This thesis reports on the research outcome of corrosion mechanism and corrosion rate of mild steel in different environments (saline, alkaline solutions and concrete media) using potentiodynamic polarization technique. The study also included the effect of corrosion on bond strength between reinforcing steel and concrete using pull-out test. Corrosion of mild steel and 316L stainless steel with different surface conditions in 1, 3 and 5% saline (NaCl + Distilled water) was investigated. Specimens ground with 200 and 600 grit silicon carbide grinding paper as well as 1μm surface finish (polished with 1μm diamond paste) were tested. In case of mild steel specimens, reduction in surface roughness caused increase in corrosion rate, while in 316L stainless steel corrosion rate decreased as the surface roughness improved. Metallographic examination of corroded specimens confirmed breakdown of passive region due to pitting corrosion. Corrosion of mild steel was also investigated in alkaline solution (saturated calcium hydroxide, pH =12.5) contaminated with 1, 3 and 5% saline. A series of corrosion experiments were also conducted to examine the efficiency of various concentrations of calcium nitrite (CN) on corrosion behaviour of both as-received and polished mild steel in alkaline solution containing 3% saline after 1 hour and 28 days of exposure. Corrosion rate was higher for the as-received than polished mild steel surface under the same testing conditions in NaCl alkaline solution with and without nitrites due to the effect of surface roughness. Morphology investigation of mild steel specimens in alkaline solution ii containing chlorides and nitrites showed localized pits even at nitrite concentration equal to chloride concentration. Corrosion of steel bars embedded in concrete having compressive strengths of 20, 30 and 46MPa was also investigated. The effect of 2 and 4% CN by weight of cement on corrosion behaviour of steel bar in low and high concrete strengths specimens were also studied. All reinforced concrete specimens were immersed in 3% saline solution for three different periods of 1, 7 and 15 days. In order to accelerate the chemical reactions, an external current of 0.4A was applied. Corrosion rate was measured by retrieving electrochemical information from polarization tests. Pull-out tests of reinforced concrete specimens were then conducted to assess the corroded steel/concrete bond characteristics. Experimental results showed that corrosion rate of steel bars and bond strength were dependent on concrete strength, amount of CN and acceleration corrosion period. As concrete strength increased from 20 to 46MPa, corrosion rate of embedded steel decreased. First day of corrosion acceleration showed a slight increase in steel/concrete bond strength, whereas severe corrosion due to 7 and 15 days corrosion acceleration significantly reduced steel/concrete bond strength. Addition of only 2% CN did not give corrosion protection for steel reinforcement in concrete with 20MPa strength at long time of exposure. However, the combination of good quality concrete and addition of CN appear to be a desirable approach to reduce the effect of chloride induced corrosion of steel reinforcement. At less time of exposure, specimens without CN showed higher bond strength in both concrete mixes than those with CN. After 7 days of corrosion acceleration, the higher concentration of CN gave higher bond strength in both concrete mixes. The same trend was observed at 15 days of corrosion acceleration except for the specimen with 20MPa compressive strength and 2% CN which recorded the highest deterioration in bond strength.

