growth mechanism of ZnO nanowires, as well as on their electrical and optical properties, are highlighted by precisely investigating the resulting well-ordered O- and Zn-polar ZnO nanowire arrays. An alternative nano-imprint lithography technique is subsequently used to grow well-ordered ZnO nanowire arrays over large areas on various polycrystalline ZnO seed layers, thus paving the way for their future integration into devices. We also demonstrate the possibility to form ZnO nanowires by chemical bath deposition on original semipolar ZnO single crystal substrates. These findings allowed a comprehensive understanding of the nucleation and growth mechanisms of ZnO nanowires on polycrystalline ZnO seed layers.In a device perspective, the ZnO nanowires are subsequently combined with p type semiconducting shells by liquid and vapor chemical deposition techniques to form original core-shell heterostructures. The formation of a cubic phase SnS absorbing shell is optimized by the successive ionic layer adsorption and reaction (SILAR) process on ZnO nanowire arrays coated with a thin protective TiO2 shell, which pave the way for their integration into extremely thin absorber solar cells. A self-powered UV photo-detector with fast response and state of the art performances is also achieved by the chemical vapor deposition of a CuCrO2 shell on ZnO nanowire arrays.

The primary objective of this research was to investigate and develop an electrostatic energy-harvesting voltage-constrained CMOS/BiCMOS integrated circuit (IC) that harnesses ambient kinetic energy from vibrations with a vibration-sensitive variable capacitor and channels the extracted energy to charge an energy-storage device (e.g., battery). The proposed harvester charges and holds the voltage across the vibration-sensitive variable capacitor so that vibrations can induce it to generate current into the battery when capacitance decreases (as its plates separate). To that end, the research developed an energy-harvesting system that synchronizes to variable capacitor's state as it cycles between maximum and minimum capacitance by controlling each functional phase of the harvester and adjusting to different voltages of the on-board battery. One of the major challenges of the system was performing all of these duties without dissipating the energy harnessed and gained from the environment. Consequently, the system reduces losses by time-managing and biasing its circuits to operate only when needed and with just enough energy while charging the capacitor through an efficient inductor-based precharger. As result, the proposed energy harvester stores a net energy gain in the battery during each vibration cycle.

Rising from the “excess demand” modern societies and economies place on limited road resources, congestion causes increased vehicle emissions, decreases national efficiency, and wastes time (Downs, 2004). In order to minimise congestion’s impacts, traffic management systems gather traffic data and use it to implement efficient management algorithms (Downs, 2004). This dissertation’s purpose has been the development of a distributable vehicle presence detection sensor, which will wirelessly provide vehicle presence information in real time. To address the sensor’s wireless power requirements, the feasibility of self-powering the device via harvested energy has been investigated. Piezoelectric, electrostatic, and electromagnetic energy harvesting devices’ principles of operation and underlying theory has been investigated in detail and an overview presented alongside a literature review of previous vibration energy harvesting research. An electromagnetic energy harvesting device was designed, which consists of: a nylon reinforced rubber bladder, hydraulic piston, neodymium magnets, and wire-wound coil housing. Preliminary testing demonstrated a harvested energy between 100mJ and 205mJ per axle. This amount is able to be transferred to a 100O load when driven over at speeds between 10km/h and 50km/h. Combined with an embedded circuit, the energy harvester facilitated the development of a passive sensor, which is able to wirelessly transmit a vehicle’s presence signal to a host computer. The vehicle detected event is displayed via a graphical user interface. Energy harvesting’s ability to power the embedded circuit’s wireless transmission, demonstrated the feasibility of developing systems capable of harvesting energy from their environment and using it to power discrete electronic components. The ability to wirelessly transmit a vehicle’s presence facilitates the development of distributable traffic monitoring systems, allowing for remote traffic monitoring and management.

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One of the most devastating effects of tetraplegia is the inability to grasp and manipulate everyday objects necessary to living an independent life. Currently surgery is widely accepted as the solution to improve hand functionality. However, surgery becomes difficult when the user has paralysed wrists as is the case with C5 tetraplegia. The aim of this research was to develop a solution which provided controlled wrist flexion and extension which, when combined with surgery, achieves a 'key pinch' grip. This particular grip is critically important for people with C5 tetraplegia as it is used for countless grasping activities, necessary on a day-to-day basis. A systematic design process was used to evolve the solution to provide controlled wrist flexion and extension. Concept brainstorming identified four alternative solutions which were evaluated to find the preferred concept. The chosen solution was called the Self Powered Wrist Extension Orthosis, more commonly referred to as the 'orthosis'. This concept contained a shoulder harness which provided both energy and control to the wrist harness, which in turn changed the wrist position. The orthosis was developed with the use of a mathematical model which theoretically predicted the functional performance by comparing the required force needed to move the wrist harness to the achievable force supplied by the user's shoulders. Using these parameters, the orthosis was optimized using the matlab Nelder-Mead algorithm which adjusted the wrist harness geometries to maximize the functional performance. A prototype was constructed and tested with the help of two participants who when combined, achieved an average of 18.5° of wrist rotation. The theoretical model however predicted an average range of motion of 28.4°. The discrepancy found between the theoretical and experimental result can be contributed to incorrect assumptions in the theoretical model. This included unaccounted friction and inaccurate modeling of the orthosis dynamics. The feedback from potential users of the orthosis was enthusiastic and encouraging especially towards the simplicity, usability and practicality of the design.