Le développement de solutions de stockage de l'énergie est un défi majeur pour permettre la transition énergétique d'un mix énergétique fortement carboné vers une part plus importante des énergies renouvelables. La nécessité de stocker de l'énergie vient de la dissociation, spatiale et temporelle, entre la source et la demande d'énergie. Stocker de l'énergie répond à deux besoins principaux : disposer d'énergie à l'endroit et au moment où on en a besoin. La consommation de chaleur à basse température (pour le chauffage des logements et des bureaux) représente une part importante de la consommation totale d'énergie (environ 35 % en France en 2010). Le développement de solutions de stockage de chaleur est donc d'une grande importance, d'autant plus avec la montée en puissance des énergies renouvelables. Parmi les technologies de stockage envisageables, le stockage par adsorption semble être le meilleur compromis en termes de densité de stockage et de maintient des performances sur plusieurs cycles de charge-décharge. Cette thèse se focalise donc sur le stockage de chaleur par adsorption, et traite de l'amélioration des performances du stockage et de l'intégration du système au bâtiment. L'approche développée pour répondre à ces questions est numérique. L'influence des propriétés thermophysiques de l'adsorbant et du fluide sur la densité de puissance d'une part, mais aussi sur la densité de stockage et l'autonomie du système, est étudiée. L'analyse des résultats permet de sélectionner les propriétés des matériaux les plus influentes et de mieux comprendre les transferts de chaleur et de masse au sein du réacteur. L'influence des conditions opératoires est aussi mise en avant. Enfin, il est montré que la capacité de stockage est linéairement dépendante du volume de matériau, tandis que la puissance dépend de la surface de section et que l'autonomie dépend de la longueur du lit d'adsorbant. Par ailleurs, le rapport entre l'énergie absorbée (charge) et relâchée (décharge) est d'environ 70 %. Mais pendant la phase de charge, environ 60 % de la chaleur entrant dans le réacteur n'est pas absorbée et est directement relâchée à la sortie. La conversion globale entre l'énergie récupérable et l'énergie fournie n'est donc que de 25 %. Cela montre qu'un système de stockage de chaleur par adsorption ne peut pas être pensé comme un système autonome mais doit être intégré aux autres systèmes de chauffage du bâtiment et aux lois de commande qui les régissent. Utiliser la ressource solaire pour le préchauffage du réacteur est une idée intéressante car elle améliore l’efficacité de la charge et permet une réutilisation de la part récupérée en sortie pour le chauffage direct du bâtiment. La part stockée sous forme sensible peut être récupérée plusieurs heures plus tard. Le système est ainsi transformé en un stockage combiné sensible/adsorption, avec une solution pour du stockage à long terme et pour du stockage à court terme. / The development of energy storage solutions is a key challenge to enable the energy transition from fossil resources to renewable energies. The need to store energy actually comes from a dissociation between energy sources and energy demand. Storing energy meets two principal expectations: have energy available where and when it is required. Low temperature heat, for dwellings and offices heating, represents a high share of overall energy consumption (i.e. about 35 %). The development of heat storage solutions is then of great importance for energy management, especially in the context of the growing part of renewable energies. Adsorption heat storage appears to be the best trade off among available storage technologies in terms of heat storage density and performances over several cycles. Then, this PhD thesis focuses on adsorption heat storage and addresses the enhancement of storage performances and system integration. The approach developed to address these issues is numerical. Then, a model of an adsorption heat storage tank is developed, and validated using experimental data. The influence of material thermophysical properties on output power but also on storage density and system autonomy is investigated. This analysis enables a selection of particularly influencing material properties and a better understanding of heat and mass transfers. The influence of operating conditions is also underlined. It shows the importance of inlet humidity on both storage capacity and outlet power and the great influence of discharge flowrate on outlet power. Finally, it is shown heat storage capacity depends on the storage tank volume, while outlet power depends on cross section area and system autonomy on bed length. Besides, the conversion efficiency from absorbed energy (charge) to released energy (discharge) is 70 %. But during the charging process, about 60 % of incoming heat is not absorbed by the material and directly released. The overall conversion efficiency from energy provided to energy released is as low as 25 %. This demonstrates that an adsorption heat storage system cannot be thought of as a self-standing component but must be integrated into the building systems and control strategy. A clever use of heat losses for heating applications (in winter) or inlet fluid preheating (in summer) enhances global performances. Using available solar heat for system preheating is an interesting option since a part is instantly retrieved at the outlet of the storage tank and can be used for direct heating. Another part is stored as sensible heat and can be retrieved a few hours later. At least, it has the advantage of turning the adsorption storage tank into a combined sensible-adsorption storage tank that offers short-term and long-term storage solutions. Then, it may differ avoidable discharges of the sorption potential and increase the overall autonomy (or coverage fraction), in addition to optimizing chances of partial system recharge.

