Les travaux présentés dans ce mémoire portent sur l’étude et le développement d’une méthode de mesure d’épaisseur et de reconstruction 3D d’objets en verre creux, dans le cadre d’une application de contrôle industriel sur ligne de production. Les techniques de mesure d’épaisseur de parois transparentes sont actuellement très limitées par leur faible tolérance angulaire sur l’orientation des surfaces. Elles nécessitent une rotation de l’article devant le capteur, donc une manutention contraignante. De plus, les surfaces considérées étant spéculaires, les techniques de numérisation standard ne fonctionnent pas. Nous avons développé deux méthodes basées sur l’observation des réflexions d’une source diffuse ponctuelle sur les deux surfaces de la paroi de l’objet. Une observation simple à l’aide d’une caméra implique une ambiguïté entre l’orientation et la position de chacune des deux surfaces. Notre première méthode consiste à utiliser des informations de polarisation pour lever cette ambiguïté. Des résultats expérimentaux, obtenus avec un ou plusieurs points source témoignent de la faisabilité de la mesure. La seconde méthode consiste à utiliser une seconde caméra, associée à un dispositif optique spécifique. Ceci permet de trianguler directement les points d’incidence sur les deux surfaces. De plus, la source peut être étendue verticalement, de manière à augmenter la taille de la zone inspectée. Les résultats obtenus avec cette seconde technique attestent de la possibilité d’une mise en oeuvre industrielle. / The work presented in this thesis focuses on the study and development of a method for measuringthe thickness and reconstructing the 3D shape of glass containers, within the frame of an industrialon-line quality monitoring. Measuring thickness techniques of transparent objects are currently limited by their lack of toleranceregarding the surface orientation at a given reflection point. A rotation of the article in front ofthe sensor is thus required, which adds complexity to the mechanical handling of the item beingmeasured. Moreover, conventional scanning techniques do not work well on specular surfaces.We developed two methods based on the observation of the reflections by both surfaces of the wallof a given item of a diffuse, point light source. Imaging these reflections with a plain camera leavesan ambiguity between the orientation and position of each surface. Our first approach uses light polarization to remove this ambiguity. Experimental results, obtainedwith one or several point sources have demonstrated the feasibility of the measure. The second approach uses a second camera, associated with a specific optical design, whichenables a mere triangulation of the incident points on the two surfaces. Moreover, the light sourcecan be vertically extended to increase the size of the inspected area. The results obtained with thissecond technique show that industrial implementation is feasible.

[pt] Nas últimas décadas a tecnologia de displays e células solares evoluiu consideravelmente. Há menos de cinco décadas atrás a tecnologia de volume (bulk) era a mais amplamente utilizada no mundo. Com o surgimento das tecnologias de dispositivos planos ocorreu uma grande revolução e, nos dias atuais, é a tecnologia dominante na área de displays e de células solares. Já a tecnologia do futuro surgiu com a descoberta dos materiais orgânicos semicondutores tornando possível a substituição dos convencionais substratos de vidro por substratos flexíveis, como os substratos poliméricos ou metálicos. Nesta tese foram desenvolvidos diferentes tipos de substratos compósitos poliméricos baseados no termoplástico comercial de alto desempenho, poli(éter imida) (PEI), e na celulose bacteriana (CB), um polímero natural e biocompatível comumente utilizado como pele artificial. Os nanocompósitos foram idealizados para aplicação como substratos flexíveis em dispositivos orgânicos. Três tipos de substratos foram estudados: nanocompósito PEI/nanotubos de carbono (CNTs); nanocompósito CB/PEI; e CB modificada por camada de dióxido de titânio dopado com alumínio (AlTiO2). Os dois primeiros substratos foram utilizados na produção de dispositivos orgânicos emissores de luz (OLEDs), enquanto o último na produção de um dispositivo fotodetector em meio aquoso – implante de retina. Os novos materiais foram caracterizados, principalmente, por suas propriedades ópticas e morfológicas, e os resultados foram utilizados para determinar suas possíveis aplicações. O nanocompósito PEI/CNT apresentou propriedades similares ao polímero puro quando produzido com baixas concentrações de CNTs. Para maiores concentrações os resultados obtidos mostraram-se inferiores aos do polímero puro. Já o nanocompósito CB/PEI apresentou propriedades comparáveis ou melhores que dos polímeros puros. Podemos destacar a grande melhoria em sua transparência óptica na região do visível, além de ter sido possível a obtenção de uma rugosidade superficial comparável à encontrada para substratos de vidro e com maior homogeneidade em relação aos substratos de PEI. Ambos substratos foram funcionalizados pela deposição de uma camada de óxido de índio-estanho (ITO), que foi utilizado como eletrodo transparente na produção dos OLEDs. A análise da funcionalização da superfície mostrou