A l’heure actuelle où la préservation de notre environnement est primordiale, les constructions en béton font intervenir de plus en plus des ciments comprenant des ajouts minéraux, tels que le laitier, les cendres volantes… En effet, la production des ciments composés permet de réduire le dégagement des gaz à effets de serre et de réutiliser des déchets industriels. Les bétons formulés à base de ciment au laitier de haut-fourneau (CEM III) sont également largement utilisés suite à leur bonne résistance aux réactions alcali-silices, à la diffusion des chlorures et aux attaques sulfatiques… Cependant, certains ouvrages construits avec ce type matériau ont présenté au jeune âge des problèmes de fissuration liés à la restriction de leurs déformations différées, telles que le retrait endogène, thermique et de dessiccation. Suite à cette observation, des essais préliminaires ont été réalisés au laboratoire du service BATir de l’Université Libre de Bruxelles. Ils ont mis en avant plusieurs caractéristiques du comportement de ces matériaux :<p><p>1. Lors du suivi du retrait restreint à l’aide de l’essai à l’anneau en condition de dessiccation, le béton formulé à base de ciment au laitier de haut-fourneau a fissuré bien avant le béton formulé à base de ciment Portland.<p>2. Le retrait total en condition libre du béton formulé à base de ciment au laitier de haut-fourneau est nettement supérieur à celui du béton formulé à base de ciment Portland. Cette différence de comportement est principalement due à l’accroissement rapide et plus élevé du retrait endogène des bétons formulés à base de ciment au laitier de haut-fourneau.<p><p>Au vu de ces résultats expérimentaux, il a semblé intéressant de déterminer quel était l’impact de la déformation endogène des bétons formulés à base de ciments au laitier de haut-fourneau (CEM III) sur leur sensibilité à la fissuration. Afin de répondre à cette question, les déformations différées (retrait endogène, fluage propre en compression et en traction) au jeune âge de trois compositions de béton avec différentes teneurs en laitier (0, 42 et 71%) ont été étudiées expérimentalement en conditions libre et restreinte. Cependant, le suivi du retrait endogène libre et restreint a nécessité le développement de plusieurs dispositifs expérimentaux limitant au maximum les artefacts de mesure, tels que la TSTM (Temperature Stress Testing Machine). De plus, l’interprétation de ces résultats expérimentaux a également nécessité une caractérisation du comportement de ces matériaux à l’échelle macro- et microscopique. <p><p>Finalement, cette étude a montré que malgré une déformation endogène plus élevée, les bétons formulés à base de ciment au laitier de haut-fourneau fissurent après le béton formulé à base de ciment Portland. Ce comportement est dû à :<p>-l’impact du laitier sur la réaction d’hydratation du matériau cimentaire ;<p>-la présence d’une expansion de la matrice cimentaire des bétons formulés à base de ciment au laitier de haut-fourneau au jeune âge qui retarde l’apparition des contraintes de traction au sein du matériau ;<p>-la plus grande capacité de ces matériaux cimentaires à relaxer les contraintes de traction/<p>Today, the use of concretes with mineral additions (fly ash, slag) for civil engineering structures is spreading worldwide. Indeed, the production of blended cements is more respectful of the environment than the production of Portland cement, because it allows reducing greenhouse gas emissions and using industrial wastes. Slag cement concretes are also largely used for their good resistance to alkali-silica reactions, sulphate attacks and chloride diffusion. However, some of constructions built with slag cement concretes have exhibited cracking at early age due to their restrained deformations, such as thermal, autogenous and drying shrinkage. Following these observations, a preliminary experimental study was realized in the laboratory of BATir Department at ULB. It revealed several characteristics of the behaviour of slag cement concretes:<p>1. The study of restrained deformations under drying conditions by means of ring tests showed that the slag cement concretes seem more prone to crack than the Portland cement concretes;<p>2. The total free shrinkage for slag cement concrete is clearly larger than for Portland cement concrete. This difference of behaviour is mainly due to the fast and large increase in the autogenous deformation of the slag cement concrete.<p><p>Following these experimental results, the effect of the autogenous deformation on the cracking sensibility of slag cement concretes seemed interesting to investigate. Their deformations (autogenous deformation, compressive and tensile basic creep) have been studied at early age for three concretes characterized by different slag contents (0, 42 and 71%) under free and restrained conditions. For monitoring free and restrained autogenous deformations, several test rigs aimed at limiting artefacts were designed, like the TSTM (Temperature Stress Testing Machine). Moreover, the behaviour of these concretes was also characterized by a study at a macro- and microstructure scale.<p><p>Finally, this study shows that the slag cement concretes under sealed and fully restrained conditions crack later than the Portland cement concrete, despite the fact that they are characterized by the largest autogenous deformation. This behaviour is due to:<p>- the slag effect on the hydration reaction of cementitious material;<p>- the cement matrix expansion of the slag cement concretes at early age which delays the occurrence of tensile stresses inside the material;<p>- the largest capacity of this concrete to relax tensile stresses.<p> / Doctorat en Sciences de l'ingénieur / info:eu-repo/semantics/nonPublished

Since their inception, building materials are constantly improving. New ways to explore and improve the material's properties are constantly investigated (especially to improve the mechanical and deformation characteristics of the materials). This thesis is focused on identifying and comparing values of the modulus of elasticity of fine-grained composites. These features are compared with respect to water cement ratio, ageing and compressive strength of the investigated materials. Afterwards, the values of the modulus of elasticity are studied in the relation to the tested materials.

