This thesis reports on the development of low-temperature processes for transition metal carbide and MAX-phase thin film growth. Magnetron sputtering and evaporation, far from thermodynamical equilibrium, have been utilised to engineer the properties of the films by physical and chemical control. Deposition of W, W2C and β-WC1-x films with controlled microstructure, from nanocrystalline to epitaxial, is shown in the W-C system down to 100 oC. W films with upto 20 at% C exhibited an extreme solid-solution hardening effect, with a nanoindentation hardness maximum of 35 GPa. Furthermore, the design of epitaxial ternary carbide films is demonstrated in the Ti1-xVxCy system in the form of controlled unit-cell parameters, strain-free films with a perfect match to the substrate, and ternary epitaxial gradient films. Moreover, phase stabilisation and pseudomorphic growth can be tuned in (Nb,Mo)C and (Ti,W)C films. The results obtained can be used for example to optimise electrical contacts in SiC high-power semiconductor devices. A large part of this thesis focuses on the deposition of MAX-phases. These compounds constitute a family of thermally stable nanolaminates with composition Mn+1AXn, n=1, 2 or 3, where M is an early transition metal, A is generally a group 13-14 element, and X is C or N. They show a combination of typical ceramic and metallic properties and are also machinable by virtue of the unique deformation behaviour observed only in laminates. So far, the MAX-phases have almost exclusively been prepared by high-temperature sintering and studied in bulk form. However, this thesis establishes a patented seed layer approach for successful MAX-phase thin film depositions down to 750 oC. For the first time, single-phase and epitaxial films of Ti3SiC2, Ti3AlC2 and Ti2AlC have been grown. The method has also been used to synthesise a new MAX-phase, Ti4SiC3. In addition, two previously unreported intergrown MAX-type structures are presented, Ti5Si2C3 and Ti7Si2C5. Combined theoretical and experimental results show the possibility to deposit films with very low bulk resistivity and designed mechanical properties. Furthermore, the demonstration of MAX-phase and carbide multilayer films paves the way for macrostructure engineering, for example, in coatings for low-friction or wear applications.

<p>This thesis reports on the development of low-temperature processes for transition metal carbide and MAX-phase thin film growth. Magnetron sputtering and evaporation, far from thermodynamical equilibrium, have been utilised to engineer the properties of the films by physical and chemical control. Deposition of W, W₂C and β-WC_1-x films with controlled microstructure, from nanocrystalline to epitaxial, is shown in the W-C system down to 100 ^oC. W films with upto 20 at% C exhibited an extreme solid-solution hardening effect, with a nanoindentation hardness maximum of 35 GPa. Furthermore, the design of epitaxial ternary carbide films is demonstrated in the Ti_1-xV_xC_y system in the form of controlled unit-cell parameters, strain-free films with a perfect match to the substrate, and ternary epitaxial gradient films. Moreover, phase stabilisation and pseudomorphic growth can be tuned in (Nb,Mo)C and (Ti,W)C films. The results obtained can be used for example to optimise electrical contacts in SiC high-power semiconductor devices. </p><p>A large part of this thesis focuses on the deposition of MAX-phases. These compounds constitute a family of thermally stable nanolaminates with composition M_n+1AX_n, n=1, 2 or 3, where M is an early transition metal, A is generally a group 13-14 element, and X is C or N. They show a combination of typical ceramic and metallic properties and are also machinable by virtue of the unique deformation behaviour observed only in laminates. So far, the MAX-phases have almost exclusively been prepared by high-temperature sintering and studied in bulk form. However, this thesis establishes a patented seed layer approach for successful MAX-phase thin film depositions down to 750 ^oC. For the first time, single-phase and epitaxial films of Ti₃SiC₂, Ti₃AlC₂ and Ti₂AlC have been grown. The method has also been used to synthesise a new MAX-phase, Ti₄SiC₃. In addition, two previously unreported intergrown MAX-type structures are presented, Ti₅Si₂C₃ and Ti₇Si₂C₅. Combined theoretical and experimental results show the possibility to deposit films with very low bulk resistivity and designed mechanical properties. Furthermore, the demonstration of MAX-phase and carbide multilayer films paves the way for macrostructure engineering, for example, in coatings for low-friction or wear applications.</p>

