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Orientador: Luiz Sérgio Amarante Simões / Resumo: Na Nappe de Passos, unidade tectônica pertencente à Faixa Brasília Meridional, em seu segmento intermediário (Unidades E e G), ocorrem megaporfiroblastos de granada (diâmetro ≥ 3 cm, alcançando até 8 cm), hospedados em cianita-mica xistos, que contrastam com os de tamanho usual (0,2 a 1,5 cm) comumente encontrados nos xistos granadíferos desta nappe. Este trabalho, como uma primeira iniciativa de estudo dessa peculiar feição metamórfica, investiga a ocorrência desses megaporfiroblastos através de levantamento de campo, análise microtectônica e determinação de perfis químicos. Parte do trabalho foi voltada para buscar ocorrências de megaporfiroblastos na porção NW da Nappe de Passos, a norte da cidade de Cássia (MG). Com o levantamento de campo, que incluiu trinta perfis seccionando as Unidades E, F G, H e I, não foi encontrada nenhuma ocorrência de camadas ricas em megaporfiroblastos neste setor da nappe. Ao longo desse levantamento, foi possível realizar uma melhor caracterização geométrica do fechamento NW da Braquissinformal de Passos e demonstrar o caráter braquiantiformal da Antiforma de Itaú de Minas. Para o estudo dos megaporfiroblastos, selecionou-se uma ocorrência no segmento SE da Nappe de Passos, no topo da Unidade E. Eles se encontram hospedados em camadas decimétricas de biotita-cianita-granada-quartzo-muscovita xistos, que se alternam com camadas de composições semelhantes, porém contendo porfiroblastos de tamanho usual. Os megaporfiroblastos têm forma elipsoida... (Resumo completo, clicar acesso eletrônico abaixo) / Abstract: The Passos Nappe is an important tectonic unit of the Southern Brasília Belt. In the intermediate segment of the Passos Nappe, represented by E and G Units, occurs megaporphyroblasts of garnet (diameter 3 to 8 cm). The megaporphyroblasts are hosted in kyanite-mica schists and contrast with the usual size (from 0.2 to 1.5 cm) commonly found in the granadiferous schists of this nappe. This work provides the first study of this peculiar metamorphic feature and aims to investigate the occurrence of these megaporphyroblasts based on field work, microtectonic analysis and determination of chemical profiles. Part of the work focused on identifying the occurrence of megaporphyroblasts to the north of the Cássia city (Minas Gerais State), within the NW sector of the Passos Nappe. Thirty transects were produced along the E, F G, H and I Units, however, no occurrence of megaporphyroblasts rich layers was found in this sector of the nappe. The improvement on the geometric characterization of the northwest closure of the Passos Brachisyncline and the demonstration of the brachianticline aspect of Itaú de Minas Antiform were possible with the transect work. For the study of megaporphyroblasts, it was selected an occurrence located in the SE sector of the Passos Nappe, situated at the top of the E Unit. The study carried out in this sector shows that megaporphyroblasts are hosted in decimetric layers of biotite-kyanite-garnet-quartz-muscovite schists, which alternate with layers of similar ... (Complete abstract click electronic access below) / Mestre

