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  • About
  • The Global ETD Search service is a free service for researchers to find electronic theses and dissertations. This service is provided by the Networked Digital Library of Theses and Dissertations.
    Our metadata is collected from universities around the world. If you manage a university/consortium/country archive and want to be added, details can be found on the NDLTD website.
61

Fate of urine nitrogen applied to peat and mineral soils from grazed pastures

Clough, Tim J. January 1994 (has links)
This study has provided fundamental information on the fate of urine nitrogen (N) when applied to pasture soils. In this work the three pasture soils used were a Bruntwood silt loam (BW), an old well-developed (lime and fertilizer incorporated and farmed for more than 20 years) peat soil (OP) and a young peat (YP) which was less developed (farmed for about 10 years). Initial soil chemical and physical measurements revealed that the peat soils were acidic, had higher cation exchange capacities, had greater carbon:nitrogen ratios and were better buffered against changes in soil pH than the BW soil. However, the BW soil was more fertile with a higher pH. The peat soils had lower bulk densities and higher porosities. Four experiments were performed. In the first experiment ¹⁵N-labelled urine was applied at 500 kg N ha⁻¹ to intact soil cores of the three soils. Treatments imposed were the presence and absence of a water table at two temperatures, 8°C or 23° C, over 11-14 weeks. ¹⁵N budgets were determined. This first experiment showed that the nitrification rate was faster in the BW soil and was retarded with a water table present. Significant leaching of nitrate occurred at 8°C in the BW soil without a water table. This was reduced when a water table was present. Leaching losses of urine-N were lower in the peat soils than in the BW soil. Apparent denitrification losses (i.e. calculated on a total-N recovery basis) ranged from 18 to 48 % of the ¹⁵N-applied with the greatest losses occurring in the peat soils. The second experiment examined denitrification losses, over 30 days, following the application of synthetic urine-N at 420 kg N ha⁻¹ to small soil cores situated in growth cabinets. The effects of temperature (8°C or 18°C) and synthetic urine (presence or absence) were measured on the BW and OP soils. Nitrous oxide (N₂0) measurements were taken from all soil cores and a sub-set of soil cores, at 18°C, had ¹⁵N-labelled synthetic urine-N applied so that ¹⁵N-labelled nitrogen gases could be monitored. This experiment showed that the application of synthetic urine and increased soil temperature enhanced denitrification losses from both soils. Denitrification losses, at 18°C, as ¹⁵N-labelled nitrogen gases accounted for 24 to 39 % of the nitrogen applied. Nitrous oxide comprised less than half of this denitrification loss. Losses of N₂0 in leachate samples from the soil cores accounted for less than 0.1 % of the nitrogen applied. A third experiment, using Iysimeters, was performed over a 150 day period in the field. The six treatments consisted of the 3 soils with applied synthetic urine, with or without a simulated water table; each replicated three times. Lysimeters were installed in the field at ground level and ¹⁵N-labelled synthetic urine-N was applied (500 kg N ha⁻¹) on June 4 1992 (day 1). Nitrification rates differed between the soils following the trend noticed in the first experiment. As in the first experiment, nitrate was only detected in the leachate from the BW soil and the inclusion of a water table reduced the concentration of nitrate. In the BW soil, the leachate nitrate concentrations exceeded the World Health Organisation's recommended limit (< 10 mg N L-1) regardless of water table treatment. No nitrate was detected in the leachates from the peat soils but there was some leaching of organic-N (< 5 % of N added) in all the peat soil treatments. Denitrification losses were monitored for the first 100 days of the experiment. In the BW soil without a water table, N₂0 production peaked at approximately day 20 and accounted for 3 % of the nitrogen applied. In the peat soils the measured denitrification losses accounted for less than 1 % of the nitrogen applied. Apparent denitrification losses in the peats were, however, calculated to be approximately 50 % of the ¹⁵N-labelled synthetic urine-N applied. It is postulated that the difference between apparent denitrification losses and those measured could have been due to; loss of dinitrogen in leachate, protracted production of dinitrogen below detectable limits, production of denitrification gases after measurements ceased (i.e. days 100 to 150) and entrapment of dinitrogen in soil cores. Due to the apparent denitrification losses being so high, further research into this nitrogen loss pathway was performed. The fourth and final experiment measured denitrification directly using highly enriched (50 atom %) ¹⁵N-labelled synthetic urine-N. It was performed in a growth cabinet held initially at 8°C. The ¹⁵N-labelled synthetic urine was applied at 500 kg N ha⁻¹ to small soil cores of each soil type. Fluxes of N₂0 and ¹⁵N-labelled gases were measured daily for 59 days. On day 42 the temperature of the growth cabinet was increased to 12°C in an attempt to simulate the mean soil temperature at the end of the field experiment. Up to this time, production of nitrogenous gases from the YP soil had been very low. Interpretation of gaseous nitrogen loss in the YP soil was difficult due to the possibility of chemodenitrification occurring. However, in the OP and BW soils, gaseous losses of nitrogen (determined as ¹⁵N-labelled gas) represented 16 and 7 % of the nitrogen applied respectively. Nitrous oxide comprised approximately half of this gaseous nitrogen loss, in both the OP and BW soils. This work implies that urine-N applied to the mineral soil (BW) could potentially threaten the quality of ground water due to nitrate contamination through leaching. In contrast, denitrification appears to be the major loss mechanism from the peat soils, with the production of nitrous oxide being the primary focus for any environmental concern. Future work should examine the fate of the nitrate leached from the BW soil and the potential for dilution, plant uptake or denitrification below a 30 cm soil depth. A better understanding of the denitrification mechanisms could help reduce denitrification and thereby improve the efficiency of nitrogen use and reduce the output of nitrous oxide.
62

