This thesis comprises an assessment of a novel concept to produce high purity hydrogen using mixed oxide ion/electronic conductor (MIEC) membranes and energy provided by solar concentrators (i.e. parabolic troughs or parabolic dishes). The vision of this concept is that it will be used to produce tons of high purity hydrogen for fuel cells, which is a scarce commodity with an increasing demand from residential and transportation power generation applications. The MIEC membrane activates a steam reforming reaction between water and methane to produce hydrogen of high purity on the water side and syngas on the fuel side. Expectations are that this concept has cost advantages over other thermo-chemical water-dissociation methods, using a lower temperature and no electricity for the reaction process. The thesis’ focus is on techno-economic aspects of the concept, as part of an application process for project financing by the European Commission of Research and Innovation. The assessment in the thesis shows that the overall efficiency of the concept is expected to be very low. It also identifies the difficulties of providing stable working conditions for the concept. Suggestions to improve the concept are proposed to address the most urgent problems of the concept. These suggestions illuminate the opportunities that actually do exist to combine MIEC membranes, solar energy and thermo-chemical water splitting into a working concept. These improvements include using parabolic dishes instead of parabolic troughs, using furnaces with control systems and using a viable flow rate. The production capacity of high purity hydrogen is expected to be approximately 89 mg per minute in a membrane bundle (i.e. 150 thin membrane fibers with an oxygen permeation flux of 1 ml cm-2 min-1) if these improvements were implemented. This would imply that the studied concept needs further development to produce high purity hydrogen in quantities that could meet the shortage on the commercial fuel cell markets.

Wireless communications has gone through tremendous growth in the past decades. There has been a shift in wireless network research from spectral efficiency and quality of service (QoS) constraints to energy efficiency and green communications to reduce power consumption. Green energy resources such as solar, wind, thermal and mechan- ical vibrations can be employed to increase the energy efficiency of energy-constrained networks such as wireless sensor networks. Converting the available energy in the sur- rounding area into electricity, energy harvesting (EH), has been the subject of recent research. EH from radio frequency (RF) signals can be utilized to prolong the lifetime of devices in energy-constrained systems. Wireless power transmission (WPT) for EH is a promising solution to provide a reliable source of energy for devices which are di cult to service due to mobility and/or hard to reach locations. The integration of relaying into conventional wireless networks is promising to increase the coverage area and reduce power consumption. However, the extra power consumed to relay signals may be a problem that can be mitigated by WPT. WPT has made it possible for relays to power themselves by capturing ambient energy wirelessly. The received signal at the relay can be utilized to both forward information and harvest energy. This dissertation focuses on practical energy harvesting schemes in wireless com- munication networks. Further, the broadcast nature of wireless systems makes wire- less transmissions more vulnerable to eavesdropping compared to wired signals. The goal of this work is to develop EH schemes that are capable of supplying sustainable energy to the relays and overcoming the secrecy hazards from potential eavesdroppers. Power splitting (PS) and time switching (TS) are studied in communication networks to prolong the lifetime of an energy-constrained relay. First, a dual hop system with an amplify and forward (AF) relay employing wireless information and power transfer (WIPT) via power splitting is studied. Optimal transmit antenna selection that max- imizes the end-to-end signal to noise ratio (SNR) at the destination is considered and the outage probability is derived. It is shown that the outage probability increases with the number of transmit antennas but this also increases the system complexity. Since the spectral efficiency with two-way relaying is higher than with one-way relaying, a two-way EH-based relay network with an eavesdropper is investigated. The secrecy capacity at the users is derived for two diversity combining cases at the eavesdropper, selection combining (SC) and maximal ratio combining (MRC). A friendly jammer is introduced to increase the secrecy capacity of the users by reducing the received signal to noise ratio at the eavesdropper since the signal of the jammer is considered as noise at the eavesdropper. The corresponding optimization problem is reformulated using the single condensation method (SCM) and geometric programming (GP) into a convex optimization problem. Then, GP is used to jointly optimize the power splitting factor of the relay and transmit powers of the two users and jammer to maximize the secrecy capacity of the system. Imperfect cancellation of the jamming signal at the relay is assumed. It is shown that increasing the power allocated to the jammer decreases the secrecy capacity at the users. However, when perfect jamming signal cancellation is assumed, increasing the power allocated to the jammer increases the secrecy capacity at the users. The secrecy capacity is also shown to be greater with a jammer than without a jammer. Channel state information uncertainty at the eavesdropper is also considered as an extra noise source. TS at the relay of a two-way EH-based relay network was also considered. GP is used to jointly optimize the time switching ratio of the relay and transmit powers of the two users and jammer to maximize the secrecy capacity of the system. It is shown that PS two-way relaying achieves a better secrecy capacity than TS two-way relaying. / Graduate

