Arctic tundra vegetation communities are rapidly responding to climate warming with increases in aboveground biomass, particularly in deciduous shrubs. This increased shrub density has the potential to dramatically alter the functioning of tundra ecosystems through its effects on permafrost degradation and nutrient cycling, and to cause positive feedbacks to global climate change through its impacts on carbon balance and albedo. Experimental evidence indicates that tundra plant growth is most strongly limited by soil nutrient availability, which is projected to increase with warming. Therefore research to date into the mechanisms driving tundra 'shrub expansion' has taken a 'bottom-up' perspective, overlooking the potential role of herbivory in mediating plant-soil interactions. In this thesis, I integrate the impacts of climate warming and caribou browsing on tundra vegetation community structure, and specifically investigate if increases in soil fertility with warming might lead to changes in vegetation biomass and chemistry that could fundamentally alter herbivore-nutrient cycling feedbacks, shifting the role of caribou browsing from restricting shrub growth to facilitating it. Using experimental greenhouses, nutrient addition plots, and caribou exclosures at Daring Lake Research Station in the central Canadian low Arctic, I showed that warming increased soil nutrient availability and plant biomass, and that caribou browsing restricted tundra shrub growth under present conditions. Plant and soil nutrient pool responses to warming demonstrated that increased growing season temperatures enhanced tundra plant growth both by increasing soil nutrient availability and by inferred increases in the rate of photosynthesis, however that the former process was comparatively more limiting. Species- and plant part-specific changes in biomass and chemistry with warming and fertilization clearly indicated the rate and magnitude of change in soil fertility substantially alters plant community structure. Nonetheless, since plant nutrient concentrations decreased with warming and plant responses to browsing were independent of soil fertility, I did not find evidence for a shift from caribou decelerating to accelerating nutrient cycling with warming. Altogether this research indicates effective conservation and management of Rangifer populations is critical to understanding how climate change will affect tundra vegetation trajectories and ultimately tundra ecosystem carbon balances. / Thesis (Ph.D, Biology) -- Queen's University, 2013-06-07 15:13:21.698

This thesis uses palaeolimnological records to reconstruct Holocene ontogeny trends from four lakes in south western Greenland. The research addresses four hypotheses investigating how Holocene lake ontogeny trends vary under different climatic settings, how long-term changes in ontogeny relate to periods of established climatic change in the region, the similarities between proxies within the lakes and between the lakes, and the role of vegetation in lake ontogeny. The study region occupies the widest ice-free area of south western Greenland and is characterised by a climatic gradient. The area inland and nearer to the ice-margin is arid, receives less precipitation and is warmer relative to the coastal areas. A paired lake approach, using lake records from two inland lakes and two coastal lakes, was adopted to examine the role of climatic setting upon lake development trajectories. Specifically, diatoms were used to reconstruct DI-alkalinity from the lakes using a DI-alkalinity model created from existing training sets in the region (WA Cla model, r2boot = 0.76, RMSEP = 0.28 log alkalinity units), sedimentary pigments to investigate trends in production and sedimentary parameters to reconstruct organic and minerogenic accumulation rates. All four lakes experienced comparable Holocene long-term ontogeny trajectories; maximum alkalinity in the first ~ 1000 cal. year BP of deglaciation followed by maximum production during the peak of Holocene Thermal Maximum (HTM) warming (~7000 -6000 cal. years BP). Following the HTM, all lakes demonstrated oligotrophication and a decline in pH. Vegetation development and catchment stabilisation at the end of the HTM may be important in determining the onset of oligotrophication in vegetated catchments. However, the impact of vegetation development on lake ontogeny cannot be isolated from the changes in the lakes associated with the colder and wetter climate which occurred at the end of the peak HTM warming. The timings of the large transitions in the ontogeny trajectories are comparable with established periods of Holocene climatic variability in the region; climate forcing drives ontogeny in these lakes. However, there are short-term differences between the lakes indicating that lakes have different thresholds of ecological change and may respond differently to the same climate forcing. It is concluded that ontogeny is driven by climate but lakes may respond differently to forcing depending on catchment specific characteristics which can filter out the climate signal or cause climate to influence the lake in a more direct way.