Modeling tools for ecohydrological characterization

Sinnathamby, Sumathy January 1900 (has links)
Doctor of Philosophy / Department of Biological & Agricultural Engineering / Stacy L. Hutchinson and Kyle R. Douglas-Mankin / Ecohydrology, a sub-discipline of hydrology, deals with the ecological impacts of and interactions with the hydrological cycle. Changes in hydrology of the Great Plains rivers, and their impacts on water quality, water resources, aquatic ecosystems, and fish species distributions have been documented. The major goal of this study was to develop and test methods to analyze watershed-level ecohydrological characteristics. The specific objectives were (a) to detect past temporal trends and spatial variability in hydrologic indices, (b) to evaluate the presence and/or extent of spatial and temporal relationships between climatic and ecohydrological variables and riverine historical data on fauna species density and distribution, and (c) to assess model calibration strategies for accurate ecohydrological indicator simulation. The Kansa River Basin (KRB), which has substantial land use, soil and climate variability, as well as variation in anthropogenic drivers (dams, diversions, reservoirs, etc.), was the focus of this study. Thirty eight hydrological indicators were generated using the indicators of hydrologic alterations software for 34 stations in the KRB using 50-year streamflow records and trend analysis using Mann-Kendall, Seasonal Kendall, and Sen’s slope estimator tests. Across the KRB a decreasing trend was evident for annual mean runoff, summer and autumn mean runoff, 30-day, 90-day minimum flows, and 1-day, 3-day, 7-day, 30-day and 90-day maximum flows. Most of the significant negative trends were observed in the High Plains ecoregion. Two hydrologic indicators, high-flow pulse count and mean summer streamflow, were significantly different in streams that lost two indicator fish species, indicating that changes in streamflow have altered the fish habitat of this region. The Soil and Water Assessment Tool (SWAT) biophysical model calibrated using a multi-objective framework (multi-site, multivariable and multi-criteria) was able to simulate most of the ecohydrological indicators at different hydrological conditions and scales. The SWAT model provided robust performance in simulating high-flow-rate ecohydrologic indicators. However ecohydrologic indicators performance was highly dependent on the level of calibration and parameterization. The effect of calibration and parameterization on ecohydrologic indicators performance varied between watersheds and among subwatersheds.
63

