<p>The risk for climate change is a growing concern for theglobal society. According to what is known as the Kyoto Protocol,developed countries have committed themselves to reduce theirgreenhouse gas (GHG) emissions. The purpose of this thesis hasbeen to analyse opportunities for CO2 reductions in Swedish pulpand paper mills. The pulp and paper industry accounts forsignificant shares of the Swedish utilisationof both electricityand, in particular, biomass fuels. In this thesis, it has been agoal to focus not only on the technical potential of alternativesfor CO2 reductions in the energy systems of pulp and paper mills,but also on analysing the costeffectiveness of the studiedmeasures. Moreover, the analysis has covered questions concerningthe capacity and willingness among the actors involved with thepulp and paper mills’energy systems to realise CO2reduction potentials.</p><p>A broad techno-economical evaluation of available technologiesfor increased power production as well as more efficient energyutilisation is carried out. Furthermore, a more indepth analysisof pulp mill-based biomass energy with CO2 removal and permanentsequestration (BECS) is presented. An evaluation is made of thepotential for pulp and paper production with a negative CO2balance through the implementation of BECS. In recent yearsoutside suppliers, mainly energy service companies (ESCOs), havebegun to operate energy facilities in some Swedish pulp and papermills. Based on interviews with managers from pulp and papercompanies and ESCOs, the main driving forces behind theincreasing co-operation as well as the opportunities and riskswith energy related co-operation are presented.</p><p>Furthermore, the technical possibility of carbon-negativitythrough the implementation of BECS is discussed in relation tocarbon management on both corporate and global levels. The extentto which CO2-reducing measures in pulp and paper mills arerealised will have an impact on Sweden’s capacity to reachCO2 reduction targets. Whether or not technologies for CO2capture and sequestration are developed and implemented inSwedish pulp mills has a very large impact on the size ofSweden’s long-term CO2 reduction potential. Moreover, thedevelopment of business and competence focus in pulp and papercompanies and ESCOs suggests that cooperation will become ofincreasing importance for future sustainable industrial energymanagement.</p><p><b>Keywords:</b>CO2 reduction, pulp and paper industry, energysystem, biomass, CO2 capture and sequestration, black liquor,gasification, power production, outsourcing, sustainable energymanagement</p>

<p>In this thesis, size-exclusion chromatography (SEC) of woodpolymers dissolved in lithium chloride/N,N-dimethylacetamide(LiCl/DMAc) has been used to characterize the molar massdistributions (MMD) of wood polymers in pulp fibers afterchemical degradation.</p><p>Characterization of birch kraft pulps subjected to ozonedegradation and acid hydrolysis, respectively, rendereddifferent changes in the MMD. Ozone degradation resulted inlarge redistributions of the original MMD, observed as thedevelopment of a distinct fraction of cellulose withintermediate molar mass. Acid hydrolysis resulted in minorchanges of the original MMD compared to ozonation. Fiberssubjected to acid hydrolysis were considerably weaker thanozonated fibers. These results indicated that there aredifferences in how the two chemicals degrade the fiber.</p><p>The solubility of softwood kraft pulp fibers was enhanced byderivatization of the fiber polymers with ethyl-isocyanateduring simultaneous dissolution in LiCl/DMAc. Thederivatization made it possible to achieve reliable estimationsof the MMD, and hence molar masses, of softwood kraft pulps.The derivatization procedure made it possible to dissolve 90 %of softwood kraft pulps with kappa numbers over 50.</p><p>Severe alkaline degradation of birch and Norway spruce woodchips was studied both by varying the pulping time and byvarying the initial alkali concentration. Differences werefound in the MMD of the two fiber types, and the alkalinedegradation was found to affect polymers in the entire MMD.</p><p>Multi-angular laser light scattering (MALLS) was used as adetection technique with SEC on cellulosic samples. The MMD andaverage molar masses obtained through directstandardcalibration with commercial standards were compared with MMDand molar masses as obtained by MALLS-detection. Largediscrepancies were found, and two methods of correcting forthese discrepancies were developed.</p><p>Theoretical simulations of polymer degradation wereperformed. Random, or homogeneous degradation was used as amodel for alkaline cellulose chain scission, and a resemblancewith experimental data was observed. End-wise depolymerizationof cellulose was also simulated and the results are discussedin the light of experimentally observed MMD.</p><p><b>Keywords:</b>cellulose, kraft pulp, birch, spruce,ozonation, acid hydrolysis, degradation, MMD, sizeexclusionchromatography, light scattering, molar mass, chainscission</p>