Climate change, with the possibility of an ice free Arctic ocean by 2015, has generated a renewed interest in the Arctic. This interest is being driven by the possibility of easier access to the abundant supply of resources such as oil, gas, minerals, and fisheries. Interest in Arctic tourism is also growing. Retreating sea ice will provide opportunities to avail of shorter routes for maritime traffic to and from Asia, North America, and Asia via the Arctic Ocean and Northwest Passage. In addition, the rate of population growth of local inhabitants in the Canadian Arctic is the fastest in Canada and one of the fastest in the world. A growing population will increase the demand for sealift resupply to Canada's northern communities. This work presents the first attempt to examine the role of privatization of icebreaking services in light of the present and projected shortages of infrastructure to support development in the Arctic. A unique combination of multiple methods within marine transportation, comprising of Delphi, grounded theory, and quantitative survey, is applied to investigate the potential for private involvement in the delivery of icebreaking services in the Canadian Arctic. This includes a novel application of Strauss and Corbin's Grounded Theory approach to develop hypotheses and relationships grounded in expert opinion. Although the Arctic Ocean may be ice free during the summers, there is still the issue of winter freezing and the threat of lingering multi-year ice which will impede marine transportation especially during periods of darkness and fog. The research shows that the future growth and development of the Canadian Arctic will undoubtedly require the use of designated icebreakers and ice strengthened vessels. However, Canada's fleet of Arctic icebreakers is ageing and considered unsuitable for future demands. While Canada has earmarked CAD $750M for the construction of one new icebreaker scheduled for delivery in 2017, the research shows that Icebreakers can be built outside of Canada for considerably less money and in less time. Also, the management and operation of the Canadian Coast Guard is under considerable security by the Auditor General of Canada. The research shows that not unlike others Arctic nations, there is potential for the creation of private-public partnerships in the delivery of Canadian Coast Guard services, principally icebreaking, in the Arctic.

In this study we determined the magnitude of plant mediated CH4 emission (flux) in two vegetation types of Carex ramenskii. The objectives of this paper were to quantify the proportion of CH4 emissions from plant mediated flux and the total flux (plant and soil). This information is needed in order to understand how grazing affects plant mediated CH4 flux. In addition, we differentiated between two vegetation morphs, grazed and ungrazed, and determined the plant mediated CH4 flux for vegetation type.  This study was conducted at a field site on the Tutakoke River (61 15’N, 165 30’W) which is located in the coastal region of the Yukon-Kuskokwim Delta. Three replicate plots of the two vegetation morphs of Carex ramenskii were established. Methane flux was measured with a total flux chamber (plant and soil) and a single leaf chamber using a Picarro Cavity Ring-Down Spectroscopy Analyzer (Model G2308, Picarro Inc., Santa Clara, California). Plant density for the two plant types was determined. Temperature measurements were taken and correlated with gas flux. This study found that total net CH4 emissions from Carex ssp. were the same in both vegetation types. This similarity could indicate that plant mediated flux through vegetation is not affected by grazing in the sense that grazing is neither facilitating nor inhibiting plant mediated CH4 flux. The magnitude of plant mediated flux was still greater in the ungrazed meadow type, indicating on both greater facilitation of CH4 flux, and below ground oxygen transport enabling higher rates of CH4 consumption.

In a time of climate change the Arctic region is undergoing rapid changes, and the decreasing sea ice cover is expected to draw increased commercial interests as The Arctic Ocean gets more accessible for resource exploitation. The central part of the ocean is common area, where, in theory, overfishing may result in a tragedy of the commons and related fish stocks collapse. This study aims to provide insights into how fishing in the central Arctic Ocean relates to successful collective management, and was conducted using Elinor Ostroms design principles and The Logic of Collective Action as a framework for an ideal type inspired analysis. The results show that conditions for collective fisheries management in the central Arctic Ocean are relatively good, and it’s concluded that collective fisheries management is already embraced and enacted upon by several actors. However, to attain the ideal state of collective management further improvements are required, although there are also multiple options as to how such requirements could be met and there was no indication of why collective management would be unsuccessful. / I samband med ett förändrat klimat så genomgår även den arktiska regionen snabba förändringar, där den minskande havsisen i Arktiska oceanen ger ökad tillgång till naturresurser och förväntas dra allt större kommersiella intressen. Den centrala delen av oceanen är en allmänning, vilken enligt teorin kan överfiskas och resultera i en allmänningens tragedi och relaterade kollapser av fiskbestånd. Denna studie ämnar ge en insikt i hur fisket i centrala Arktiska oceanen förhåller sig till lyckad kollektiv förvaltning, och utfördes genom att låta Elinor Ostroms designprinciper och det kollektiva handlandets logik utgöra ett ramverk för en idealtypsinspirerad analys. Resultaten visar att förutsättningarna för kollektiv förvaltning är relativt goda och att fisket i viss utsträckning redan förvaltas kollektivt. För att uppnå en idealtypisk kollektiv fiskeförvaltning framgår det dock att ytterligare insatser behövs men att det även finns flera alternativ för att möta dessa behov, och det fanns heller ingen antydan av att kollektiv förvaltning skulle misslyckas.