Understanding Collaboration Among Political Subdivisions of State Government: Examining the Perceptions and Use of Collaboration by Virginia's Soil & Water Conservation Districts

Tyree, Kendall 02 April 2014 (has links)
The purpose of this study was to explore the definitions, benefits, challenges, methods and perceived levels of current collaboration of Virginia’s 47 Soil and Water Conservation Districts, each a political subdivision of state government. The study was guided by the following questions (1) What is collaboration and how is it used by political subdivisions of state government? (2) What collaborative strategies are used specifically by soil and water conservation districts? (3) At what level are districts currently collaborating? (4) At what level do districts prefer to collaborate? A mixed methods research survey was used. The quantitative section measured current perceptions of collaboration based on six indicators of successful collaborations as determined and tested by the Amherst Wilder Foundation—environment, membership, process and structure, communication, purpose, and resources—through use of its Collaborative Factors Inventory. The qualitative portion allowed further exploration into how districts are utilizing collaboration at a grassroots level. Desired levels of collaboration were also captured. The entire district population—district directors, associate directors, and staff—was surveyed and responses analyzed to better understand collaborative efforts. The results indicate that collaborations occur because of both the resource benefits received and the support of a greater cause—or a mix of relational exchange and resource dependency theories. Of the six collaborative indicators, resources proved the greatest area of concern. The process and structure variable was found to be a second needed area of growth. Trust issues with key partners, a component of the membership variable, were also identified as hindering collaboration. Overall, current perceived levels of collaboration occur between coordination and coalition, or a three to four on a five point scale. However, districts identified a desire to operate more often at the coalition level. By focusing on improvement to process and structure needs as well as resource issues, trust will improve and desired levels of collaboration can be reached. This study will enrich the existing literature by expanding on the use of collaboration as it relates to political subdivisions. Findings will be of value to all conservation districts, with greatest value to Virginia. Partner agencies, policymakers, and public administrators will further benefit by gaining insights into the collaborative process.
64

Efeitos de fatores físicos e da manutenção na produção de sedimentos finos em estradas florestais / Effects of physical factors and maintenance on the production of fine sediments in forest roads

