Alkali Silica Reaction in concrete is a chemical deterioration process occurring between alkalis in cement paste and reactive aggregates. ASR increases expansion and cracking as well as other durability problems such as freezing and thawing. It is most probable that concrete structure will collapse unless mechanical, mineral, or chemical preventive measures are taken against ASR or this problem is realized and solved in the design stage of the concrete structure or later on. Rather than ordinary preventive measures in which mineral admixtures are used, mechanical ones were investigated in this study. In the experiment done by using the accelerated mortar bar method, reinforced concrete specimens on which pre-stressing force was applied were examined. The effects of reinforcement ratio and pre-stressing force on ASR based expansion and cracking were studied. Expansion and cracking developments in time were followed, and the connection between these phenomena and the energy produced by ASR was made. By applying the same mechanical preventive measures on the specimens prepared by using different reactive aggregates, the effectiveness of these methods with respect to the degree of v ASR was investigated. Also, the methods in question were compared with traditional preventive measures (fly ash). The investigation results show that reinforcement and pre-stressing force play a significant role in diminishing the effects of ASR.Keywords:Alkali-Silica Reaction, Reinforced Concrete Specimen, Pre-stressed Concrete, Mechanical Preventive Measures, Energy of ASR

The use of recycled aggregates in concrete opens a whole new range of possibilities in the reuse of materials in the building industry. This could be an important breakthrough for our society in our endeavours towards sustainable development. The trend of the utilisation of recycled aggregates is the solution to the problem of an excess of waste material, not forgetting the parallel trend of improvement of final product quality. The utilisation of waste construction materials has to be related to the application of quality guarantee systems in order to achieve suitable product properties. Therefore the complete understanding of the characteristics of new material becomes so important in order to point out its real possibilities. The studies on the use of recycled aggregates have been going on for 50 years. In fact, none of the results showed that recycled aggregates are unsuitable for structural use. Only having inadequate number of studies in durability aspects, made recycled aggregates to be preferred just as stuffing material for road construction. My thesis, aimed to focus on the possibility of the structural use of recycled aggregate concrete based on a better understanding of its microstructure.To begin with the characteristics of the aggregates were established, to study their possible application in concrete production. After analysis, the dosage procedure was carried out in order to produce four concrete mixtures using different percentages of recycled coarse aggregates (0% (HC), 25% (HR25), 50% (HR50) and 100% (HR100)) with the same compression strength. Raw coarse aggregates (granite) and sand (crushed limestone) were used in the different concrete mixes.Macroscopic and microscopic examination were carried out in HC, HR25, HR50 and HR100 concretes in order to observe the durability effects. The macroscopic examination determined the aggregates distribution, composition, the contaminants and aureoles around adhered mortar. Microscopic examination was carried out by Optical light transmitted microscope Leica Leitz DM-RXP, using Fluorescence Thin Sections, in order to analyse the cement paste, the new and old interfacial transition zones, secondary reactions as well as damage. Original aggregates and cement paste, interfacial transition zones and alkali silica gel produced due to reactive aggregates present in adhered mortar were analysed by SEM and EDX-maps. Beside macro and micro observations, shear failure behaviour of recycled aggregate concretes was studied. Shear failure test was found more appropriate, as concrete properties had more influence in this type of failure behaviour compared to the flexural failure where the reinforcement plays the important role. Sixteen beam specimens were cast and the structural behaviour of these beams was analysed using four different transversal reinforcements for each kind of concrete. An analytical prediction of the experimental results are carried out using a numerical model (Modified Compression Field Theory), using the codes AASHTO LRFD, CSA, Eurocode-2 and expressions proposed in the Spanish code EHE-99.Organic and inorganic compounds were found to be released from waste materials through leaching and dispersed into the soil and surface water. The leaching of these compounds were measured employing different codes, the two Dutch codes (NEN 7341 and 7345) and the European Normative (EN 12457-2).Some recommendations are given as to the aggregates characteristics to be used in concrete mixes, taking into account the European standards for recycled aggregates. Also suggestions are made for the production process of concrete using recycled aggregate. Mechanical properties of recycled aggregate concrete are studied and they are compared with that of conventional concrete. Based on the durability of the concrete, some suggestions are proposed with respect to possible alkali silica reaction between new cement and original fine aggregates. It is also determined that the effect of the use of recycled aggregate on the beams' shear strength depend on the percentage of coarse aggregate substituted. The applicability of concrete recycled aggregate with respect to its environmental behaviour is demonstrated. In conclusion, some suggestions for future studies are made which would help us in the evolution of our understanding in this field.

