This work describes a master’s thesis in engineering physics at Umeå University carried out during the spring semester of 2014. In the thesis the student has constructed and tested a temperature controlled cell for cooling/heating of surface-enhanced-Raman-spectroscopy (SERS) substrates for rapid detection of volatile substances. The thesis was carried out at the Swedish Defence Research Agency (FOI) in Umeå, Sweden. A Linkam Scientific Instruments TS1500 cell was equipped with a Peltier element for cooling/heating and a thermistor temperature sensor. A control system was constructed, based on an Arduino Uno microcontroller board and a pulse-width-modulated (PWM) H-bridge motor driver to control the Peltier element using a proportional-integral (PI) control algorithm. The temperature controlled cell was able to regulate the temperature of a SERS substrate within -15 to +110 °C and maintain the temperature over prolonged periods at ±0.22 °C of the set point temperature. Gas phase of 2-chloro-2-(difluoromethoxy)-1,1,1-trifluoro-ethane (isoflurane) was flowed through the cell and SERS spectra were collected at different temperatures and concentrations. This test showed that the signal is increased when the substrate is cooled and reversibly decreased when the substrate was heated. Keywords: temperature control, Raman scattering, surface enhanced Raman spectroscopy SERS, SERS substrate, volatile substances, Peltier module, thermistor, PWM, H-bridge, PI(D) control. / Detta dokument beskriver ett examensarbete för civilingenjörsexamen i teknisk fysik vid Umeå Universitet som utförts under vårterminen 2014. I examensarbetet har en kyl-/värmecell för temperaturkontroll av substratytor för ytförstärkt ramanspektroskopi (SERS) för snabb detektion av farliga flyktiga ämnen konstruerats och testats. Arbetet utfördes vid Totalförsvarets forskningsinstitut (FOI) i Umeå, Sverige. Utgångspunkten var ett Linkam Scientific Instruments TS1500 mikroskopsteg, vilket utrustades med ett Peltierelement för kylning/värmning och en termistor för temperaturövervakning. Ett styrsystem baserat på ett Arduino Uno mikrostyrenhetskort konstruerades med ett motordrivkort (H-brygga) vilket använder pulsbreddsmodulering (PWM) för att reglera spänningen till Peltierelementet utifrån en PI-regulator. Den färdiga cellen klarade att reglera temperaturen på ett SERS-substrat i ett temperaturspann på ungefär -15 till +110 °C med en temperaturstabilitet på ±0.22 °C av måltemperaturen. Cellen testades sedan på flyktiga ämnen för att visa dess funktion. Difluorometyl-2,2,2-trifluoro-1-kloroetyleter (isofluran) i gasfas, med instrumentluft som bärargas, flödades genom cellen och SERS-spektra erhölls vid olika koncentrationer och temperaturer. Vid samtliga koncentrationer visades att lägre temperatur ger ökad signalstyrka. När ytan sedan värmdes upp sjönk signalen reversibelt tillbaka till ursprungsvärdet. Nyckelord: temperaturkontroll, ytförstärkt ramanspektroskopi, SERS, flyktiga ämnen, Peltierelement, thermistor, PWM, H-brygga, PI(D)-regulator.

<p>Thermistor material can be used to fabricate un-cooled IR detectors their figure of merit is the Temperature Coefficient of Resistance (TCR). Ge dots in Si can act as a thermistor material and they have a theoretical TCR higher than for SiGe layers but they suffer from intermixing of Si into the Ge dots. Ge dots were grown on unstrained or strained Si layers and relaxed or strained SiGe layers at temperatures of 550 and 600°C by reduced pressure chemical vapor deposition (RPCVD). Both single and multilayer structures where grown and characterized. To achieve a strong signal in a thermal detector a uniform shape and size distribution of the dots is desired. In this thesis work, an endeavor has been to grow uniform Ge dots with small standard deviation of their size. Scanning electron microscopy (SEM) and Atomic force microscopy (AFM) have been used to characterize the size and shape distribution of Ge dots. Ge contents measured with Raman spectroscopy are higher at lower growth temperatures. Simulation of TCR for the most uniform sample grown at 600°C give 4.43%/K compared to 3.85%/K for samples grown at 650°C in a previous thesis work.</p><p>Strained surfaces increases dot sizes and make dots align in crosshatched pattern resulting in smaller density, this effect increases with increasing strain.</p><p>Strain from buried layers of Ge dots in a multilayer structure make dots align vertically. This alignment of Ge dots was very sensitive to the thickness of the Si barrier layer. The diameter of dots increase for each period in a multilayer structure. When dots are capped by a Si layer at the temperature of 600°C intermixing of Si into the Ge dot occurs and the dot height decrease.</p>