Bandpass microwave filters are often modeled as a set of coupled discrete and localized resonators. This model is adequate in the narrow-band case. It, however, fails to describe accurately compact structures where stray couplings can be strong. To address this problem, a new view is proposed in this thesis. Instead of basing the model on localized discrete resonances, we start by constructing a model that is based on the global resonances of the structure. These are the resonances that the ports see and emerge when the entire structure is treated as a single unit. The resulting circuit, the transversal circuit, is universal. It is valid for any coupled resonator filter. The circuit is used in optimization of compact and ultra wideband suspended stripline filters and excellent results were obtained. In order to relate the global-eigen modes model to the conventional model, the issue of representation of microwave filters is investigated in detail. It is shown that a microwave filter can be represented by an infinite number of similar coupling matrices by using different modes as basis. According to this new view, a similarity transformation in microwave coupled resonator filters is interpreted as a change of basis. Two circuits that are related by a similarity transformation represent the same filter structure by using different sets of modes as basis. These conclusions were exploited in establishing a design theory for filters with dual-mode cavities. The new theory leads to direct and accurate design techniques that need no, or minimal, optimization. No tuning is used in the CAD steps. Tuning may only be required to account for manufacturing tolerances. A new tuning configuration is described and validated by computer simulation. A novel dual-mode filter with improved quality factor and reduced sensitivity is developed and designed within the same approach. The filter is fabricated and measured and excellent results are achieved. The same design methodology was used to introduce a new class of dual-mode dual-band microwave filters with improved sensitivity. It is also shown that canonical dual-mode filters can be designed within the same view with minimal local optimization of the input cavity. / Thesis (Ph.D, Electrical & Computer Engineering) -- Queen's University, 2010-03-31 01:33:36.818

Ce travail de recherche est réalisé dans le cadre d'une collaboration internationale entre l'Université Technique de Cluj-Napoca en Roumanie et l'Ecole Centrale de Lille en France. Cette thèse a comme premier objectif, de réduire l’ondulation de couple d’une machine triphasée 6/8 à réluctance variable grâce aux paramètres de contrôle dans le mode de fonctionnement moteur et générateur. Par conséquent, un modèle analytique a été développé et mis en œuvre dans un environnement de calcul numérique. Un outil d'optimisation permettant de trouver les meilleurs paramètres de contrôle a été utilisé. Toutefois, le processus d’optimisation est très lent.En conséquence, une stratégie pour réduire le temps du processus d'optimisation sans abaisser la précision des résultats est proposée. Une stratégie de ‘mapping’ est utilisée entre un modèle grossier mais rapide et un modèle fin mais lent. Un travail est mené sur le choix du modèle grossier, dans le cadre d’un modèle fournissant des valeurs en fonction du temps. Deux stratégies de ‘mapping’ ont été utilisées dans cette thèse : l’‘Output Space Mapping Proportional’(OSMP) et le Manifold Mapping (MM). Ces deux stratégies sont utilisées pour déterminer les paramètres de contrôle optimaux. Le problème d’optimisation est ensuite complété en ajoutant des variables géométriques au processus d’optimisation du contrôle. Les outils développés sont ensuite utilisés dans le cadre du dimensionnement par optimisation d’un alterno-démarreur automobile. Finalement, des expériences et des essais sur un prototype de Machine à RV sont menés afin de valider les résultats du processus d'optimisation en mode moteur et générateur. / The switched reluctance machine has a simple construction making it cheaper in execution but one of the drawbacks of this machine is the torque ripple. This thesis had as first target, the usage of an optimization tool to calculate the best control parameters to correct this major drawback in motor and generator operation modes. Hence, an analytical model that takes into account the machine geometry and that is able to be simulated in both operation modes by adjusting the commutation angles was provided and implemented in a calculation environment. The second target of this work is to investigate a method to reduce the optimization time without lowering the accuracy of the results. The strategy used in the optimization process is known in literature as the space mapping technique, more precisely for this thesis output space mapping proportional and manifold mapping were studied. After testing them on a mathematical model it was possible to continue the investigation on defining the optimal control parameters of a three-phases 6/8 SR machine prototype, being able that further to use this strategy in a much complicated process, i.e. defining the right geometry and control of a SR machine to be used in automotive integrated starter alternator systems. The final target of the thesis was to conduct experiments and tests on the existing prototype in order to partially validate the results of the optimization process.

