Pour étendre l'utilisation des composites dans des applications plus variées (applications intelligentes et multifonctionnelles), l'une des barrières est leur faible conductivité électrique et thermique. Dans le cas de composites renforcés par des fibres de carbone, la matrice organique est responsable des propriétés isolantes du composite résultant. L'une des solutions pour améliorer les conductivités des matériaux est l'utilisation des nanocharges conductrices. L'amélioration des propriétés électriques et thermiques des polymères nanochargés est une problématique récurrente dans la littérature. Cependant, étudier les propriétés des composites à fibre de carbone continue et nanochargés est moins abordée. Ce travail porte sur la fabrication et la caractérisation des composites nanochargés par du noir de carbone et des nanotubes de carbone. Tout d'abord, un intérêt particulier a été accordé à la phase délicate de la fabrication. Comme mentionné ci-dessus, la mise en œuvre des composites à renfort continu et matrice nanochargée implique des problèmes liés à l'agglomération et à la dispersion inhomogène des nanocharges dans le composite final. Pour résoudre ces problèmes, le choix de la matrice thermoplastique (Polyamide 6) était judicieux. En fait, la dispersion des nanocharges a été faite par extrusion bi-vis qui est connue comme l'une des voies les plus efficaces de séparation d'agglomérats. De plus, la méthode de fabrication à base de films de Polyamide 6, appelée film stacking, assure une partition homogène dès le début du processus. Des observations MEB ont été effectuées pour localiser les nanoparticules. Ceux-là ont montré que les particules pénétraient dans la zone des fibres. En effet, en atteignant le cœur des torons, les nano-charges ont créé un réseau de connectivité entre les fibres pour le passage de courant. Ceci explique l'amélioration constatée de la conductivité électrique des composites en présence de noir de carbone et des nanotubes de carbone. Ces essais ont été réalisés avec la méthode à 4 points. La conductivité électrique du composite à matrice « pure » est passée de 20S / cm à 80S / cm en ajoutant 8% en poids de noir de carbone et à 15S / cm en ajoutant 18% en poids de la même charge nanométrique. Pour les nanotubes de carbone, avec 2,5% en poids, la conductivité était d'environ 150S / cm. Pour les propriétés thermiques, des tests basés sur l'effet Joule ont été réalisés. L'augmentation de la température a été enregistrée en utilisant une caméra IR. Les résultats obtenus sont en accord avec ceux de la conductivité électrique, montrant une amélioration du comportement thermique en présence de nanocharges. Grâce à ces résultats, l'utilisation de ces composites comme outil de suivi d’endommagement était possible. Par ailleurs, la méthode de variation de la résistance électrique a été effectuée. Les matériaux nanochargés ont montré une meilleure sensibilité aux endommagements. Les résultats ont été comparés aux outils classiques de suivi d’endommagement. A la fin, plusieurs applications « intelligentes » ont été testées telles que : le composite à gradients de propriétés et des matériaux nanochargés cousus. / To extend the use of composites in more varied application (smart applications, multifunctional issues), one of the actual barrier is their poor electrical and thermal conductivities. In the case of carbon fiber reinforced composites, organic matrix are in charge of the insulating properties of the resulting composite. One of the solutions to enhance conductivities of materials is the use of conductive nanofillers. Improving the electrical and thermal properties of nanofilled polymers has been investigated in several studies. However, studiing the properties of continuous carbon fiber nano-filled composites is less approached. This work tends to fabricate and characterize carbon black and carbon nanotubes nano-filled composites. First of all, special interest was given to the delicate phase of manufacturing. As mentioned before, processing continuous fiber reinforced nanofilled polymers implies issues related to nanofillers agglomeration and inhomogeneous dispersion in the final composite. To resolve these problems, the choice of the thermoplastic (Polyamide6) matrix seemed preferable. In fact, the dispersion of nanofillers was made by twin screw extrusion which is known as one of the most effective agglomeration separation ways. Adding to this, the fabrication method based on Polyamide 6 shects called film stacking, ensure a homogeneous partition at the beginning of the process. SEM observations were performed to localize the nano-particles. It showed that particles penetrated on the fiber zone. In fact, by reaching the fiber zone, the nano-fillers created network connectivity between fibers which means an easy pathway for the current. It explains the noticed improvement of the electrical conductivity of the composites by adding carbon black and carbon nanotube. This test was performed with the 4 points electrical circuit. It shows that electrical conductivity of 'neat' matrix composite passed from 20S/cm to 80S/cm by adding 8wt% of carbon black and to 15S/cm by adding 18wt% of the same nano-filler. For carbon nanotubes, with '2.5wt% the conductivity was around 150S/cm. For the thermal properties, tests based on Joule's effect were performed. The rise of temperature was recorded using IR camera. Results obtained are in agreement with the electrical conductivity ones, showing enhancement of the thermal behavior in presence of nanofillers. Thanks to these results, the use of these composites as a damage-monitoring tool was possible. By the way, the electrical resistance change method was performed. Nanofilled materials showed better sensitivity to damage. Results were compared with classical damage monitoring tools. At the end, several 'smart' applications were tested such as graded functionalities composite and stitched nanofilled materials.