que os filmes de ITO sobre os compósitos apresentou propriedades elétricas também comparáveis aos obtidos para substratos de vidro e PEI. No caso do substrato de CB/PEI foi verificada melhor estabilidade do filme de ITO nos testes de flexão, não sendo observado variações no valor de sua resistividade mesmo após sofrer flexão de 5mm de diâmetro. Os dispositivos produzidos no substrato compósito PEI/CNT também apresentaram propriedades semelhantes às obtidas pela utilização do polímero puro. A maior eficiência atingida por ambos dispositivos flexíveis chegou a 1,45 cd/m2, ainda abaixo dos valores obtidos para os substratos de vidro – 2,15 cd/m2 no caso do substrato com ITO comercial e 2,00 cd/m2 no caso do substrato com ITO depositado. Já os dispositivos produzidos no nanocompósito CB/PEI apresentou excelente eficiência (2,50 cd/m2), sendo maior que o obtido para subtratos revestidos com ITO comercial. O substrato de CB/AlTiO2 foi idealizado para melhorar a aderência do ITO no filme de CB quando em contato com a água. O resultado obtido foi bastante satisfatório, pois, além de manter a camada de ITO aderido ao substrato, melhorou em 46 porcento sua rugosidade superficial. Essa modificação na morfologia da superfície acarretou em uma melhora significativa da resistividade elétrica do filme de ITO sobre o substrato flexível, uma redução de aproximadamente 63 porcento. Os substratos modificados foram utilizados para a produção de um dispositivo fotodetector. Os resultados obtidos apontam substratos promissores para a produção de implantes de retinas flexíveis e biocompatíveis. / [en] Over the past decades displays and solar cells technology had substantially evolved. For less than five decades ago the bulk technology was the most widely used worldwide. With the emergence of flat device technology a great revolution has occurred and, nowadays, this is the dominant technology in the field of displays and solar cells. The future technology has begun with the discovery of the organic semiconductor material which makes possible to replace conventional glass substrates for flexible substrates such as polymeric or metallic ones. In this thesis different types of polymeric composite substrates based on commercial high performance thermoplastic polyetherimide (PEI), and a natural and biocompatible polymer commonly used as artificial skin, bacterial cellulose (BC) has been developed. The above mentioned nanocomposites were developed for application as flexible substrates in organic devices. Three types of substrates were studied: PEI/carbon nanotubes (CNTs) nanocomposite; BC/PEI nanocomposite; and BC modified with an aluminum doped titanium dioxide (AlTiO2) layer. The first two substrates were used for the production of organic emitting devices (OLEDs), while the latter one was used for the production of a photodetector device in aqueous medium – retinal prosthesis. The new materials were mainly characterized by its optical and morphological properties and the results were used to determine its possible applications. PEI/CNT nanocomposite presented similar properties to the pure polymer when produced with low CNTs contents. For higher concentrations the results were inferior to those of the pure polymer. BC/PEI nanocomposite has showed comparable or better properties when compared with pure polymers. A highlight was the great improvement in their optical transparency in the visible region of electromagnetic spectrum, and the smooth surface achieved by the nanocomposite – comparable to that found for glass substrates and with better uniformity in relation to PEI substrates. Both substrates were functionalized by depositing a layer of tin doped indium oxide (ITO), which was used as a transparent electrode in the production of OLEDs. The analysis of surface functionalization showed that electrical properties of ITO films onto composites were also comparable to those obtained for glass and PEI substrates. However, BC/PEI substrate presented better ITO film stability in bending tests, showing no changes in its resistivity value even after undergoing 5 mm diameter of bending. The devices produced in the PEI/CNT composite substrate has also similar properties to those obtained by using pure polymer. The higher efficiency achieved by both flexible devices reached 1.45 cd/m2 which is still below the values obtained for the glass substrates – 2.15 cd/m2 in the case of commercial ITO substrate and 2.00 cd/m2 in the case the substrate with deposited ITO. The devices produced onto CB/PEI composite substrates showed excellent efficiency (2.50 cd/m2), a higher value than that obtained for substrates coated with commercial ITO. The CB/AlTiO2 substrate was designed to improve the adhesion of the ITO film onto BC substrate when in contact with water. The result was quite satisfactory, because in addition to maintaining the ITO layer adhered to the substrate it has a 46 percent improvement in surface roughness. This change in surface morphology resulted in a significant improvement of ITO electrical resistivity, a reduction of approximately 63 percent was observed. The modified substrates were used for production of a photodetector device and the results showed a promising substrate for production of biocompatible and flexible retinal prosthesis.