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Στην παρούσα Μεταπτυχιακή Διατριβή αναλύονται τα παραμορφωτικά και συστασιακά (πετρογραφικά - ορυκτοχημικά) χαρακτηριστικά μυλωνιτιωμένων λιθολογιών από την πλαστική ζώνη διάτμησης του Φελλού (Βορειοδυτική Άνδρος). Η ζώνη διάτμησης του Φελλού είναι μια μεσοσκοπικής κλίμακας δομή, ΒΒΑ διεύθυνσης, με δομικό πάχος της τάξεως των 200 μέτρων. Το κεντρικό τμήμα της ζώνης διάτμησης φιλοξενείται σε μετα-πηλιτικές λιθολογίες και οριοθετείται από έντονα παραμορφωμένα μετα-υπερβασικά και μετα-βασικά λιθολογικά σώματα. Οι μυλωνιτιωμένες λιθολογίες της ζώνης διάτμησης χαρακτηρίζονται σαν S έως S – L τεκτονίτες. Η τεκτονική χαρτογράφηση στην περιοχή μελέτης αποκάλυψε ότι η μυλωνιτική ζώνη αναπτύχθηκε υπο-παράλληλα με το αξονικό επίπεδο ενός ήπια κεκλιμένου συγκλινοειδούς το οποίο έχει υποστεί καθολικό μετασχηματισμό. Οι ρεολογικές αντιθέσεις μεταξύ του πυρήνα της ζώνης διάτμησης και των περιθωρίων της σε συνδυασμό το τεκτονικό περιβάλλον ενός μετασχηματισμένου συγκλινοειδούς έχουν συμβάλλει στον εντοπισμό της παραμόρφωσης στην θέση ανάπτυξης της ζώνης διάτμησης. Σε χαρτογραφική κλίμακα ο προσανατολισμός των γραμμώσεων έκτασης μεταβάλλεται από ΝΝΔ , παράλληλα στη διεύθυνση της ζώνης διάτμησης, σε ΔΒΔ διεύθυνση βύθισης. Η μεταβολή στον προσανατολισμό των γραμμώσεων έκτασης δείχνει ότι η διεύθυνση κίνησης εντός της ζώνης διάτμησης διαμερίζεται χωρικά σε συνιστώσες κίνησης παράλληλα και κάθετα στην παράταξη της μυλωνιτικής φολίωσης. Ο κινηματικός διαμερισμός στην πλαστική ζώνη διάτμησης του Φελλού είναι χαρακτηριστικό γνώρισμα ζωνών διάτμησης πλάγιας συστολής. Ο κινηματικός διαμερισμός που αναγνωρίστηκε, ερευνήθηκε περαιτέρω με την εξέταση της χωρικής κατανομής των κρυσταλλογραφικών αξόνων [c] του χαλαζία, από δείγματα χαλαζιακών φλεβών και χαλαζιακών μυλωνιτών, προσανατολισμένα παράλληλα στη μυλωνιτική φολίωση και κάθετα στη γράμμωση έκτασης (ΧΖ επίπεδο ελλειψοειδούς παραμόρφωσης). Τα ιστολογικά διαγράμματα [c] αξόνων χαλαζία παρουσιάζουν μεταβολές στην τοπολογία τους σε διαφορετικά δομικά επίπεδα της ζώνης διάτμησης και διακριτές διαφορές με τα πρότυπα κρυσταλλογραφικά διαγράμματα [c] αξόνων μονοκλινικής συμμετρίας. Διακριτό χαρακτηριστικό , ειδικά για τα ανώτερα δομικά επίπεδα της ζώνης διάτμησης, είναι η εστίαση των [c] αξόνων σε σημειακά μέγιστα που προβάλλονται σε περιφερειακές θέσεις των κρυσταλλογραφικών διαγραμμάτων. Η βάση , δομικά, της ζώνης διάτμησης βρίσκεται στην ρεολογική διεπιφάνεια μετα-πηλιτών – μετα-βασιτών. Στην επαφή αυτή, ιστολογικά διαγράμματα από γειτονικά δείγματα χαλαζιακών φλεβών παρουσιάζουν συστηματικά διαγράμματα τύπου μικρών κύκλων. Η συστηματικότητα αυτή υποδηλώνει εντοπισμό της γεωμετρίας της παραμόρφωσης στην λιθολογική επαφή των μετα-πηλιτών - μετα-βασίτων. Η ποσοτική ανάλυση της παραμόρφωσης έδειξε ότι η παράμετρος Rxz μεταβάλλεται από 2.1 έως 6.45 ενώ η παράμετρος Flinn κυμαίνεται από 0.01 έως 0.93, υποστηρίζοντας και ποσοτικά ότι η γεωμετρία της παραμόρφωσης ανήκει στο πεδίο της πλάτυνσης. Η γεωμετρία της παραμόρφωσης στο πεδίο της πλάτυνσης είναι ένα επιπλέον διαγνωστικό χαρακτηριστικό των ζωνών διάτμησης πλάγιας συστολής. Η πετρογραφικη εξέταση μυλωνιτιωμένων λιθολογιών εστίασε στην αναγνώριση ζωνωμένων ορυκτών φάσεων με σκοπό την στοιχειοθέτηση των ορυκτοχημικών χαρακτηριστικών τους. Η πετρογραφική εξέταση δειγμάτων από μια επιφανειακή εμφάνιση μεταβασιτών από την βάση της μυλωνιτικής ζώνης συνέβαλλε στην αναγνώριση, σε κλίμακα λεπτής τομής, δύο λιθολογικών τύπων οι οποίοι είναι (α) Γρανατούχος – γλαυκοφανιτικός σχιστόλιθος και (β) Επιδοτιτικός - γλαυκοφανιτικός σχιστόλιθος. Η ορυκτοχημεία ζωνωμένων γρανατών και αμφιβόλων από τους δύο λιθολογικούς τύπους εξετάστηκε μέσω SEM/EDS.Η ορυκτοχημική ανάλυση οδήγησε στην αναγνώριση τριών τύπων ζώνωσης στις αμφιβόλους με τα εξής χαρακτηριστικά (α) Σκούροι πράσινοι πυρήνες σιδηρο-Κεροστίλβης με κροσσιτικά περιθώρια (β) Παλίνδρομη ζώνωση μεταξύ μπλε (σιδηρο-Γλαυκοφανής) και πράσινων αμφιβόλων (σιδηρο-Βαρροϊσίτης) και (γ) Απομονωμένοι κρύσταλλοι με κροσσιτικούς πυρήνες και ριβεκιτικά περιθώρια. Τα περιθώρια των ζωνωμένων γρανατών που εξετάστηκαν βρίσκονται σε ιστολογική ισορροπία με μπλέ αμφιβόλους, το γεγονός αυτό σε συνδυασμό με τα ορυκτοχημικά πειστήρια της κλασμάτωσης του μαγγανιου στους πυρήνες αποδεικνύει ότι η βλάστηση των γρανατών συνέβη σε αυξανόμενες