<p>Activated carbon is an adsorbent that is commonly used for removing organic contaminants from air due to its abundant pores and large internal surface area. This thesis is concerned with the static adsorption capacity and adsorption kinetics for single and binary organic compounds on different types of activated carbon. These are important parameters for the design of filters and for the estimation of filter service life. Existing predictive models for adsorption capacity and kinetics are based on fundamental “hard” knowledge of adsorption mechanisms. These models have several drawbacks, especially in complex situations, and extensive experimental data are often needed as inputs. In this work we present a systematic approach that can contribute to the further development of predictive models, especially for complex situations. The approach is based on Multivariate Data Analysis (MVDA), which is ideally suited for the development of soft models without incorporating any assumptions about the mathematical form or fundamental physical principles involved. </p><p>Adsorption capacity and adsorption kinetics depend on the properties of the carbon and the adsorbate as well as experimental conditions. Therefore, to make general statements regarding adsorption capacity and kinetics it is important for the resulting models to be representative of the conditions they will simulate. Accordingly, the first step in the investigations underlying this thesis was to select a minimum number of representative and chemically diverse organic compounds. The next steps were to study the dependence of the derived affinity coefficient, β, in the Dubinin-Radushkevich equation on properties of organic compounds and to establish a new, improved model. This new model demonstrates the importance of adding descriptors for the specific interaction with the carbon surface to the size and shape descriptors. The adsorption capacities of the same eight organic compounds at low relative pressures were correlated with compound properties. It was found that different compound properties are important in the various stages of adsorption, reflecting the fact that different mechanisms are involved. Ideal adsorbed solution theory (IAST) in combination with the Freundlich equation was developed to predict the adsorption capacities of binary organic compound mixtures. A new model was proposed for predicting the rate coefficient of the Wheeler-Jonas equation which is valid for breakthrough ratios up to 20%. Finally, it was shown that the Wheeler-Jonas equation can be adapted to describe the breakthrough curves of binary mixtures. New models were proposed for predicting its parameters, the adsorption rate coefficients, and the adsorption capacities for both components of the binary mixture. Thus, multivariate data analysis can not only be used to assist in the understanding of adsorption mechanisms, but also contribute to the development of predictive models of adsorption capacity and breakthrough time for single and binary organic compounds.</p>

The current study presents an induction heating system design for fiber optics pipes joints. Remote heating methods are probably inconvenient due to non-uniform heat distribution resulting in unreliable joints. The induction heating generates uniform heat distribution which can be achieved by proper designing of inductive heating coil, and power system inverter that drives the induction system. Two different shaped open jaw type heating coils were designed i.e open claw type coil (OCTC) and curved spiral rectangular coil (CSRC). The coils were designed in COMSOL simulation software to check the coil and workpiece behaviours. These coil designs were then wounded by hand and resistance and inductance of each coil were measured. The OCTC is a short loop coil, having small inductance while the CSRC has a long loop so its inductance is high. CSRC design was selected in the current application. The CSRC inductance was calculated through modified Wheeler formula and current sheet approximation. To design the power inverter, firstly the power density of heating material i.e workpiece was calculated. Then the thermal losses of the coil were calculated, these losses were due to skin effect and proximity effect; and switch losses due to drain to source resistance(RDS) of Mosfets were estimated. The Mazzilli inverter was proposed for power system inverter design which works as a parallel resonant circuit. It was designed in Mandi simulation software and then implemented on hardware. Theoretical results were compared with the practical measurements through Matlab software. Coil efficiency, power inverter efficiency and overall system efficiency were also calculated. This induction heating method for fiber optics joints is repeatable, consistent, generates uniform heat and is more convenient for site-specific heat generated on workpiece. It is portable, user friendly and environmental friendly as well.

The work presents life and work of Vladimir Jan Amos Novak, it shows his main thoughts unified by the principle of sociogenesis and points at its inspiration in older traditions of german and russian biology. It also concerns his anthropology as related to the principle of sociogenesis and shows some peculiar Novak's contributions, mainly his opinions on progessive neotenization of man and evolutionary tedency for association. It grasps the principle of sociogenesis as a biological and also a political concept and therefore shows its very political consequences presented mainly on his social thoughts. The work also deals with the relations between eastern and western science on Novák's efforts to unify all sciences under one universal evolutionary framework regardless its geographical belonging. Throughout the work is Novak shown in the context of man-animal relations and the principle of sociogenesis as arising from myrmecological studies. There are therefore presented anthropological works of three important myrmecologists A. Forel, W.M. Wheeler and E.O. Wilson as inspired in the study of ants.