L’objectif de cette thèse est d’étudier expérimentalement les performances énergétiques d'une installation de micro-cogénération solaire. Le prototype réalisé est constitué d'un concentrateur cylindro-parabolique associé à un moteur à vapeur fonctionnant suivant un cycle de Hirn (Rankine avec surchauffe). Les originalités de ce projet sont l’utilisation de l’énergie solaire, renouvelable et inépuisable mais intermittente, la génération directe de vapeur au sein d'un concentrateur de taille réduite (46,5 m²), le système de suivi solaire sur deux axes et le couplage à un moteur à piston non lubrifié. La première partie de l'étude porte sur le concentrateur seul. Son fonctionnement est étudié sur deux journées types (ensoleillée et nuageuse) et son rendement thermique est évalué. La dynamique du système est également abordée notamment par l'étude de sa réponse à des perturbations. Une régulation de type boucle ouverte a été mise en place et validée. La seconde partie concerne la caractérisation du moteur seul. Des essais ont été menés avec une puissance de source chaude stable puis variable. À partir des résultats obtenus, un modèle empirique est développé, puis exploité dans le cadre d'une étude paramétrique du moteur. Cette étude montre l'influence importante du ratio de pression et de la vitesse de rotation sur le rendement. Dans la dernière partie, les performances globales (rendement, puissances électrique et thermique produites) du micro-cogénérateur sont évaluées. Des essais à pression et à vitesse régulées sont présentés. A partir de cartographies de fonctionnement réalisées à l’aide d’un modèle empirique, une régulation basée sur l'utilisation d'un by-pass est alors mise en place, puis testée. / The objective of this thesis is the experimental study of the energy performances of a micro combined solar heat and power (micro-CHP) unit. The prototype is composed of a solar parabolic trough collector coupled to a Hirn (superheated Rankine) cycle engine. The originalities of this project are the use of solar energy which is renewable and inexhaustible but intermittent, the direct steam generation with a reduced size parabolic trough collector (46.5 m²), the two axis tracking system and the coupling with an oil-free reciprocating steam engine. The first part of this study is focussed on the solar collector. Thermal performances under sunny and cloudy conditions are presented and the thermal efficiency is evaluated. The system dynamic is also investigated through the characterization of the inertia as well as a study of its response to perturbations. Then a control strategy is set up and validated. The second part deals with the characterization of the engine. Tests have been performed with a stable and variable heat source power. From these tests, an empirical model has been developed and used in a parametrical study. This study shows the significant influence of the pressure ratio and of the rotational speed on the efficiency of the engine. In the last part, global performances (efficiency, output thermal and electrical powers) of the entire micro-CHP unit are evaluated. Tests with controlled pressure and speed are presented. From operating maps established from an empirical model, a control strategy based on the use of a by-pass is set up and tested.

Cooking is an integral part of each and every human being as food is one of the basic necessities for living. Commonly used sources of energy for cooking are firewood, crop residue, cow dung, kerosene, electricity, liquefied petroleum gas(LPG), biogas etc. Half of the world’s population is exposed to indoor air pollution, mainly the result of burning solid fuels for cooking and heating. Wood cut for cooking purpose contributes tothe16 million hectares(above4% of total area of India) of forest destroyed annually. The World Health Organization(WHO) reports that in 23 countries 10% of deaths are due to just two environmental risk factors: unsafe water, including poor sanitation and hygiene; and indoor air pollution due to solid fuel usage for cooking. In under-developed countries, women have to walk 2kms on average and spend significant amount of time for collecting the firewood for cooking. The cooking energy demand in rural areas of developing countries is largely met with bio-fuels such as fuel wood, charcoal, agricultural residues and dung cakes, whereas LPG or electricity is predominantly used in urban areas. India has abandon amount of solar energy in most of the regions making it most ideal place for harvesting solar energy. With almost 300 sunny days each year, one can confidently relay on this source of energy. India’s geographical location is in such a way that theoretically it receives 5x1015 kWh/ year of solar energy. Solar cooking is the simplest, safest, environmental friendly and most convenient way to cook. It is a blessing for those who cook using firewood or cow dung, who walk for miles to collect wood, who suffer from indoor air pollution. Hence solar cooking is going to play major role in solving future energy problem. Solar based cooking has never been a strong contender in the commercial market or even close to being a preferred method of cooking. They have been relegated to demonstration appliances to show case the solar based concepts. In this mode, cooking is no longer a time independent activity that can be performed at any time of day. One is forced to cook only at certain times when there is sufficient insolation. The geography of the cooking activity also shifts away from the kitchen. The kitchen is no longer the hearth of the home as the actual cooking activity shifts to the roof tops or high insolation platforms. This further adds to the inconvenience apart from being unable to cook at night