Ultra-high performance concrete (UHPC) has progressively gained interest because of its favorable strength and durability properties. Literature shows that curing temperature has a significant effect on the resultant mechanical properties of UHPC, generally resulting in increased compressive strength. However, limited datasets are currently available to ascertain the degree of change related to compressive strength as a function of curing temperature and conditions. This study investigates the effect of isothermal and submerged curing temperature conditions, ranging from 10°C to 90°C, on the compressive strength and elastic modulus development of UHPC and generates a numerical model to capture these effects. The extent and rate of compressive strength development in Cor-Tuf UHPC was found to increase with curing temperature, while only the rate of elastic modulus development increased with curing temperature. The numerical model shows reasonable agreement when compared with the experimental results and was successfully implemented in finite element analysis software.

The demand for ultra-high-speed machines (UHSM) is rapidly growing in high-tech industries due to their attractive features. A-mechanically-based-antenna (AMEBA) system is another emerging application of UHSM. It enables portable wireless communication in the radio frequency (RF)-denied environment, which was not possible until recently. The AMEBA system requires a high-power (HP) UHSM for its effective communication performance. However, at the expected rotational speed range of 0.5 to 1 million rpm, the power level of UHSM is limited, and no research effort has succeeded to improve the power level of UHSM. The design of HP-UHSM is highly iterative, and it presents several critical challenges, unlike low-power UHSM, such as critical-bending-resonance (CBR), strong mutual influence among Multiphysics performances, exponential air-friction loss, and material limitation. When the magnetic loading of the UHSM rotor is increased to improve the power level, the rotor experiences serious mechanical vibration due to the excessive centrifugal forces and CBR. This vibration limits the operation of HP-UHSM and leads to structural breakdown. Furthermore, the design process becomes more critical when it considers the multidisciplinary design constraints and application requirements. This dissertation proposed a new Multiphysics design method to develop HP-UHSM for critical applications. First, the critical design constraints which prevent increasing the output power of UHSM are investigated. Then, a Multiphysics optimization model is developed by coupling several multidisciplinary analysis modules. This proposed optimization model enables (i) defining multidisciplinary design constraints, (ii) consideration of Multiphysics mutual influence, and (iii) a trade-off analysis between the efficiency and design-safety-margin. The proposed design model adopts the multiphase winding system to effectively increase the electrical loading in the slotless stator. Finally, a 2000 W 500,000 rpm HP-UHSM is optimized for an AMEBA system using the proposed design method. The optimized 2 kW 500,000 rpm machine prototype and its dynamo setup are built in the laboratory. Extensive finite element simulations and experimental testing results are presented to validate the effectiveness of the proposed design method. The results show that the proposed HP-USHM has 94.5% efficiency, 47 kW/L power density, 30% global design safety margin at the maximum speed and no CBR frequency below 11 kHz.

With the desire to improve passenger safety and fuel efficiency, Ultra High Strength Steels (UHSS) have been developed for use in the automotive industry. UHSS are high strength steels with high ductility and strength. DP 980 is one of these UHSS being applied in automobile manufacturing. DP 980 is difficult to join with Resistance Spot Welding (RSW) because of the high carbon content and alloying in this material. The weld becomes brittle when it solidifies during the welding process. With the desire and motivation of widely using UHSS, new welding processes are needed to be developed in order to effectively join DP 980. Friction Stir Spot Welding (FSSW) is a developing welding process aimed to replace RSW in the automotive industry because of its ability to join materials at a lower temperature. Currently the welding loads of the tools are higher than 2000 pounds, ranging from 3,000 to 5,000 pounds, which exceeds the limit of the welding robots in the automotive factories. It is proposed that the welding loads can be reduced by increasing the spindle speed of the FSSW tool. Other focuses in the research include increasing the life of the tool and developing acceptable welding parameters for High Speed FSSW. The experimental work done for this thesis provided support that weld strength can be obtained at levels above the acceptable standard for DP 980 material (greater than 2400 pound lap shear fracture load for 1.2 mm material) while keeping the vertical load on the welding machine spindle below 2000 lbs.