συνθήκες πίεσης και θερμοκρασίας κατά την διάρκεια του υψηλής πίεσης μεταμορφικού γεγονότος. / The subject of the present contribution is the analysis of deformation in the Fellos ductile shear zone, which crops out in the island of Andros. Fellos shear zone (FSZ) is an outcrop scale NNE –striking structure with a total structural thickness of, approximately, 200 m. The central main domain of the shear zone is defined by mylonitized metapelitic rocks, bounded by strongly deformed meta-basic and meta–ultrabasic rocks both on top and bottom. Mylonitic rocks in the shear zone can be classified as S to S – L tectonites. Structural mapping revealed that the Fellos shear zone resulted from the complete transposition of a gently inclined synform the axial plane of which is orientated sub – parallel to the mylonitic foliation. The rheological contrasts between the core of the shear zone and its margins in conjunction with the structural framework of a transposed synform are first order influences to the localization of deformation. The map scale pattern of the stretching lineations in the shear zone shows that the lineation swings from a NNE orientation, trending parallel to the strike of the shear zone, to an ESE orientation. This variation shows that transport orientation in the shear zone is spatially partitioned into strike parallel and strike normal movements. This kinematic partitioning in the Fellos shear zone is a characteristic feature of transpressional high strain shear zones. The recognized partitioning was further investigated by examining the pattern of quartz [c]-axes fabrics in quartz veins oriented parallel to the mylonitic foliation as well as in quartz –rich mylonites. Quartz [c] axes fabric diagrams shows variations in their topology at different structural levels of the shear zone and distinct differences with the [c] axes patterns of monoclinic strain symmetry. Distinct feature, especially at the uppermost structural levels of the shear zone, is the point maxima clustering of the [c] axes in peripheral position of the crystallographic diagrams. At the base of the shear zone, in the rheological interface of metapelites with metabasites, the fabric diagrams from neighboring quartz vein specimens shows consistently small circle girdle pattern. This observation denotes localization in the geometry of deformation (flattening) at this lithological contact. Finite strain analysis shows that Rxz varies from 2.1 to 6.45, while the Flinn parameter range between 0.01 and 0.93, supporting quantitatively the flattening geometry of strain. Flattening strain is another diagnostic criterion of transpressional shear zones. The means to constrain the compositional features of the mylonitic rocks was mineral chemistry and petrologic analysis. Petrographic examination, specifically, of a metabasite outcrop from the base of the shear zone revealed, in thin section scale, two lithologic types : (a) Garnet blueschist and (b) Epidote blueschist. The mineral chemistry of zoned garnets and amphiboles from these petrographic types has been examined using SEM/EDS. The microchemical analysis revealed three different zoning patterns in the amphiboles which are characterized by (a) dark green Ferro – hornblende cores with crossite rims (b) Amphiboles with compositional zoning and alternations of blue (Ferro – glaucophane) and green amphiboles (Ferro – barroisite) and (c) Isolated grains with crossite cores and riebeckite rims. Compositional mapping of zoned garnets witnessed fractionation of manganese to the cores, which is the Prima facie evidence of growth zoning. In addition, the almandine rims of the zoned garnets are in textural equilibrium with blue amphiboles, observation which implies that these garnets nucleated during the HP event.