Estudamos a Eletrodinâmica de Wheeler-Feynman usando um princípio variacional para um funcional de ação finito acoplado a um problema de valor na fronteira. Para trajetórias C2 por trechos, a condição de ponto crítico desse funcional fornece as equações de movimento de Wheeler-Feynman mais uma condição de continuidade dos momentos parciais e energias parciais, conhecida como condição de quina de Weierstrass-Erdmann. Estudamos em detalhe um sub-caso mais simples, onde os dados de fronteira têm um comprimento mínimo. Nesse caso, mostramos que a condição de extremo se reduz a um problema de valor na chegada para uma equação diferencial com retardo misto dependente do estado e do tipo neutro. Resolvemos numericamente esse problema usando um método de shooting e um método de Runge-Kutta de quarta ordem. Para os casos em que as fronteiras mínimas têm velocidades descontínuas, elaboramos uma técnica para resolver as condições de quina de Weierstrass-Erdmann junto com o problema de valor na chegada. As trajetórias com velocidades descontínuas previstas pelo método variacional foram verificadas por experimentos numéricos. Em um segundo desenvolvimento, para o caso mais difícil de fronteiras de comprimento arbitrário, implementamos um método de minimização com gradiente fraco para o princípio variacional e problema de fronteira acima citado. Elaboramos dois métodos numéricos, ambos implementados em MATLAB, para encontrar soluções do problema eletromagnético de dois corpos. O primeiro combina o método de elementos finitos com o método de Newton para encontrar as soluções que anulam o gradiente fraco do funcional para fronteiras genéricas. O segundo usa o método do declive máximo para encontrar as soluções que minimizam a ação. Nesses dois métodos as trajetórias são aproximadas dentro de um espaço de dimensão finita gerado por uma Galerkiana que suporta velocidades descontínuas. Foram realizados diversos testes e experimentos numéricos para verificar a convergência das trajetórias calculada numericamente; também comparamos os valores do funcional calculados numericamente com alguns resultados analíticos sobre órbitas circulares. / We study the Wheeler-Feynman electrodynamics using a variational principle for an action functional coupled to a finite boundary value problem. For piecewise C2 trajectories, the critical point condition for this functional gives the Wheeler-Feynman equations of motion in addition to a continuity condition of partial moments and partial energies, known as the Weierstrass-Erdmann corner conditions. In the simplest case, for the boundary value problem of shortest length, we show that the critical point condition reduces to a two-point boundary value problem for a state-dependent mixed-type neutral differential-delay equation. We solve this special problem numerically using a shooting method and a fourth order Runge-Kutta. For the cases where the boundary segment has discontinuous velocities we developed a technique to solve the Weierstrass-Erdmann corner conditions and the two-point boundary value problem together. The trajectories with discontinuous velocities presupposed by the variational method were verified by numerical experiments. In a second development, for the harder case with boundaries of arbitrary length, we implemented a method of minimization with weak gradient for the variational principle quoted above. Two numerical methods were implemented in MATLAB to find solutions of the two-body electromagnetic problem. The first combines the finite element method with Newtons method to find the solutions that vanish the weak gradient. The second uses the method of steepest descent to find the solutions that minimize the action. In both methods the trajectories are approximated within a finite-dimensional space generated by a Galerkian that supports discontinuous velocities. Many tests and numerical experiments were performed to verify the convergence of the numerically calculated trajectories; also were compared the values of the functional computed numerically with some known analytical results on circular orbits.