Neste trabalho estuda-se o comportamento de laminados fibra-metal em regime de impacto, a partir de uma abordagem teórica, numérica e experimental. Os materiais estudados consistem em camadas finas intercaladas de alumínio 2024-T4 e de um novo material termoplástico de polipropileno (PP) de alta resistência mecânica. Eventos de impacto de baixa e alta velocidade contra placas destes laminados foram realizados a partir de um martelo de impacto e de um canhão pneumático, respectivamente. Nestes experimentos buscou-se identificar as condições limite de ruptura e perfuração das amostras, assim como parâmetros de comportamento do material. O laminado fibra metal de PP (ou TFML) e seus constituintes foram caracterizados a taxas de deformação entre 10-4 / s e 102 / s, utilizando-se máquinas de ensaio universal comerciais e um dispositivo desenvolvido especificamente para este estudo, capaz de caracterizar materiais em taxas intermediárias de deformação. Os modelos teóricos de Jones e Reid-Wen foram adaptados para utilização com TFMLs, sendo capazes de identificar o comportamento do material em regime de baixa e alta velocidade de impacto, respectivamente. Um modelo numérico do TFML em regime de impacto foi desenvolvido utilizando o programa comercial LSDyna. Resultados experimentais e teóricos foram confrontados com esse, apresentado boa correlação na predição do limiar de falha e limite balístico do material. Uma vez que o comportamento do TFML ao impacto foi modelado, buscou-se identificar o efeito da distribuição de camadas e composição de constituintes no comportamento do material ao impacto. Estudos também foram conduzidos com o intuito de identificar a influência da taxa de deformação, geometria do indentador e localização do impacto no comportamento dos laminados. Por fim, uma configuração de TFML foi proposta visando melhoria de seu desempenho ao impacto. / In this work, the behaviour of fibre-metal laminates under impact loading is studied by using theoretical, numerical and experimental approaches. The material is a combination of thin aluminium 2024-T3 layers and an innovative high strength thermoplastic polypropylene material. Low and high velocity impact events were performed using a falling weight machine and a gas-gun projectile launcher, respectively. The thermoplastic fibre-metal laminates (or TFML) and its constituents were mechanically characterized in the range of strain rates between 10-4 / s and 102 / s , using commercial universal testing machines and a specifically designed rig for tensile tests at intermediate strain rates. The Jones and Reid-Wen theoretical models were adapted to be used with TFML plates. A finite element model of the TFML under impact events was developed using LS-Dyna software. The numerical model revalled results that were compared with the theoretical models and the experimental data, providing reasonably similar results. Once the TFML impact behaviour was identified and modelled, the effect of the layers distribution and constituent composition on the TFML impact response was studied. Studies of the strain rate effect, identor geometry and the impact location were also performed. Finally, a TFML configuration was suggested in order to improve the TFML impact performance.