The work presented has the ultimate aim to increase dynamic mechanical properties by improvements in density and optimisation of microstructure of ultra high carbon PM steels by careful selection of processes, i.e. mixing, binding, alloying, heating profile and intelligent heat treatment. ThermoCalc modelling was employed to predict liquid phase amounts for two different powder grades, Astaloy 85Mo or Astaloy CrL with additive elements such as (0.4-0.6wt%)Si, (1.2-1.4wt%)C and (1-1.5wt%)Mn, in the sintering temperature range 1285-1300ºC and such powder mixes were pressed and liquid phase sintered. In high-C steels carbide networks form at the prior particle boundaries, leading to brittleness, unless the steel is heat-treated. To assist the breaking up of these continuous carbide networks, 0.4-0.6% silicon, in the form of silicon carbide, was added. The water gas shift reaction (C + H2O = CO + H2, start from ~500ºC) and Boudouard reaction (from ~500ºC complete ~930ºC) form CO gas in the early part of sintering and can lead to large porosity, which lowers mechanical properties. With the use of careful powder drying, low dew point atmospheres and optimisation of heating profiles, densities in excess of 7.70g/cm3 were attained. The brittle microstructure, containing carbide networks and free of cracks, is transformed by intelligent heat treatment to a tougher one of ferrite plus sub-micron spheroidised carbides. This gives the potential for production of components, which are both tough and suitable for sizing to improve dimensional tolerance. Yield strengths up to 410 MPa, fracture strengths up to 950 MPa and strains of up to 16 % were attained. Forging experiments were subsequently carried out for spheroidised specimens of Fe-0.85Mo+06Si+1.4C, for different strain rates of 10-3, 10-2, 10-1 and 1sec-1 and heated in argon to 700¿C, density ~7.8g/cm3 and 769 MPa yield strength were obtained. / Libyan Education Ministry Office

[pt] O presente trabalho avalia o efeito da utilização de concreto de ultra-alto desempenho (CUAD) em elementos estruturais, analisando seu comportamento à flexão e o impacto da utilização desse material no seu dimensionamento. Através de ensaios de caracterização do material, foram estudadas as suas propriedades mecânicas. Os resultados dos testes já apresentavam resistência à compressão de 104 MPa com 7 dias de idade e 142 MPa aos 28 dias de idade, além de um aumento na capacidade de carga e na ductilidade dos corpos de prova com o aumento da quantidade de fibras utilizadas no CUAD. Na escala estrutural, foram analisadas quatro vigas de concreto armado, onde duas foram produzidas com concreto de ultra-alto desempenho e duas com concreto convencional (CC), com taxa de armaduras de 0,44 por cento e 1,78 por cento. Primeiramente foi realizada uma análise comparativa dos resultados dos momentos obtidos experimentalmente e teoricamente (baseado nas normas NBR 6118:2014, ACI 544.4R-18 e Model Code 2010) não apresentando diferença significativa. Posteriormente, através dos resultados dos ensaios foi possível verificar que, a utilização do CUAD melhora, no geral, as propriedades mecânicas dos elementos analisados. A utilização do CUAD em vigas subarmadas apresenta resultados similares às vigas normalmente armadas com CC. Além disso, quando combinadas a utilização do CUAD com o aumento da taxa de armaduras, os resultados melhoram significativamente, apresentando, por exemplo um ganho na capacidade de carga de aproximadamente 40 por cento no aumento da taxa geométrica de armaduras e de 75 por cento com o aumento da taxa de armaduras combinada com a utilização do CUAD. / [en] The present work evaluates the effect of the use of ultra-high performance concrete (UHPC) in structural elements, analyzing its behavior to bending and the impact of the use of this material on its dimensioning. Through tests of characterization of the material, its mechanical properties were studied. The results of the tests already presented compressive strength of 104 Mpa at 7 days of age and 142 Mpa at 28 days of age, in addition to an increase in load capacity and ductility of the specimens with the increase in the amount of fibers used in the UHPC. In the structural scale, four reinforced concrete beams were analyzed, two of which were produced with ultra-high performance concrete and two with conventional concrete (CC), with an armor rate of 0.44 percent and 1.78 percent. First, a comparative analysis of the results of the moments obtained experimentally and theoretically (based on the norms NBR 6118:2014, ACI 544.4R-18 and Model Code 2010) was performed, with no significant difference. Subsequently, through the results of the tests it was possible to verify that the use of UHPC improves, in general, the mechanical properties of the analyzed elements. The use of UHPC in underarmed beams presents similar results to beams normally armed with CC. In addition, when combined with the use of UHPC with increased reinforcement rate, the results improve significantly, presenting, for example, a gain in load capacity of approximately 40 percent in the increase in the geometric rate of reinforcements and 75 percent with the increase in the reinforcement rate combined with the use of UHPC.