<p>Cellulosans tillgänglighet och reaktivitet är nyckelparametrar vid framställning av regenererad cellulosa och cellulosaderivat. Det är välkänt att på grund av cellulosans kristallina struktur är tillgängligheten begränsad för lösningsmedel och olika reagens. Till exempel kan en inhomogen substitution av hydroxylgrupperna i cellulosakedjan resultera i cellulosaderivat av sämre kvalitet. Baserat på detta har en del av arbetet i denna studie fokuserat på att förbättra cellulosans tillgänglighet och reaktivitet genom att studera effekten av olika enzymatiska behandlingar med monokomponent endoglukanaser. Resultaten visar att närvaron av en cellulosabindande domän fyller en viktig funktion för att öka cellulosans reaktivitet, men strukturen för den katalytiska domänen visade sig ha den största inverkan på cellulosans tillgänglighet. I kompletterande studier har även effekten av en mekanisk förbehandling i kombination med enzymatisk behandling utvärderats. Kombinationen av förbehandlingarna resulterade i en positiv effekt, cellulosans reaktivitet kunde ökas i större omfattning.</p><p>I dag används huvudsakligen dissolvingmassor som råvara vid framställning av cellulosaregenerat och cellulosaderivat. Kraven för dessa s.k. specialmassor är högt cellulosainnehåll samt lågt hemicellulosa- respektive lignininnehåll. På grund av dessa specifika krav är produktionskostnaderna för dessa massor högre än konventionella sulfatmassor. Den andra delen av studien har därför fokuserat på möjligheten att använda dessa sulfatmassor som dissolvingmassa. Det har visats att kombinationen av enzymatiska behandlingar med monokomponent endoglukanas och xylanas följt av ett alkaliskt steg kan resultera i massor där kraven uppfylls med avseende på cellulosans reaktivitet, och cellulosa- respektive hemicellulosainnehåll.</p> / <p>The accessibility and reactivity of cellulose are key parameters on the manufacturing of cellulose derivatives and regenerated cellulose. It is well known that, due to the crystalline structure of cellulose, the accessibility of solvents and reagents is limited. For instance, an inhomogeneous substitution of the hydroxyl groups of the cellulose chain might lead to the production of derivatives of low quality. As a consequence, part of this work has focused on improving the accessibility and reactivity on cellulose by studying the effect of different monocomponent endoglucanases. It has been demonstrated that the presence of the cellulose-binding domain plays an important role on the enhancement of cellulose reactivity; however, the structure of the catalytic domain has been showed to have the highest influence on this parameter. Furthermore, the influence of mechanical treatment prior to enzymatic treatment has been examined. The combination of pretreatments showed a positive effect enhancing to a larger extent the cellulose reactivity.</p><p>Currently, dissolving-grade pulps are commonly used for the production of cellulose derivatives and regenerated cellulose. The requirements for these so-called “special pulps” are a high cellulose content and a low hemicelluloses and lignin content. As a result of these specific demands, the production costs of these pulps are higher than those of common kraft pulps. The second part of this work, therefore, has been focused on the study on the viability of converting kraft pulps into dissolving pulps. It has been demonstrated that the combination of enzymatic treatments using a monocomponent endoglucanase and a xylanase together with the addition of an alkaline step could fulfil the requirements of a commercial dissolving pulp in terms of cellulose reactivity and cellulose and hemicellulose content.</p>

Thesis (M.S.)--West Virginia University, 2002. / AH26 is a registered trademark. Title from document title page. Document formatted into pages; contains vii, 55 p. : ill. (some col.). Includes a video file in the AVI format. Vita. Includes abstract. Includes bibliographical references (p. 48-53).

Diss. (sammanfattning) Uppsala : Sveriges lantbruksuniv., 2009. / Härtill 5 uppsatser.

