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Att ha ständig tillgång till ett hälsosamt, rent och gärna gott dricksvatten tas idag ofta som självklart av många människor i Sverige. Sveriges sammanlagda nybildning av vatten innebär idag inga problem för dricksvattenförsörjningen om man bortser från ojämn fördelning av vattentillgångar samt lokala kvalitetsproblem. Många områden förses med dricksvatten från något av landets omkring 2000 vattenverk. En del får sitt vatten från enskilda brunnar, medan vissa har löst vattenfrågan tillsammans med andra i samfälligheter. Vissa samfälligheter som inte har någon egen vattentäkt kan ibland förses med vatten från ett allmänt distributionsnät. I Vaxholms kommun finns nära ett 30-tal samfälligheter som får sitt vatten från Görvälnverket i Järfälla kommun vilket ägs och drivs av kommunalförbundet Norrvatten AB. Behandlat dricksvatten distribueras vidare av Norrvatten AB. I Vaxholms kommun är Vaxholmsvatten AB/ Roslagsvatten AB VA-huvudman och förvaltar kommunens allmänna VA-anläggning. Roslagsvatten AB levererar vatten till vattenkonsumenter som är anslutna till det allmänna VA-nätet i Vaxholms kommun, men bolaget levererar även dricksvatten till nämnda samfälligheter. Vattenverket behandlar (renar) det så kallade råvattnet från vattentäkten (i detta fall Mälaren) för att åstadkomma ett kvalitetsmässigt bra dricksvatten sett ur såväl kemisk som ur mikrobiologisk synvinkel. Kan då dricksvattensamfälligheterna slå sig till ro med att de har ett dricksvatten av god kvalitet? SRMH bedriver kontroll och tillsyn av dricksvattensamfälligheterna och deras distributionsanläggningar. SRMH har gjort sina första pilotinspektioner hos samfälligheterna och uppmärksammat ett antal förmodade brister med vissa rutiner och installationer. I forskningsfältet kring distributionsanläggningar för dricksvatten studeras bland annat faktorer som påverkar mikrobiologisk förekomst och tillväxt i distributionsanläggningar. Mot bakgrund av utvalda delar ur detta forskningsfält har jag skapat ett analytiskt ramverk för att söka värdera mikrobiologiska risker i samfälligheternas distributionsanläggningar. Förutom detta görs några typer av mikrobiologiska analyser för att jämföra med uppskattad risk. Förutom protokoll från SRMH:s inspektioner av samfälligheterna görs små intervjuer av vattenkonsumenter och samfällighetsansvariga. För att se var eventuella kvalitetsproblem uppstår används sekundärdata från Norrvatten som beskriver kvalitet efter vattenverkets behandling och kvalitet vid ett vattentorn på ”halva vägen” samt vid en referenspunkt i Vaxholm. Relevant dricksvattenjuridik studeras också för att ta reda på vem som ansvarar för vad samt för att se vilka kvalitetskrav som är relevanta avseende samfälligheterna. Resultatet antyder försiktigt att riskerna men även vattentemperaturen samt den mikrobiologiska vattenkvaliteten (odlingsbara mikroorganismer) i undersökningen till viss del skiljer mellan olika typer av samfälligheter. För samfälligheter med året-runt-vatten verkar problemen vara mindre, medan för samfälligheter som endast har sommarvatten verkar det finnas fler risker. Det senare verkar även gälla för samfälligheter där fritidsbostäder ingår. Skillnader i antal långsamväxande mikroorganismer mellan olika samfällighetstyper är dock mer osäkra. Kvalitetsreglerna avseende mikrobiologi i samfällighetsnätet och i det allmänna nätet styrs av livsmedelsverkets föreskrifter och EU:s dricksvattendirektiv och alla parter måste försäkra sig om att kvalitetskraven uppfylls inom respektive distributionsnät. Återströmning av vatten från samfälligheter till den allmänna distributionsanläggningen verkar inte kunna regleras av lagen om allmänna vattentjänster och därmed ej heller av det lokala regelverket ABVA för Vaxholm. Enligt min tolkning av regelverket är respektive ägare av distributionsnäten ansvariga för om kvaliteten påverkas i det egna nätet när/om återströmning sker från mottagande part. I diskussionsdelen görs även jämförelser avseende temperatur och mikrobiologiska parametrar mellan de olika typerna av studerade samfälligheter och Norrvattens perifera kommuner för att se om det finns några skillnader. / Continuous access to healthy, clean and good-tasting drinking-water is perceived as obvious for many people in Sweden. The total regeneration of water is currently not a problem in Sweden if uneven distribution and local quality problems are not accounted for. Many regions are supplied with drinking water from one of Sweden’s around 2000 water treatment plants. Other water consumers get their water from private wells, while others get water access via community-owned distribution systems. Sometimes communities that do not have their own water supply can get water supply through a public distribution system. In the municipality of