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High Pressure Liquid Chromatography (HPLC) is a well-known and widely used analytical technique which is prevalent throughout the pharmaceutical industry as a research tool. Despite its prominence HPLC possesses some disadvantages, most notably slow analysis time and large consumption of organic solvents. Ultra Pressure Liquid Chromatography (UPLC) is a relatively new technique which offers the same separation capabilities of HPLC with the added benefits of reduced run time and lower solvent consumption. One of the key developments which facilitate the new UPLC technology is sub 2-µm particles used as column packing material. These particles allow for higher operating pressures and increased flow rates while still providing strong separation. Although UPLC technology has been available since early 2000, few laboratories have embraced the new technology as an alternative to HPLC. Besides the resistance to investing in new capital, another major roadblock is converting existing HPLC methodology to UPLC without disruption. This research provides a framework for converting existing HPLC methods to UPLC. An existing HPLC method for analysis of Galantamine hydrobromide was converted to UPLC and validated according to ICH guidelines. A series of statistical evaluations on the validation data were performed to prove the equivalency between the original HPLC and the new UPLC method. This research presents this novel statistical strategy which can be applied to any two methodologies to determine parity. / Chemistry

[pt] O concreto de ultra-alto desempenho (CUAD) é um material cimentício avançado que possui excelente desempenho mecânico, ductilidade e durabilidade devido a uma elevada densidade de empacotamento e ao uso de fibras, promovendo benefícios à vida útil das estruturas. Grande parte das estruturas está sujeita a ações cíclicas, ou seja, variáveis com o tempo, resultando em danos de fadiga, como o surgimento e a propagação de trincas, que podem comprometer sua integridade. Assim, é essencial compreender o comportamento dos materiais sob fadiga para que sejam propostas diretrizes de projeto seguras e adequadas ao bom funcionamento das estruturas. Este trabalho visa, portanto, investigar o comportamento do concreto de ultra-alto desempenho pré-fissurado sob fadiga na flexão, quantificando sua degradação mecânica ao longo do carregamento cíclico a partir dos parâmetros de abertura de fissura (CMOD) e rigidez, contribuindo para o estudo desse tipo especial de concreto. Foram propostas equações para prever a vida à fadiga em relação ao limite superior de carga e estabelecer o limite de fadiga do concreto de ultra-alto desempenho, igual a 75,3 por cento, considerando o limite inferior igual a 30 cento do limite superior. Ainda, avaliou-se o comportamento pós-fadiga de amostras que não sofreram ruptura ao longo de 1.000.000 de ciclos, sendo possível observar que o mecanismo não gerou alterações no desempenho das amostras sob flexão para limites inferiores ao limite de fadiga. / [en] Ultra-high Performance Concrete (UHPC) is an advanced cementitious material that has excellent mechanical performance, ductility and durability due to a high packing density and the use of fibers, contributing to increase the structures lifespan. Most of the structures are subject to cyclic loads, which vary with time, resulting in fatigue damage such as the formation and propagation of cracks that could compromise its integrity. Thus, it is essential to understand the behavior of materials subjected to fatigue so that safe and proper design guidelines can be proposed for the appropriate performance of the structures. Therefore, this work aims to investigate the behavior of pre-cracked ultra-high performance concrete under flexural fatigue, quantifying its mechanical deterioration during cyclic loading through both crack mouth opening displacement (CMOD) and stiffness, which will contribute to the study of this special type of concrete. Equations were proposed to predict fatigue life according to the upper load limit during the cyclic loading and to establish the endurance limit of ultra-high performance concrete in 75,3 percent, considering the lower limit load equal to 30 percent of the upper limit. Also, when evaluating the post-fatigue behavior of samples that did not fail over 1,000,000 cycles it was possible to identify that the cyclic loading did not change the performance of the samples under bending, which was due to the use of upper loads below the endurance limit.