Miranda, Frederico Tomas de Souza e 02 February 2016 (has links)
As estradas rurais não pavimentadas são importantes geradoras de crescimento em países subdesenvolvidos, desempenhando papel essencial na produção e comercialização de produtos primários e no acesso a bens e serviços. Cerca de 78,6% do sistema de transporte brasileiro é composto por estradas não pavimentadas, sem contabilizar as estradas de uso privado de propriedades rurais. No âmbito florestal as estradas não pavimentadas tem sido o principal foco de estudos relacionados à erosão, pois são os agentes que mais contribuem para o escoamento superficial e geração de sedimentos. A aceleração dos processos erosivos proporcionada pelas estradas está vinculada às mudanças dos processos hidrológicos. A interceptação direta da chuva e do escoamento superficial e subsuperficial, a divergência e a concentração do fluxo d\'água nas estruturas das estradas são as principais mudanças ocorridas. Entre os danos ambientais causados pela introdução das estradas se destacam a redução da qualidade da água e o assoreamento dos cursos d\'água. Diante a necessidade de se entender as funções atribuídas às estradas nas relações entre o manejo florestal e a água, as estradas não pavimentadas da Estação Experimental de Ciências Florestais de Itatinga (EECFI) foram submetidas a duas análises. O trabalho foi dividido em duas partes, a primeira identificou os trechos de estradas suscetíveis à erosão (análise qualitativa) e a segunda parte estimou as taxas de produção de sedimentos e volume de enxurrada nas superfícies das estradas (análise quantitativa). Toda a malha viária da EECFI foi mapeada e digitalizada em plataformas de Sistema de Informações Geográficas (SIG). A partir do modelo digital do terreno e dos mapas de tipo e cobertura de solo foram calculados os quatro indicadores (hidrológicos e topográficos) utilizados na identificação dos trechos com maiores riscos de erosão. Por meio de métodos estatísticos multivariados, todos os indicadores de cada trecho de estrada, simultaneamente, foram divididos em grupos com características similares. A identificação dos grupos de trechos suscetíveis à erosão foi realizada pela interpretação da análise de variância (One Way ANOVA). Para a estimativa proposta na segunda parte do trabalho, foram instaladas 16 parcelas com diferentes declividades, com e sem realização de manutenção nas superfícies das estradas. As taxas de produção de sedimentos e de volume de enxurrada foram analisadas pela análise de covariância, sendo que os efeitos das variáveis e covariáveis foram analisados pelo modelo linear generalizado misto. Os resultados mostraram que tanto os indicadores quanto o método utilizado para a separação foram capazes de identificar dois grupos de trechos com características distintas quanto à suscetibilidade à erosão. Essas características foram proporcionadas pelo posicionamento das estradas em relação às curvas de nível do terreno. A declividade e a manutenção das superfícies das estradas aumentaram significativamente a produção de sedimentos, com maior destaque para as declividades. No que diz respeito ao aumento do volume de enxurrada, somente a realização da manutenção apresentou efeito significativo. A adequação das técnicas de manutenção, assim como a adoção de técnicas complementares em trechos de estradas considerados mais suscetíveis, reduzirão a perda de solo e água e os danos ambientais decorrentes. / Unpaved rural roads generate important growth in developing countries, they play an essential role in the production and marketing of primary products and access to goods and services. Approximately 78.6% of Brazil\'s transport system consists of unpaved roads, not counting the roads of private use of rural properties. In the forest sector the unpaved roads have been the main focus of studies related to erosion, as are the agents that contribute most to the runoff and sediment production. The erosion acceleration provided by roads are linked to changes in hydrological processes. The main changes are rainfall and surface and subsurface flow interception, and the divergence and the concentration of water flow on the roads\' structures. Among the environmental damage caused by the introduction of roads it\'s possible to emphasize the reduction of water quality and stream aggradation. In view of the need to understand the functions of roads in the relations between forest management and water, the unpaved roads of the Experimental Station of Forest Sciences Itatinga (EECFI) were subjected to two analyzes. The study was divided into two parts, the first identified road segments susceptible to erosion (qualitative analysis) and the second part estimated the sediments production rates and volume runoff on road surfaces (quantitative analysis). The entire road network of EECFI was mapped and digitalized using System Geographic Information (GIS) platforms. From the digital elevation model (DEM) and the soil type and land cover maps were calculated four indicators (hydrological and topographical) used in the identification of segments with greater erosion risks. Through multivariate statistical methods, all indicators of each road segment, simultaneously, were divided into groups with similar characteristics. The identification of segments groups susceptible to erosion was performed by the interpretation of the analysis of variance (one way ANOVA). For the estimative proposed in the second part, 16 plots were installed with different slopes, with and without carrying out maintenance on the surfaces of the roads. The sediment production rates and runoff volume were analyzed by analysis of covariance, and the effects of the variables and covariates were analyzed using generalized linear mixed model. The results showed that both the indicators and the method used for the separation were able to identify two segments groups with different characteristics for susceptibility to erosion. These characteristics were provided by the positioning of roads in relation to the terrain contour lines. The slope and the maintenance of road surfaces significantly increased the production of sediments, most notably the slopes. Regarding the increase of the runoff volume, only maintenance activities showed significant effect. The adjustment of maintenance techniques, as well as the adoption of complementary techniques in segments roads considered more susceptible, will reduce the soil and water losses and resulting environmental damages.
65