Alkali-silica reaction (ASR) is a common deterioration mechanism responsible for numerous concrete durability issues. Since ASR was first discovered in the 1940's, a significant number of investigations have been carried out in order to understand its mechanisms. However, due to the complexity of the reaction and to the numerous factors that affect its development, many aspects still remain unexplained. The research described in this document was funded by the Texas Department of Transportation (TxDOT), and it focused on a specific type of reactive aggregates, known as 'pessimum'; they present an unexpected behavior with respect to the relation between the amount of material present in the mixture and the extent of ASR related damage. The main objective of this investigation was to determine a method for identifying aggregates that exhibit the 'pessimum' behavior by means of a short-term testing regime. Modified versions of the Accelerated Mortar Bar Test (AMBT) and the Concrete Microbar Test (CMBT) were considered for this purpose. In addition, the behavior of a selected group of 'pessimum' aggregates in the Concrete Prism Test (CPT) and the Chemical Method was evaluated. The petrographic characteristics for a reduced number of the aggregates studied were linked to their performance in the ASR tests. The results obtained from the experimental program conducted were combined with results from previous investigations performed at UT Austin to draw conclusions about the overall behavior of ‘pessimum’ aggregates. ‘Pessimum’ aggregates were successfully identified with a modification proposed to the AMBT. As for their behavior, it was found that depending on the amount of reactive constituents present in each test, these aggregates are classified as reactive (for low chert contents) or as non-reactive (for chert contents above the 'pessimum' proportion). Whether these aggregates will generate durability problems depends on the amount of reactive silica in the concrete mixture. / text

Concrete bridges in Texas have developed large cracks in bent caps and pretensioned trapezoidal bridge girders. The bridges show premature concrete deterioration due to alkali-silica reaction (ASR) and delayed ettringite formation (DEF). There is concern that deterioration due to ASR/DEF may lead to a loss of structural capacity. However, there are no quantitative guidelines to relate the level of concrete deterioration due to ASR/DEF to structural performance. Using such guidelines, the need for rehabilitation of beams with ASR/DEF cracking can be assessed. The goal of this research was to determine the shear capacity of pretensioned trapezoidal box girder specimens exhibiting varying degrees of ASR and/or DEF cracking and to use the shear testing results to evaluate the severity of the problem that may exist in Texas bridge structures. To achieve this goal, beams that were severely deteriorated due to ASR/DEF over a period of more than ten years were transported to the University of Texas for testing to failure. Both severely deteriorated and uncracked beams were tested in shear. The test results were used to evaluate the shear performance of trapezoidal box beams affected by ASR/DEF. In addition, three different types of forensic analyses were conducted on the beams to understand the nature of the ASR/DEF cracks and severity of the deterioration. After testing, it is found that the shear capacity of the test specimens was not significantly reduced even with heavy ASR/DEF cracking. Assessment using current US design provisions for bridges or buildings (ACI 318-08 and AASHTO LRFD 2008) and the proposed provision from an earlier project (TxDOT Project 5253) yielded conservative estimates of strength. Results from forensic analyses provided a qualitative indication of ASR/DEF damage but did not correlate with the observed levels of ASR/DEF deterioration. / text