Στην Ελλάδα γενικά, αλλά και στο Νομό Αχαΐας ειδικότερα, υπάρχουν αρκετές μονάδες παραγωγής χάρτου. Αρκετές από αυτές δεν βρίσκονται εντός των ορίων Βιομηχανικών Περιοχών (ΒΙ.ΠΕ.), με συνέπεια τα ακατέργαστα απόβλητά τους να συμβάλλουν σημαντικά στη ρύπανση του περιβάλλοντος. Το μεγαλύτερο περιβαλλοντικό πρόβλημα που προκαλείται από τις συγκεκριμένες μονάδες είναι η εναπόθεση μεγάλων ποσοτήτων υγρών ακατέργαστων αποβλήτων κυρίως στα υδάτινα οικοσυστήματα. Τα απόβλητα αυτά περιέχουν μεγάλο οργανικό φορτίο, οργανοαλογονωμένες ενώσεις, υψηλά επίπεδα αιωρούμενων στερεών , φαινολών και λιγνινών, με αποτέλεσμα να προκαλούν δυσμενείς επιπτώσεις στους υδάτινους αποδέκτες, όπως τοξικότητα στους υδρόβιους οργανισμούς, ευτροφισμό και άνοδο της θερμοκρασίας. Η παρούσα μελέτη έχει ως βασικό σκοπό την εκτίμηση της τοξικότητας των αποβλήτων δυο μονάδων παραγωγής χάρτου, εγκατεστημένων στην ΒΙ.ΠΕ. Πατρών, με τη χρήση βιοδεικτών. Ως βιοδείκτες χρησιμοποιήθηκαν τόσο ψάρια του γλυκού νερού (πέστροφες του είδους Oncorhynchus mykiss), όσο και μακροασπόνδυλα (των ειδών Daphnia pulex και Thamnocephalus platyurus) με τη μορφή των μικροβιοτέστ Thamnotoxkit F και Daphtoxkit FTM pulex. Συνολικά ελήφθησαν 16 δείγματα (τέσσερα διπλά δείγματα από την κάθε μονάδα). Στα τεστ τοξικότητας που εφαρμόστηκαν (Thamnotoxkit F, Daphtoxkit FTM pulex και πέστροφες), υπολογίσθηκαν τα L(Ε)C50 24h, 48h και 96h αντίστοιχα σύμφωνα με τα πρωτόκολλα εργασίας. Για το μικροβιοτέστ Thamnotoxkit F, τα απόβλητα και από τις δυο μονάδες δεν ήταν τοξικά. Μετά από την μετατροπή των τιμών αυτών σε τοξικές μονάδες, ευρέθη ότι στο Daphtoxkit FTM pulex κυμαίνονταν από 0,79 εώς 1,12 για την ΜΠΧ1 και 1,21 έως 1,38 για την ΜΠΧ2, ενώ στις πέστροφες μεταξύ 2,92 και 4,85 για την ΜΠΧ2. Τα απόβλητα της ΜΠΧ1 δεν ήταν τοξικά για την πέστροφα. Οι τιμές αυτές και για τους τρεις ελέγχους κατατάσσουν τα απόβλητα ως «τοξικά», εκτός από το δείγμα Β της ΜΠΧ1 που ταξινομείται ως «ελαφρά τοξικό». Τα προαναφερθέντα αποδεικνύουν ότι η μονάδα παραγωγής χάρτου με πρώτη ύλη ανακυκλωμένο χαρτί (ΜΠΧ2) είναι σε κάθε περίπτωση πιο τοξική από εκείνη που παράγει χαρτί από καθαρό χαρτοπολτό (ΜΠΧ1). Τέλος, θα πρέπει να σημειωθεί ότι η παρούσα μελέτη είναι η πρώτη μελέτη εκτίμησης της τοξικότητας με βιοδείκτες των αποβλήτων μονάδων παραγωγής χάρτου που γίνεται στη χώρα μας, παρ’ ότι αυτά συμμετέχουν στην επιβάρυνση του περιβάλλοντος. Εκτιμάται ότι τα στοιχεία τοξικότητας που παρατίθενται στη παρούσα εργασία θα είναι χρήσιμα τόσο για την εκπόνηση διαχειριστικών μοντέλων, όσο και μοντέλων εκτίμησης της επικινδυνότητάς τους (risk assessment). / In Greece in general and subsequently in the Achaias Prefecture, several units of paper production exist. Many of them are not located in Industrial Areas and so they contribute significantly to the environmental pollution. The most adverse environmental problem caused by these manufacturing units, is considered to be the release of large quantities of raw liquid effluents, mainly into the aquatic ecosystems. These wastes contain a high organic load, chlorinated compounds (AOCl), high levels of suspended solids, as well as phenols and lignins resulting in hazardous effects on aquatic receivers, like toxicity and eutrophication. In this study, the toxicity of the wastewaters from two paper mills (PM1 and PM2) located in Achaias prefecture is estimated, firstly by using macroinvertebrates (Daphnia pulex και Thamnocephalus platyurus) in the form of microbiotests Thamnotoxkit F and Daphtoxkit FTM pulex, and secondly by using the trout (Onchorynchus mykiss) as a test organism. Sixteen samples were collected from both units overall (four duplicated samples from each mill). In the toxicity tests Thamnotoxkit F, Daphtoxkit FTM pulex and trout, the L(E)C50 in 24, 48 and 96 hours respectively were calculated according to the protocols. Thamnotoxkit F showed no sensitivity for the wastewaters from both mills. After the transformation of these values in toxic units, for Daphtoxkit FTM pulex ranged from 0,79 - 1,12 for PM1 and 1,21 - 1,38 for PM2. In the trout bioassay they varied from 2,92 - 4,85 for PM2, while the values for PM1 were zero. These values classify the tested paper mill effluents as “toxic”, except sample B from PM1 which was classified as “slightly toxic”. Therefore, it is shown that the paper mill which uses recycled paper as primary raw material (PM2) has more toxic waste for the environment than the paper mill which uses pre-treated paper pulp (PM1). Finally, it must be noted that the present study is the first toxicity evaluation study with bioindicators for paper mill wastewaters in our country, even though they contribute significantly to the environmental pollution. It is estimated that the measured toxicity parameters in the present study will be very useful for the designing of management plans, as well as for risk assessment models.