Thermistor material can be used to fabricate un-cooled IR detectors their figure of merit is the Temperature Coefficient of Resistance (TCR). Ge dots in Si can act as a thermistor material and they have a theoretical TCR higher than for SiGe layers but they suffer from intermixing of Si into the Ge dots. Ge dots were grown on unstrained or strained Si layers and relaxed or strained SiGe layers at temperatures of 550 and 600°C by reduced pressure chemical vapor deposition (RPCVD). Both single and multilayer structures where grown and characterized. To achieve a strong signal in a thermal detector a uniform shape and size distribution of the dots is desired. In this thesis work, an endeavor has been to grow uniform Ge dots with small standard deviation of their size. Scanning electron microscopy (SEM) and Atomic force microscopy (AFM) have been used to characterize the size and shape distribution of Ge dots. Ge contents measured with Raman spectroscopy are higher at lower growth temperatures. Simulation of TCR for the most uniform sample grown at 600°C give 4.43%/K compared to 3.85%/K for samples grown at 650°C in a previous thesis work. Strained surfaces increases dot sizes and make dots align in crosshatched pattern resulting in smaller density, this effect increases with increasing strain. Strain from buried layers of Ge dots in a multilayer structure make dots align vertically. This alignment of Ge dots was very sensitive to the thickness of the Si barrier layer. The diameter of dots increase for each period in a multilayer structure. When dots are capped by a Si layer at the temperature of 600°C intermixing of Si into the Ge dot occurs and the dot height decrease.

Increasing demand on more effective cell culture reactors has driven optimization works to increase output of products. This has led to development of soft sensors that uses mathematical formulas to increase the available information for the parameters during runs. In the project two parameters was evaluated for use in such a soft sensor, viability by measuring on-line capacitance with Aber probe and L-lactate production using BioSenz apparatus. To determine how well these could be used both were used on batch reactors measuring on a mouse-mouse B cell hybridoma culture which produced IgG1. On-line measurements were performed by probes which measured directly on the cell suspension or withdrew sterile sample from the reactor. Measuring viability gave results with low error, which can be concluded to the variation in reference cell count, but it could not be determined if measuring L-lactate production with BioSenz works in reactors of this size. More work needs to be done on other types of reactors, like fed-batch or perfusion, or lower working volumes.

The aim of the project is a design of the temperature controler based on microprocessor. There are described the most widely used sensors for the temperature measuring and their involvement in the electric circuit. The temperature controler is based on the Peltier’s thermoelectric battery. Project desribes power control of this thermoelectric battery and also a design of the entire system and a description of the blocks takes a part.