Made available in DSpace on 2016-04-04T18:31:45Z (GMT). No. of bitstreams: 1 RICARDO VICENTE FAVERO.pdf: 1635235 bytes, checksum: d51f441103ff9f2ad94576b0bdd11b9f (MD5) Previous issue date: 2015-11-13 / The wavelength division multiplexing (WDM) optical network accommodates traffic load in 100, 50 and 25 GHz fixed-grid channel. This fixed-grid condition limits the number of lightpath for each optical fiber (80 channels in c-band) and doesn t allow bit rates with bandwidth over 50 GHz. To improve these factors, the flexibly grid elastic optical network (EON) was proposed, aiming accommodate adequately bit rates demand by customers. This proposal allows efficiency bandwidth and also expands bit rates supported by network. The EON bandwidth efficiency is obtained by routing and spectrum assignment (RSA) algorithm which acts to maximize the bandwidth utilization. Even with RSA, EON still show fragmentation rates substantial. In this context, this work proposes a new elastic optical network defragmentation strategy. This defragmentation strategy selects the lightpaths from the most fragmented link. The defragmentation process is based on RSA (DF-RSA). The DF-RSA determines the new position to reallocate the connection selected and performs. Using computer simulation of EON operation, were submitted several bit rates demands with different modulations format and traffic load between 45 and 100 erlang. Two simulation scenarios were proposed. The first one, compare the performance of RSA algorithm first-fit (FF) with and without defragmentation. It was considered as defragmentation process beginning point (trigger), the number of release connections. This scenario had until 48% of relative gain on minimizing blocking probability. The second scenario compared the performance of the follows RSA algorithms: FF, Maximize Path Spectrum Consecutiveness (MPSC) and Fragmentation Aware (FA). The FF was evaluated with and without defragmentation process and the others just with defragmentation process. The trigger employed was eventual connection blocked. The second scenario reached over the 80% blocking probability relative gain in 50 erlang traffic load. We conclude that the new elastic optical network defragmentation offers substantial gain bandwidth utilization and consequently blocking probability reduction. / As redes ?pticas de multiplexa??o por divis?o de comprimento de onda (WDM) acomodam o tr?fego em canais fixos de 100, 50 e 25 GHz. Esta condi??o de grade fixa limita o n?mero de conex?es por fibra ?ptica (80 canais na banda C), e n?o permite taxas de transmiss?o com ocupa??o espectral acima de 50 GHz. Para melhorar estes fatores, foram propostas as redes ?pticas el?sticas (EON) com canais flex?veis, visando acomodar adequadamente as taxas de transmiss?o demandas pelos usu?rios. Esta proposta possibilita maior efici?ncia espectral e tamb?m amplia as taxas de transmiss?o suportadas pela rede. A efici?ncia espectral nas EONs ? obtida com os algoritmos de roteamento e atribui??o espectral (Routing and Spectrum Assignment, RSA), que atuam para maximizar seu uso espectral. Mesmo com o uso de RSAs, as EONs ainda apresentam ?ndices de fragmenta??o consider?veis. Neste contexto, este trabalho prop?e uma nova estrat?gia de desfragmenta??o espectral para EONs. Esta proposta de desfragmenta??o seleciona as conex?es do enlace mais fragmentado, para o processo de desfragmenta??o. A desfragmenta??o baseia seu processo de realoca??o de conex?es por RSA, denominado DF-RSA. O DF-RSA determina a nova posi??o e realiza a realoca??o das conex?es. Com o uso de simula??o computacional da opera??o de funcionamento da EON, foram submetidas v?rias demandas de taxas