Phylogenetic hybridization and phenotypic fingerprinting were applied to the analysis of bacterial communities in wastewater treatment systems. These approaches were aimed at (i) developing monitoring tools able to foresee operational problems, and (ii) providing the rationale to optimize the operation of bioreactors. The work presented is intended to first describe the community found in two reactors treating pulp and paper mill effluent, and second evaluate the possibilities of these techniques with respect to the development of new monitoring tools. / Phylogenetic membrane hybridization showed that the bacterial communities were dominated by Alpha and Beta Proteobacteria, a structure probably linked to the low F:M ratio. Other important factors determining the community structure were the proportion of COD in the high molecular weight fraction, the sludge age, phosphate addition, and the concentration of specific compounds (alcohols, phenols, volatile fatty acids) in the influent. The community structure partly determined the sludge characteristics demonstrating its potential value in the assessment of reactor performance. The results obtained by phylogenetic membrane hybridization suggest that the probes used in a monitoring tool would not need to be targeted to the species level to provide relevant information. However, they also suggest that the technique is more sensitive to changes in population density as opposed to changes in bacterial metabolism. / Phenotypic fingerprinting measured a smaller difference between the communities of the two reactors studied than what was measured by phylogenetic membrane hybridization. However, differences in heterotrophic activities observed between the two communities were linked to differences in influent composition.

Sappi is one of the leading producer and supplier of Eucalyptus pulp to the world market. It is also a great contributor to South Africa economy in terms of employment opportunity to the rural people through its large plantation and export earnings. Pulp mills production of quality wood pulp is mainly affected by the supply of non uniform raw material namely Eucalyptus tree supply from various plantations. Improvement in quality of the pulp depends directly on the improvement on the quality of the raw materials. Knowing factors which affect the pulp quality is important for tree breeders. Thus, the main objective of this research is first to determine which of the anatomical, chemical and pulp properties of wood are significant factors that affect pulp properties namely viscosity, brightness and yield. Secondly the study will also investigate the effect of the difference in plantation location and site quality, trees age and species type difference on viscosity, brightness and yield of wood pulp. In order to meet the above mentioned objectives, data for this research was obtained from Sappi’s P186 trial and other two published reports from the Council for Scientific and Industrial Research (CSIR). Principal component analysis, cluster analysis, multiple regression analysis and multivariate linear regression analysis were used. These statistical analysis methods were used to carry out mean comparison of pulp quality measurements based on viscosity, brightness and yield of trees of different age, location, site quality and hybrid type and the results indicate that these four factors (age, location, site quality and hybrid type) and some anatomical and chemical measurements (fibre lumen diameter, kappa number, total hemicelluloses and total lignin) have significant effect on pulp quality measurements. / Thesis (M.Sc.)-University of KwaZulu-Natal, Pietermaritzburg, 2010.