This thesis deals with optimization of coaxial cavity filters. It thoroughly describes optimization method Tuning – Space Mapping (TSM) in CST Studio. It focuses on the explanation of the fine and the coarse model and their mutual link. The whole algorithm is illustrated and tested on the third-order coaxial cavity filter working in the band of 880 – 960MHz. In order to check the function of TSM, the algorithm is applied on fourth-order filter, triplet filter and quadruplet filter. Another part of the thesis focuses on the automatization of the whole optimization procedure. Macros for automatic determination of calibration constants and automatic calibration process between the coarse and the fine model are proposed and programmed in CST. The complete optimization procedure is applied on optimization of seventh-order filter with two cross couplings.

RF and microwave applications represent one of the fastest-growing segments of the high performance electronics market, where ongoing innovation is critical. Manufacturers compete intensively to meet market needs with reduced cost, size, weight and many other performance criteria demands. Under this scenario, transmission lines based on metamaterial concepts can be considered a very interesting alternative to the conventional transmission lines. They are more compact (compatible with planar manufacturing processes) and present higher degrees of design flexibility. Furthermore, metamaterial transmission lines can also provide many other unique properties not achievable with ordinary transmission lines, such as dispersion or impedance engineering. Nevertheless, the impact in the industry is still not relevant, mostly due to the complexity of the related synthesis and design procedures. These procedures are mainly based on the engineer’s experience, with the help of costly full-wave electromagnetic (EM) simulators and parameter extraction methods. The aim of this thesis is to contribute to simplify and speed up the synthesis and design procedures of artificial transmission lines. In particular, the lines obtained by periodically loading a conventional transmission line with electrically small resonators, such as split ring resonators (SSRs) or its complementary particle (CSRR). The design procedure is automated by using Space Mapping techniques. In contrast to other alternative methods, real synthesis is found from the circuit schematic (that provides a given target response) and without need of human intervention. Some efforts to make the method practical and useful have been carried out. Given a certain target response, it is determined whether it can be physically implemented with a chosen technology, and hence proceeding next to find the synthesis, or not. For this purpose, a two-step Aggressive Space Mapping approach is successfully proposed. In contrast to other methods, the real synthesis is found from certain target circuit values (corresponding to the equivalent circuit model that characterizes the structure to be synthesized). Different efforts have been carried out in order to implement a useful and practical method. Some of them were focused to determine if, given certain circuit parameters (which determine the target response) and certain given technology specifications (permittivity and height of the substrate, technology limits), that response is physically realizable (convergence region). This technique was successfully formulated and it is known as “Two-Step Aggressive Space Mapping Approach”. In this work, the latest improvements made till date, from the synthesis of basic unit cells until different applications and kinds of metamaterial-based circuits, are presented. The results are promising and prove the validity of the method, as well as its potential application to other basic cells and more complex designs. The general knowledge gained from these cases of study can be considered a good base for a coming implementation in commercial software tools, which can help to improve its competitiveness in markets, and also contribute to a more general use of this technology. / Rodríguez Pérez, AM. (2014). Synthesis of Planar Microwave Circuits based on Metamaterial Concepts through Aggressive Space Mapping [Tesis doctoral]. Universitat Politècnica de València. https://doi.org/10.4995/Thesis/10251/48465

This thesis deals with development of tool – macros which help to create coaxial cavity filters. It describes problematic design of complex structures at CST Studio Suite 2009. For this purpose macros supporting coarse and fine model to method Tuning – Space Mapping (TSM) was made. This means creating fine model at CST MWS and coarse model at CST DS.