Este trabalho discute caminhos para tornar o projeto de detalhamento da armadura um indutor da melhoria da produtividade da mão-de-obra no serviço de armação. Uma revisão bibliográfica inicial precede a apresentação de estudos de campo, que foram realizados para se entender como a produtividade em armação varia. Tal entendimento (expresso na forma de faixas de variação da produtividade e apresentação dos fatores influenciadores) deu apoio a entrevistas com projetistas, visando levantar suas opiniões sobre as alterações no projeto, levando à melhoria da produtividade, que seriam mais viáveis de serem adotadas. Em paralelo, estudaram-se as diferentes formas de apresentação dos projetos de detalhamento da armadura e, uma vez descritas estas possibilidades, coletaram-se as opiniões de gestores da produção sobre as formas de representação mais convenientes. Todos estes conhecimentos, de base teórica e empírica, servem de subsídio para a tomada de decisões sobre diretrizes a serem seguidas na futura elaboração de projetos de detalhamento da armadura, o que é bastante desejável no sentido de se aumentar a competitividade das empresas de construção de edifícios. / This thesis presents directions to make the steel reinforcement design a tool to improve rebar labor productivity. Bibliography review served as basis to go through a site study that allowed understanding rebar labor productivity variation. Such an information, expressed in terms of a labor productivity unit rate range associated to the influencing factors presentation, supported designers interviews where they stated the ideas they are willing to use in their designs to improve labor productivity. The thesis also discusses different approaches to be used in order to represent the product being defined in the design. In this case, production managers were listened to, aiming to understand the ones they prefer. The whole knowledge here described, coming from theory or reality evaluation, can help managers in taking decisions in relation to the steel reinforcement design directions to be followed. This can be very helpful to make construction companies more competitive.

Detection and monitoring of the damage created by the corrosion of the steel reinforcement in concrete structures is a challenging and multidisciplinary problem. Economical monitoring strategy that is long-term and nondestructive requires low-cost, battery-free, wireless sensors. Our Electronic Structural Surveillance (ESS) platform uses battery-free passive resonant circuit (tag) as a sensor. The tag is magnetically coupled to an external reader coil. It is interrogated/read remotely in a non-contact (wireless) manner and the state of the sensor is determined from a swept frequency impedance measurement. When paired with the correct sensing element (transducer), the tag can be used for a variety of sensing applications for example, chemical & biochemical sensors. A circuit model of the reader and tag for such a universal battery-free wireless sensor platform is developed. The interaction between design and detection limit is examined. The dependence of the measured signal strength and read range on the various reader and tag circuit parameters is analyzed. Since the values of the circuit of the coils are dependent on their geometries, the effect of specific coil geometry is evaluated and design recommendations are made. / text

Appropriate transverse confinement can significantly improve strength, ductility and energy dissipation capacity of reinforced concrete columns, therefore enhancing their seismic resistance. This study is conducted to evaluate the seismic behaviour of concrete columns transversely confined by steel spirals, ties or fiber reinforced polymer (FRP) wrapping. In the experimental program of this study, fifteen circular concrete columns of 356 mm (14 in.) diameter and 1473 mm (58 in.) length were tested under lateral cyclic displacement excursions while simultaneously subjected to constant axial load thus simulating earthquake loads. Eight columns were solely confined by various amounts of steel spirals, while seven other columns containing only minimal steel spirals were retrofitted by external FRP wrapping. Test results revealed that the increased transverse confinement can improve the energy dissipation capacity, ductility, deformability and flexural strength of concrete columns. The required transverse confinement should also be enhanced with the increase of axial load level to satisfy certain seismic design criterion. A computation program was developed to conduct monotonic pushover analysis for confined concrete columns, which can predict the envelope curves of moment vs. curvature and shear vs. deflection hysteresis loops with reasonable accuracy for columns subjected to simulated seismic loading. Based on extensive numerical analysis, expressions were developed for the relationships between the amount of transverse confinement and different ductility parameters, as well as the strength enhancement of confined columns. Finally, design procedures to determine the amount of transverse confinement were developed for concrete columns to achieve a certain ductility target. The enhancement of flexural strength of columns due to transverse confinement was also evaluated.

