Thesis (M.S.)--State University of New York at Binghamton, Program of Materials Science and Engineering, 2007. / Includes bibliographical references.

Thesis (M.S.)--California Polytechnic State University, 2008. / Major professor: Albert Liddicoat, Ph.D. "Presented to the faculty of California Polytechnic State University, San Luis Obispo." "In partial fulfillment of the requirements for the degree [of] Master of Science in Electrical Engineering." "June 2008." Includes bibliographical references (leaves 70-73). Also available online. Also available on microfiche (2 sheets).

Thesis (M.S.)--University of Michigan, 1981.

Thesis (M.S.)--University of Michigan, 1981.

Thesis (Ph. D.)--University of Texas at Austin, 1999. / Vita. Includes bibliographical references (leaves 110-112). Available also in a digital version from Dissertation Abstracts.

Thesis (M.Sc.)--City University of Hong Kong, 2005. / At head of title: City University of Hong Kong, Department of Physics and Materials Science, Master of Science in materials engineering & nanotechnology dissertation. Title from title screen (viewed on Sept. 4, 2006) Includes bibliographical references.

Thesis (Ph. D.)--State University of New York at Binghamton, Thomas J. Watson School of Engineering and Applied Science, Department of Systems Science and Industrial Engineering, 2007. / Includes bibliographical references.

abstract: For decades, microelectronics manufacturing has been concerned with failures related to electromigration phenomena in conductors experiencing high current densities. The influence of interconnect microstructure on device failures related to electromigration in BGA and flip chip solder interconnects has become a significant interest with reduced individual solder interconnect volumes. A survey indicates that x-ray computed micro-tomography (µXCT) is an emerging, novel means for characterizing the microstructures' role in governing electromigration failures. This work details the design and construction of a lab-scale µXCT system to characterize electromigration in the Sn-0.7Cu lead-free solder system by leveraging in situ imaging. In order to enhance the attenuation contrast observed in multi-phase material systems, a modeling approach has been developed to predict settings for the controllable imaging parameters which yield relatively high detection rates over the range of x-ray energies for which maximum attenuation contrast is expected in the polychromatic x-ray imaging system. In order to develop this predictive tool, a model has been constructed for the Bremsstrahlung spectrum of an x-ray tube, and calculations for the detector's efficiency over the relevant range of x-ray energies have been made, and the product of emitted and detected spectra has been used to calculate the effective x-ray imaging spectrum. An approach has also been established for filtering `zinger' noise in x-ray radiographs, which has proven problematic at high x-ray energies used for solder imaging. The performance of this filter has been compared with a known existing method and the results indicate a significant increase in the accuracy of zinger filtered radiographs. The obtained results indicate the conception of a powerful means for the study of failure causing processes in solder systems used as interconnects in microelectronic packaging devices. These results include the volumetric quantification of parameters which are indicative of both electromigration tolerance of solders and the dominant mechanisms for atomic migration in response to current stressing. This work is aimed to further the community's understanding of failure-causing electromigration processes in industrially relevant material systems for microelectronic interconnect applications and to advance the capability of available characterization techniques for their interrogation. / Dissertation/Thesis / Doctoral Dissertation Materials Science and Engineering 2015

Abstract In the interest of improving reliability, electrical monitoring methods were utilized to observe the degradation of electronics interconnections while simultaneously characterizing accelerated testing-induced changes in test structures by means of optical examination, X-ray, scanning acoustic microscopy and scanning electron microscopy. To improve the accuracy of lifetime prediction for the PCSB interconnections investigated in this work, a modified Engelmaier’s solder joint lifetime prediction model was recalibrated. The results show that with most of the presented lead-free (SAC387, SAC405, SAC-In) solder and structure combinations with a large global thermal mismatch (ΔCTE > 10 ppm/°C), lifetime was adequate in the presented TCT ranges of 0‒100 °C and −40‒125 °C, while the amount of non-preferred crack types, i.e. ceramic cracks, was minimized. Degradation of interconnections was characterized using RF measurements both during TCT and intermittently during TCT breaks. A grounded coplanar waveguide was arranged either in a straight back-to-back configuration or together with a filter module with a passband at 22‒24 GHz—both with two transitions—and characterized during cycling breaks up to 25 GHz and 30 GHz, respectively. Besides off-cycle measurements, in-cycle measurements were done on an antenna structure with an in-band at 10‒11 GHz, up to 14 GHz. The results show that the signal response was initially affected at some frequencies as short-duration (< 1 s) glitches in the monitored signal when measured during cycling in 0‒100 °C TCT. Later on the degradation could be observed in the whole frequency band as TCT was continued. Development of the semi-empirical lifetime prediction model for PCSB interconnections showed the temperature range dependency of the correction term to be a second order polynomial instead of a logarithmic one. For components with PCSB BGA, promising prediction results were achieved which differed from the realized lifetime by less than 0.5% at best. / Tiivistelmä Elektroniikkaliitosten rikkoontumisen seurantaan tarkoitettuja sähköisiä monitorointimenetelmiä kehitettiin samanaikaisesti karakterisoimalla testauksella liitoksiin aikaansaatuja muutoksia optisesti, akustisella mikroskoopilla sekä röntgen- ja pyyhkäisyelektronimikroskoopeilla. Liitosten eliniän ennustamiseen soveltuva muokattu Engelmaierin malli kalibroitiin PCSB-liitosten elinikäennusteen tarkkuuden parantamiseksi. Tulosten perusteella useimmille tässä työssä käytetyille lyijyttömille (SAC387, SAC405, SAC-In) juotteille ja suuren termisen epäsovituksen (ΔCTE > 10 ppm/°C) rakenneyhdistelmille eliniät lämpösyklaustesteissä 0‒100 °C ja −40‒125 °C alueilla olivat riittävät ja haitallisimpien murtumien, eli keraamimurtumien, määrä saatiin minimoiduksi. RF-mittauksia käytettiin liitosten vikaantumisen seurantaan sekä lämpösyklauksen aikana että syklausten välillä. Maadoitettua koplanaarista aaltojohtoa käytettiin joko suoraan perättäiskytkennässä tai suodatinmoduulin kanssa, jonka päästökaista oli 22–24 GHz. Rakenteet karakterisoitiin syklausten välillä 25 GHz ja 30 GHz asti tässä järjestyksessä. Näiden mittausten lisäksi 10–11 GHz kaistalla toimivaa antennirakennetta karakterisoitiin syklauksen aikana 14 GHz asti. Tulokset osoittavat, että signaalivasteen muutos ilmenee aluksi joillakin taajuuksilla lyhyinä, alle 1 s mittaisina häiriöpiikkeinä, 0‒100 °C syklauksen aikana. Syklauksen edetessä vasteen huononeminen havaitaan myöhemmin koko mittausalueella. Puolikokeellista elinikäennustemallia tarkasteltaessa havaittiin, että PCSB-liitosten lämpötila-alueesta riippuvia korjauskertoimia kuvasivat logaritmisen riippuvuuden sijaan parhaiten toisen asteen polynomifunktiot. PCSB BGA ‒rakenteille saadun ennusteen ja toteutuneen eliniän välinen ero oli pienimmillään alle 0.5 %.

The purpose of this project has been to investigate potential correlations between rheological properties and jetting quality of solder paste. The project was carried out for Mycronic AB. Data from previously obtained measurements for both rheological properties and jetting quality were used in the analysis. We were only able to suggest preliminary correlations. One reason for this was that the jetting data was not designed for correlation work. It was performed to set parameters for new fluids. The data was inconsistent and difficult to work with in a correlation studie. However, the work led to a framework for future studies and correlation work.