de transmiss?o com diferentes modula??es e cargas de tr?fego entre 45 e 100 erlang. Foram propostos dois cen?rios de simula??o. No primeiro, foi comparado o desempenho do algoritmo RSA First-Fit (FF) com e sem o processo de desfragmenta??o. Considerou-se como ponto de inicio das desfragmenta??es (gatilho), o n?mero de conex?es liberadas da rede. Neste cen?rio obteve-se at? 48% de ganho relativo na minimiza??o da probabilidade de bloqueio. No segundo cen?rio, foram comparados os desempenhos dos seguintes algoritmos RSAs: FF, Maximize Path Spectrum Consecutiveness (MPSC) e Fragmentation Aware (FA). O FF foi avaliado com e sem desfragmenta??o e os demais somente com desfragmenta??o. Empregou-se como gatilho o eventual bloqueio de conex?o. O segundo cen?rio alcan?ou mais de 80% de ganho relativo de probabilidade de bloqueio para carga de tr?fego de 50 erlang. Conclui-se que a nova estrat?gia de desfragmenta??o para EONs oferece ganhos consider?veis na utiliza??o espectral e, consequentemente, redu??o na probabilidade de bloqueio.

Les travaux de cette thèse sont en rapport avec la caractérisation de cellules solaires organiques et se déclinent suivant 3 axes :- Dans le cadre du projet IMPCELPHOTOR, nous avons développé un banc de caractérisation LBIC/LBIV permettant de cartographier des dispositifs OPV afin de visualiser et d’identifier les défauts de fonctionnement.- Dans le cadre du projet Européen SPrinTronics, nous avons travaillé sur l’amélioration des électrodes. Pour l’électrode collectrice d’électrons, nous avons sélectionné, testé et validé des encres métalliques à base de nanoparticules d’argent compatibles avec l’impression jet d’encre et permettant de réaliser des dispositifs OPV fonctionnels. Pour l’électrode collectrice de trous, nous avons testé des encres à base de nanofils d’argent et de nanotubes de carbone afin de remplacer l’ITO. Des résultats satisfaisants ont été obtenus avec une encre à base de nanofils d’argent. Cette dernière permet de réaliser des cellules semi-transparentes fonctionnelles sur verre et sur plastique. - Un travail sur l’aspect couleur d’un dispositif OPV a été mené au sein du projet PHASME. Nous avons mis en œuvre différentes techniques afin de modifier la couleur d’un dispositif OPV sans détruire ses performances photovoltaïques, le but étant de réaliser des modules polychromes. Nous avons développé simultanément un logiciel de colorimétrie permettant de contrôler et de prévoir le rendu de couleur dû à l’ajout de filtre coloré sur le dispositif OPV. / The work of this thesis is related to the characterization of organic solar cells and is structured in three independant parts :- Within the IMPCELPHOTOR project, we developed an experimental bench based on LBIC/ LBIV mapping, in order to visualize and identify defects within OPV device and modules.- Within the European SPrinTronics project, we worked on the improvement of OPV electrodes. For the top electrode, we selected, tested, and validated metallic inks based on silver nanoparticles compatible with inkjet printing. For the bottom electrode, we tested silver nanowires and carbon nanotubes inks to replace ITO. Satisfactory results have been obtained with an ink based on silver nanowires, which allowed us to obtain functional semi-transparent cells on glass and plastic.- Within the PHASME project, we worked on the visual aspect of a coloured OPV device. We implemented various strategies to change the color of an OPV device without altering its photovoltaic performance, the aim being to achieve full color modules. Simultaneously, we developed a colorimetric software to control and predict the color rendering on the final device (OPV plus filter).