Vaxholm almost 30 small communities get their water from the water treatment plant (WTP) Görvälnverket, which is owned and operated by a municipal association called Norrvatten AB. Norrvatten AB redistributes the treated drinking water. In Vaxholm, Roslagsvatten AB is the legal principal of water and sewage. Roslagsvatten AB distributes water to water consumers in the municipality of Vaxholm. The WTP treats (purifies) the surface water from the water source (in this case Mälaren) in order to provide a good quality drinking water seen from both a chemical and microbiological point of view. Under these circumstances, could the water communities be complacent that they have a good quality drinking water? Södra Roslagens Miljö- och hälsoskyddskontor (SRMH) is the local health protection agency responsible for control and enforcement of drinking water communities in Vaxholm. After having performed pilot inspections at the water communities, SRMH drew attention to some assumed risks and deficiencies with routines and water pipe installations. In the drinking water distribution systems research field, factors influencing microbiological presence and growth are investigated. In the view of selected portions from this research field, I have created an analytical framework to be able to evaluate some kind of microbiological risks in the communities’ water distribution systems. Besides this, some microbiological analyzes are made to compare with assessed risk. In addition to studied protocols from inspections of the communities, some minor interviews are made with water consumers and persons responsible for plumbing in the communities. To assess whether potential quality problems occur, secondary historical quality analysis data from Norrvatten AB is used. Quality data from directly after treatment at the WTP, from a water tower “halfway” to Vaxholm, and from a reference location in Vaxholm is used. Swedish and European Union legal framework of relevance regarding drinking water is studied to find out relevant legal quality requirements with regards to the communities. The result gently suggests that identified risks but also water temperature and investigated microbiological quality (culturable microorganisms; HPC counts, 22 °C, 3 days) in the study to some extent differ between different types of communities. For communities with full-year water supply, the problems seem to be less. On the contrary, for communities with supply only during summer, problems seem to be greater. Problems also seem to exist for communities where holiday residences exist. Differences in the number of slower growing microorganisms (HPC counts, 22 °C, 7 days) between community types is more uncertain. The microbiological quality of drinking water is regulated by Swedish national regulations and by European Union’s drinking water directive. All parties must ensure that quality standards are met in each distribution network. Backflow of water from communities’ distribution networks does not seem to be regulated by the Swedish law on public water services and thus neither by the local regulatory called “ABVA” for Vaxholm. According to my interpretation of the regulations, the respective owners of the distribution networks are responsible for if quality is adversely affected in its own network if backflow occurs from the receiving party. In the discussions chapter, temperature and HPC counts are compared between studied communities and Norrvatten’s peripheral municipalities to assess if differences exist.

Water quality was one of the biggest problems of environment in beginning of 90. of 20th century in the Czech republic. Since 90. the level of water quality was in czech rivers rapidly better. Mainly in big rivers have accomplished great changes. The small rivers haven't notice that rapid changes. The Czech republic, after entrance to the European Union have committed to comply with Directive 91/271/EEC reduce urban waste water and which should have big influence to water quality also in small rivers. During 90. industry technology, agriculture, cleaning technology of waste water etc. reached big development. Therefore the presumption is higher quality of water in the Czech republic since 90. Goal of the thesis is comparison of results from 1999-2000 with results from 2012- 2014 from Mladoticky brook catchment, which is lined up to small river catchments (79,77km2 ). From this comparison there is obvious trend, if conditions of the water quality are really better or not since 90. [33] Since 2012 to 2014 were taken 12 times samples from 11 profiles of water from Mladotice brook catchment and they were consequential chemically analyzed. The samples were evaluated according to ČSN 757221 and compared with results from 1999-2000. From comparison with data 1999-2000 and 2012-2014 was confirmed the...