[ES] La presente tesis doctoral tiene como objetivo principal el estudio, desarrollo, diseño y fabricación de nuevos componentes pasivos de microondas, tales como filtros y multiplexores que operen en las bandas de alta frecuencia de los actuales y futuros satélites de telecomunicación (bandas Ku, K y Ka) entre 12 y 40 GHz. Dichos componentes deben ser capaces de ofrecer tanto respuestas clásicas sencillas como avanzadas (elípticas), y presentar una capacidad de resintonización (tanto en términos de frecuencia central como de ancho de banda). Estos componentes darán solución a las necesidades actuales de los sistemas de comunicaciones espaciales, que requieren de mayores tasas de transmisión de datos (señales de mayor ancho de banda), así como de mayor flexibilidad en las frecuencias de operación, para ofrecer con un mismo dispositivo distintos servicios y prestaciones. Para ello, se proponen tanto modificaciones a las estructuras de filtros clásicos de microondas actuales, como la introducción de nuevas estructuras. Asimismo, también se investigará el uso de los tornillos de ajuste post-fabricación de los filtros como tornillos de sintonía metálicos, así como la posible introducción de tornillos de sintonía realizados con distintos materiales dieléctricos. Se pretende, de esta forma, mejorar las respuestas de los dispositivos actuales; reduciendo su tamaño y costes de producción (debido a la relajación de las tolerancias de fabricación), abaratando de esta forma la fabricación y futura operación de los mismos. Aprovechando estos nuevos dispositivos, se abordará también el diseño, fabricación y medida de componentes más complejos, como pueden ser los los diplexores de canal o los conmutadores con respuesta selectiva en frecuencia, todos ellos necesarios en los sistemas de comunicaciones espaciales y en íntima relación con los filtros previamente mencionados. Por último, el desarrollo de todos estos nuevos dispositivos vendrá acompañado de una metodología de diseño basado en el uso del Mapeo Espacial Agresivo (Aggressive Space Mapping, ASM) especialmente adaptado a los filtros en guía de onda. / [CA] La present tesis doctoral té com a objectiu el estudi, desenvolupament, diseny i fabricació de nous components pasius de microones, tals com els filtres i multiplexors que operen en les bandes d'alta freqüencia dels actuals i futurs satèl.lits de telecomunicació (bandes Ku, K i Ka) entre 12 i 40 GHz, Aquests components han de ser capaços d'oferir tant, respostes clàsiques sencilles com avançades (eliptiques), i que a més a més presenten una capacitat de resintonització (tant en termes de freqüència central com d'amplada de banda). Aquestos nous components pasius donaràn solució a les necesitats dels actuals sistemes espacials, que requereixen de majors taxes de transmissió de dades (senyals de major amplada de banda), així com de major flexibilitat en les frequencies de operació, per oferir en un mateix dispositiu distints serveis i prestacions. Per aquesta raó, es proposen tant modificacions a les estructures del filtres clàsics de microones actuals, com la introducció de noves estructures. Així mateix, també s'investigarà l'us dels tornells d'ajustament post-fabricació dels filtres com a tornells de sintonía metàl.lica i la introducció de tornells de sintonía realitzats amb diferents materials dielèctrics Es pretén, d'aquesta forma, la millora de les respostes del dispositius actuals; reduint la envergadura i els costos de producció (gràcies a la relaxació de les toleràncies de fabricació), abaratint d'aquesta forma la fabricació i futura operació dels filtres mateixos. Aprofitant aquestos nous dispositius es treballarà també en el disseny, fabricaçió i mesura de components més complexes, com poden ser els multiplexors de canal i els commutadors amb resposta selectiva en freqüencia, tots ells necessaris en els sistemes de comunicacions espacials i en íntima relació amb els filtres abans esmenats. Per analitzar, el desenvolupament de tots aquestos dispositius vindrà