Dans le cadre du concept de stockage de déchets radioactifs à vie longue en couche géologique profonde développé par l'Andra, l’IRSN mène une étude in situ sur la Station Expérimentale de Tournemire, en collaboration avec EDF afin de déterminer les interactions acier/argilite dans un contexte naturel. Au terme de 10 ans d’interaction, deux forages ont été sur-carottés afin de caractériser les transformations de l’argilite de Tournemire au contact d’aciers carbone et inoxydables et de comparer les phénomènes réactifs mis en évidence et ceux induits par des simulations numériques par des codes de calcul géochimique et couplant chimie-transport.Les échantillons argilite/acier carbone montrent une importante corrosion du disque d’acier. Le fer libéré sous la forme d’auréoles et dans les fissures de la roche perturbe l’argilite au contact entraînant des modifications minéralogiques et structurales. La précipitation d’oxydes de fer ainsi qu’une dissolution de la calcite et des feuillets smectitiques des interstratifiés I/S sont identifiés. Une zonation métal/métal corrodé/argilite perturbée/argilite saine est mise en évidence et des variations de porosité sont observées marquant les interfaces entre deux zones. Les simulations géochimiques montrent que l’essentiel des modifications est rapidement initié lors de la mise en place du système et que l’oxygène piégé à la fermeture du système est consommé par la corrosion des aciers mais surtout qu’il diffuse dans le matériau encaissant par gradient de concentration.Les échantillons argilite/acier inoxydable présentent une très faible corrosion par piqûration de l’acier. La minéralogie de l’argilite ne semble pas perturbée au cont / Within the framework of a long lived radioactive waste storage concept in deep geological layer developed by Andra, IRSN leads an in situ study on the Experimental Station of Tournemire, in association with EDF to determine the interactions steel/argillite in a natural context. After 10 years of interaction, two drillings overcoring performed to characterize the processings of the Tournemire argillite in contact with carbon and stainless steels and to compare reactive phenomena highlighted and those induced by simulations tools combining chemistry and transport.Argillite/carbon steel samples show a significant corrosion of steel disk. Iron released, in the form of rings and cracks in the rock, disrupts the argillite in contact resulting in mineralogical and structural changes. Iron oxides precipitation and a calcite and smectitic leaf of mixed-layers I/S dissolution are identified. A succession of areas: metal/metal corroded/argillite disturbed/argillite is highlighted and porosity variations are observed on the interfaces between two areas. Geochemical simulations show that major changes are initiated speedly during establishment of the system and the oxygen trapped in the closed system is consumed by the corrosion of steel but mostly it diffuses into the surrounding material through concentration gradient.Argillite/stainless steel samples have a very low pitting corrosion of steel disk. This does not seem to affect the mineralogy of the argillite in contact.

The objective of this thesis is to improve understanding of the development of corrosion products (scales) that form on the inner walls of carbon steel pipelines in CO2-rich (sweet) oilfield environments. If well adherent to the carbon steel surface, such scales can significantly reduce the metal’s rate of corrosion. Typically, the open literature labels sweet corrosion scale as ferrous (II) carbonate (FeCO3) or siderite, although this may not always be the case. For example, Fe2(OH)2CO3 (chukanovite) and Fe3O4 (magnetite) are known to modify the protective character of a sweet corrosion product scale. Practical electrochemical methods for the assessment of substrate corrosion, and electron/photon-based characterisation techniques for investigating scale structure and composition, have revealed interesting aspects of the nature of sweet corrosion scale development on model high purity Fe and real-world pipeline steel surfaces. Concerning scale development on model Fe substrates immersed in CO2-saturated deionised water (buffered to pH = 6.8, T = 80°C, Ptotal = 1 bar), electrochemical data supplemented by grazing incidence x-ray diffraction (GIXRD) and scanning electron microscopy (SEM) show that a semi-protective mixed corrosion scale comprising siderite and chukanovite becomes a highly protective siderite scale with longer exposure time. The introduction of sodium chloride to the CO2-saturated solution (T = 80°C, pH = 6.8, Ptotal = 1 bar) impedes the rate of scale formation. Increasing [NaCl] from the start of experiment is suspected to limit the precipitation kinetics of sweet corrosion scale crystals, since chukanovite is no longer observed, and siderite formation is somewhat slowed as well. SEM imaging, using an electronic workfunction-sensitive detector (in lens), reveals nanoscale deposits on the corroded Fe surface in regions that are devoid of µm-scale crystals. With the Raman spectra from these regions considered, it is interpreted that the nanoscale deposits are likely amorphous iron carbonate, albeit oxidised to a significant extent. Moving to real-world carbon steel immersion in sweet solutions, a scale comprising predominantly chukanovite is observed (using GIXRD and SEM) on the 1% Ni weld zone (WZ) surface of a pipeline weld-joint, but not on adjacent, distinct regions (heat affected zones (HAZ) and base metal (BM)). This selective scaling is suggested to be due to some initial corrosion of the weld-joint, which generates sufficient [Fe2+(aq)], and a macro-galvanic effect across the weld, i.e. WZ is cathodic to HAZ and BM. Further, to gain mechanistic insight into compositional changes during sweet corrosion scale growth, an electrochemical cell for in situ GIXRD (named E-cell) has been developed and commissioned. Diffraction patterns acquired using synchrotron radiation, from a pipeline steel surface, reveal the formation and temporal evolution of a multicomponent corrosion scale. Accompanying electrochemical data suggest that the scale is quite protective.