Appropriate transverse confinement can significantly improve strength, ductility and energy dissipation capacity of reinforced concrete columns, therefore enhancing their seismic resistance. This study is conducted to evaluate the seismic behaviour of concrete columns transversely confined by steel spirals, ties or fiber reinforced polymer (FRP) wrapping. In the experimental program of this study, fifteen circular concrete columns of 356 mm (14 in.) diameter and 1473 mm (58 in.) length were tested under lateral cyclic displacement excursions while simultaneously subjected to constant axial load thus simulating earthquake loads. Eight columns were solely confined by various amounts of steel spirals, while seven other columns containing only minimal steel spirals were retrofitted by external FRP wrapping. Test results revealed that the increased transverse confinement can improve the energy dissipation capacity, ductility, deformability and flexural strength of concrete columns. The required transverse confinement should also be enhanced with the increase of axial load level to satisfy certain seismic design criterion. A computation program was developed to conduct monotonic pushover analysis for confined concrete columns, which can predict the envelope curves of moment vs. curvature and shear vs. deflection hysteresis loops with reasonable accuracy for columns subjected to simulated seismic loading. Based on extensive numerical analysis, expressions were developed for the relationships between the amount of transverse confinement and different ductility parameters, as well as the strength enhancement of confined columns. Finally, design procedures to determine the amount of transverse confinement were developed for concrete columns to achieve a certain ductility target. The enhancement of flexural strength of columns due to transverse confinement was also evaluated.

It is well-known that concrete permeability is a good indicator of its expected durability until it remains uncracked. However, in various stages of its service life, different types of cracking in concrete can be developed due to exposure to different deterioration processes such as early plastic shrinkage or chloride-induced reinforcement corrosion. Although these cracks may not endanger concrete’s structural performance from the mechanical point of view, they create a pathway for aggressive ions that can initiate degradation processes, lead to increase in concrete permeability and thus reduce its durability. Cracking in concrete might not be preventable, but its capability to naturally seal small cracks, named autogenous self-healing (SH), provides an additional feature to manufacture more durable concrete structures. However, natural self-healing capability of concrete is limited and therefore it is typically omitted in the design of concrete structures. Hence, more attention has been recently paid to Engineered Self-healing Concrete (EShC) which is associated with artificially triggered healing mechanisms into the cementitious matrix by incorporating various substances such as crystalline products. EShC helps in reducing concrete permeability; thus, increasing its service-life and durability. Due to formation of needle-shaped pore-blocking crystals, Crystalline Admixtures (CA), as a candidate from the Permeability-Reducing Admixtures (PRA) category, can be implemented into concrete mixtures to fabricate EShC concretes. Crystalline waterproofing technology is not new, but still is unknown to many researchers, engineers, and construction industry professionals. The lack of knowledge of its microstructure and self-healing properties limits CA’s proper usage in the construction industry. The techniques to assess the self-healing capability of mortar and concrete are not well-standardized yet. No research work has been done to address certain durability characteristics of this material (i.e. electrical resistivity (ER) or chloride diffusivity) especially when combined with Supplementary Cementitious Materials (SCM) and Portland Limestone Cement (PLC). Since the resistance of concrete against ions’ penetration is a function of its permeability, it might be a straightforward and reliable parameter to rapidly evaluate concrete’s durability during its intended service life. Hence, electrical resistivity measurement is considered as an indirect and alternative tool for other time-consuming permeability testing techniques to examine the CA’s efficiency as it modifies the concrete’s microstructure by crystals’ deposition; thus, leads to permeability improvement. In comparison to previous studies, on a larger scale, this thesis aims to systematically study the effects of CA on the microstructural features, self-healing properties and long-term durability and resistivity of cement-based materials and in addition, draw some comprehensive conclusions on the use of CA in new and repair applications. This study is divided into three major phases