Das Ultraschall-Punktschweißen von faserverstärkten thermoplastischen Kunststoffen hat in der letzten Zeit bei Forschern in der Luftfahrt- und Automobilindustrie großes Interesse hervorgerufen. Es bietet eine effiziente Lösung zum Verbinden großer thermoplastischer Verbundbauteile durch Punktschweißen mit einem hohen Automatisierungsgrad. In der vorliegenden Arbeit wurde eine neue Technik zum Fokussieren der Ultraschallschwingungsenergie an der gewünschten Fügestelle zwischen zwei Fügepartnern aus thermoplastischen Verbundlaminaten untersucht. Bei diesem untersuchten Verfahren waren keine zusätzlichen Energierichtungsgeber zwischen den Fügepartnern erforderlich, um die Vibrationsenergie zu fokussieren. Es wurde festgestellt, dass es durch Schweißen der Laminate zwischen einer Sonotrode und einem Amboss möglich war, eine lokalisierte Wärme durch Reibung zu erzeugen in dem die Sonotrode eine größere Kontaktfläche mit dem Laminat als mit dem Amboss aufwies. In der Anfangsphase des Schweißens wurden die Grenzflächenschichten durch die reibungsverursachte Erwärmung abgeschwächt. Folglich zentrierte sich die zyklische Verformung in diesen abgeschwächten Grenzflächen. Die Annahme des Vorhandenseins der Reibung und ihres Einflusses auf die Wärmeerzeugung wurde mittels mechanischer FEM-Analyse untersucht. Die mikroskopische Analyse des Schweißpunktes lieferte schließlich den Beweis für die Schmelzauslösung an einem Ring um den Schweißpunkt und das anschließende Punktwachstum. Um die räumliche Verteilung der Temperatur und ihre zeitliche Entwicklung in der Schweißzone während des Ultraschallschweißprozesses besser zu verstehen, wurde das thermische Problem numerisch modelliert. Zur Verifizierung der mathematischen Modelle wurden die berechneten Zeitverläufe der Temperatur im Schweißpunktzentrum mit den experimentell ermittelten Werten unter vergleichbaren Bedingungen gegenübergestellt. Es wurde festgestellt, dass nach einer bestimmten Schweißzeit die Temperatur im Schweißzentrum plötzlich anstieg und das Polymer an der Schweißstelle überhitzt und die Zersetzung begann. Es wurde beobachtet, dass der Zeitverlauf der verbrauchten Leistungskurve durch das Schweißgerät einem ähnlichen Muster folgte, wie der Zeitverlauf der Temperatur in der Schweißpunktmitte. Basierend auf dieser Beobachtung wurde ein Steuerungssystem entwickelt. Die zeitliche Ableitung der Schweißleistung wurde in Echtzeit überwacht. Sobald ein kritischer Wert überschritten wurde, wurde die Ultraschallschwingungsamplitude aktiv durch einen Mikrocontroller eingestellt. Bei diesem Ansatz wurde die Temperatur im Schweißpunkt indirekt gesteuert, um während der gesamten Schweißdauer in einem optimalen Bereich zu bleiben. Die Ergebnisse des gesteuerten Schweißprozesses wurden mittels Temperaturmessungen und Computertomographie bewertet. Aus der Studie wurde der Schluss gezogen, dass das leistungsgesteuerte Ultraschall-Punktschweißverfahren eine effiziente und stabile Methode zum automatischen Verbinden von faserverstärkten thermoplastischen Teilen ist.:1 Introduction 1.1 Motivation 1.2 State of the Art 1.3 Statement of the Theses and Methods 2 Theoretical Background 2.1 Ultrasonic Welder 2.1.1 Ultrasonic Stack 2.1.2 Working Principle of the Ultrasonic Welder 2.2 Viscoelasticity 2.2.1 Viscoelasticity of Continuous Fibre-Reinforced Laminates 2.2.2 Viscoelastic Heating of CFRTP during the DUS Welding 2.3 Frictional heating at the Weld Interface during the DUS Welding 2.4 Fusion Mechanism during the USW 2.4.1 Contact of the Matrix at the Weld Interface 2.4.2 Healing of the Weld Interface through Autohesion 3 Experimental Analysis of the DUS Process 3.1 Experimental Setup 3.2 Experimental Procedure, Results and Discussions 3.2.1 Weld Progress and Formation Analysis 3.2.2 The Influence of the Amplitude and Static Force on the DUS 3.2.3 Computed Tomography Analysis of the DUS Welded Spots 3.2.4 Influence of the Weld Parameters on the Weld Force at Break 3.2.5 Influence of the Main Process Variables on the Weld