This thesis concerns the development and the study of Iron-based water oxidation catalysts (WOCs) and how to immobilize them onto the hydrophobic surface of a carbon paste electrode. In the introductory chapter a general background of the field of water splitting and this thesis is given. In the second chapter, experimental performance is described from synthesis to measurements of a complete complex-doped electrode. The third chapter deals with the results and the discussion of the performed experiments. In chapter four, a descriptive conclusion of the obtained data is held. / Det här arbetet berör studien och utvecklingen utav järnbaserade katalysatorer, speciellt framtagna för för delning utav vatten. Utöver detta undersöks även om dessa katalysatorer (WOCs) kan immobiliseras på den hydrofoba ytan hos elektroder gjorda på kol-pasta. I det inledande kapitlet ges en generell bakgrund till området som berör delning utav vatten. I det andra kapitlet presenteras det experimentella utförandet utav synteser samt elektrokemiska mätningar som berörts under arbetets gång i jakten på en komplexdopad elektrod. I det tredje kapitlet diskuteras resultaten från mätningarna samt möjliga framtidsutsikter. I det fjärde kapitlet presenteras slutsatserna utav studien.

Tor is a Privacy-Enhancing Technology based on onion routing which lets its users browse the web anonymously. Even though the traffic is encrypted in multiple layers, traffic analysis can still be used to gather information from meta-data such as time, size, and direction of the traffic. A Website Fingerprinting (WF) attack is characterized by monitoring traffic locally to the user in order to predict the destination website based on the observed patterns. TrafficSliver is a proposed defence against WF attacks which splits the traffic on multiple paths in the Tor network. This way, a local attacker is assumed to only be able to observe a subset of all the user's total traffic. The initial evaluation of TrafficSliver against Deep Fingerprinting (DF), the state-of-the-art WF attack, showed promising results for the defence, reducing the accuracy of DF from over 98% down to less than 7% without adding artificial delays or dummy traffic. In this thesis, we further evaluate TrafficSliver against DF beyond what was done in the original work by De la Cadena et al. by using a richer data representation and finding out whether it is possible to utilize simulated training data to improve the accuracy of the attack. By introducing directional time as a richer data representation and increasing the size of the training dataset using a simulator, the accuracy of DF was improved against TrafficSliver on three different datasets. Against the original dataset provided by the authors of TrafficSliver, the accuracy was initially 7.1% and then improved to 49.9%. The results were confirmed by using two additional datasets with TrafficSliver, where the accuracy was improved from 5.4% to 44.9% and from 9.8% to 37.7%. / Tor är ett personlig-integritetsverktyg baserat på onion routing som låter sina användare anonymnt besöka hemsidor på internet. Även om trafiken är enkrypterad i flera lager, kan trafikanalys användas för att utvinna information från metadata som exempelvis: tid, storlek och riktning av trafik. En Website Fingerprinting (WF)-attack karaktäriseras av att övervaka trafik nära användaren för att sedan avgöra vilken hemsida som besökts utifrån mönster. TrafficSliver är ett föreslaget försvar mot WF-attacker genom att dela upp trafiken på flera vägar genom nätverket. Detta gör att en attackerare antas endast kunna se en delmängd av användarens totala trafik. Den första utvärderingen av TrafficSliver mot Deep Fingerprinting (DF), spjutspetsen inom WF-attacker, visade lovande resultat för försvaret genom att reducera träffsäkerheten av DF från över 98% till mindre än 7% utan att lägga till artificiella fördröjningar eller falsk trafik. I denna uppsats strävar vi att fortsätta utvärderingen av TrafficSliver mot DF utöver vad som redan har gjorts av De la Cadena et al. med en rikare datarepresentation och en undersökning huruvida det går att använda simulerad data för att träna attacker mot försvaret. Genom att introducera riktad tid och öka mängden data för att träna attacken, ökades träffsäkerheten av DF mot TrafficSliver på tre distinkta dataset. Mot det dataset som samlades in av TrafficSliver var träffsäkerheten inledelsevis 7.1% och sedan förbättrad med hjälp av riktad tid och större mängder av simulerad träningsdata till 49.9%. Dessa resultat bekräftades även för två ytterligare dataset med TrafficSliver, där träffsäkerheten blev förbättrad från 5.4% till 44.9% och från 9.8% till 37.7%.