This diploma thesis compares impact of various high-energy grinding technologies on crystallographic and granulometric properties of portland cement. It also observes the influence of the conventional and high-speed grinding technology on the resulting physical and mechanical properties of portland cement, depending on the storage time.

[EN] The test for determining the resonance frequencies has traditionally been used to investigate the mechanical integrity of concrete cores, to assess the conformity of concrete constituents in different accelerated durability tests, and to ascertain constitutive properties such as the elastic modulus and the damping factor. This nondestructive technique has been quite appealed for evaluation of mechanical properties in all kinds of durability tests. The damage evolution is commonly assessed from the reduction of dynamic modulus which is produced as a result of any cracking process. However, the mechanical behavior of concrete is intrinsically nonlinear and hysteretic. As a result of a hysteretic stress-strain behavior, the elastic modulus is a function of the strain. In dynamic tests, the nonlinearity of the material is manifested by a decrease of the resonance frequencies, which is inversely proportional to the excitation amplitude. This phenomenon is commonly referred as fast dynamic effect. Once the dynamic excitation ceases, the material undergoes a relaxation process whereby the elastic modulus is restored to that at rest. This phenomenon is termed as slow dynamics. These phenomena (fast and slow dynamics) find their origin in the internal friction of the material. Therefore, in cement-based materials, the presence of microcracks and interfaces between its constituents plays an important role in the material nonlinearity. In the context of the assessment of concrete durability, the damage evolution is based on the increase of hysteresis, as a result of any cracking process. In this thesis three different nondestructive techniques are investigated, which use impacts for exciting the resonant frequencies. The first technique consists in determining the resonance frequencies over a range of impact forces. The technique is termed Nonlinear Impact Resonant Acoustic Spectroscopy (NIRAS). It consists in ascertaining the downward resonant frequency shift that the material undergoes upon increasing excitation amplitude. The second technique consists in investigating the nonlinear behavior by analyzing the signal corresponding to a single impact. This is, to determine the instantaneous frequency, amplitude and attenuation variations corresponding to a single impact event. This technique is termed as Nonlinear Resonant Acoustic Single Impact Spectroscopy (NSIRAS). Two techniques are proposed to extract the nonlinear behavior by analyzing the instantaneous frequency variations and attenuation over the signal ring down. The first technique consists in discretizing the frequency variation with time through a Short-Time Fourier Transform (STFT) based analysis. The second technique consists of a least-squares fit of the vibration signals to a model that considers the frequency and attenuation variations over time. The third technique used in this thesis can be used for on-site evaluation of structures. The technique is based on the Dynamic Acousto- Elastic Test (DAET). The variations of elastic modulus as derived through NIRAS and NSIRAS techniques provide an average behavior and do not allow derivation of the elastic modulus variations over one vibration cycle. Currently, DAET technique is the only one capable to investigate the entire range of nonlinear phenomena in the material. Moreover, unlike other DAET approaches, this study uses a continuous wave source as probe. The use of a continuous wave allows investigation of the relative variations of the elastic modulus, as produced by an impact. Moreover, the experimental configuration allows one-sided inspection. / [ES] El ensayo de determinación de las frecuencias de resonancia ha sido tradicionalmente empleado para determinar la integridad mecánica de testigos de hormigón, en la evaluación de la conformidad de mezclas de hormigón en diversos ensayos de durabilidad, y en la terminación de propiedades constitutivas como son el módulo elástico y el factor de amortiguamiento. Esta técnica no destructiva ha sido ampliamente apelada para la evaluación de las propiedades mecánicas en todo tipo de ensayos de durabilidad. La evolución del daño es comúnmente evaluada a partir de la reducción del módulo dinámico, producido como resultado de cualquier proceso de fisuración. Sin embargo, el comportamiento mecánico del hormigón es intrínsecamente no lineal y presenta histéresis. Como resultado de un comportamiento tensión-deformación con histéresis, el módulo elástico depende de la deformación. En ensayos dinámicos, la no linealidad del material se manifiesta por una disminución de las frecuencias de resonancia, la cual es inversamente proporcional a la amplitud de excitación. Este fenómeno es normalmente denominado como dinámica rápida. Una vez la excitación cesa, el material experimenta un proceso de relajación por el cual, el módulo elástico es restaurado a aquel en situación de reposo. Este fenómeno es denominado como dinámica lenta. Estos fenómenos ¿dinámicas rápida y lenta¿ encuentran su origen en la fricción interna