Strength 4 Process Modelling and Simulation 4.1 Dynamic Mechanical 3D Finite Element Analysis 4.1.1 Woven Fabric Laminate Models 4.1.2 Laminate Properties and Meshing 4.1.3 FEM Analysis Procedure 4.1.4 Results of the Dynamic Analysis 4.2 Numerical Analysis of the Temperature Temporal and Spatial Development 4.2.1 The Numerical Method 4.2.2 Matrix Loss Modulus Calculation at the Welding Frequency 4.2.3 Model Validation 4.2.4 Analysis of the Spatial and Temporal development of the Temperature 4.2.5 Influence of Uncontrollable Factors on the DUS Process 5 Logical Control Method and Industrialisation 5.1 Process Controlling Hypothesis 5.2 Control System and Instruments 5.3 Experimental Procedure for Analysing the Control System 5.4 Analysis of the Controlled DUS Process 5.5 Control System Validation and Industrialisation 5.6 Automation of the Ultrasonic Spot Welding Process 6 Summary and Outlook 6.1 Conclusions 6.2 Outlook References Appendix / The ultrasonic spot welding of fibre-reinforced thermoplastic composites has recently received strong interest among researchers mainly in the fields of aerospace and automotive industries. It offers an efficient solution to join large thermoplastic composite parts through the spot welding approach with a high level of automation. In this study, a new technique for focusing the ultrasonic vibration energy at the desired spot between two mating thermoplastic composite laminates was investigated. In this method, no additional energy directing protrusions between the weldments were required to focus the vibration energy. It was found that by welding the laminates amid an ultrasonic sonotrode and an anvil in which the prior had a larger contact surface with the laminate as the latter, it was possible to generate a localised frictional heating. In the initial phase of the welding, the frictional heating softened the interfacial layers and thus caused the focusing of the strain energy in the weld spot centre. The assumption for the presence of the friction and its influence on the heat generation was investigated by means of finite element method analysis. Microscopic analysis of the weld spot delivered the proof for the melt initiation at a ring around the weld spot and subsequent inwards growth of the weld spot. In order to gain a better understanding of the temperature spatial distribution and its temporal development in the weld zone during the ultrasonic welding process, the thermal problem was analysed using the explicit finite difference method. The mathematical model was verified through a comparison between the calculated temperature curves and the experimentally obtained counterparts. It was found that after a certain weld duration the temperature in the weld centre underwent a sudden increase and caused the overheating and decomposition of the polymer in the weld spot. It was observed that the time trace of the consumed power curve by the welder followed a similar pattern as the time trace of the temperature in the weld spot centre. Based on this observation, a control system was developed accordingly. The time derivative of the weld power was monitored in real time and as soon as it exceeded a critical value, the ultrasonic vibration amplitude was actively adjusted through a microcontroller. In this approach, the temperature in the weld spot was indirectly controlled to remain within an adequate range throughout the welding duration. The results of the controlled welding process were evaluated by means of temperature measurements and computed tomography scans. It was concluded from the study that the power-controlled differential ultrasonic spot welding process could be an efficient method to fusion bond the fibre-reinforced thermoplastic parts in an automated manner.:1 Introduction 1.1 Motivation 1.2 State of the Art 1.3 Statement of the Theses and Methods 2 Theoretical Background 2.1 Ultrasonic Welder 2.1.1 Ultrasonic Stack 2.1.2 Working Principle of the Ultrasonic Welder 2.2 Viscoelasticity 2.2.1 Viscoelasticity