The introduction of the use of Tire Pressure Control Systems (TPCS) to improve the productivity of the Canadian trucking industry is gaining momentum. The imposition of seasonal load restrictions (SLR) on the thaw-weakened secondary roads interrupts the transportation of raw materials to processing facilities For the forestry industry in particular, this has very significant impacts on productivity and costs. FPInnovations-Feric Division (Feric) has investigated the potential for TPCS-equipped trucks to travel with full, legal loading during the SLR period without accelerating road wear and tear. The TPCS monitors and adjusts the inflation pressure of the trucks’ tires while driving and allows the operator to optimize the inflations for changes in loading, travel speed, or road quality encountered in the trip. This thesis describes an investigation to determine whether TPCS can be used to mitigate traffic generated damage to secondary roads and also reduce the need to implement load restrictions. The project involves a partnership with the Ontario Ministry of Transportation Ontario (MTO), Forest Engineering Research Institute of Canada (FERIC), Ontario Ministry of Natural Resources (MNR) and the Centre for Pavement and Transportation Technology (CPATT) located at the University of Waterloo. The thesis will describe the methodology, design, and instrumentation of the two test sites which are located in Dryden, Ontario and Chapleau, Ontario. In addition, repeated Portable Falling Weight Deflectometer (PFWD) testing is being carried out at these sites and the initial results of this examination and associated impacts of the environment and traffic on the road will be presented. This study also involves looking into the reliability of using the portable FWD, offering a lower cost alternative instead of the trailer mounted FWD to monitor pavement strength for the identification the SLR period. The use of innovative sensors and data collection techniques are proving to be very informative and are advancing pavement engineering knowledge. Moreover, the thesis is aimed at exploring the possibilities of achieving the current objectives of the government DOTs such as TPCS potential for addressing the timber industry in crisis, reduced road maintenance budgets, and global warming increasing road damage.

The introduction of the use of Tire Pressure Control Systems (TPCS) to improve the productivity of the Canadian trucking industry is gaining momentum. The imposition of seasonal load restrictions (SLR) on the thaw-weakened secondary roads interrupts the transportation of raw materials to processing facilities For the forestry industry in particular, this has very significant impacts on productivity and costs. FPInnovations-Feric Division (Feric) has investigated the potential for TPCS-equipped trucks to travel with full, legal loading during the SLR period without accelerating road wear and tear. The TPCS monitors and adjusts the inflation pressure of the trucks’ tires while driving and allows the operator to optimize the inflations for changes in loading, travel speed, or road quality encountered in the trip. This thesis describes an investigation to determine whether TPCS can be used to mitigate traffic generated damage to secondary roads and also reduce the need to implement load restrictions. The project involves a partnership with the Ontario Ministry of Transportation Ontario (MTO), Forest Engineering Research Institute of Canada (FERIC), Ontario Ministry of Natural Resources (MNR) and the Centre for Pavement and Transportation Technology (CPATT) located at the University of Waterloo. The thesis will describe the methodology, design, and instrumentation of the two test sites which are located in Dryden, Ontario and Chapleau, Ontario. In addition, repeated Portable Falling Weight Deflectometer (PFWD) testing is being carried out at these sites and the initial results of this examination and associated impacts of the environment and traffic on the road will be presented. This study also involves looking into the reliability of using the portable FWD, offering a lower cost alternative instead of the trailer mounted FWD to monitor pavement strength for the identification the SLR period. The use of innovative sensors and data collection techniques are proving to be very informative and are advancing pavement engineering knowledge. Moreover, the thesis is aimed at exploring the possibilities of achieving the current objectives of the government DOTs such as TPCS potential for addressing the timber industry in crisis, reduced road maintenance budgets, and global warming increasing road damage.

La technologie des microbolomètres est à ce jour la plus avancée pour l'imagerie IR non refroidie. Le LETI développe une technologie basée sur l'utilisation du silicium amorphe comme matériau thermistor. L'introduction d'un matériau alternatif doit permettre de poursuivre l'amélioration des performances. Cette étude considère une solution alternative à base de films minces d'oxydes nanocristallins. Deux procédés sont envisagés : le dépôt IBS et le dépôt MOCVD. L'étude des procédés ainsi que la caractérisation des matériaux ont permis la maîtrise et la compréhension des évolutions structurales et fonctionnelles mises en jeux. Des caractérisations électriques (résistivité, TCR, bruit en 1/f) sur dispositifs ont permis de débattre de l'intérêt de ces nouveaux matériaux. Une réflexion a été menée sur les relations microstructure-propriétés. / Microbolometers FPAs are nowadays the most advanced technology for uncooled IR imaging. Developments at CEA-LETI are based on the use of amorphous silicon as thermistor material. Introduction of an alternative material is necessary to keep on improving detectors performances. This study considersnanocrystalline oxides thin films as an alternative material. Two deposition techniques have been studied : IBS and MOCVD. Process studies as well as materials characterizations allowed us to control and understand the involved micro-structural evolutions. Electrical characterizations (resistivity, TCR, 1/f noise) on integrated devices were achievedin order to estimate the potential of these new materials. Microstructure-property relationships are also discussed.