del material. Por tanto, en materiales basados en cemento, la presencia de microfisuras y las interfaces entre sus constituyentes juegan un rol importante en la no linealidad mecánica del material. En el contexto de evaluación de la durabilidad del hormigón, la evolución del daño está basada en el incremento de histéresis, como resultado de cualquier proceso de fisuración. En esta tesis se investigan tres técnicas diferentes las cuales utilizan el impacto como medio de excitación de las frecuencias de resonancia. La primera técnica consiste en determinar las frecuencias de resonancia a diferentes energías de impacto. La técnica es denominada en inglés: Nonlinear Impact Resonant Acoustic Spectroscopy (NIRAS). Ésta consiste en relacionar el detrimento que el material experimenta en sus frecuencias de resonancia, con el aumento de la amplitud de la excitación. La segunda técnica consiste en investigar el comportamiento no lineal mediante el análisis de la señal correspondiente a un solo impacto. Ésta consiste en determinar las propiedades instantáneas de frecuencia, atenuación y amplitud. Esta técnica se denomina, en inglés, Nonlinear Single Impact Resonant Acoustic Spectroscopy (NSIRAS). Se proponen dos técnicas de extracción del comportamiento no lineal mediante el análisis de las variaciones instantáneas de frecuencia y atenuación. La primera técnica consiste en la discretización de la variación de la frecuencia con el tiempo, mediante un análisis basado en Short-Time Fourier Transform (STFT). La segunda técnica consiste en un ajuste por mínimos cuadrados de las señales de vibración a un modelo que considera las variaciones de frecuencia y atenuación con el tiempo. La tercera técnica empleada en esta tesis puede ser empleada para la evaluación de estructuras in situ. La técnica se trata de un ensayo acusto-elástico en régimen dinámico. En inglés Dynamic Acousto-Elastic Test (DAET). Las variaciones del módulo elástico obtenidas mediante los métodos NIRAS y NSIRAS proporcionan un comportamiento promedio y no permiten derivar las variaciones del módulo elástico en un solo ciclo de vibración. Actualmente, la técnica DAET es la única que permite investigar todo el rango de fenómenos no lineales en el material. Por otra parte, a diferencia de otras técnicas DAET, en este estudio se emplea como contraste una onda continua. El uso de una onda continua permite investigar las variaciones relativas del módulo elástico, para una señal transito / [CA] L'assaig de determinació de les freqüències de ressonància ha sigut tradicionalment empleat per a determinar la integritat mecànica de testimonis de formigó, en l'avaluació de la conformitat de mescles de formigó en diversos assajos de durabilitat, i en la terminació de propietats constitutives com són el mòdul elàstic i el factor d'amortiment. Esta tècnica no destructiva ha sigut àmpliament apel·lada per a l'avaluació de les propietats mecàniques en tot tipus d'assajos de durabilitat. L'evolució del dany és comunament avaluada a partir de la reducció del mòdul dinàmic, produït com resultat de qualsevol procés de fisuración. No obstant això, el comportament mecànic del formigó és intrínsecament no lineal i presenta histèresi. Com resultat d'un comportament tensió-deformació amb histèresi, el mòdul elàstic depén de la deformació. En assajos dinàmics, la no linealitat del material es manifesta per una disminució de les freqüències de ressonància, la qual és inversament proporcional a l'amplitud d'excitació. Este fenomen és normalment denominat com a dinàmica ràpida. Una vegada l'excitació cessa, el material experimenta un procés de relaxació pel qual, el mòdul elàstic és restaurat a aquell en situació de repòs. Este fenomen és denominat com a dinàmica lenta. Estos fenòmens --dinámicas ràpida i lenta troben el seu origen en la fricció interna del material. Per tant, en materials basats en ciment, la presència de microfissures i les interfícies entre els seus constituents juguen un rol important en la no linealitat mecànica del material. En el context d'avaluació de la durabilitat del formigó, l'evolució del dany està basada en l'increment d'histèresi, com resultat de qualsevol procés de fisuración. En esta tesi s'investiguen tres tècniques diferents les quals utilitzen l'impacte com a mitjà d'excitació de les freqüències de ressonància. La primera tècnica consistix a determinar les freqüències de ressonància a diferents energies d'impacte. La tècnica és denominada en anglés: Nonlinear Impact Resonant Acoustic Spectroscopy (NIRAS). Esta consistix a relacionar el detriment que el material experimenta en les seues freqüències de ressonància, amb l'augment de l'amplitud de l'excitació. La segona tècnica consistix a investigar el comportament no lineal per mitjà de l'anàlisi del senyal corresponent a un sol impacte. Esta consistix a determinar les propietats instantànies de freqüència, atenuació i amplitud. Esta tècnica es denomina, en anglés, Nonlinear Single Impact Resonant Acoustic Spectroscopy (NSIRAS). Es proposen dos tècniques d'extracció del comportament no lineal per mitjà de l'anàlisi de les variacions instantànies de freqüència i atenuació. La primera tècnica consistix en la discretización de la variació de la freqüència amb el temps, per mitjà d'una anàlisi basat en Short-Time Fourier Transform (STFT). La segona tècnica consistix en un ajust per mínims