Above ground steel storage tanks are used worldwide for the storage of various liquids. EN 14015:2005, which has traditionally been used to design the tanks, does not necessarily fulfil the requirements of the Swedish Building Code. This has been underlined by hand calculation models in EN 1993-1-6:2007, EN 1993-4-2:2007 and numerical analysis using Finite Element Method (FEM). Therefore, this thesis investigates the differences between these design models and, preliminarily, the use of high-strength steel in tank shells. A 10600 m3 cylindrical steel tank of diameter 26 m and height of 21 m located in Gothenburg, Sweden is studied. The study is limited to the assessment of the stress in the shell courses due to the hydrostatic pressure from the fluid action of a filled tank, and the buckling behaviour of the shell courses of an empty tank subjected to self-weight, snow and wind loads. Particularly, models of the tank shell with a yield strength of 355 MPa are investigated in detail, while the results of the 700 MPa model are considered as preliminary study, since the material is currently not used for tank shells. An analysis of the fluid action on the tank shell courses in each of the three hand calculation models, showed that the EN 14015 model utilizes thicker courses than both Eurocodes. One benefit of the Eurocode models is that they do not limit the thickness of the shell courses, but it is still necessary to have thicker courses in the upper part of the tank in order to achieve sufficient resistance against buckling. EN 14015:2005, on the other hand, limits the minimum thickness to 6 mm for the investigated tank. Furthermore, only EN 1993-1-6 is applicable to the models with a yield strength of 700 MPa as per EN 1993-1-12 and this resulted in a uniform shell thickness of 6 mm. However, an increase in yield strength has no buckling benefits whatsoever.  Buckling is the most critical aspect as observed in this study. EN 14015 has no specific buckling calculations but uses the approach of determining the number of stiffening rings which are deemed adequate against buckling. In this study, 3 secondary stiffening rings were found to be adequate. In comparison, the results of EN 1993-4-2 are very conservative and lead to a very high and uneconomical number of stiffening rings, ranging from 30 to 52 stiffening rings depending on the reliability class. EN 1993-1-6 resulted in 6-17 stiffening rings, for reliability classes 1-3 and fabrication classes A-C. Therefore, the so-called analytical models in the Eurocodes result in a much denser spacing of stiffening rings than 14015:2005.  The buckling stresses due to the design loads were found to be lower than the yield strength of the tank shells for both hand calculation and FEM models. This means that the tank shells failed in buckling before the yield strength of the material was reached. Based on the parametric study of the EN 1993-1-6 (355 MPa) model regarding reliability class 1 and fabrication class A using FEM, the spacing of the stiffening rings can be increased up to 60 % (from 3825 mm to 6120 mm) with the variable loads also increased simultaneously up to 3.8 times before the shell buckles. Therefore, the design of future tanks using numerical analysis guarantee’s more reliability than all the aforementioned standards.  The design for buckling according to EN 14015 is only valid for a design snow load and under-pressure ≤ 1.2 KN/m2. However, according to the standard itis possible to agree to use it for larger actions or use another design model for buckling.

The study deals with mechanical characteristic of heterogeneous weld joint. The low carbon steel 22K and austenitic steel have been used as a experimetnal materials. The low carbon steel has special properties in basic condition. The sample has been evaluated in basic condition and after annealation. There have been evaluated impact of annealation proces to structure and mechanical charakteristics in experimental part of study. The particularised analysis of microstructure has been done by pictorial analysis. Mechanical characteristics has been examinated in both conditions by 2 different methods – measurment of microhardness according to Vickers and test of fracture toughness on compact tension specimens.

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Structure-property quantification of an A36 steel alloy was the focus of this study in order to calibrate and validate a plasticity-damage model. The microstructural parameters included grain size, particle size, particle number density, particle nearest neighbor distances, and percent of ferrite and pearlite. The mechanical property data focused on stress-strain behavior under different applied strain rates (0.001/s, 0.1/s, and 1000/s), different temperatures (293 K and 573 K), and different stress states (compression, tension, and torsion). Notch tension tests were also conducted to validate the plasticity-damage model. Also, failure of an A36 I-beam was examined in cyclic loads, and the crack growth rates were quantified in terms of fatigue striation data. Dynamic strain aging was observed in the stress-strain behavior giving rise to an important point that there exists a critical temperature for such behavior.

No description available.

No description available.

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No description available.