This study investigates the Swedish translations of extended premodifiers in a non-fictional German text on pedagogical theory and practice. The aim is to analyse complications and implications connected to different translation options and strategies. The analysis is based on Solfjeld’s (2003, 2004) German-Norwegian translation studies, which propose a classification model for translation strategies for German extended premodifiers with regard to aspects of explicitation and implicitation. The results show relations between postnominal finite target clauses and explicitation on the one hand, and on the other hand between prenominal non-clausal units and implicitation. Explicitation tends to result in sentence splitting which affects the text length and text cohesion.In addition, the study defines three main categories of German extended modifiers. The first category of adverbial extender premodifiers describe time, degree, and perspective and can easily be transferred into Swedish premodifying structures. The second category includes objects or predicatives which must be transferred into postmodifying structures. For the extended premodifiers belonging to the third category, the transferring into pre- or postmodifying target structures is optional. The study shows that the complexity of the extended premodifiers is a crucial factor which determines the choice of translation strategy. While explicifying relative clauses have a high amount of correspondence with Swedish language structures, the analysis emphasizes that implicifying premodifying target structures have less negative impact on text length, sentence splitting and text cohesion.

京都大学 / 新制・課程博士 / 博士(工学) / 甲第23216号 / 工博第4860号 / 新制||工||1759(附属図書館) / 京都大学大学院工学研究科物質エネルギー化学専攻 / (主査)教授 阿部 竜, 教授 陰山 洋, 教授 藤田 晃司 / 学位規則第4条第1項該当 / Doctor of Philosophy (Engineering) / Kyoto University / DGAM

We examine steady transonic flows of Bethe-Zel\'dovich-Thompson (BZT) fluids over thin turbine blades or airfoils. BZT fluids are ordinary fluids having a region of negative fundamental derivative over a finite range of pressures and temperatures in the single phase regime. We derive the transonic small disturbance equation (TSDE) capable of capturing the qualitative behavior of BZT fluids. The shock jump conditions, and shock existence conditions consistent with the derived TSDE are presented. The flux function is seen to be quartic in the pressure or density perturbation rather than the quadratic (convex) flux function of the perfect gas theory. We show how this nonconvex flux function can be used to predict and explain the complex flows possible in transonic BZT fluids. Numerical solutions using a successive line relaxation (SLR) scheme are presented. New results of interest include shock-splitting, collisions between expansion and compression shocks, the prediction and observation of two compressive bow shocks in supersonic flows, and the observation of as many as three normal stern shocks following an oblique trailing edge shock. / Master of Science

Philosophiae Doctor - PhD / The widespread use of fossil energy has been most convenient to the world, while they also cause environmental pollution and global warming. Therefore, it is necessary to develop clean and renewable energy sources, among which, hydrogen is considered to be the most ideal choice, which forms the foundation of the hydrogen energy economy, and the research on hydrogen production and fuel cells involved in its production and utilization are naturally a vital research endeavor in the world. Electrocatalysts are one of the key materials for proton exchange member fuel cells (PEMFCs) and water splitting. The use of electrocatalysts can effectively reduce the reaction energy barriers and improve the energy conversion efficiency.