This study deals with the association of trace elements with colloids and particles in surface waters and groundwaters of mining and smelting district of Příbram. Colloids were studied using combination of cascade filtration a tangential flow ultrafiltration method to separate individual colloid fractions. Colloids were separated by filtration membranes with nominal pore size 0,8 μm, 0,45 μm, 0,1 μm, 100 kDa, and 5 kDa. Water samples were analyzed using ICP-OES, ICP-MS and HPLC. The data were used for thermodynamic modeling using PHREEQC-2 programme. The results show that major and trace elements can be divided into several groups, based on their abundance in individual size fractions. Most elements dominate in fraction of truly dissolved matter as dissociated ions (< 5 kDa), maximum concentration in colloid fraction is 5-20 % and almost exclusively in fraction 5 kDa - 100 kDa. Gradual decrease of concentration in all fractions at low ionic strength (1,2 mmol/l) was observed in case of elements such as As, Co, Cr, Si, Sb and U. Gradual decrease of concentration in several samples was observed for Cd, Fe, Pb, Mn and Zn. Dominant binding to colloids and particles in surface waters was observed for Fe and Pb, where these fractions accounted for over 90 %. The main factor influencing colloid...

Thesis (M. Tech. - Dept. of Chemistry, Faculty of Applied and Computer Sciences) -- Vaal University of Technology, 2010 / The increased production and application of pesticides for agricultural and non-agricultural purposes has caused the pollution of air, soil, ground and surface water. This has a negative impact on the environment as well as human health due to direct exposure or through residues in food and drinking water. The continuous monitoring of pesticides residues in environmental samples has great importance and demands high efficiency, unique selectivity and high sensitivity techniques. Gas chromatography and high performance liquid chromatography have been established for years as the techniques for the analysis of pesticides residues. The dissertation deals with the qualitative and quantitative determination of selected pesticides in the Southern Gauteng region using Liquid- liquid extraction solid-phase extraction, high performance liquid chromatography, gas chromatography equipped with electron capture detector and gas chromatography mass spectrometry. Liquid-liquid extraction and solid-phase extraction using dichloromethane, hexane and ethyl acetate as the extracting solvent were optimized and evaluated for the determination of pesticides in surface water in the Southern Gauteng region. From the developed method the techniques were applied to water samples taken from different rivers selected namely: Zuikerbosch, Rand Water barrage and Kliprivier for sampling. Dichloromethane was used as a solvent in this study since a recovery test was done between dichloromethane, Ethyl acetate and n-hexane. The percentage recovery test for 4,4-DDT, 4,4-DDE, 2,4-DDD and Endosulfan 1 & 2 ranged from 89.9% -97.3% for dichloromethane, 87.3%-96.8% for hexane 88.4%-97.1% for ethyl acetate. The extracts obtained were subjected to column chromatography for clean up. Thereafter 1µl of the cleaned extracts were injected into the Gas chromatography equipped with an electron capture detector. Organochlorines 4,4-DDT and its metabolites, Organophosphate Chlorypyriphos and carbamates were detected using Gas chromatography electron capture, Gas chromatography mass spectrometry and high performance liquid chromatography.