The surface climate response to 11-yr solar forcing during northern winter is first reestimated by applying a multiple linear regression (MLR) statistical model to Hadley Centre sea level pressure (SLP) and sea surface temperature (SST) data over the 1880–2009 period. In addition to a significant positive SLP response in the North Pacific found in previous studies, a positive SST response is obtained across the midlatitude North Pacific. Negative but insignificant SLP responses are obtained in the Arctic. The derived SLP response at zero lag therefore resembles a positive phase of the Arctic Oscillation (AO). Evaluation of the SLP and SST responses as a function of phase lag indicates that the response evolves from a negative AO-like mode a few years before solar maximum to a positive AO-like mode at and following solar maximum. For comparison, a similar MLR analysis is applied to model SLP and SST data from a series of simulations using an atmosphere–ocean general circulation model with a well-resolved stratosphere. The simulations differed only in the assumed solar cycle variation of stratospheric ozone. It is found that the simulation that assumed an ozone variation estimated from satellite data produces solar SLP and SST responses that are most consistent with the observational results, especially during a selected centennial period. In particular, a positive SLP response anomaly is obtained in the northeastern Pacific and a corresponding positive SST response anomaly extends across the midlatitude North Pacific. The model response versus phase lag also evolves from a mainly negative AO-like response before solar maximum to a mainly positive AO response at and following solar maximum.

Our understanding of the global marine xed nitrogen budget has undergone rapid growth, and as a result there is debate as to whether or not it is balanced. The Arctic plays a disproportionately large role in the sink terms of this budget. This paper works to understand the role of the Canada Basin in the nitrogen cycle. We utilize two tracers of denitri cation: N2/Ar, a dissolved gas tracer, and N*, a nutrient ratio tracer. We aim to quantify the current state of nitrogen cycling in the Canada Basin, and determine its role in the global cycle. Our paired tracer method provides support for shelf denitri cation rates while providing an estimate of ventilation in the same water mass, and provides an estimate for deep benthic denitri cation rates. We observe a disconnect between N2/Ar and N* in the Paci c Upper Halocline Layer (PUHL), wherein the excess N2/Ar we expect from N* is nearly 250% larger than the excess we observe. Our calculations suggest that an approximate steady state between benthic denitri cation and gas exchange on the Chukchi shelf maintains this disconnect. Our measurements of the PUHL support the shelf denitri cation rates reported from direct measurements, and can predict wind speeds required for ventilation within a factor of two. A 1D diffusion model of the old deep waters of the Canada Basin supports benthic denitri cation rates of 0.095-0.15 Tg N y-1. Benthic denitri cation rates determined from the model are on the low end of rates in other deep basins. Our results suggest additional measurements of these tracers in the Canada Basin and surrounding areas would help to constrain both the physical and biological processes controlling nitrogen cycling. / Graduate / 0425 / jen.l.reeve@gmail.com

Bering Sea storms regularly bring adverse environmental conditions, including large waves and storm surges of up to 4 m, to the west coast of Alaska. These conditions can cause flooding, erosion and other damage that affects marine subsistence activities and infrastructure in the low-lying coastal communities. Storm impacts also include interactions with sea ice in various states: large floes, shore-fast ice, the acceleration of sea-ice formation in frazil or slush state, and the formation of slush-ice berms. Slush-ice berms are accumulations of slush ice that develop under the right wind, water level, water and air temperature, and snow conditions. During a strong wind event, large amounts of slush may be formed and pushed onto the shore, where the slush can accumulate, solidify and protect communities from flooding and erosion. Slush ice berms can also be problematic, restricting access to the coast and presenting other hazards. Residents of Shishmaref and Shaktoolik, communities on the west coast of Alaska, observed the formation of slush-ice berms during storms that occurred in 2007, 2009 and 2011. These formations are important to the communities, and it would be useful to develop the capacity to predict their occurrence. However, scientific work has not been conducted on this phenomenon, with the result that a physical conceptual model describing the formation of slush-ice berms does not exist. In recognition of this need, a project thesis was designed, and had as its main objective to identify and document the environmental and synoptic weather conditions that lead to these types of events, and to develop a descriptive physical conceptual model of slush-ice berm formation. A key to this work was the engagement of traditional knowledge holders and local observers to gather data and information about slush ice and slush-ice berm formation, along with the specific dates when these events took place. This dissertation is organized around three major elements: development of a conceptual model of slush-ice berm formation; presenting the traditional knowledge gathered that led to the development of this model; and documenting the methods and tools used to engage traditional knowledge holders and local observers in this process. In this dissertation, the knowledge from traditional knowledge holders on slush ice formation is presented in the context of feeding into a physical scientific process – specifically, developing a descriptive physical conceptual model of slush-ice berm formation. It is expected that this type of research will contribute to slush-ice berm forecasting which would aid communities’ safety by improving assessment of environmental risk. / Graduate