Estudamos a Eletrodinâmica de Wheeler-Feynman usando um princípio variacional para um funcional de ação finito acoplado a um problema de valor na fronteira. Para trajetórias C2 por trechos, a condição de ponto crítico desse funcional fornece as equações de movimento de Wheeler-Feynman mais uma condição de continuidade dos momentos parciais e energias parciais, conhecida como condição de quina de Weierstrass-Erdmann. Estudamos em detalhe um sub-caso mais simples, onde os dados de fronteira têm um comprimento mínimo. Nesse caso, mostramos que a condição de extremo se reduz a um problema de valor na chegada para uma equação diferencial com retardo misto dependente do estado e do tipo neutro. Resolvemos numericamente esse problema usando um método de shooting e um método de Runge-Kutta de quarta ordem. Para os casos em que as fronteiras mínimas têm velocidades descontínuas, elaboramos uma técnica para resolver as condições de quina de Weierstrass-Erdmann junto com o problema de valor na chegada. As trajetórias com velocidades descontínuas previstas pelo método variacional foram verificadas por experimentos numéricos. Em um segundo desenvolvimento, para o caso mais difícil de fronteiras de comprimento arbitrário, implementamos um método de minimização com gradiente fraco para o princípio variacional e problema de fronteira acima citado. Elaboramos dois métodos numéricos, ambos implementados em MATLAB, para encontrar soluções do problema eletromagnético de dois corpos. O primeiro combina o método de elementos finitos com o método de Newton para encontrar as soluções que anulam o gradiente fraco do funcional para fronteiras genéricas. O segundo usa o método do declive máximo para encontrar as soluções que minimizam a ação. Nesses dois métodos as trajetórias são aproximadas dentro de um espaço de dimensão finita gerado por uma Galerkiana que suporta velocidades descontínuas. Foram realizados diversos testes e experimentos numéricos para verificar a convergência das trajetórias calculada numericamente; também comparamos os valores do funcional calculados numericamente com alguns resultados analíticos sobre órbitas circulares. / We study the Wheeler-Feynman electrodynamics using a variational principle for an action functional coupled to a finite boundary value problem. For piecewise C2 trajectories, the critical point condition for this functional gives the Wheeler-Feynman equations of motion in addition to a continuity condition of partial moments and partial energies, known as the Weierstrass-Erdmann corner conditions. In the simplest case, for the boundary value problem of shortest length, we show that the critical point condition reduces to a two-point boundary value problem for a state-dependent mixed-type neutral differential-delay equation. We solve this special problem numerically using a shooting method and a fourth order Runge-Kutta. For the cases where the boundary segment has discontinuous velocities we developed a technique to solve the Weierstrass-Erdmann corner conditions and the two-point boundary value problem together. The trajectories with discontinuous velocities presupposed by the variational method were verified by numerical experiments. In a second development, for the harder case with boundaries of arbitrary length, we implemented a method of minimization with weak gradient for the variational principle quoted above. Two numerical methods were implemented in MATLAB to find solutions of the two-body electromagnetic problem. The first combines the finite element method with Newtons method to find the solutions that vanish the weak gradient. The second uses the method of steepest descent to find the solutions that minimize the action. In both methods the trajectories are approximated within a finite-dimensional space generated by a Galerkian that supports discontinuous velocities. Many tests and numerical experiments were performed to verify the convergence of the numerically calculated trajectories; also were compared the values of the functional computed numerically with some known analytical results on circular orbits.

Cette thèse a pour objet l'étude de l'interaction laser-matière dans un régime d'éclairement extrême que visent à atteindre plusieurs installations multi-pétawatt en cours de développement (CILEX-Apollon, ELI, IZEST, etc.). Pour un éclairement supérieur à 1022 Wcm-2, la dynamique relativiste des électrons accélérés dans l'onde laser est modiée par un important rayonnement Compton inverse non-linéaire. Au-delà de 1023 Wcm2, les photons ainsi produits peuvent, en interagissant à leur tour avec le champ laser, se désintégrer en paires électron-positron via le mécanisme de Breit-Wheeler non-linéaire. Ces mécanismes d'électrodynamique quantique, dont l'étude expérimentale était jusqu'ici l'apanage des grands accélérateurs de particles, peuvent grandement affecter les mécanismes usuels d'interaction laser-plasma, notamment ceux régissant l'accélération de particules chargées et, par conséquent, le bilan global de l'interaction. Afin de modéliser ce régime inédit d'interaction, qui combine processus collectifs, relativistes et d'électrodynamique quantique, nous avons enrichi des mécanismes précédents le code de simulation particle-in-cell calder développé de longue date au CEA/DIF. L'influence de ces mécanismes est d'abord explorée dans le cas d'une impulsion laser interagissant avec une cible dense de taille micrométrique. Un rendement de conversion de l'énergie laser en photons supérieur à 10% est observée au-dessus de 1023 Wcm-2, tandis que la production d'anti-matière s'emballe, via un mécanisme de cascade, à partir de 1024 Wcm2. Dans un second temps, nous étudions la génération de positrons lors de la collision frontale entre un faisceau d'électrons ultra-relativistes issu d'un accélérateur plasma et une impulsion laser ultra-intense. Dans une dernière partie, nous considérons un scénario prospectif d'intérêt astrophysique, à savoir la collision de plasmas de paires issus de cibles solides irradiées à 1024 Wcm-2 montrant la croissance rapide d'une instabilité de lamentation magnétique combinée à d'intenses effets radiatifs. / This PhD thesis is concerned with the regime of extreme-intensity laser-matter interaction that should be accessed on upcoming multi-petawatt facilities (e.g. CILEX-Apollon, ELI, IZEST). At intensities IL > 1022 Wcm-2, the relativistic dynamics of the laser-driven electrons becomes significantly modified by high-energy radiation emission through nonlinear inverse Compton scattering. For IL > 1023 Wcm-2, the emitted-ray photons can, in turn, interact with the laser field and decay into electron-positron pairs via the nonlinear Breit-Wheeler process. These quantum electrodynamic processes, which until recently could only be explored on large-scale particle accelerators, can greatly alter the "standard" mechanisms of laser-plasma interaction, and therefore its overall energy budget. In order to model their intricate interplay with the laser-induced plasma processes, they have been implemented within the particle-in-cell code calder developed at CEA. In a first part, we study these QED processes in the interaction of an ultra-intense laser with a micrometric overdense target. It is found that the laser-to--ray energy conversion efficiency can by far exceed 10% for intensities IL > 1023 Wcm-2, while copious pair production (through pair cascading) kicks in for IL > 1024 Wcm-2. In a second part, we consider positron generation in the collision between a GeV electron bunch issued from a laser-wake eld accelerator and a counterpropagating laser pulse. In a third part, we analyze a prospective scheme of astrophysical interest, consisting in the collision between two dense pair plasmas produced from solid targets irradiated at 1024 Wcm-2 showing a fast-growing magnetic lamentation instability amplified by intense synchrotron emission.