quadrats dels senyals de vibració a un model que considera les variacions de freqüència i atenuació amb el temps. La tercera tècnica empleada en esta tesi pot ser empleada per a l'avaluació d'estructures in situ. La tècnica es tracta d'un assaig acusto-elástico en règim dinàmic. En anglés Dynamic Acousto-Elastic Test (DAET). Les variacions del mòdul elàstic obtingudes per mitjà dels mètodes NIRAS i NSIRAS proporcionen un comportament mitjà i no permeten derivar les variacions del mòdul elàstic en un sol cicle de vibració. Actualment, la tècnica DAET és l'única que permet investigar tot el rang de fenòmens no lineals en el material. D'altra banda, a diferència d'altres tècniques DAET, en este estudi s'empra com contrast una ona contínua. L'ús d'una ona contínua permet investigar les variacions relatives del mòdul elàstic, per a un senyal transitori. A més, permet la inspecció d'elements per mitjà de l'accés per una sola cara. / Eiras Fernández, JN. (2016). Studies on nonlinear mechanical wave behavior to characterize cement based materials and its durability [Tesis doctoral]. Universitat Politècnica de València. https://doi.org/10.4995/Thesis/10251/71439 / Premios Extraordinarios de tesis doctorales

HOLCIM has various cement production plants across India. These plants struggle to produce the projected amount of cement due to electricity shortages. Although coal is abundant in India, the production thereof is in short supply. It is proposed that a thorium HTR (100 MWt) combined with a PCU (Rankine cycle) be constructed to supply a cement production plant with the required energy. The Portland cement production process is investigated and it is found that process heat integration is not feasible. The problem is that for the feasibility of this IPP to be assessed, a Rankine cycle needs to be adapted and optimised to suit the limitations and requirements of a 100 MWt thorium HTR. Advantages of the small thorium HTR (100 MWt) include: on-site construction; a naturally safe design and low energy production costs. The reactor delivers high temperature helium (750°C) at a mass flow of 38.55 kg/s. Helium re-en ters the reactor core at 250°C. Since the location of the cement production plant is unknown, both wet and dry cooling tower options are investigated. An overall average ambient temperature of India is used as input for the cooling tower calculations. EES software is used to construct a simulation model with the capability of optimising the Rankine cycle for maximum efficiency while accommodating various out of the norm input parameters. Various limitations are enforced by the simulation model. Various cycle configurations are optimised (EES) and weighed against each other. The accuracy of the EES simulation model is verified using FlowNex while the optimised cycle results are verified using Excel’s X-Steam macro. It is recommended that a wet cooling tower is implemented if possible. The 85% effective heat exchanger delivers the techno-economically optimum Rankine cycle configuration. For this combination of cooling tower and heat exchanger, it is recommended that the cycle configuration consists of one de-aerator and two closed feed heaters (one specified). After the Rankine cycle (PCU) has been designed and optimised, it is evident that the small thorium HTR (100 MWt) can supply the HOLCIM plant with the required energy. The optimum cycle configuration, as recommended, operates with a cycle efficiency of 42.4% while producing 39.867 MWe. A minimum of 10 MWe can be sold to the Indian distribution network at all times, thus generating revenue. / MIng (Mechanical Engineering), North-West University, Potchefstroom Campus, 2014

Water is an essential element for life and crucial to survival. South Africa is a semi-arid country and therefore water should be protected and managed effectively by all residents of the country. In the 1830s the Mooi River was the key reason for the Voortrekkers to establish Potchefstroom at a locality adjacent to this river. The Voortrekkers noticed the dolomitic outcroppings in the vicinity, but still opted to reside next to the river for it provided easily accessible water and fertile soil. Since the 1830s water legislation regulating the management and use of the water in the Mooi River has been amended innumerable times to bring us to the current situation of Potchefstroom’s water (mis)management by the role-players and stakeholders of the water source. As a resident of Potchefstroom, the researcher has a keen interest in the origin of the city’s water sources, the re-routing of the water from the origin to the water purification unit via the open-on-top cement canal system, and the overall management of these canals and their servitudes. In order to conduct a research study on the Mooi River’s water re-routing canals and servitudes, the following research methods were applied: The researcher performed a comprehensive literature review, conducted fieldwork, held interviews with landowners and experts in the geographical area of the Mooi River Valley, and performed statistical analyses as well as content analyses of the findings. Some of the most alarming findings include the lack of co-operative governance between water users and – authorities, and the current public management and disaster risk management challenges in the re-routing of water from Klerkskraal Dam