Across the State of Texas and many other areas of the world, relatively young concrete structures have developed signs of premature concrete deterioration. Large cracks form on the surface of the concrete due to expansive forces from alkali-silica reaction (ASR) and delayed-ettringite formation (DEF). The goal of this project is to assess the effect of ASR/DEF on the trapezoidal box beam bridges in the US 59 corridor and Katy Central Business District (CBD) HOV lanes in Houston, TX. Five dapped-end beams were rejected during the casting process and have been in storage at a local precast yard for nearly fifteen years. These beams have been subject to accelerated deterioration and represent the potential severity of the ongoing ASR/DEF distress within the dapped end regions of the in-service trapezoidal box beams. The results from five load tests, corresponding strut-and-tie models, and forensic investigation are used to provide insights into the relationship between the severity of the deterioration and the capacity margin. / text

Submitted by Cássia Santos (cassia.bcufg@gmail.com) on 2017-06-29T12:25:26Z No. of bitstreams: 2 Dissertação - Geovanne Caetano Gomes - 2017.pdf: 4000475 bytes, checksum: 9ebf09d429582174011cbfd00331c5d4 (MD5) license_rdf: 0 bytes, checksum: d41d8cd98f00b204e9800998ecf8427e (MD5) / Approved for entry into archive by Luciana Ferreira (lucgeral@gmail.com) on 2017-07-10T14:15:56Z (GMT) No. of bitstreams: 2 Dissertação - Geovanne Caetano Gomes - 2017.pdf: 4000475 bytes, checksum: 9ebf09d429582174011cbfd00331c5d4 (MD5) license_rdf: 0 bytes, checksum: d41d8cd98f00b204e9800998ecf8427e (MD5) / Made available in DSpace on 2017-07-10T14:15:56Z (GMT). No. of bitstreams: 2 Dissertação - Geovanne Caetano Gomes - 2017.pdf: 4000475 bytes, checksum: 9ebf09d429582174011cbfd00331c5d4 (MD5) license_rdf: 0 bytes, checksum: d41d8cd98f00b204e9800998ecf8427e (MD5) Previous issue date: 2017-05-19 / Coordenação de Aperfeiçoamento de Pessoal de Nível Superior - CAPES / Among the several deleterious actions may attack concrete elements, is the alkali-aggregate reaction (AAR), which affects, mainly, structures of dams, bridges and foundations, where the alkali-silica reaction (ASR) is the most common. One of the main challenges regarding the prediction of this phenomenon is the development of models that may predict damage specific for this reaction, which constitute the theme of this research. Firstly, a systematic literature review was conducted with respect to the models developed, with the organization and classification of the data found, presenting a clear and detailed state-of-art. Therefore, the studies published in journals in the last five years (2012-2016) were selected, in order to conduct their categorization regarding the scale and nature of the analysis, type of modeling, and the software necessary to execute the simulations, besides the summarizing, grouping and analysis of the information concerning the input data necessary to the execution of each modeling, as well as the results generated by each one of them. The models which do not predict damage, i.e. general models that simulate the ASR, were investigated to verify their contribution to a better understanding of the chemical and physical processes that occur in the concrete affect by the reaction. Finally, it was verified that the models analyzed are based on different theories and methods of analyses, demanding distinct input data and generating heterogeneous output data, which are meticulously explained in this paper. / Dentre as várias ações deletérias que podem atacar elementos de concreto tem-se a reação álcali-agregado (RAA), a qual afeta principalmente as estruturas de barragens, pontes e fundações, sendo a reação do tipo álcali-sílica (RAS) a mais recorrente nelas. Um dos principais desafios no que tange à predição desse fenômeno é o desenvolvimento de modelos de previsão de dano específicos dessa reação, constituindo-se o tema da presente pesquisa. A priori, executou-se uma revisão sistemática da literatura a respeito dos modelos desenvolvidos, com a organização e classificação dos dados encontrados, apresentando-se o estado da arte de forma clara e detalhada. Em seguida, foram elencados os trabalhos publicados em periódicos indexados nos últimos cinco anos (2012-2016), executando-se a categorização dos modelos quanto à escala e natureza de análise, tipo de modelagem, e softwares necessários para executar as simulações, além da sintetização, agrupamento e análise de informações concernentes aos dados de entrada necessários para a execução de cada modelação, bem como dos resultados gerados por elas. Para os modelos que não preveem dano, isto é, modelos gerais que simulam a RAS, investigou-se sua contribuição para o melhor entendimento dos processos químico-físicos que ocorrem no concreto afetado por ela. Verificou-se, assim, que os modelos analisados são pautados em diferentes teorias e métodos de análise, demandando dados de entrada distintos e gerando dados de saída heterogêneos, os quais são discriminados minuciosamente neste trabalho.