La nouvelle génération de réseaux mobiles (5G) devrait faire face, durant les cinq prochaines années, à une importante croissance du volume de données, échangé entre plusieurs milliards d'objets et d'applications connectés. En outre, l'émergence de nouvelles technologies, telles que Internet of Things (IoT), conduite autonome et réalité augmentée, impose de plus fortes contraintes de performance et de qualité de service (QoS). Répondre aux besoins cités, tout en réduisant les dépenses d'investissement et d'exploitation (CAPEX/OPEX), sont les objectifs poursuivis par les opérateurs télécom, qui ont défini une nouvelle architecture d'accès radio, appelée Cloud Radio Access Network (C-RAN). Le principe du C-RAN est de centraliser, au sein d'un pool, les parties de traitement, BaseBand Unit (BBU), d'un RAN traditionnel. Les BBU sont alors dissociées de la station de base et de la partie radio, Remote Radio Unit (RRU). Ces deux parties restent néanmoins connectées à travers un réseau intermédiaire appelé Fronthaul (FH). Dans cette thèse, nous allons concevoir une nouvelle architecture C-RAN partiellement centralisée qui intègrera une plateforme de virtualisation basée sur un environnement Xen, nommée " Metamorphic Network " (MNet). A travers cette architecture, nous viserons à : i) mettre en place un pool, dans lequel des ressources physiques (processeurs, mémoire, ports réseaux, etc.) seront partagées entre des BBU virtualisées et d'autres applications, ii) établir un réseau FH ouvert aux fournisseurs de services et aux tierces parties, facilitant ainsi le déploiement des services au plus près des utilisateurs, pour une meilleure qualité d'expérience, iii) exploiter, à travers le FH, les infrastructures Ethernet existantes pour réduire les CAPEX/OPEX et enfin, iv) atteindre les performances réseau préconisées pour la 5G. Dans la première contribution, nous allons définir une nouvelle architecture Xen pour la plateforme MNet, intégrant le framework de packet processing, OpenDataPlane (ODP), au sein d’un domaine Xen privilégié, nommé « Driver Domain ». Notre objectif, à travers cette architecture, est d’accélérer le traitement des paquets de données transitant par MNet, en évitant la surutilisation, par ODP, des cœurs du processeur physique (CPU) de la plateforme. Pour cela, des cœurs CPU virtuels (vCPU) seront alloués dans le Driver Domain pour être exploités durant le traitement des paquets par ODP. Cette nouvelle plateforme MNet servira de base pour notre architecture C-RAN. Dans la seconde contribution, nous allons implémenter, au sein du FH, deux solutions réseau. La première solution, consistera à déployer le réseau de couche 2, Transparent Interconnection of Lots of Links (TRILL), pour connecter les différents éléments de notre architecture C-RAN. La seconde solution, consistera à déployer un réseau Software Defined Network (SDN), géré par le contrôleur distribué ONOS, qui sera virtualisé dans le pool BBU. Une comparaison des performances réseau sera réalisée entre ces deux solutions. / Over the next five years, the new generation of mobile networks (5G) would face a significant growth of the data volume, exchanged between billions of connected objects and applications. Furthermore, the emergence of new technologies, such as Internet of Things (IoT), autonomous driving and augmented reality, imposes higher performance and quality of service (QoS) requirements. Meeting these requirements, while reducing the Capital and Operation Expenditures (CAPEX/OPEX), are the pursued goals of the mobile operators. Consequently, Telcos define a new radio access architecture, called Cloud Radio Access Network (C-RAN). The C-RAN principle is to centralize, within a pool, the processing unit of a radio interface, named BaseBand Unit (BBU). These two units are interconnected through a Fronthaul (FH) network. In this thesis, we design a new partially centralized C-RAN architecture that integrates a virtualization platform, based on a Xen environment, called Metamorphic Network (MNet). Through this architecture, we aim to: i) implement a pool in which physical resources (processors, memory, network ports, etc.) are shared between virtualized BBUs and other applications; ii) establish an open FH network that can be used by multiple operators, service providers and third parties to deploy their services and Apps closer to the users for a better Quality of Experience (QoE); iii) exploit, through the FH, the existing Ethernet infrastructures to reduce CAPEX/OPEX; and finally iv) provide the recommended network performance for the 5G. In the first contribution, we define a new Xen architecture for the MNet platform integrating the packet-processing framework, OpenDataPlane (ODP), within a privileged Xen domain, called Driver Domain (DD). This new architecture accelerates the data packet processing within MNet, while avoiding the physical CPUs overuse by ODP. Thus, virtual CPU cores (vCPU) are allocated within DD and are used by ODP to accelerate the packet processing. This new Xen architecture improves the MNet platform by 15%. In the second contribution, we implement two network solutions within the FH. The first solution consist of deploying a layer 2 network protocol, Transparent Interconnection of Lots of Links (TRILL), to connect multiple elements of our C-RAN architecture. The second solution consists of implementing a Software Defined Network (SDN) model managed by Open Network Operating System (ONOS), a distributed SDN controller that is which is virtualized within BBU pool. Moreover, a network performance comparison is performed between these two solutions.