Post-war sculpture created by members of the Royal Academy of Arts was seemingly marginalised by Keynesian state patronage which privileged a new generation of avant-garde sculptors. This thesis considers whether selected Academicians (Siegfried Charoux, Frank Dobson, Maurice Lambert, Alfred Machin, John Skeaping and Charles Wheeler) variously engaged with pedagogy, community, exhibition practice and sculpture for the state, to access ascendant state patronage. Chapter One, The Post-war Expansion of State Patronage , investigates the existing and shifting parameters of patronage of the visual arts and specifically analyses how this was manifest through innovative temporary sculpture exhibitions. Chapter Two, The Royal Academy Sculpture School , examines the reasons why the Academicians maintained a conventional fine arts programme of study, in contrast to that of industrial design imposed by Government upon state art institutions for reasons of economic contribution. This chapter also analyses the role of the art-Master including the influence of émigré teachers, prospects for women sculpture students and the post-war scarcity of resources which inspired the use of new materials and techniques. Chapter Three, The Royal Academy as Community , traces the socialisation of London-based art societies whose memberships helped to identify sculptors for potential election to the Royal Academy; it then considers the gifting of elected Academicians Diploma Works. The empirical mapping of sponsorship for elected sculptors is investigated to determine how the organic profile of the Royal Academy s membership began to accommodate more modern sculptors and identifies a petition for change which may have influenced Munnings s speech (1949). Chapter Four, The Royal Academy Summer Exhibitions , explores the preparatory rituals of the Selection and Hanging Committees, processes for the selection of amateurs works, exhibit genres and critical reception. Moreover it contrasts the Summer Exhibitions with the Arts Council s Sculpture in the Home exhibition series to identify potential duplications. Chapter Five, Sculpture for the State , considers three diverse conduits facilitating the acquisition of sculpture for the state: The Chantrey Collection administered by the Royal Academy and exhibited at the Tate Gallery; the commissioning of Charles Wheeler s Earth and Water (1951 1953) for the new Ministry of Defence, London; and the selection of Siegfried Charoux s The Neighbours (1959) for London County Council s Patronage of the Arts Scheme . For these sculptures, complex expressions of Britishness are considered. In summary this thesis argues that unfettered by their allegiance to the Royal Academy of Arts its sculptors sought ways in which they might participate in the unprecedented opportunities that an expanded model of state patronage presented.