down to the water purification plant of Potchefstroom. It is recommended that the major stakeholders of the Mooi River Valley, e.g. the disaster management centre in Potchefstroom, the Department of Water and Sanitation’s (DWS) regional offices in Potchefstroom, as well as the Tlokwe Local Municipality need to join forces for a combined effort to accomplish the overarching research objective of achieving improved cooperative municipal governance and Integrated Water Resources Management (IWRM) to eventually ensure the safe and effective re-routing of water from the Klerkskraal Dam to the Potchefstroom water purification plant. Note: Since July 2014 the Department of Water Affairs (DWA) has changed to the Department of Water and Sanitation (DWS). / MA (Public Management and Governance), North-West University, Potchefstroom Campus, 2015

HOLCIM has various cement production plants across India. These plants struggle to produce the projected amount of cement due to electricity shortages. Although coal is abundant in India, the production thereof is in short supply. It is proposed that a thorium HTR (100 MWt) combined with a PCU (Rankine cycle) be constructed to supply a cement production plant with the required energy. The Portland cement production process is investigated and it is found that process heat integration is not feasible. The problem is that for the feasibility of this IPP to be assessed, a Rankine cycle needs to be adapted and optimised to suit the limitations and requirements of a 100 MWt thorium HTR. Advantages of the small thorium HTR (100 MWt) include: on-site construction; a naturally safe design and low energy production costs. The reactor delivers high temperature helium (750°C) at a mass flow of 38.55 kg/s. Helium re-en ters the reactor core at 250°C. Since the location of the cement production plant is unknown, both wet and dry cooling tower options are investigated. An overall average ambient temperature of India is used as input for the cooling tower calculations. EES software is used to construct a simulation model with the capability of optimising the Rankine cycle for maximum efficiency while accommodating various out of the norm input parameters. Various limitations are enforced by the simulation model. Various cycle configurations are optimised (EES) and weighed against each other. The accuracy of the EES simulation model is verified using FlowNex while the optimised cycle results are verified using Excel’s X-Steam macro. It is recommended that a wet cooling tower is implemented if possible. The 85% effective heat exchanger delivers the techno-economically optimum Rankine cycle configuration. For this combination of cooling tower and heat exchanger, it is recommended that the cycle configuration consists of one de-aerator and two closed feed heaters (one specified). After the Rankine cycle (PCU) has been designed and optimised, it is evident that the small thorium HTR (100 MWt) can supply the HOLCIM plant with the required energy. The optimum cycle configuration, as recommended, operates with a cycle efficiency of 42.4% while producing 39.867 MWe. A minimum of 10 MWe can be sold to the Indian distribution network at all times, thus generating revenue. / MIng (Mechanical Engineering), North-West University, Potchefstroom Campus, 2014

Water is an essential element for life and crucial to survival. South Africa is a semi-arid country and therefore water should be protected and managed effectively by all residents of the country. In the 1830s the Mooi River was the key reason for the Voortrekkers to establish Potchefstroom at a locality adjacent to this river. The Voortrekkers noticed the dolomitic outcroppings in the vicinity, but still opted to reside next to the river for it provided easily accessible water and fertile soil. Since the 1830s water legislation regulating the management and use of the water in the Mooi River has been amended innumerable times to bring us to the current situation of Potchefstroom’s water (mis)management by the role-players and stakeholders of the water source. As a resident of Potchefstroom, the researcher has a keen interest in the origin of the city’s water sources, the re-routing of the water from the origin to the water purification unit via the open-on-top cement canal system, and the overall management of these canals and their servitudes. In order to conduct a research study on the Mooi River’s water re-routing canals and servitudes, the following research methods were applied: The researcher performed a comprehensive literature review, conducted fieldwork, held interviews with landowners and experts in the geographical area of the Mooi River Valley, and performed statistical analyses as well as content analyses of the findings. Some of the most alarming findings include the lack of co-operative governance between water users and – authorities, and the current public management and disaster risk management challenges in the re-routing of water from Klerkskraal Dam down to the water purification plant of Potchefstroom. It is recommended that the major stakeholders of the Mooi River Valley, e.g. the disaster management centre in Potchefstroom, the Department of Water and Sanitation’s (DWS) regional offices in Potchefstroom, as well as the Tlokwe Local Municipality need to join forces for a combined effort to accomplish the overarching research objective of achieving improved cooperative municipal governance and Integrated Water Resources Management (IWRM) to eventually ensure the safe and effective re-routing of water from the Klerkskraal Dam to the Potchefstroom water purification plant. Note: Since July 2014 the Department of Water Affairs (DWA) has changed to the Department of Water and Sanitation (DWS). / MA (Public Management and Governance), North-West University, Potchefstroom Campus, 2015