or during cloudy conditions or during most of the winter days. Another issue of significant inconvenience is the general social structure in most families of the developing countries wherein the cooking activity is carried out by the senior ladies of the home. They are generally not athletic enough to be moving to and from the kitchen and the roof top to carry out the cooking exercise. As the solar cookers are enclosed spaces, interactive cooking is not possible let alone having any control on the rate of cooking. These are some of the more significant issues in the social psyche that has abundantly impeded the acceptance of solar thermal based cooking appliances. These issues and problems are in fact the motivating factors for this thesis. Based on these motivating factors, this thesis aims to propose solutions keeping the following points as the major constraints. cooking should be performed in the kitchen. one should be able to perform the cooking activity independent of the time of day or insolation. the cooking activity should be interactive the time taken for cooking should be comparable with the conventional methods in vogue. there should be a reduction in the use of conventional energy. Using the constraints and the motivating factors discussed above as the central theme, this thesis proposes a method to transfer solar thermal energy to the kitchen and act as a supplement to the conventional source of energy like the LPG or other sources that are traditionally being used in the households. The method proposed is in fact a hybrid scenario wherein the solar thermal is used to supplement the traditional source. Solar photovoltaic cells are also used to power the electronics and apparatus proposed in this thesis. This thesis addresses in detail the issues in analysis, modeling, designing and fabrication of the proposed hybrid solar cooking topology. The main goal of the proposed system is to transfer heat from sun to the cooking load that is located in the kitchen. The topology includes an additional feature for storing the energy in a buffer. The heat is first transferred from the solar thermal collector to a heat storage tank(that acts as the buffer) by circulating the heat transfer fluid at a specific flow rate that is controlled by a pump. The stored heat energy that is collected in the buffer is directed into the kitchen by circulating the heat transfer fluid into the heat exchanger, located in the kitchen. This is accomplished by controlling the flow rate using another pump. The solar thermal collector raises the temperature of the thermic fluid. The collector can be of a concentrating type in order to attain high temperatures for cooking. Concentrating collector like linear parabolic collector or parabolic dish collector is used to convert solar energy into heat energy. Absorption of energy from the incident solar insolation is optimized by varying the flow rate of circulating thermic fluid using a pump. This pump is energized from a set of photovoltaic panels(PV cell) which convert solar energy into electrical energy. The energy absorbed from the solar thermal collector is stored in a buffer tank which is thermally insulated. Whenever cooking has to be carried out, the high temperature fluid from the buffer tank is circulated through a heat exchanger that is located in the kitchen. The rate of cooking can be varied by controlling both the flow rate of fluid from the buffer tank to heat exchanger and also by controlling the amount of energy drawn from the auxiliary source. If the available stored energy is not sufficient, the auxiliary source of energy is used for cooking in order to ensure that cooking is in-dependent of time and solar insolation. In the proposed hybrid solar cooking system, the thesis addresses the issues involved in optimization of energy extracted from sun to storage tank and its subsequent transfer from the storage tank to the load. The flow rate at which maximum energy is extracted from sun depends on many parameters. Solar insolation is one of the predominant parameters that affect the optimum flow rate. Insolation at any location varies with time on a daily basis (diurnal variations) and also with day on a yearly basis(seasonal variation). This implies that the flow rate of the fluid has to be varied appropriately to maximize the energy absorbed from sun. In the proposed system, flow rate control plays a very significant role in maximizing the energy transfer from the collector to the load. The flow rate of the thermic fluid in the proposed system is very small on the order of 0.02kg/s. It is very difficult to sense such low flows without disrupting the operating point of the system. Though there are many techniques to measure very low flow rates, they invariably disrupt the system in which flow rate has to be measured. Further, the low flow sensors are far too expensive to be included in the system. A reliable, accurate and inexpensive flow measuring technique has been proposed in this thesis which is non-disruptive and uses a null-deflection technique. The proposed measuring method compensates the pressure drop across the flow meter using a compensating pump. The analysis, modeling, design and fabrication of this novel flow meter are addressed. The design and implementation of different subsystems that involves the selection and design of solar concentrating collector and tracking are explained. Finally, it is essential to know the economic viability of the proposed system that is designed and implemented. To understand the economics, the life cycle cost analysis of the proposed system is presented in this thesis. The major contributions of this thesis are: Energy transport: Major challenge in energy transport is to bring heat energy