of Continuous Fibre-Reinforced Laminates 2.2.2 Viscoelastic Heating of CFRTP during the DUS Welding 2.3 Frictional heating at the Weld Interface during the DUS Welding 2.4 Fusion Mechanism during the USW 2.4.1 Contact of the Matrix at the Weld Interface 2.4.2 Healing of the Weld Interface through Autohesion 3 Experimental Analysis of the DUS Process 3.1 Experimental Setup 3.2 Experimental Procedure, Results and Discussions 3.2.1 Weld Progress and Formation Analysis 3.2.2 The Influence of the Amplitude and Static Force on the DUS 3.2.3 Computed Tomography Analysis of the DUS Welded Spots 3.2.4 Influence of the Weld Parameters on the Weld Force at Break 3.2.5 Influence of the Main Process Variables on the Weld Strength 4 Process Modelling and Simulation 4.1 Dynamic Mechanical 3D Finite Element Analysis 4.1.1 Woven Fabric Laminate Models 4.1.2 Laminate Properties and Meshing 4.1.3 FEM Analysis Procedure 4.1.4 Results of the Dynamic Analysis 4.2 Numerical Analysis of the Temperature Temporal and Spatial Development 4.2.1 The Numerical Method 4.2.2 Matrix Loss Modulus Calculation at the Welding Frequency 4.2.3 Model Validation 4.2.4 Analysis of the Spatial and Temporal development of the Temperature 4.2.5 Influence of Uncontrollable Factors on the DUS Process 5 Logical Control Method and Industrialisation 5.1 Process Controlling Hypothesis 5.2 Control System and Instruments 5.3 Experimental Procedure for Analysing the Control System 5.4 Analysis of the Controlled DUS Process 5.5 Control System Validation and Industrialisation 5.6 Automation of the Ultrasonic Spot Welding Process 6 Summary and Outlook 6.1 Conclusions 6.2 Outlook References Appendix

Diplomová práca sa zaoberá prípravou teromplastických kompzoitov s PMMA a PC matricou s potenciálnym využitím v automobilovom priemysle. Ako výstuž boli použité krátke sklenené, uhlíkové a PBO (poly(p-fenylén benzobisoxazol)) vlákna známe pod obchodným názvom Zylon®. Práve do PBO vlákien boli vkladané veľké nádeje vzhľadom na ich ohromujúce mechanické vlastnosti. Vplyv objemového zlomku vlákien na modulu pružnosti, pevnosť a ťažnosť kompozitov bol skúmaný. Experimentálne zistený modul pružností bol porovnaný so semi-empirickým Halpin-Tsai modelom. Prídavok sklenených a uhlíkových vlákien viedol k značnému zvýšeniu modulu pružnosti. Ukázalo sa, že po istej hodnote objemového zlomku dochádza k poklesu pevností kompozitov v dôsledku zvyšujúceho sa počtu defektov. Prídavok PBO vlákien preukázal len nepatrný vystužujúci efekt. Viskoelastické vlastností kompozitov boli skúmané pomocou dynamicko mechanickej analýzy (DMA). Termogravimetrická analýza (TGA), konfokálna laserová rastrovacia mikroskopia (CLSM) a rastrovacia elektrónová mikroskopia (SEM) boli využité k štúdiu štruktúry kompozitov.

This paper presents an innovative, eco-friendly and sustainable tape manufacturing technology that transforms waste carbon and polyamide fibers into a new class of fibrous structure with unidirectional fiber orientation, termed “unidirectional tapes structure” for the fabrication of high performance composites. This novel technology imparts homogeneity, uniformity, orientation and thermal stability in unidirectional tapes structure that resemble conventional prepreg material. Unidirectional configuration of the tapes structure brings a revolution towards development of cost efficient carbon fiber composites for load bearing structural applications. This paper introduces the concept of tape manufacturing technology and highlights the modifications, optimization, and technological developments carried out to develop unidirectional tapes. The structural parameters that play a significant role in the properties of the high performance composite, such as fiber length, fiber orientation, fiber damage, and uniformity, were assessed during tape manufacturing. The results reveal composites fabricated from unidirectional tape structures with optimum parameters deliver tensile strength and modulus of 1370 ± 22 MPa and 85 ± 4 GPa, respectively.