acompanyat d'una metodologia de disseny basada en l'us del Mapatge Espacial Agressiu (Aggressive Space Mapping, ASM), especialment adaptat als filtres en guia d'ona. / [EN] The main objective of this doctoral thesis is the study, development, design and manufacture of new passive microwave components in waveguide technology, such as filters and multiplexers, that operate in the high frequency bands of current and future telecommunication satellite payloads between 12 and 40 GHz (Ku, K and Ka bands). The new solutions developed must other both classic and advanced (elliptical) responses, as well as the possibility of being reconfigured both in terms of center frequency and bandwidth. The motivation for this research is to address the current and future needs of space communication systems which require higher data rate transmission (that is larger bandwidths), as well as flexibility with respect to the operating frequency to dynamic adaptation to possible changes in user demands. In this context, we propose in this thesis alternative microwave filter structures in metallic waveguide, as well as novel solutions. We explore different approaches to adjust the filter performance, using both traditional metallic tuning screws as well as tuning elements made with dierent dielectric materials. We also advance the state-of-the-art by developing more performing Space Mapping procedures for the design, optimization and tuning of the filter structures that we propose. The objective is to improve the response of the devices and reduce, at the same time, their manufacturing time and costs. As a fundamental element of our work, in addition to theoretical developments, we also apply the findings of our research to the design, manufacture and measurement of a number of more complex components, such as diplexers and integrated switches and filters. They are practical devices to demonstrate the ability of the novel filters that we propose to satisfy the requirements of current and future advanced satellite payloads. / Ossorio García, J. (2021). Development of New Tunable Passive Microwave Components in Waveguide Technology [Tesis doctoral]. Universitat Politècnica de València. https://doi.org/10.4995/Thesis/10251/166100

Metal oxides are of immense technological importance. Their wide variety of structural and electronic characteristics leads to a flexibility unrivalled by other groups of materials. However, there is still much debate about the fundamental properties of some of the most widely used oxides, including TiO₂ and In₂O₃. This work presents high quality, in-depth characterisation of these two oxides in pure and doped form, including soft and hard X-ray photoelectron spectroscopy and X-ray diffraction. Bulk samples as well as thin film samples were prepared analysed. For the preparation of thin films a high quality sol-gel dip-coating method was developed, which resulted in epitaxial films. In more detail the organisation of the thesis is as follows: Chapter 1 provides an introduction to key ideas related to metal oxides and presents the metal oxides investigated in this thesis, In₂O₃, Ga₂O₃, Tl₂O₃, TiO₂, and SnO₂. Chapter 2 presents background information and Chapter 3 gives the practical details of the experimental techniques employed. Chapters 4 presents reciprocal space maps of MBE-grown In₂O₃ thin films and nanorods on YSZ substrates. Chapters 5 and 6 investigate the doping of In₂O₃ bulk samples with gallium and thallium and introduce a range of solid state characterisation techniques. Chapter 7 describes the development of a dip-coating sol-gel method for the growth of thin films of TiO₂ and shows 3D reciprocal space maps of the resulting films. Chapter 8 concerns hard x-ray photoelectron spectroscopy of undoped and Sn-doped TiO₂. Chapter 9 interconnects previous chapters by presenting 2D reciprocal space maps of nano structured epitaxial samples of In₂O₃ grown by the newly developed sol-gel based method. Chapter 10 concludes this thesis with a summary of the results.