Aerosol particles, especially in the high Arctic are still not very well represented in climate models. Particle size and number concentrations are strongly under-predicted and temporal variations of aerosol composition and size are still not very well understood, mainly due to the sparsity of observations. The main objective of this thesis is the characterization of the high Arctic summer aerosol by means of electron microscopy in order to extend the existing data set from previous expeditions by size resolved data on aerosol number, morphology and chemical composition and to gain a better understanding of the evolution of the aerosol in the atmosphere. Ambient aerosol was collected over the pack ice during the Arctic Summer Cloud and Ocean (ASCOS) campaign to the high Arctic in summer 2008. Aerosol particles were evaluated with scanning electron microscopy and subsequent digital image processing to assess particle size and morphology. More than 3900 aerosol particles from 9 sampling events were imaged with scanning electron microscopy and merged into groups of similar morphology which contributed to different degrees to the total aerosol: single particles (82%), gel particles (11%) and halo particles (7%). Single particles were observed over the whole size range with a maximum at 64 nm in diameter, gel particles appeared &gt; 45 nm with a maximum in number at 174 nm, halo particles appeared &gt; 75 nm with a maximum in number at 161 nm. The majority of particles showed the morphology of marine gels, no sea salt or otherwise crystalline particles were observed. Transmission electron microscopy enabled more subtle insights into particle morphology and allowed further subdivision of gel particles into aggregates, aggregates with film and mucus-like particles. Energy dispersive X-ray spectroscopy of individual particles revealed a gradual transition in the content of Na+/K+ and Ca2+/Mg2+ between particle morphologies. Single particles and aggregate particles preferentially contained Na+/K+ whereas aggregate with film particles and mucus-like particles mainly contained Ca2+/Mg2+ suggesting a connection between particle morphology and ion content. Back-trajectory analysis was used to identify aerosol sources and to understand the evolution of the aerosol as a function of the synoptic weather situation. Particle numbers, size and morphology changed with the days the air mass spent over the pack-ice. A morphological descriptor applied to gel particles showed a clear trend suggesting that the contour of the particles becomes sharper and more distinct with increased time spent over the pack-ice. For a very long time over the pack-ice, however, we observed a morphology comparable to freshly emitted particles suggesting aerosol sources over the inner pack-ice. Size resolved aerosol chemical composition measurements were utilized to investigate the inorganic composition of laboratory generated nascent sea spray aerosol particles and ambient aerosol samples collected during ASCOS. A significant enrichment of Ca2+ was observed in submicrometer particles in either case with a tendency for increasing Ca2+ enrichment with decreasing particle size. This has strong implications for the alkalinity of sea spray aerosol particles with consequences for the sulfur chemistry in the marine boundary layer, the hygroscopicity and thus the potential of sea spray aerosol particles to act as cloud condensation nuclei. / <p>At the time of the doctoral defense, the following paper was unpublished and had a status as follows: Paper 4: Manuscript.</p>

Studying calcium carbonate (otoliths) and calcium phosphate (fins, scales, bones) hard structure chemistry has numerous applications in the fisheries field for both freshwater and marine environments. The overall thesis objectives were: 1.) to provide an integrated and multidisciplinary approach to understanding the incorporation of trace elements and isotopes into biomineralized hard structures, and 2.) to apply this multidisciplinary perspective in the examination of element marking, stock discrimination, and migration in teleost fish species found within the Canadian Polar North. Varying physiological mechanisms within fishes control the uptake of essential and non-essential trace elements and isotopes during biomineralization processes. Essential life elements such as zinc and magnesium are controlled by their own uptake regulation systems whereas non-essential elements such as strontium and barium are controlled primarily by calcium uptake at the gills driven by internal calcium homeostasis. Secondarily, environmental trace elements compete with calcium and with each other for uptake at the gills. The ability of certain hard structures such as bones, fins, and scales to remobilise calcium and associated calcium-like elements, plays a role in the prolonged high concentrations of strontium that were observed in otolith marking of Greenland Halibut, Reinhardtius hippoglossoides. High doses of strontium chloride resulted in a prolonged expulsion of excess strontium. Strong associations of Dolly Varden Char, Salvelinus malma malma, with groundwater allowed discrimination of populations among studied river systems using otolith strontium and barium, and strontium isotopes. Calculation of otolith strontium freshwater baselines allowed for a quantitative method to examine migration histories of Arctic Char, S. alpinus, in Canada and western Greenland. Migration seaward was related to ease of access to estuary and marine habitats. Easy access to estuaries resulted in migration at a young age and small size whereas longer rivers resulted in a delay of migration to older ages and larger sizes. Understanding the role of fish physiology in association with calcium homeostasis provided a stronger basis for understanding the incorporation and presence of trace elements and isotopes found within biomineralized hard structures. These studies underscore the utility of microchemical studies for elucidating biological phenomena, thus linking the aspects of biology, physiology, and geology. / February 2017