Thesis (M. Tech. - (Civil Engineering, Faculty of Engineering and Technology))--Vaal University of Technology, 2010. / During the last few years, concern has been growing among many stakeholders all over the world about declining levels of surface water bodies accompanied by reduced water availability predominantly due to ever increasing demand and misuse. Furthermore, overexploitation of environmental resources and haphazard dumping of waste has made the little water remaining to be so contaminated that a dedicated rehabilitation/remediation of the environment is the only proactive way forward. River Rwizi Catchment is an environment in the focus of this statement. The overall objective of this research was to plan, restore and rationally allocate the water resources in any river basin with similar attributes to the study area. In this research, Integrated Water Resources Management (IWRM) methodology was applied through Watershed/Basin Simulation Models for general river basins. The model chosen and used after subjection to several criteria was DHI Model, MIKE BASIN 2009 Version. It was then appropriately developed through calibration on data from the study catchment, input data formatting and its adaptation to the catchment characteristics. The methodology involved using spatio-temporal demographic and hydrometeorological data. It was established that the model can be used to predict the impact of projects on the already existing enviro-hydrological system while assigning priority to water users and usage as would be deemed necessary, which is a significant procedure in IWRM-based environmental rehabilitation/remediation. The setback was that the available records from the various offices visited had a lot of data gaps that would affect the degree of accuracy of the output. These gaps were appropriately infilled and gave an overall output that was adequate for inferences made therefrom. Several scenarios tested included; use and abstraction for the present river situation, the effect of wet/dry seasons on the resultant water available for use, and proposed projects being constructed on and along the river. Results indicated that the river had insufficient flow to sustain both the current and proposed water users. It was concluded that irrespective of over exploitation, lack of adequate rainfall was not a reason for the low discharge but rather the loss of rainwater as evaporation, storage in swamps/wetlands, and a considerable amount of water recharging groundwater aquifers. Thus, the proposed remedy is to increase the exploitation of the groundwater resource in the area and reduce the number of direct river water users, improve farming methods and conjunctive use of groundwater and surface water - the latter as a dam on River Rwizi. The advantage of the dam is that the water usage can be controlled as necessary in contrast to unregulated direct abstraction, thus reducing the risk of subsequent over-exploitation. / Vaal University of Technology

Die genaue Kenntnis über den Wasserhaushalt stellt die Grundlage für die Bewirtschaftung der Ressource Wasser dar. Im urbanen Raum spielen dabei die siedlungshydrologischen Randbedingungen, wie Versiegelung, Anschlussgrad an die Kanalisation oder wasserbauliche Eingriffe, eine nicht zu vernachlässigende Rolle. Zur Quantifizierung der verschiedenen Wasserhaushaltsgrößen wurde ein konzeptioneller Ansatz entwickelt, der die jeweiligen Randbedingungen berücksichtigt und deren gegenseitige Beeinflussung abbildet. Hierbei muss der Einfluss auf den Wasserhaushalt auch bei veränderten Bedingungen simulierbar sein. Als Untersuchungsgebiet wurde das Gebiet der Wuhle, ein rechter Nebenfluss der Spree, gewählt, da es alle relevanten Aspekte der Wasserwirtschaft beinhaltet. Die Wuhle entspringt auf der Barnim-Grundmoränenhochfläche bei Ahrensfelde und mündet nach etwa 15,7 km Lauflänge im Stadtteil Köpenick in die Spree. Der Ansatz beruht auf der Berechnung der Wasserhaushaltsgrößen mit Hilfe eines flächendifferenzierten Verfahrens zur Ermittlung des Gesamtabflusses aus Niederschlag abzüglich der Verdunstung sowie dessen Aufteilung in einen oberirdischen und einen unterirdischen Teil. Zur Verifizierung der wasserhaushaltlich bestimmten Abflussgrößen wurden detaillierte hydraulische Untersuchungen an der Wuhle durchgeführt und abschnittsweise interpretiert. Anschließend wurde mit Hilfe der Förderdaten der Wasserwerke eine Grundwasserhaushaltsbilanz durchgeführt. Im Ergebnis ließ sich hydrogeologisch der Anteil an Uferfiltrat an der Gesamtfördermenge ermitteln. Zur Simulation des Einflusses des Wasserhaushaltes und der Grundwassernutzung auf den Grundwasserkörper wurde mit Hilfe des Simulators FEFLOW© eine numerische Modellierung der Strömungsverhältnisse durchgeführt. Über den Abgleich der simulierten Grundwasserhöhen mit den Grundwasserständen aus der Stichtagsmessung erfolgte eine zusätzliche Überprüfung der wasserhaushaltlich berechneten Abflussgrößen. / The exact knowledge of the water balance is the basis of the water supply and distribution within a catchment area. In an urban area the boundary conditions of the civil engineering like the sewer system or the hydraulic engineering plays an important role. To quantify the water balance a conceptual approach was developed which takes the current conditions and their interdependence into consideration. The impact of changing conditions on the water balance can also be simulated. As investigation area the catchment of the Wuhle River was chosen because it includes all relevant aspects of water management. The Wuhle River has its source on the ground moraine of the Barnim plateau directly at the city boundary in Ahrensfelde and reaches the Spree in the quarter Köpenick after about 15.7 km. This method uses a differentiated calculation by area to determine the total outflow of rainfall minus evaporization. It also determines the submontane and aboveground distribution. For verification purposes detailed hydraulic investigations were carried out at the Wuhle. With the production rate of the waterworks the groundwater balance was then calculated. As a result the amount of bank filtrate of the total groundwater withdrawal was determined in a hydro geological way. Using the simulation software FEFLOW© a numeric model of the flow pattern was created to simulate the influence on the water balance and the groundwater. The displayed subterranean catchment area of the water work Wuhlheide was based on the water table contours which were interpolated from a fixed date measurement of the groundwater heads. By comparing the simulated groundwater heads and the water levels from the fixed date measurement an additional verification of the water balance was realised.