to propose all-inclusive work on using CA in construction industry. To satisfy the goals of each individual phase, a test matrix consisting of a series of four mixes with variables such as use of PLC or presence of CA in powder form is considered. In order to address to the lack of research and industry knowledge discussed above, this PhD thesis includes the following phases: Phase (I) In this phase, the main focus is on the microstructural properties and the changes in the pore structure and chemical compositions of the cement phase of mortar mixes when treated with CA. These microstructural features are studied using Scanning Electron Microscope (SEM) and Scanning Transmission Electron Holography Microscope (STEHM). Moreover, physical and chemical characteristics of the hydration products are determined using image analysis and Energy Dispersive X-ray (EDX) Spectroscopy, respectively. Phase (II) This phase is allocated to macro-level investigation of durability characteristics such as chloride/water permeability and electrical resistivity of concrete structures containing CA and PLC cement. To non-destructively measure the chloride ion concentration in the field conditions, both changes in corrosion potential of rebars and concrete electrical resistivity in treated circular hollow-section steel reinforced columns exposed to simulated marine environment is monitored and compared over a 2-year period with control samples. In addition, laboratory-size concrete samples are studied to investigate the effects of CA presence on long-term resistivity, rapid chloride permeability, water permeability and chloride diffusivity of concrete. Later, a resistivity-based model is developed to predict long-term performance of concretes incorporating slag or metakaolin, studied in various environmental conditions. The long-term goal of this phase is to develop a standard design guideline and durability-based model. Phase (III) Using an innovative self-healing testing method [1], quantitative analysis of crack closure ability and self-healing potential of CA treated and control concretes with OPC or PLC cement is accomplished during this phase. The obtained results from first phase showed that hydrated CA particle revealed fine, compact, homogenous morphology examined by STEHM and its diffraction pattern after water-activation indicated nearly amorphous structure, however, diffuse rings, an evidence for short-range structural order and sub-crystalline region, were observed which requires further investigation. The SEM micrographs taken from specimen’s fractured surface showed formation of pore-blocking crystals for all treated mixes while similar spots in un-treated sections were left uncovered. Although needle-shaped crystals were observed in the treated mortar specimens, but not all of them had shapes and chemical compositions other than ettringite (well-known to form needle-like crystals). Using backscatter SEM images and EDX spectrums, examination of polished mortar sections with and without CA also showed typical hydration phases, forming in the control system. Results from phase II showed that concretes treated with CA had almost 50% lower water penetration depth and thus smaller permeability coefficient when compared with the virgin OPC or PLC concretes. According to salt ponding test results, the use of CA helped in enhancing the resistance to chloride penetration compared to control concrete. This improvement increases with increasing in concrete age. Strong linear relationship between Surface Resistivity (SR) and Bulk Resistivity (BR) data was observed which indicates that these test methods can be used interchangeably. The presence of SCM in concrete indicated considerable increase in both SR and BR compared to control concrete. Concretes incorporating slag or metakaolin have tendency to react more slowly (or rapidly in MK case), consume calcium hydroxide over time, form more Calcium Silicate Hydrate (C-S-H) gel, densify internal matrix, and also reduce OH- in the pores’ solution; thus, increase concrete electrical resistivity. For laboratory specimens, environmental conditions such as temperature variation and degree of water saturation indicated considerable effects on electrical resistivity measurements. As temperature or water content of concrete decreases, its electrical resistivity greatly increases by more than 2-3 times from reference environmental condition. This is mostly because of variation or accessibility in electron mobility. Experimental results from field investigation showed that electrical resistivity readings were highly influenced by the presence of rebar and concrete moisture conditions. In addition, concrete cover thickness and CA addition into cementitious matrix had a negligible effect on its resistivity. In the last phase, an optical microscope was used to measure the average crack width. OPC samples had an average measured crack width of 0.244 mm as compared to 0.245 mm for OPC-CA, 0.251 mm for PLC, and 0.247 mm for PLC-CA. Self-healing test results also showed 90% self-healing ratio for CA modified mix within few days after starting experiment. Addition of CA into the mix led to higher rates of healing and full crack closure (width up to 250 µm) when compared to reference concrete. An empirical equation that relates water initial flow rate to the crack width (Q∝〖CW〗^3) was also proposed in this phase. Presence of PLC and CA in the mixture resulted in positive improvement in crack-closing capability and self-healing ratio. / Graduate / 2019-09-11