A period of cement hydration is one of critical in the life span of concrete structures. One of the reasons of collapse of concrete structural elements during and after construction is the error in determining the concrete characteristics at early age. Recently, non-destructive test emerged as a popular way to evaluate the properties of cement-based materials. This test offers continuous measurements of concrete properties as well as ability to monitor any changes in the current state of structural materials. In the existing research, some of these methods fail to capture well properties of the materials in the plastics stage. A new piezoelectric pulse testing device (Piezoelectric Ring Actuators Technique), (P-RAT ) was initially developed at the University of Sherbrook as a non-destructive test (NDT ) for soil. This technique is considered a completely new, versatile, advanced and accurate. The development of the new technique (P-RAT ) was done on two main bases: the first was the development of piezoelectric ring actuators set-up and the second is the development of the interpretation method. The setup is composed of two main units; emitter and receiver, and is capable of measuring shear and compression wave velocities in specimens. With this technique, many problems of pulse tests, which make interpretation of results difficult and ambiguous, were solved in soil. The P-RAT overcomes wave reflections at boundaries (end-caps and sides), sample disturbance, weak shear coupling between soil and device (interaction) as well as the fixation problems, low resonant frequency and limited input voltage of the existing device. The previous method is exploited forward to measure the hydration properties of cement-based material. To apply this test method, it is necessary to determine how the evolution of shear wave velocity can be related and sensitive to the hydration of cement-based materials. Validation of the P-RAT with four conventional test setups that can be used to monitor early setting and hydration of cement-based materials is carried out. These tests include penetration resistance to monitor initial and final setting respectively, calorimetric to monitor heat of hydration, electrical conductivity to monitor change in continuity of the pore structure and compressive strength at 24 hours. The phase one of this investigation included trial tests to investigate the possibility of employing the original setup used for soil (P-RAT ) to determine setting and hardening properties of cement-based material. Based on the results of the preliminary test, two modifications were conducted to the previous test device to fit with cement based material and to obtain adequate resonant frequency for cement-based materials. These modifications are the design of the container and changing the dimensions of the rings. The resultant version of P-RAT after the modification was referred to be as P-RAT2 . Calibration of the P-RAT2 with water specimen was undertaken using the compression wave velocity and resulted in 99.33% accuracy. One paste mixture was tested three times to determine the experimental error of the P-RAT2 . The repeatability carried out on the P-ART2 proved the ability of this setup to capture accurate results of the shear wave velocity. This relative error is limited to 9 %. A number of series of validation was performed on cement paste and mortar mixtures proportioned with various water cement ratios (w/cm ) as well as chemical admixtures. The w/cm ratio ranged between (0.35 and 0.50). The investigated chemical admixtures comprise of high-range water-reducing agent, viscosity-modifying agent, set-accelerating agent, and set-retarding agent. The presented validations examine the ability of a P-RAT2 to monitor the hydration of the cement-based materials. The hydration is characterized by setting time, heat of hydration, electrical conductivity, and compressive strength at 24 hours. The results obtained using the P-RAT2 was correlated to those obtained using the conventional tests and strength measurement. The results enable to validate the ability of P-RAT2 to accurately detect variations in the hydration of cement-based materials. In addition, the initial and final time of setting can be determined from the derivation of velocity vs. time curve. The results show that conductivity, resistivity, has a bilinear relationship to shear wave velocity. The compressive strength at 24 hours was correlated to both the shear wave velocity and shear modulus obtained using the P-RAT2 . Furthermore, analytical model was derived to estimate the w/cm in mortar mixture by measuring the shear wave velocity (V[subscript s] ) and the corresponding time (t )||Résumé : La période d'hydratation du ciment est l'une des périodes clé du cycle de vie des structures en béton. L'une des raisons de l'effondrement d'éléments structuraux en béton pendant et