The effects of drying and rewetting cycles on carbon and nitrogen dynamics in soils of differing textures and organic matter contents

Harrison-Kirk, T. January 2008 (has links)
Many researchers have reported differences in soil C and N dynamics between soils of different textures and/or soil organic matter contents. However, it has proven difficult to determine the exact relationships and mechanisms between C and N dynamics and soil texture/SOM. There are few studies that consider how these soil physical and chemical conditions influence the effects of drying and rewetting on the mineralisation of C and N and the microbial transformations that follow. The objectives of this study were: 1) To determine the effects of repeated drying and rewetting cycles on C and N dynamics in soils of differing textural class and organic matter levels. 2) To use C & N mineralised at constant moisture contents to calculate mineralisation during dry/wet cycles for comparison with actual mineralisation. Two soil types with contrasting textures were chosen and 6 paddocks on each soil type were selected to produce an OM gradient for each soil. Three moisture treatments were chosen to simulate moist (field capacity at -0.01 MPa), moderately dry (120% of wilting point at -1.5 MPa) and very dry (80% of wilting point at - 1.5 MPa) field conditions. The dry moisture treatments were then combined with a rewet treatment where they were either rewet or maintained dry (+ or – rewet), resulting in a total of five dry/rewet treatments. Soils were packed into funnel tops to a BD of 1.1 g/cm³ and sealed in glass jars fitted with septa to allow gas sampling. Drying was achieved using silica gel which allowed continued gas measurement during drying periods. Gas samples were collected throughout the experiment and analysed for CO₂ by IRGA and N₂O by GC. At the start and end of the study, soils were analysed for Min N, MBC, MBN, HWC, DOC, POM, total C and total N. The correlation between calculated and actual C mineralisation data indicates that the intercept is not consistent with the origin and that the slope is not consistent with the 1:1 line. While those paddocks with high %C had high cumulative C mineralisation, there didn’t appear to be any strong relationship between soil texture or OM content and the difference between actual and calculated C mineralisation. A plot of calculated C mineralisation rates against the actual C mineralisation rates shows that much of the error in the calculated cumulative data arises from an underestimation of the mineralisation flush when the dry soil is rewetted, especially during the first dry-rewet cycle, and an over estimation of the rate at which respiration decreases as the soil dries. In order to use C mineralisation data from soils held at constant moisture contents to accurately predict C mineralisation in soils exposed to dry-rewet cycles, knowledge of the stress history for the soil would be required e.g. size, duration and frequency of rainfall events, dry rates etc. The N₂O-N emission data is inherently more variable than the C mineralisation data. The fine-textured soils tend to have much higher N₂O-N emissions than the coarser soils, probably due to the creation of anoxic sites upon rewetting in the fine-textured soils. The data indicates that prediction of N₂O-N emissions in soils exposed to dry-rewet cycles using emission data from soils held at constant moisture contents would be very inaccurate, primarily due to the inherent variability of N₂O-N emissions in soils.
66

Understorey effects on phosphorus fertiliser response of second-rotation Pinus radiata : a thesis presented in partial fulfilment of the requirements for the degree of Doctor of Philosophy in Soil Science at Massey University, Palmerston North, New Zealand