<p><strong>Apstrakt je obrađen tehnologijama za optičko prepoznavanje teksta (OCR).</strong></p><p>Cilj ovog rada je teorijska (računarska) analiza primenljivosti dvomembranskog reaktora za izvodenje povratnih gasnih reakcija. Specijalno, analizira se primenljivost dvomern- branske konhguracije za termolizu vode. Rezultati simulacije su pokazali značajnu pred- nost, u pogledu povečanja konverzije reaktanta iznad ravnotežne, dvomembranske u odnosu na jednomembransku konhguraciju, u slučaju kada su membrane najmanje pro- pustljive za reaktant. Rezultati neizotermske analize dvomembranskog reaktora su pokazali da je efekat energije aktivacije u odnosu na efekat toplote reakcije zanemarljiv, u oblasti vehkih Damk&ouml;hler-ovih brojeva (odnos maksimalne brzine reakcije i protoka reaktanta u napoju). I za endotermne i za egzotermne reakcije, konverziona efikasnost opada sa porastom indeksa generisanja toplote (odnos toplotnog efekta reakcije i toplotnog kapaciteta reaktanta), a raste sa intenzitetom dovodenja odnosno odvodenja toplote. &Scaron;to se tiče uticaja temperature napoja, kod endotermnih reakcija postoji optimum ako permeabilnosti komponenata opadaju sa temperaturom. Na bazi raspoloživih literaturnih podataka formulisan je izotermski model dvomembranskog reaktora za termolizu vode sa jednom membranom propustljivom za vodonik, a drugom propustljivom za kiseonik. Pokazano je da se pri dovoljno velikim vrednostima Damk&ouml;hler-ovih broja i odnosa brzina (odnos maksimalne brzine permeacije za membranu i maksimalne brzine reakcije) u reaktoru može postići potpuna disocijacija vode. Zapaženo je postojanje optimalne raspodele ukupnog odnosa brzina izmedu dve membrane kao i, u slučaju uvodenja inerta u separacionu zonu, optimalne raspodele inerta između dve zone. Analiza je pokazala da dvomembranski reaktor predstavlja perspektivno re&scaron;enje problema termolize vode koje zaslužuje dalja teorijska i eksperimentaina istraživanja.</p> / <p><strong>Abstract was processed by technology for Optical character recognition (OCR).</strong></p><p>The aim of this study is a theoretical (computer) analysis of the applicability of a double-membrane reactor for reversible gas phase reactions. Particulaidy, the applicability of double-membrane configuration for the direct thermal water splitting is studied. The double-membrane configuration proved to be significantly superior over the single membrane configuration with respect to the equilibrium shift, in the case when the reac- tant is the slowest permeating component. By the non-isothermal analysis, it is shown that, in the region of high Damk&ouml;hler numbers (the ratio of the maximal reaction rate to the feed reactant flow), the effect of activation energy is negligible when compared to the effect of reaction heat. The conversion efficiency is decreasing by the increase of the heat generation index (the ratio of reaction heat to reactant heat capacity) and increasing by the increase of the added or removed heat, for both endo- and exothermic processes. As to the feed temperature, an optimal value exists for endothermic reactions, if component permeabilities are decreasing functions of temperature. On the basis of the available literature data, the isothermal model of double-membrane reactor (one membrane permeable for hydrogen an the other for oxygen) for direct thermal splitting of water is formulated. It is shown that the complete water dissociation could be achieved at the high enough values of Damk&ouml;hler number and of the rate ratio (the ratio of maximal permeability of membrane to the maximal reaction rate). The optimal distribution of the total rate ratio between the membranes as well as the optimal inert flow distribution could be determined. Double-membrane configuration seems to be a promising solution for the problem of direct thermal water splitting, deserving further theoretical and experimental investigations.</p>