Concrete has proven to be, by far, one of the most reliable materials for the construction of critical infrastructure. However, despite its structural capacity, concrete members are susceptible to damage mechanisms that may decrease its performance and durability throughout its service life. One such mechanism is alkali-silica reaction (ASR), which takes place when unstable siliceous phases present in coarse or fine aggregates react with the alkali hydroxides from the concrete pore solution, generating a secondary product (i.e., ASR gel); this product swells upon moisture uptake from the surrounding environment, leading to cracking and expansion of the affected concrete. In severe cases of ASR-affected infrastructure, structural safety could become a problem, and thus requiring the demolition of affected members. It is, therefore, necessary to adopt effective protocols for the diagnosis and prognosis of aging infrastructure, to ensure its performance over time along with properly planning for rehabilitation strategies, whether required. This work presents a two-stage case study of the S.I.T.E. building at the University of Ottawa for the diagnosis and prognosis of ASR-affected members (i.e., columns) after nearly 20 years in service. The diagnosis phase was conducted with the aim of evaluating the cause and extent of distress and interpreting its impact on the performance of the affected structure. First, a visual inspection was conducted to evaluate potentially damaged members, in order to select the best location for core-drilling. Once ASR was confirmed through petrographic examination, specimens were evaluated through the multi-level assessment (i.e., coupling of microscopic and mechanical assessment). A range of damage was discovered among the examined columns (i.e., 0.03%, 0.05%, and 0.08% expansion). Moreover, evidence of developing freeze and thaw (FT) damage was discovered in columns with greater levels of expansion, raising future concerns regarding the durability and serviceability of members affected by this coupling of damage (i.e., ASR+FT). For the second stage of this project (i.e., prognosis), a novel ASR semi-empirical model was developed with the aim of predicting future ASR-induced expansion and damage in the S.I.T.E. building. The above model was developed and validated (using ASR exposure site data) through the coupling of existing chemo-mechanical macro-models, which were used to predict material behaviour on the structural scale, and novel mathematical relationships for the prediction of anisotropy in the columns. Moreover, the use of the multi-level assessment to predict the mechanical implications of predicted distress was found to enhance the model’s capacity for prognosis and demonstrated important potential for the accurate prediction of multi-level damage in the S.I.T.E. columns.

Alcali – silica reaction often causes destruction of a concrete.constructions. In the theoretical part is described creation and causes of the ASR including assessment of individual components of concrete and their testing. The practical part is devoted to the results of some control tests of the concrete cover in the section 18 of the highway D1 (Měřín - Velké Meziříčí) and section D1-20 (Velké Meziříčí - Lhotka), the mechanical properties of the upper and the lower layer of the concrete cover and measuring the resistance of concrete against chemical deicing agents.