Ravaie, A. Arivin January 2004 (has links)
The current silvicultural regimes of Pinus radiata plantations in New Zealand with wider initial tree spacings have created the potential for increased growth of understorey vegetation. A consequence of this is that the response of P. radiata to P fertiliser is expected to be more influenced by the interaction between the P fertiliser, the tree and the understorey vegetation than was the case in the past. The objectives of this study were to investigate the influence of different rates of a soluble and a sparingly-soluble P fertiliser (Triple superphosphate and Ben-Geurier phosphate rock) and weed control, and their interactions, on soil P chemistry and the growth and P uptake of 4-5-year-old second-rotation P. radiata on an Allophanic Soil (Kaweka forest) and a Pumice Soil (Kinleith forest). The results showed that the application of P fertilisers had no effect on P. radiata growth at both field trial sites two years after this treatment, although it increased radiata needle P concentration. However, at both sites, the understorey vegetation removal treatment increased tree diameter at breast height and basal area. At the highly P-deficient (Bray-2 P 4 µg g-1) Kaweka forest, the presence of understorey (bracken fern and some manuka) reduced resin-Pi and Olsen P concentrations, but at the moderate P fertility (Bray-2 P 13 µg g-1) Kinleith forest, the understorey (Himalayan honeysuckle, buddleia and some toetoe) increased Bray-2 P, resin-Pi, and Olsen P concentrations. A glasshouse study on P. radiata seedlings was conducted to test the hypothesis that when ryegrass (Lolium multiflorum) is grown with P. radiata, it increases radiata needle P concentration, while when broom (Cytisus scoparius L.) is grown with P. radiata, it has no effect. The acid phosphatase activity in the rhizosphere of P. radiata was higher when radiata was grown with broom than that when it was grown with ryegrass. This is consistent with the higher P concentration in needles of radiata grown with broom than that of radiata grown with ryegrass, in the absence of P fertiliser addition. However, when P fertiliser was added (50 and 100 µg P g-1 soil) the needle P concentration of radiata grown with broom was lower than that when radiata was grown with ryegrass.
67

Modélisation des dynamiques de pollution diffuse dans le bassin versant de la rivière d'Auray : quantification, caractérisation et gestion des apports nutritifs terrigènes

Rollo, Nicolas 23 January 2012 (has links) (PDF)
La contamination des eaux marines par les apports terrigènes induit de nombreuses perturbations biogéochimiques. La conséquence la plus marquante de ces apports est très certainement le phénomène d'eutrophisation des masses d'eau côtières résultant de l'apport excessif de nutriments et accentuant les efflorescences algales. Néanmoins, la contribution des bassins versants ainsi que l'origine des polluants incriminés restent généralement difficiles à évaluer finement à partir des mesures intermittentes ponctuelles issues des réseaux de surveillance, particulièrement dans le cas d'émissions diffuses. Dans ce cadre, le recours à la modélisation des bassins versants apparaît comme une solution complémentaire pertinente en termes de gestion, notamment de par les possibilités de scénarisation qu'elle offre. En s'appuyant sur un site d'étude localisé en Bretagne Sud, constituant le principal hydrosystème à alimenter le Golfe du Morbihan, le modèle Soil and Water Assessment Tool a été mis en oeuvre sur une période de six ans. Dans une optique opérationnelle, des protocoles de paramétrage ont été établis à partir de référentiels de données courants et différents utilitaires ont été développés afin de favoriser l'exploitation autonome de cet outil par les gestionnaires en charge du suivi et de la gestion des eaux littorales. Cette implémentation a notamment permis de quantifier de manière continue les apports nutritifs terrigènes et d'en déterminer les principales origines. Ainsi, l'identification des bassins versants élémentaires les plus contributeurs, peut constituer un appui pour la désignation de secteurs d'intervention prioritaires pour les actions de reconquête de la qualité des masses d'eau de l'hydrosystème alréen.
68

An interdisciplinary approach to the prediction of pit lake water quality, Martha Mine pit lake, New Zealand