A limited number of studies have been conducted in the literature in order to investigate the behaviour of high-strength fibre-reinforced concrete (HSFRC) structural components subjected to blast loads. This study summarizes the results of a research program investigating the potential of using steel fibres to improve the blast performance of high-strength reinforced concrete beams. As part of the experimental investigation twenty beams were tested, including nine beams tested under static four-point bending, and eleven beams tested under dynamic blast loads using a shock-tube. Parameters considered in the study include the effect of concrete strength, steel fibres, fibre content, fibre type, longitudinal reinforcement ratio, and presence of shear reinforcement. All beams in the study have identical dimensions, with a cross-section of 125 x 250 mm and length of 2440 mm. To manufacture the specimens, two beams were cast with normal-strength self-consolidate concrete (SCC), with a specified strength of 50 MPa, while the remaining beams were cast with either plain or fibre-reinforced high-strength concrete having a compressive strength which varied between 95-110 MPa. The steel fibre content in the HSFRC beams varied between 0.5 and 1.0%, by volume of concrete. To investigate the effect of reinforcement ratio (ρ), the beams were reinforced with 2-#4 (American size) bars, 2-15M bars or 2-20M bars (ρ = 1.02%, 1.59%, and 2.41%, respectively). The majority of the plain concrete beams had transverse reinforcement which consisted of 6 mm stirrups arranged at a spacing of 100 mm in the shear spans, while most of the HSFRC beams were built without stirrups. The results indicate that all the parameters in this study (reinforcement ratio, presence of stirrups, concrete strength, steel fibres, fibre content and fibre type) affected the static and blast response of the beams, however, the results demonstrate that steel fibres have a more remarkable effect when compared to the other parameters. The provision of fibres is found to improve the blast performance of the HSC beams by increasing shear capacity, reducing maximum and residual mid-span displacements, reducing blast fragments and increasing damage tolerance.

Este trabalho discute caminhos para tornar o projeto de detalhamento da armadura um indutor da melhoria da produtividade da mão-de-obra no serviço de armação. Uma revisão bibliográfica inicial precede a apresentação de estudos de campo, que foram realizados para se entender como a produtividade em armação varia. Tal entendimento (expresso na forma de faixas de variação da produtividade e apresentação dos fatores influenciadores) deu apoio a entrevistas com projetistas, visando levantar suas opiniões sobre as alterações no projeto, levando à melhoria da produtividade, que seriam mais viáveis de serem adotadas. Em paralelo, estudaram-se as diferentes formas de apresentação dos projetos de detalhamento da armadura e, uma vez descritas estas possibilidades, coletaram-se as opiniões de gestores da produção sobre as formas de representação mais convenientes. Todos estes conhecimentos, de base teórica e empírica, servem de subsídio para a tomada de decisões sobre diretrizes a serem seguidas na futura elaboração de projetos de detalhamento da armadura, o que é bastante desejável no sentido de se aumentar a competitividade das empresas de construção de edifícios. / This thesis presents directions to make the steel reinforcement design a tool to improve rebar labor productivity. Bibliography review served as basis to go through a site study that allowed understanding rebar labor productivity variation. Such an information, expressed in terms of a labor productivity unit rate range associated to the influencing factors presentation, supported designers interviews where they stated the ideas they are willing to use in their designs to improve labor productivity. The thesis also discusses different approaches to be used in order to represent the product being defined in the design. In this case, production managers were listened to, aiming to understand the ones they prefer. The whole knowledge here described, coming from theory or reality evaluation, can help managers in taking decisions in relation to the steel reinforcement design directions to be followed. This can be very helpful to make construction companies more competitive.