obtained from the sun to the kitchen for cooking. Energy transferred from solar insolation to the cooking load has to be optimized to maximize the overall efficiency. This can be split in to two parts,(a) optimizing efficiency of energy transferred from the collect or to the energy buffer tank,(b) optimizing efficiency of energy transferred from the buffer tank to the load. The optimization is performed by means of a maximum power point tracking(MPPT) algorithm for a specific performance index. Modeling of the cooking system: There are several domains that exist in the solar cooking system such as electrical domain, thermal domain, and hydraulic domain. The analysis of power/energy flow across all these domains presents a challenging task in developing a model of the hybrid cooking system. A bond graph modeling approach is used for developing the mathematical model of the proposed hybrid cooking system. The power/energy flow across different domains can be seamlessly integrated using the bond graph modeling approach. In this approach, the various physical variables in the multi-domain environment are uniformly de-fined as generalized power variables such as effort and flow. The fundamental principle of conservation of power/energy issued in describing the flow of power/energy across different domains and thus constructing the dynamic model of the cooking system. This model is validated through experimentation and simulation. Flow measurement: A novel method of low fluid mass flow measurement by compensating the pressure drop across the ends of measuring unit using a compensating pump has been proposed. The pressure drop due to flow is balanced by feedback control loop. This is a null-deflection type of measurement. As insertion of such a measuring unit does not affect the functioning of the systems, this is also a non-disruptive flow measurement method. This allows the measurement of very low flow rate at very low resolution. Implementation and design of such a unit are discussed. The system is modeled using bond graph technique and then simulated. The flow meter is fabricated and the model is experimentally validated. Design Toolbox: Design of hybrid cooking system involves design of multi domain systems. The design becomes much more complex if the energy source to operate the system is hybrid solar based. The energy budget has to be evaluated considering the worst case conditions for the availability of the solar energy. The design toolbox helps in assessing the user requirement and help designing the cooking system to fulfill the user requirement. A detailed toolbox is proposed to be developed that can be used in designing/selecting sub-systems like collector, concentrator, tracking system, buffer tank, heat exchanger, PV panel, batteries etc. The toolbox can also be used for performing life cycle costing.

This study centered on a novel thermoelectric generator (TEG) integrated into the built environment. Designed by Watts Thermoelectric LLC, the TEG is essentially a novel assembly of thermoelectric modules whose required temperature differential is supplied by hot and cold streams of water flowing through the TEG. Per its recommended operating conditions, the TEG nominally generates 83 Watts of electrical power. In its default configuration in the built environment, solar-thermal energy serves as the TEG’s hot stream source and geothermal energy serves as its cold stream source. Two systems-level, thermodynamic analyses were performed, which were based on the TEG’s upcoming characterization testing, scheduled to occur later in 2011 in Detroit, Michigan. The first analysis considered the TEG coupled with a solar collector system. A numerical model of the coupled system was constructed in order to estimate the system’s annual energetic performance. It was determined numerically that over the course of a sample year, the solar collector system could deliver 39.73 megawatt-hours (MWh) of thermal energy to the TEG. The TEG converted that thermal energy into a net of 266.5 kilowatt-hours of electricity in that year. The second analysis focused on the TEG itself during operation with the purpose of providing a preliminary thermodynamic characterization of the TEG. Using experimental data, this analysis found the TEG’s operating efficiency to be 1.72%. Next, the annual emissions that would be avoided by implementing the zero-emission TEG were considered. The emission factor of Michigan’s electric grid, RFCM, was calculated to be 0.830 tons of carbon dioxide-equivalent (CO2e) per MWh, and with the TEG’s annual energy output, it was concluded that 0.221 tons CO2e would be avoided each year with the TEG. It is important to note that the TEG can be linearly scaled up by including additional modules. Thus, these benefits can be multiplied through the incorporation of more TEG units. Finally, the levelized cost of electricity (LCOE) of the TEG integrated into the built environment with the solar-thermal hot source and passive ground-based cold source was considered. The LCOE of the system was estimated to be approximately $8,404/MWh, which is substantially greater than current generation technologies. Note that this calculation was based on one particular configuration with a particular and narrow set of assumptions, and is not intended to be a general conclusion about TEG systems overall. It was concluded that while solar-thermal energy systems can sustain the TEG, they are capital-intensive and therefore not economically suitable for the TEG given the assumptions of this analysis. In the end, because of the large costs associated with the solar-thermal system, waste heat recovery is proposed as a potentially more cost-effective provider of the TEG’s hot stream source. / text