[ES] La búsqueda de nuevas soluciones e ideas innovadoras en el campo de la fotónica de silicio mediante la integración de nuevos materiales con prestaciones únicas es un tema de alta actualidad entre la comunidad científica en fotónica y con un impacto potencial muy alto. Dentro de esta temática, esta tesis pretende contribuir hacia una nueva generación de dispositivos fotónicos basados en la integración de óxidos metálicos en tecnología de silicio. Los óxidos metálicos elegidos pertenecen a la familia de óxidos conductores transparentes (TCO), concretamente el óxido de indio y estaño (ITO) y el óxido de cadmio (CdO), y materiales de cambio de fase (PCM) como el dióxido de vanadio (VO2). Dichos materiales se caracterizan especialmente por una variación drástica de sus propiedades optoelectrónicas, tales como la resistividad o el índice de refracción, frente a un estímulo externo ya sea en forma de temperatura, aplicación de un campo eléctrico o excitación óptica. De esta forma, nuestro objetivo es diseñar, fabricar y demostrar experimentalmente nuevas soluciones y dispositivos clave tales como dispositivos no volátiles, desfasadores y dispositivos con no linealidad óptica. Tales dispositivos podrían encontrar potencial utilidad en diversas aplicaciones que comprenden las comunicaciones ópticas, redes neuronales, LiDAR, computación, cuántica, entre otros. Las prestaciones clave en las que se pretende dar un salto disruptivo son el tamaño y capacidad para una alta densidad de integración, el consumo de potencia, y el ancho de banda. / [CA] La recerca de noves solucions i idees innovadores al camp de la fotònica de silici mitjançant la integració de nous materials amb prestacions úniques és un tema d'alta actualitat entre la comunitat científica en fotònica i amb un impacte potencial molt alt. D'aquesta temàtica, aquesta tesi pretén contribuir cap a una nova generació de dispositius fotònics basats en la integració d'òxids metàl·lics en tecnologia de silici. Els òxids metàl·lics elegits pertanyen a la família d'òxids conductors transparents (TCO), concretament l'òxid d'indi i estany (ITO) i l'òxid de cadmi (CdO), i materials de canvi de fase (PCM) com el diòxid de vanadi (VO2). Aquests materials es caracteritzen especialment per una variació dràstica de les propietats optoelectròniques, com ara la resistivitat o l'índex de refracció, davant d'un estímul extern ja siga en forma de temperatura, aplicació d'un camp elèctric o excitació òptica. D'aquesta manera, el nostre objectiu és dissenyar, fabricar i demostrar experimentalment noves solucions i dispositius clau com ara dispositius no volàtils, desfasadors i dispositius amb no-linealitat òptica. Aquests dispositius podrien trobar potencial utilitat en diverses aplicacions que comprenen les comunicacions òptiques, xarxes neuronals, LiDAR, computació, quàntica, entre d'altres. Les prestacions clau en què es pretén fer un salt disruptiu són la grandària i la capacitat per a una alta densitat d'integració, el consum de potència i l'amplada de banda. / [EN] The search for new solutions and innovative ideas in the field of silicon photonics through the integration of new materials featuring unique optoelectronic properties is a hot topic among the photonics scientific community with a very high potential impact. Within this topic, this thesis aims to contribute to a new generation of photonic devices based on the integration of metal oxides in silicon technology. The chosen metal oxides belong to the family of transparent conducting oxides (TCOs), namely indium tin oxide (ITO) and cadmium oxide (CdO), and phase change materials (PCMs) such as vanadium dioxide (VO2). These materials are characterized by a drastic variation of their optoelectronic properties, such as resistivity or refractive index, in response to an external stimulus either in the form of temperature, application of an electric field, or optical excitation. Therefore, our objective is to design, fabricate and experimentally demonstrate new solutions and key devices such as non-volatile devices, phase shifters, and devices with optical nonlinearity. Such devices could find potential utility in several applications, including optical communications, neural networks, LiDAR, computing, and quantum. The key features in which we aim to take a leapfrog are footprint and capacity for high integration density, power consumption, and bandwidth. / This work is supported in part by grants ACIF/2018/172 funded by Generaliltat Valenciana, and FPU17/04224 funded by MCIN/AEI/10.13039/501100011033 and by “ESF Investing in your future”. / Parra Gómez, J. (2022). Toward a new generation of photonic devices based on the integration of metal oxides in silicon technology [Tesis doctoral]. Universitat Politècnica de València. https://doi.org/10.4995/Thesis/10251/190883