Castendyk, Devin N. January 2005 (has links)
Lakes resulting from open pit mining may be potential water resources or potential environmental problems, depending on their water quality. As the global abundance of pit mines and pit lakes increases, there is increasing pressure on the mining industry to create pit lakes that have environmental, social, and/or economical utility. This thesis uses an interdisciplinary approach involving mineralogy, physical limnology, and geochemistry to predict and improve the water quality of a proposed pit lake at the Martha gold mine, New Zealand. A mineral quantification method developed for this study measured the distributions and concentrations of wall rock minerals, and identified 8 relatively homogeneous wall rock regions, called mineral associations. Acid-base accounting using calcite and pyrite quantities identified 3 associations with acid-generating potential. Three physical limnology tools (relative depth, wedderburn number, and numerical modeling with DYRESM), predicted that the upper 2/3 of the lake will circulate annually during the winter turnover period, whereas the lower 1/3 will remain permanently isolated. Permanent stratification resulted from density differences between groundwater and river water inputs during lake filling, plus lake morphology. The geochemical model used the distribution of mineral associations to characterize the composition of pit wall runoff, and used the limnologic prediction to define the mixing frequency, mixing depth, and layer volumes. Initial modeling with the geochemical program PHREEQC indicated the lake will have a pH of 5, and Cu and Zn concentrations that exceed aquatic life protection guidelines. Sensitivity analyses showed that subaqueous water-rock reactions did not have a significant affect on lake pH, suggesting these reactions are less important geochemical factors in pyrite-bearing pit lakes. Surface adsorption onto ferrihydrite reduced concentrations of As, Pb, and Cu, suggesting these reactions are important geochemical factors in pit lakes. By covering the acid-generating mineral associations, lake pH increased above 6.5, allowing for future recreational use. Concentrations of Cu complied with aquatic life protection guidelines, however, Zn concentrations remained above these guidelines. This study demonstrates the value of interdisciplinary pit lake predictions in the design of closure plans for open pit mines. Such studies improve the ability of mining companies to sustainably develop mineral resources.
69

An interdisciplinary approach to the prediction of pit lake water quality, Martha Mine pit lake, New Zealand

Castendyk, Devin N. January 2005 (has links)
Lakes resulting from open pit mining may be potential water resources or potential environmental problems, depending on their water quality. As the global abundance of pit mines and pit lakes increases, there is increasing pressure on the mining industry to create pit lakes that have environmental, social, and/or economical utility. This thesis uses an interdisciplinary approach involving mineralogy, physical limnology, and geochemistry to predict and improve the water quality of a proposed pit lake at the Martha gold mine, New Zealand. A mineral quantification method developed for this study measured the distributions and concentrations of wall rock minerals, and identified 8 relatively homogeneous wall rock regions, called mineral associations. Acid-base accounting using calcite and pyrite quantities identified 3 associations with acid-generating potential. Three physical limnology tools (relative depth, wedderburn number, and numerical modeling with DYRESM), predicted that the upper 2/3 of the lake will circulate annually during the winter turnover period, whereas the lower 1/3 will remain permanently isolated. Permanent stratification resulted from density differences between groundwater and river water inputs during lake filling, plus lake morphology. The geochemical model used the distribution of mineral associations to characterize the composition of pit wall runoff, and used the limnologic prediction to define the mixing frequency, mixing depth, and layer volumes. Initial modeling with the geochemical program PHREEQC indicated the lake will have a pH of 5, and Cu and Zn concentrations that exceed aquatic life protection guidelines. Sensitivity analyses showed that subaqueous water-rock reactions did not have a significant affect on lake pH, suggesting these reactions are less important geochemical factors in pyrite-bearing pit lakes. Surface adsorption onto ferrihydrite reduced concentrations of As, Pb, and Cu, suggesting these reactions are important geochemical factors in pit lakes. By covering the acid-generating mineral associations, lake pH increased above 6.5, allowing for future recreational use. Concentrations of Cu complied with aquatic life protection guidelines, however, Zn concentrations remained above these guidelines. This study demonstrates the value of interdisciplinary pit lake predictions in the design of closure plans for open pit mines. Such studies improve the ability of mining companies to sustainably develop mineral resources.
70

The effect of poplar stand density on hill country pastures : a thesis submitted in partial fulfilment of the requirements for the degree of Doctor of Philosophy (PhD), Massey University, Palmerston North, New Zealand