Les ciments sulfoalumineux sont des liants hydrauliques qui, jusqu’aujourd’hui ne sont pas normalisés et ne possèdent donc pas une composition fixe. La teneur en ye’elimite – la phase principale de ce ciment- peut varier de 5 à 70 %. Or la composition du ciment sulfoalumineux (la composition du clinker ainsi que le pourcentage de gypse ajouté) est un paramètre critique qui contrôle sa réactivité, ses performances mécaniques, ainsi que sa durabilité. L’objectif principal de cette thèse est donc l’étude de l’influence de la composition des ciments sulfoalumineux sur leurs propriétés techniques, telles que les performances mécaniques et durabilité. Trois axes principaux ont été abordés. Tout d’abord une étude de l’influence de la composition du ciment sulfoalumineux (25-75 % en masse de ye’elimite) sur ses propriétés hydrauliques et mécaniques ainsi que sur la valeur limite en élément trace (Zn) a été menée. Dans ce but trois ciment sulfoalumineux (25, 50 et 75 % en masse de ye’elimite) ont été synthétisés. Ensuite l’effet de la variabilité de ce ciment sur sa durabilité dans l’eau pure et sulfatée a été investigué par rapport à un ciment sulfoalumineux commercial. Enfin, une étude des potentialités du ciment sulfoalumineux commercial à inhiber la réaction alcali silice dans les mortiers, lors de l’utilisation d’un granulat réactif (Silex), a été conduite. Il en résulte de cette étude qu’une augmentation de taux de ye’elimite dans le ciment sulfoalumineux engendre une augmentation des performances mécaniques. La valeur limite en Zn est de 0,3 % indépendamment de la composition du ciment sulfoalumineux. Par contre cette dernière influence la durabilité de ces ciments. Les résultats révèlent que même si la formulation contenant 75 % en ye’elimite confère les meilleures performances mécaniques, sa durabilité était la plus faible due à l’absence de stratlingite dans sa matrice cimentaire. Enfin, l’utilisation du ciment sulfoalumineux présente des bonnes potentialités à inhiber la réaction alcali silice. / Sulfoaluminate cements are hydraulic binders that, until today, are not standardized and therefore do not have a fixed composition. The content of ye'elimite - the main compound of this cement - can vary from 5 to 70 %. However, the composition of sulfoaluminate cement (clinker composition as well as the percentage of added gypsum) is a critical parameter that controls its reactivity, mechanical performance, as well as its durability. The main objective of this thesis is to study the influence of sulfoaluminate cements composition on their technical properties, such as mechanical performances and durability. Three main axes were discussed in this work. First, the influence of the sulfoaluminate cement composition (25-75 wt. % of ye'elimite) on its hydraulic and mechanical properties, as well as on the threshold limit of Zn, was studied. For this purpose three sulfoaluminate cements (25, 50 and 75 wt. % of ye'elimite) were synthesized. Then the effect of the variability of this cement on its durability in pure and sulphated water was investigated compared to a commercial sulfoaluminate cement. Finally, a study of the potentialities of commercial sulfoaluminate cement to inhibit the alkali silica reaction in mortars, when using a reactive aggregate (flint), was conducted. This study reveals that an increase in ye'elimite content in the sulfoaluminate cement increases the mechanical performance. The threshold limit of Zn is 0.3 % independently of the sulfoaluminate cement composition. Contrariwise, the sulfoaluminate cement composition influences the durability of these cements. Although the formulation containing 75 % of ye’elimite gives the best mechanical performances, its durability was lowest due to the absence of stratlingite in its cement matrix. Finally, the use of sulfoaluminate cement has good potential towards the inhibition of the alkali silica reaction.

This thesis deals with deterioration observed in cement-concrete cover (CBK) for three selected road sections of highways in the Czech Republic. The main objective was to determine whether concrete failure arose due to alkali-silica reaction, or other mechanism. The deterioration of concrete failure was observed in the macroscopic and microscopic scale. The mostly macroscopically observed deterioration of the concrete were cracks breaking the surface and inner parts of concrete. In micro- scale the microcracks and alcali-silica gels were observed. The CBK deterioration was quantitatively determined by three main parameters: specific length of microcracks on the CBK surface, specific length of microcracks in the drill cores and volume of alcali-silica gels and microcracks in thin sections. According to these indicators it was possible to distinguish two different types of CBK deteriorations. (1) Degradation mainly associated by alkali-silica reaction (observed on highways D11 - Vrbová Lhota and D1) and (2) degradation connected with another mechanism (cycles of freezing and thawing, mechanical degradation) was observed on the highway D5.