après la construction peut être attribuée à une détermination des caractéristiques au jeune âge erronée. Depuis quelques années, l’auscultation des structures est devenue une méthode très populaire pour évaluer les propriétés des matériaux cimentaires. Cette méthode permet d'obtenir les propriétés du béton en continue et possibilité un suivi de changements dans I'état des matériaux structuraux. Dans I'état actuel de la recherche dans ce domaine, certaines méthodes ne sont pas adéquates pour bien mesurer les propriétés des matériaux à I'état plastique. Un nouvel appareil d'essai à impulsions piezoélectriques (Piezoelectric Ring Actuators technique), (P-RAT) a initialement été développé à l’Université de Sherbrooke comme technique d'auscultation des sols. Cette technique est considérée complètement nouvelle, polyvalente, évoluée et précise. Le développement de cette nouvelle technique (P-RAT) a été effectué en deux volets : la première sole est le développement du dispositif de vérin de commande annulaire piezoélectrique et le deuxième est le développement d'une méthode d'interprétation. Le dispositif d'essai est composé de deux unités principales, un émetteur et un récepteur. Et permet de mesurer la vitesse de propagation des ondes de cisaillement et de compression. Grâce à cette technique, plusieurs des problèmes associés aux dispositifs d'essais par impulsion des ondes, qui rendent les résultats ambigus et difficiles à interpréter, ont été résolu pour les sols. Le dispositif P-RAT surmonte les problèmes de réflexion des ondes aux limites (embouts et côtés), la perturbation de l’échantillon, le couplage de cisaillement faible entre le sol et l'appareil (interaction) ainsi que les problèmes de fixation, la faible résonnance des fréquences et le voltage d'entrée limité du dispositif. La méthode décrite a été utilisée pour mesurer les propriétés d'hydratation des matériaux cimentaires. Pour pouvoir appliquer cette méthode, il faut déterminer comment l’évolution de la propagation des ondes de cisaillement peut être reliée à l'hydratation des matériaux cimentaires et être sensible à ces dernières. La validation de la méthode P-RAT est réalisée, à l'aide de quatre configurations conventionnelles que l’on peut utiliser pour faire le suivi de la prise et de l'hydratation des matériaux cimentaires. Ces essais consistent à la résistance à la pénétration afin de pouvoir déterminer la prise initiale et finale, la calorimétrie pour suivre l’evolution de la chaleur d'hydratation, la conductivité électrique pour effectuer le suivi de la structure des pores et la résistance à la compression à 24 heures. La phase 1 de l'étude comprend des essais pour évaluer la possibilité d'utiliser la configuration originale utilisée pour les sols (P-RAT) pour déterminer les propriétés de prise et de durcissement des matériaux cimentaires. Selon les résultats des essais préliminaires, deux modifications ont été effectuées à l'appareil original pour permettre son utilisation avec des matériaux cimentaires et pour obtenir une fréquence de résonnance raisonnable sur les matériaux cimentaires. Les modifications effectuées sont la conception du contenant et un changement de la dimension des anneaux. La version modifiée du P-RAT est designée P-RAT2. La calibration du P-RAT2 à l'aide d'échantillon liquide sous propagation d'ondes de compression a été menée, avec des résultats d'une précision de 99,33 %. Un mélange a été testé trois fois pour déterminer l'erreur expérimentale du P-RAT2. La répétitivité des essais sur le PART2 a démontré la capacité de cet appareil à produire des résultats de cisaillement de propagation des ondes de cisaillement très précis. L'erreur relative se limite à 9 %. Une série d'essais de validation a été menée sur des mélanges de pâte de ciment et de mortier de rapport eau/ciment variés (e/c) ainsi qu'avec des adjuvants. Le rapport e/c variait entre 0,35 et 0,50. Les adjuvants utilisés étaient des supers plastiflants (réducteur d'eau), des agents de viscosité, des agents accélérateurs de prise et des agents retardateurs de prise. Les validations présentées ont pour but de valider la capacité du P-RAT2 à suivre l'hydratation des matériaux cimentaires. L'hydratation est caractérisée par le temps de prise, la chaleur d'hydratation, la conductivité électrique et la résistance à la compression à 24 heures. Les résultats obtenus à l'aide du P-RAT2 ont été comparés à ceux obtenus à l'aide d'essais de mesure des caractéristiques physiques et de résistance traditionnels. Ces résultats permettent de valider la capacité du P-RAT2 à détecter avec précision les variations dans l'hydratation des matériaux cimentaires. De plus, le dispositif P-RAT2 peut avoir une correction avec mesure obteniez avec les appareils traditionnels. II est aussi possible de déterminer le temps de prise initial et final à l'aide d'une courbe de propagation vs le temps. Les résultats montrent que la conductivité et la résistivité ont une relation bilinéaire à la propagation des ondes de cisaillement. La résistance à la compression à 24 heures a été comparee à la fois à la propagation des ondes de cisaillement et au module de cisaillement obtenus avec le P-RAT2. De plus, un modèle analytique a été établi pour estimer le rapport e/c dans le mélange de mortier en mesurant la propagation des ondes de cisaillement (V) correspondant au temps (t).