Le but de cette thèse est de développer des sources d'intrication photonique pour étudier les réseaux de communication quantique et l'optique quantique fondamentale. Trois sources très performantes sont construites uniquement autour de composants standards de l'optique intégrée et des télécommunications optiques. La première source génère de l'intrication en polarisation via une séparation deterministe des paires de photons dans deux canaux adjacents des télécommunications. Cette source est donc naturellement adaptée à la cryptographie quantique dans les réseaux à multiplexage en longueurs d'ondes. La seconde source génère, pour la première fois, de l'intrication en time-bins croisés, autorisant l'implémentation de crypto-systèmes quantiques à base d'analyseurs passifs uniquement. La troisième source génère, avec une efficacité record, de l'intrication en polarisation via un convertisseur d'observable temps/polarisation. La bande spectrale des photons peut être choisie sur plus de cinq ordres de grandeur (25 MHz - 4 THz), rendant la source compatible avec toute une variété d'applications avancées, telles que la cryptographie, les relais et les mémoires quantiques. Par ailleurs, cette source est utilisée pour revisiter la notion de Bohr sur la complémentarité des photons uniques en employant un interféromètre de Mach-Zehnder dont la lame s ́eparatrice de sortie se trouve dans une superposition quantique d'être à la fois présente et absente. Enfin, pour adapter la longueur d'onde des paires des photons télécoms intriqués vers les longueurs d'ondes d'absorption des mémoires quantiques actuelles, un convertisseur cohérent de longueur d'onde est présenté et discuté.

Two and three-wheeled vehicles are being used in increasing numbers in many emerging countries. The dynamics of such vehicles are very different from those of cars and other means of transportation. This thesis deals with a study of the dynamics of a motorcycle and an extensively used three-wheeled vehicle, called an “auto-rickshaw” in India. The commercially available multi-body dynamics (MBD) software, ADAMS, is used to model both the vehicles and simulations are performed to obtain insight into their dynamics. In the first part of the thesis, a study of the two wheeler dynamics is presented. A fairly detailed model of a light motorcycle with all the main sub-systems, such as the frame, front fork, shock absorbers , power train, brakes, front and rear wheel including tire slips and the rider is created in ADAMS-Motorcycle. The simulation results dealing with steering torques and angles for steady turns on a circular path are presented. From the simulation results and analytical models, it is shown that for path radius much greater than motorcycle wheel base, the steering torque and angle can be described by only two functions for each of the two variables. The first function is related to the lateral acceleration and can be determined numerically and the second function, in terms of the inverse of the path radius, is derived as an analytical approximation. Various tire and geometric parameters are varied in the ADAMS simulations and it is clearly shown that steady circular motion of a motorcycle can be reasonably approximated by only two curves–one for steering torque and one for steering angle. In the second part of the thesis, a stability analysis of the three-wheeled “autorickshaw” is presented. The steering instability is one of the major problems of the “auto-rickshaw” and this is studied using a MBD model created in ADAMS-CAR .In an Initial model the frame ,steering column and rear-forks (trailing arms) are assumed to be rigid. A linear eigenvalue analysis, at different speeds, reveals a predominantly steering oscillation, called a “wobble” mode, with a frequency in the range of 5 to 6Hz. The analysis results show that the damping of this mode is small but positive up to the maximum speed(14m/s) of the three-wheeled vehicle. Experiments performed on the three-wheeled vehicle show that the mode is unstable at speeds below 8.33m/s and thus the experimental results do not agree with the model. Next, this wobble instability is studied with an analytical model, similar to the model proposed for wheel shimmy problem in aircrafts. The results of this model show that the wobble is stable at low speeds regardless of the magnitude of torsional stiffness of steering column. This is also not matching with the experimental result. A more refined MBD model with flexibility incorporated in the frame, steering column and the trailing arm is constructed. Simulation results with the refined model show three modes of steering oscillations. Two of these are found to be well damped and the third is found to be lightly damped with negative damping at low speeds, and the results of the model with the flexibility is shown to be matching reasonably well with the experimental results. Detailed simulations with flexibility of each body incorporated, one at a time, show that the flexibility in the steering column is the main contributor of the steering instability and the instability is similar to the wheel shimmy problem in aircrafts. Finally, studies of modal interaction on steering instabilities and parametric studies with payload and trail are presented.

This thesis describes Burrow-Wheeler compression algorithm. It focuses on each part of Burrow-Wheeler algorithm, most of all on and entropic coders. In section are described methods like move to front, inverse frequences, interval coding, etc. Among the described entropy coders are Huffman, arithmetic and Rice-Golomg coders. In conclusion there is testing of described methods of global structure transformation and entropic coders. Best combinations are compared with the most common compress algorithm.