Cette thèse porte sur la synthèse et la caractérisation de nouvelles phases d’oxydes multifonctionnels de la famille Ln2B2O7 avec Ln = lanthanide, B = Ti ; Zr. Ces oxydes présentent de nombreuses propriétés : photocatalytiques, ferroélectriques, piézoélectriques, de luminescence... Sous forme massive, des solutions solides (La1-xLnx)2Ti2O7 avec Ln = Pr à Lu et La2(Ti1-xZrx)2O7 ont été synthétisées par réaction solide-solide. L’étude portant sur la substitution du site Ln a permis de déterminer les limites de stabilité de la phase pérovskite en feuillets en fonction de la nature du lanthanide. Des analyses menées par spectrométrie Raman, ainsi que par spectrofluorimétrie ont mis en évidence des propriétés de luminescence dans les solutions solides (La1-xEux)2Ti2O7 et (La1-xTbx)2Ti2O7, suggérant ainsi la possibilité d’utiliser ces composés pour la fabrication de nouveaux systèmes luminophores. Des couches minces de Ln2Ti2O7 ont été élaborées par ablation laser pulsé, puis caractérisées par diffraction de rayons X haute résolution et par microscopie électronique à transmission haute résolution. Les nouvelles limites de stabilité des films minces à structure pérovskite en feuillets ont pu être déterminées dans le cas de dépôts réalisés sur des substrats de SrTiO3 et LaAlO3 orientés (100) et (110). Le caractère piézoélectrique/ferroélectrique des films de Ln2Ti2O7 cristallisés dans la phase α monoclinique a été confirmé à l’échelle locale par la microscopie à force piézoélectrique. Enfin, nous avons montré que la croissance épitaxiale d’un film de La2Zr2O7 déposé sur SrTiO3-(110) pouvait conduire à l'existence de la ferroélectricité en raison d'une structure pyrochlore géométriquement frustrée et la perte de la symétrie cubique. Ces résultats prometteurs font de ces composés Ln2B2O7 des candidats de premier choix en vue du développement de nouvelles phases oxydes multifonctionnelles. De plus, l’absence de plomb au sein de ces structures, ainsi que leur formidable résistance à la température et à l’irradiation ouvrent des perspectives intéressantes quant à l’utilisation de ces matériaux dans les équipements électroniques et en milieux extrêmes. / This thesis focuses on the synthesis and characterization of new multifunctional Ln2B2O7 oxides phases with Ln = lanthanide, B = Ti, Zr. These oxides possess many properties, including photocatalysis, ferroelectricity, piezoelectricity and luminescence. In bulk form, solid solutions of (La1-xLnx)2Ti2O7 with Ln = Pr to Lu and La2(Ti1-xZrx)2O7 were synthesis by solid-solid reaction. Study on the Ln site substitution highlighted the limits of stability of the layered perovskite depending on the nature of the lanthanide. Analysis carried out by Raman spectroscopy and spectrofluorimetry also permit the detection of luminescence in (La1-xEux)2Ti2O7 and (La1-xTbx)2Ti2O7 solid solutions, suggesting the possibility to use such compounds for fabrication of new phosphor systemes. Ln2Ti2O7 thin films were grown by pulsed laser deposition, and characterized by high resolution X-rays diffraction and high resolution transmission electron microscopy. The new limits of stability of films with layeredperovskite structure have been determined in the case of samples grown on (100)- and (110)-oriented SrTiO3 and LaAlO3 substrates. The piezoelectric/ferroelectrique properties of Ln2Ti2O7 thin films crystallized in the monoclinic α phase were confirmed at the local level by piezoelectric force microscopy measurements. Finally, we have shown the the epitaxial growth of La2Zr2O7 films deposited on (110)-oriented SrTiO3 substrate can induce ferroelectricity for geometrically frustrated pyrochlore structure with the loss of cubic symmetry. These interesting results make Ln2B2O7 compounds promising candidates for the development of new multifunctional oxides. Moreover, the absence of lead in these structures and their resistance to the temperature and irradiation open interesting perspectives for the use of such materials in electronic equipments and in extreme environments.