Thesis (MScEng)--Stellenbosch University, 2011. / ENGLISH ABSTRACT: Strain hardening cement‐based composites (SHCC) are fibre‐reinforced composites designed to form multiple fine cracks under tensile and flexural load. The cracks are controlled to small widths, whereby significant toughness, or energy dissipation, is realised on the one hand, and high resistance to gas and liquid ingress is maintained on the other hand. These two physical phenomena define application fields of SHCC, i.e. for instance elements of buildings and infrastructure for enhanced earthquake resistance, and protection of steel bars under service loads which lead to crack formation. Also exploiting the potential protection offered by SHCC to existing structures, thin overlays have been applied to existing dam faces, reinforced concrete retaining walls, water channels and RC road pavements. The layers vary between 20 and 40 mm in thickness. Considering the fibre length, usually 8 or 12 mm, as well as the application method, such thin layers may have dominantly two dimensional fibre orientation, with little or no component in the layer thickness direction. While several research groups have performed uniaxial tensile tests and flexural tests on SHCC specimens, little or no information is available on SHCC response to biaxial loading, as is to be expected in road pavement repair layers, or other repair layers. This paper reports the results of biaxial testing of 20 mm thick SHCC specimens produced in such a way to have dominantly two‐dimensional fibre orientation, and another group of specimens produced by cutting from larger specimens, whereby three‐dimensional fibre orientation was preserved in the resulting 20 mm thick specimens. Biaxial tests were performed in three quadrants, i.e. compressioncompression, compression‐tension, and tension‐tension. A clear fibre orientation‐related difference in the failure patterns involves out‐of‐plane splitting under biaxial compression of specimens with twodimensional fibre orientation, at significantly lower load, as opposed to in‐plane tensile splitting of specimens containing three‐dimensional fibre orientation. / AFRIKAANSE OPSOMMING: Vervormingsverhardende sement‐gebaseerde saamgestelde materiale (SHCC) is veselversterke saamgestelde materiale wat ontwerp is om verskeie fyn krakies te vorm onder trekspanning en buig spanning. Die kraakbreedtes word beheer, waardeur betekenisvolle taaiheid verkry, of energie verlies beheer word aan die een kant, en die hoë weerstand teen die gas en die vloeistof penetrasie aan die ander kant gehandhaaf word. Hierdie twee fisiese verskynsels definieer die toepassingsvelde van SHCC, d.w.s vir byvoorbeeld elemente van geboue en infrastruktuur vir verbeterde aardbewing weerstand, en die beskerming van staal stawe onder die dienslaste wat lei vorming te kraak. By eksploitasie van die potensiële beskerming aangebied deur SHCC aan bestaande strukture, is dun oorlae op bestaande dam walle, versterkte beton keermure, water kanale en staal‐versterkte beton paaie gebruik. Die SHCC lae wissel tussen 20 en 40 mm in dikte. Met inagneming van die vesel lengte, gewoonlik 8 of 12 mm, sowel as die toepassingsmetode, kan so 'n dun lag ‘n oorheersend tweedimensionele vesel oriëntasie hê, met min of geen komponent in die rigting van die laag dikte nie. Terwyl verskeie navorsingsgroepe eenassige trektoetse en buigtoetse op SHCC monsters gedoen het; is daar min of geen inligting beskikbaar op SHCC se reaksie op biaksiale belasting, soos verwag kan word in die pad herstel lae, of ander herstel lae. Hierdie verslag rapporteer die resultate van die biaksiale toetsing van 20 mm dik SHCC monsters wat op so 'n manier gemaak word om dominante twee‐dimensionele vesel oriëntasie te hê, en 'n ander groep monsters wat deur die sny van groter monsters, waarvolgens die drie‐dimensionele vesel oriëntasie verseker is. Biaksiale toetse is uitgevoer in drie kwadrante, d.w.s druk‐druk, druk‐trek en trek‐trek. 'n Duidelike verskil in die falingspatrone, aan die hand van vesel oriëntasie, behels uit‐vlak splyting onder biaksiale toetsing van monsters met twee‐dimensionele vesel oriëntasie, op 'n aansienlik laer lading, in teenstelling met die in‐vlak trek splyting van monsters wat ‘n drie‐dimensionele vesel oriëntasie het.