Steel corrosion is one of the major distress mechanisms that causes the deterioration of reinforced concrete structures around the world. It is an electrochemical reaction between the reinforcing steel and the surrounding concrete that produces a mass loss of the metal. Through the process of corrosion in reinforced concrete, iron ions get oxidized to form corrosion products (CP). Although multiple experiments and studies have been developed to understand the rheological behavior of corrosion products, this topic stays inconclusive. This work aims to characterize corrosion products at micro-scale in order to trace the progress of the formation of rust, to determine its nature and to analyse its rheological behavior in reinforced concrete. An experimental procedure to produce CP in the laboratory is also presented in this research. In addition, material characterization methods have been used to identify the iron oxide phases present in CP, determine their viscosity and rheological behavior and to study how CP flows in a porous media. In order to identify the different stages in the corrosion process, the CP was analysed at 2, 4, 6 and 8 weeks. The experiments identified four phases of iron oxide for each period. Furthermore, it was found that CP behaves as a shear-thinning slurry and as a result, its viscosity decreases with the applied shear rate. In addition, the damage caused by CP on concrete depends on the w/c ratio of the concrete mix and the exposure time to a corroding environment. The rebar mass loss results show that CP is formed in layers around the rebar, and the flow of each CP layer can differ.

This thesis reports on the research outcome of corrosion mechanism and corrosion rate of mild steel in different environments (saline, alkaline solutions and concrete media) using potentiodynamic polarization technique. The study also included the effect of corrosion on bond strength between reinforcing steel and concrete using pull-out test. Corrosion of mild steel and 316L stainless steel with different surface conditions in 1, 3 and 5% saline (NaCl + Distilled water) was investigated. Specimens ground with 200 and 600 grit silicon carbide grinding paper as well as 1¿m surface finish (polished with 1¿m diamond paste) were tested. In case of mild steel specimens, reduction in surface roughness caused increase in corrosion rate, while in 316L stainless steel corrosion rate decreased as the surface roughness improved. Metallographic examination of corroded specimens confirmed breakdown of passive region due to pitting corrosion. Corrosion of mild steel was also investigated in alkaline solution (saturated calcium hydroxide, pH =12.5) contaminated with 1, 3 and 5% saline. A series of corrosion experiments were also conducted to examine the efficiency of various concentrations of calcium nitrite (CN) on corrosion behaviour of both as-received and polished mild steel in alkaline solution containing 3% saline after 1 hour and 28 days of exposure. Corrosion rate was higher for the as-received than polished mild steel surface under the same testing conditions in NaCl alkaline solution with and without nitrites due to the effect of surface roughness. Morphology investigation of mild steel specimens in alkaline solution ii containing chlorides and nitrites showed localized pits even at nitrite concentration equal to chloride concentration. Corrosion of steel bars embedded in concrete having compressive strengths of 20, 30 and 46MPa was also investigated. The effect of 2 and 4% CN by weight of cement on corrosion behaviour of steel bar in low and high concrete strengths specimens were also studied. All reinforced concrete specimens were immersed in 3% saline solution for three different periods of 1, 7 and 15 days. In order to accelerate the chemical reactions, an external current of 0.4A was applied. Corrosion rate was measured by retrieving electrochemical information from polarization tests. Pull-out tests of reinforced concrete specimens were then conducted to assess the corroded steel/concrete bond characteristics. Experimental results showed that corrosion rate of steel bars and bond strength were dependent on concrete strength, amount of CN and acceleration corrosion period. As concrete strength increased from 20 to 46MPa, corrosion rate of embedded steel decreased. First day of corrosion acceleration showed a slight increase in steel/concrete bond strength, whereas severe corrosion due to 7 and 15 days corrosion acceleration significantly reduced steel/concrete bond strength. Addition of only 2% CN did not give corrosion protection for steel reinforcement in concrete with 20MPa strength at long time of exposure. However, the combination of good quality concrete and addition of CN appear to be a desirable approach to reduce the effect of chloride induced corrosion of steel reinforcement. At less time of exposure, specimens without CN showed higher bond strength in both concrete mixes than those with CN. After 7 days of corrosion acceleration, the higher concentration of CN gave higher bond strength in both concrete mixes. The same trend was observed at 15 days of corrosion acceleration except for the specimen with 20MPa compressive strength and 2% CN which recorded the highest deterioration in bond strength.