Orientador: Gabriela Rezende Fernandes / Resumo: Neste trabalho é apresentada uma formulação do MEC (Método dos Elementos de Contorno) considerando-se não-linearidade física para analisar microestruturas de materiais heterogêneos no contexto da análise em multi-escala. A microestrutura, também denominada como EVR (Elemento de Volume Representativo), é modelada como uma chapa em sub-regiões onde vazios ou inclusões podem ser considerados dentro da matriz, sendo diferentes propriedades elásticas e modelos constitutivos definidos para cada sub-região. A equação integral para o deslocamento é obtida a partir do Teorema de Betti, onde para considerar o fenômeno dissipativo, um campo de esforços iniciais é considerado. A equação algébrica da chapa é obtida após a discretização do contorno externo e interface em elementos e do domínio das subregiões em células. Na análise multi-escala cada ponto da estrutura (macrocontínuo) é representado por um EVR, onde o comportamento do material não é definido por um modelo constitutivo, mas através da solução do problema de equilíbrio do EVR quando sujeito à deformação referente ao ponto do macrocontínuo. O problema de equilíbrio do EVR é definido em termos da flutuação dos deslocamentos, sendo o mesmo satisfeito quando seu campo de forças se encontra em equilíbrio. Após a solução do EVR, os deslocamentos no contorno e as forças dissipativas são atualizados e as forças de superfície sobre o contorno recalculadas para se obter a tensão homogeneizada. O custo computacional obtido com a presente... (Resumo completo, clicar acesso eletrônico abaixo) / Mestre

Submitted by LUIS HENRIQUE DE REZENDE CROZARIOL null (luiscrozariol@gmail.com) on 2017-09-26T22:06:47Z No. of bitstreams: 1 Dissertação Luis 26-09.pdf: 3642072 bytes, checksum: 6bd5d174cfe596f9dc2def41f1270185 (MD5) / Approved for entry into archive by Monique Sasaki (sayumi_sasaki@hotmail.com) on 2017-09-28T13:33:18Z (GMT) No. of bitstreams: 1 crozariol_lhr_me_ilha.pdf: 3642072 bytes, checksum: 6bd5d174cfe596f9dc2def41f1270185 (MD5) / Made available in DSpace on 2017-09-28T13:33:18Z (GMT). No. of bitstreams: 1 crozariol_lhr_me_ilha.pdf: 3642072 bytes, checksum: 6bd5d174cfe596f9dc2def41f1270185 (MD5) Previous issue date: 2017-07-31 / Coordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES) / Neste trabalho é apresentada uma formulação do MEC (Método dos Elementos de Contorno) considerando-se não-linearidade física para analisar microestruturas de materiais heterogêneos no contexto da análise em multi-escala. A microestrutura, também denominada como EVR (Elemento de Volume Representativo), é modelada como uma chapa em sub-regiões onde vazios ou inclusões podem ser considerados dentro da matriz, sendo diferentes propriedades elásticas e modelos constitutivos definidos para cada sub-região. A equação integral para o deslocamento é obtida a partir do Teorema de Betti, onde para considerar o fenômeno dissipativo, um campo de esforços iniciais é considerado. A equação algébrica da chapa é obtida após a discretização do contorno externo e interface em elementos e do domínio das subregiões em células. Na análise multi-escala cada ponto da estrutura (macrocontínuo) é representado por um EVR, onde o comportamento do material não é definido por um modelo constitutivo, mas através da solução do problema de equilíbrio do EVR quando sujeito à deformação referente ao ponto do macrocontínuo. O problema de equilíbrio do EVR é definido em termos da flutuação dos deslocamentos, sendo o mesmo satisfeito quando seu campo de forças se encontra em equilíbrio. Após a solução do EVR, os deslocamentos no contorno e as forças dissipativas são atualizados e as forças de superfície sobre o contorno recalculadas para se obter a tensão homogeneizada. O custo computacional obtido com a presente formulação é menor que aquele referente ao modelo desenvolvido pelo Método dos Elementos Finitos, sendo a resposta homogeneizada do EVR comparada ao modelo de elementos finitos a fim de validar a formulação apresentada nesse trabalho. / A BEM formulation, considering dissipative phenomena, to analyze microstructures of heterogeneous materials in the context of multi-scale analysis is