Immersion heaters are used by industries to heat fluids. The element of an immersion heater need to be fully immersed into the heated liquid, otherwise it could be subject to overheat. The main purpose of this thesis is to find a temperature sensor, which could signal in case the immersion heater is at risk to suffer from overheat due to low liquid level. A comparison of accuracy, size and cost between an analog and a digital sensor is held, to conclude whether either one is at an advantage for this application.An immersion heater with ceramic element and quartz glass tube and a water tank, both provided by Scandymet, is used during experiments. First, the position for the sensor inside the heater was examined, by placing the sensor at different positions. Next, measurements of the operating temperature of the immersion heater were made at different liquid levels. This resulted in a placement for the sensor near the head of the immersion heater and an approximate temperature range from 41 ℃ to 58 ℃. Both the analog and digital sensors is chosen with measurable ranges to match the result from previous experiments. A thermistor along with a linearizing series resistor make the analog design and a DS18B20+ with a pull-up resistor the digital design. The microcontroller for both designs is Adafruit Feather Adalogger M0, which is programmed in C/C++ using Arduino IDE software. It is concluded that it is possible to signal in case liquid level decrease below minimum level, by inserting a temperature sensing device into the immersion heater. The sensor should be placed above the maximum liquid level mark, close to the head of the heater. The analog design would be recommended as overheat protection, due to its smaller size, less expensive and, with further calibration, accurate response.

Glaciers cover ca 10% of the Earth's land and are found in the high altitudes and latitudes. They are important components of environmental systems due to the multiple feedbacks linking them with the atmosphere, hydrosphere and periglacial landscapes. The cold sloping surfaces of glaciers change the patterns of atmospheric circulation at different scales and at the same time glaciers are largely controlled by climate. They are commonly used as climatic archives for reconstruction of the past environmental changes based on evidences from the areas affected by glaciation at the moment and in the past. Glaciers are the largest fresh-water reservoirs on our planet and runoff thereof significantly affects the global sea level and life in glaciated catchments. However, melt- and rain-induced runoff from glaciers greatly depends on the subsurface conditions which thus need to be taken into account, particularly in a changing climate. This thesis focuses on the processes of subsurface mass and energy exchange in the accumulation zones of glaciers, which are largely driven by the climate at the surface. Results are largely based on empirical data from Lomonosovfonna ice cap, Svalbard, collected during field campaigns in 2012-2017. Observations of subsurface density and stratigraphy using shallow cores, video records from boreholes and radar surveys returned detailed descriptions of the snow and firn layering. The subsurface temperature data collected using multiple thermistor strings provided insights into several subsurface processes. The temperature values measured during three summer seasons were used to constrain the suggested parameterization of deep preferential water flow through snow and firn. The part of data recorded during the cold seasons was employed for an inverse modelling exercise resulting in optimized values of effective thermal conductivity of the subsurface profile. These results are then used to compute the subsurface water content by comparing the simulated and measured rates of freezing front propagation after the melt season in 2014. The field observations and quantitative estimates provide further empirical evidences of preferential water flow in snow/firn packs at glaciers. Results presented in the thesis call for implementation of description of the process in layered models simulating the subsurface fluxes of energy and mass at glaciers. This will result in a better understanding of glacier response to the past and future climatic changes and more accurate estimates of glacier runoff. / Stability and Variations of Arctic Land Ice (SVALI)