Wall, Andrew James January 2006 (has links)
Page xvi is missing from both the electronic and print copy / One-third of the North Island of New Zealand has been identified as requiring increased soil conservation if pastoral farming is to be sustainable. For over 50 years the planting of widely spaced poplar trees (Populus spp.) has been one of the main methods used to control soil erosion on hill pastures. Research has shown that these plantings have successfully decreased soil erosion but their impact on the productivity of pastoral farming has received little research attention. The research that has been undertaken has found poplars can suppress understorey pasture production by up to 40%, suggesting that farmers require more research information on the impact of planting conservation trees on the productivity of their farm if the use of conservation trees is to be more widely adopted on erosion prone land. The objective of this thesis was to provide comprehensive data on the relationship between the range of poplar densities used for soil conservation on the light and soil under poplars, and consequently the effect on understorey pastures. Three field sites on commercial sheep and beef hill farms, in regions with contrasting summer soil moisture availability, Manawatu (one site) and Central Hawke's Bay (two sites), were monitored for two years. Tree stocking rates ranged from 0 to 375 trees/ha. Measurements were based on units of four trees with most measurements either directly below the tree crowns or in the gaps between the trees, but more intensive transect measurements were also made. Photosynthetically active radiation (PAR) and the ratio of red to far red light (R:FR) were measured under the trees and in open pasture controls. Stand density indices used included all the commonly used measures of tree canopies, including digital photography, and stem diameter at breast height (DBH). PAR transmission was inversely related to all of the stand density indices with canopy closure based on digital photographs being the most robust of the indices used. PAR under the trees, relative to open pasture, was greater in the gaps than below tree crowns. Under a completely closed canopy, PAR transmission was reduced to 15-20% and 50-55% of the open pasture in summer and winter, respectively. The RFR under the trees, relative to open pasture, decreased markedly at high stand densities (allowing less than 40% PAR transmission) in summer, but was similar in winter. The change in PAR under the trees was shown to be a major factor limiting pasture growth, particularly directly below the tree crowns. For both summer and winter, canopy closure measured with a standard digital camera was strongly related to stand level PAR transmission (r2=0.88-0.97; P<0.0001) and was also a practical method of measuring canopy closure in the field. The soil measurements confirmed earlier research that soil pH increases under mature poplar trees. There was a 0.2 - 0.7 unit increase in soil pH in the upper 75 mm of soil over both contrasting regions. The soil fertility under the trees in terms of requirements for pasture growth was similar to that of the open pasture with calcium and potassium up to 2.2 and 9.0 quick test units higher in the soil under the trees than in the open pasture, respectively. The direct cause of the increased concentration of some cations under the trees was the annual tree leaf litter. Overall, the soil fertility under the trees had the potential to produce similar pasture production to that of the open pasture with the added advantage of less acid conditions. Averaged over all sites the respective annual net herbage accumulation (ANHA) under poplar canopy closures of 25, 50 and 75 % was estimated from the equations developed to be 77, 60 and 48% of the open pasture. The greatest decrease was directly below the tree crowns where at canopy closures greater than 20% the ANHA was a relatively constant 50% of open pasture. In the vertically projected gap between trees the ANHA decreased by 6.6% relative to open pasture for each 10% increase in canopy closure. At approximately 80% canopy closure there was no difference between the ANHA directly below the trees and in the gap. Pasture net herbage accumulation (NHA) under the trees relative to open pasture was at its lowest in summer and autumn (36% of open pasture under a closed canopy), and at its greatest in early spring before tree canopy leafed out (72% of open pasture under a closed canopy). The botanical composition and feed value of the pasture under the trees was broadly similar to that of the open pasture. The greatest impact of the poplars on the pasture was decreased NHA due to shading. The decrease in NHA directly below mature unpruned poplars is substantial and would decrease farm profitability if the poplar stand density were high over a large area of the farm. The use of poplars for soil conservation is essential but these results show the importance of managing trees through pruning and thinning so that canopy closure is minimised. ANHA under the trees can be maintained at 75% of the open pasture if canopy closure is prevented from exceeding 30-40%.

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