presented. The microstructure, also denoted as RVE (Representative Volume Element), is modelled as a zoned plate where voids or inclusions can be considered inside a matrix, being different elastic properties and constitutive models defined for each sub-region. The integral representation for displacement is obtained from Betti’s Theorem, where to consider the dissipative phenomena, an initial forces field is considered. The plate algebraic equation is obtained after discretizing the external boundary and interfaces into elements and the sub-regions domain into cells. In the multi-scale analysis, each macro-continuum point is represented by a RVE, being the material behaviour not governed by a phenomenological constitutive model, but defined after the solution of the RVE equilibrium problem due to the macro strain. The RVE equilibrium problem is defined in terms of displacement fluctuations, being satisfied when the forces field is in equilibrium. After the RVE solution, the boundary displacements and dissipative forces are updated and the boundary tractions recalculated to obtain the homogenized stress. The computational cost obtained with the proposed formulation is smaller than the formulation developed by the Finite Element Method. Besides, the homogenized response is compared to the finite element model to show its accuracy.

Ce travail a pour but d’étudier les paramètres physico-chimiques qui contrôlent les transferts de matière ainsi que la formation et l’évolution des argiles dans des failles chevauchantes en environnement sédimentaire. Deux failles chevauchantes pyrénéennes de faible grade métamorphique ont été étudiées : la faille de Millaris (cf. Mont Perdu) et le chevauchement du Pic-de-Port-Vieux (cf. Gavarnie). Dans la faille de Millaris, la déformation s’accompagne principalement d’une dissolution de la calcite matricielle par pression-solution induisant un changement de volume de la roche de 20 à 40%. Le chevauchement du Pic-de-Port-Vieux enregistre des modifications importantes au coeur de la faille mais aussi dans la zone d’endommagement. Dans les calcaires du mur du chevauchement, une mylonitisation est associée à une dissolution partielle des dolomites en présence de fluides ne dépassant pas 320-340°C. Dans les pélites du toit du chevauchement, la dissolution de l’hématite par un fluide réducteur entraine un changement de l’état redox de la roche (confirmé par spectroscopie Mössbauer) et la précipitation de chlorite dans des veines syncinématiques. Des chlorites à zonations chimiques oscillatoires présentes dans certaines veines révèlent, en combinant cartographie chimique à la microsonde, mesures de l’état redox par μXANES et thermométrie, des variations cycliques de température d’au moins 50°C au cours de la cristallisation. Un processus de valves sismiques pourrait donc être associé à la mise en place du chevauchement du Pic de Port Vieux. / This work aims to study the physical and chemical parameters that control the mass-transfer and the clays formation and evolution in sedimentary environment thrust faults. Two Pyrenean thrust faults in low metamorphic grade were studied: the Millaris fault (related to Mont Perdu) and the Pic-de-Port-Vieux thrust (related to Gavarnie). In the Millaris fault, the deformation is accompanied mainly by dissolution of the matrix calcite by pressure-solution which induces a volume change of the rock from 20 to 40%. The Pic-de-Port-Vieux thrust records significant changes in the fault core-zone, but in the damaged zone also. In the footwall limestone, a mylonitisation is associated with a partial dissolution of dolomite in the presence of not exceeding 320-340°C fluids. In the hanging-wall pelites, the hematite dissolution by a reducing fluid causes a redox state change of the rock (confirmed by Mössbauer spectroscopy) and chlorite precipitation in synkinematic veins. Oscillatory zoning pattern chlorites located in some shearing veins revealed, by combining chemical mapping microprobe, redox state measurements with μ-XANES and thermometry, cyclic temperature variations of at least 50°C during the crystallization. A seismic valves process could be associated to Pic-de-Port-Vieux thrusting.