In North America, deepening economic integration under free trade has led to the formation of several cross-border regions between Canada and the United States and such regions have become a significant focus for public policy research in Canada. A key question is whether, as a result of increased economic integration, there are tendencies towards policy and institutional convergence within cross-border regions; especially in areas viewed as critical in determining competitive economic advantage. One such area is employment relations. However, relatively little research has focused on how, or even if, employment relations are changing within cross-border regions. Previous studies comparing differences and similarities in employment relations between Canada and the United States have tended to focus on one of three scales: the nation, the firm, or the individual workplace. Here, the focus is on employment relations within a cross-border region. Such regions often share similar economic and social characteristics. Thus, we might expect that if cross-national employment relations are becoming more similar due to deepening economic integration this would manifest most clearly at this scale. The empirical focus is the forest products industry in the cross-border region of Cascadia, comprised of British Columbia, Washington state, and Oregon. Employment relations are compared across three components of the forest products industry: pulp and paper, solid wood processing, and logging. Data are organized around case studies of each component and focus on employment, wages, and productivity; the restructuring of firms and ownership; the labour movement; work practices, training, and the reproduction of the labour force. The dissertation concludes that employment relations in the pulp and paper and logging industries in Cascadia are becoming more similar cross-nationally, while those in solid wood processing are increasingly differentiated cross-nationally. Moreover, it concludes that employment relations in British Columbia’s solid wood processing and pulp and paper industry are becoming more similar, while employment relations in the PNW solid wood processing and pulp and paper industries are increasingly differentiated. The dissertation contributes to broader debates in economic geography by examining the tensions between national and sub-national political economic actors contribute to the production of scale and territory. / Thesis (Ph.D, Geography) -- Queen's University, 2010-05-28 11:48:30.745

<p>&nbsp / </p> <p align="left">The domesticated apple (<i><font face="TimesNewRomanPS-ItalicMT">Malus </font><font face="TimesNewRomanPSMT">x </font><i><font face="TimesNewRomanPS-ItalicMT">domestica </font><font face="TimesNewRomanPSMT">Borkh.), belonging to the </font><i><font face="TimesNewRomanPS-ItalicMT">Malus </font><font face="TimesNewRomanPSMT">genus of the Rosaceae family, is one of the edible pomaceous fruits. Since it is one of the important commercial fruit crops worldwide, the quality of the fruit is crucial to breeders and farmers as it ultimately determines acceptance of a cultivar for consumption. Fruit quality is also a critical determinant factor that is used to estimate the potential of apples to have a long shelf life. The introduction of marker-assisted selection (MAS) has allowed hastening of traditional breeding and selection of high-quality apple cultivars. The availability of genetic linkage maps, constructed by positioning molecular markers throughout the apple genome, enables the detection and analysis of major genes and quantitative trait loci (QTLs) contributing to the quality traits of a given genotype.&nbsp / herefore, the primary aim of this study was to construct a genetic linkage map of the &lsquo / Golden Delicious&rsquo / x &lsquo / Dietrich&rsquo / population for the identification of QTLs associated with fruit quality traits and then to examine the apple fruit pulp proteome with a specific focus on fruit firmness. In this regard, genomic DNA was extracted from leaves of the &lsquo / Golden Delicious&rsquo / x Dietrich&rsquo / population and used in megaplex PCR reactions. The PCR products were analysed prior to scoring of alleles. Polymorphic markers were then used to construct genetic linkage maps. The genetic linkage maps constructed in this study comprise of 167 simple sequence repeats (SSR) markers, 33 of these were newly developed markers. The 17 linkage groups of apple were constructed and aligned to existing apple genetic maps. The maps span 1,437.8 cM and 1,491.5 cM for &lsquo / Golden Delicious&rsquo / and &lsquo / Dietrich&rsquo / , respectively.</font></i></i></i></p>