In der vorliegenden Arbeit wurde untersucht, inwieweit die Reproduktionsbiologie von aquatischen Lebewesen durch die Gewässerbelastung mit endokrin wirksamen Substanzen (endocrine disruptors, ED) beeinflusst wird. Mit dem Amphib Xenopus laevis steht ein etabliertes Studienmodell zur Untersuchung der Wirkungen von ED auf die Reproduktionsbiologie zur Verfügung, das für die vorliegenden Studien modifiziert und erweitert sowie mit gewässeranalytischen Methoden verknüpft wurde. Die Gefährdung wasserlebender Tiere durch Gewässerbelastung mit ED kann erfasst werden, indem die Wirkung einer ausgewählten Einzelsubstanz auf die Reproduktionsbiologie untersucht wird. Anschließend erfolgt ein Nachweis der Substanz in Umweltproben. Durch Expositionsversuche, histologische Untersuchungen und Expressionsnachweis eines molekularen östrogenen Biomarkers konnte festgestellt werden, dass Bisphenol A (BPA) in Kaulquappen von Xenopus laevis verweiblichend wirkt und seine Effekte über eine Bindung an den Östrogenrezeptor vermittelt. Chemische Analysen während der Expositionsversuche zeigten, dass BPA von den Kaulquappen aufgenommen wird und dass eine geringe Abbaubarkeit der Substanz während eines Zeitraums von 48 Stunden besteht. Die Analyse von BPA in Wasserproben, die aus dem Fluss Alb oder aus Kläranlagenausläufen stammten, zeigte, dass BPA im Gewässer in relevanten Konzentrationen vorhanden ist und hauptsächlich durch eine Kläranlage in den Fluss eingeleitet wird. In einem Gewässer liegt allerdings ein Gemisch aus unterschiedlichen ED mit verschiedenen Wirkmechanismen vor. Die Gewässerbelastung mit endokrin wirksamen Substanzen kann weiterhin untersucht werden, indem Gewässerextrakte fraktioniert und in in vitro-Screeningmethoden getestet werden. Als Screeningmethoden dienten Rezeptorbindungsstudien an Östrogen- und Androgenrezeptoren sowie die Behandlung von Leberzellkulturen mit den Gewässerextrakten aus der Alb, um eine Regulation der Expression bestimmter Biomarkergene durch potenzielle ED nachzuweisen. Dazu wurde als neuer (anti)androgener und (anti)östrogener Biomarker das Retinol-binding Protein eingeführt. Die Untersuchung der Gewässerextrakte mit diesen Methoden zeigte, dass die Alb eine Belastung mit endokrin wirksamen Substanzen aufweist und dass hauptsächlich östrogen wirksame Substanzen vorkommen. Die Proben aus den Kläranlagenausläufen weisen die höchste endokrine Aktivität auf. / The present study examined the influence of endocrine active compounds (endocrine disruptors, ED), which are present in surface waters, on reproductive biology of aquatic organisms. The amphibian Xenopus laevis is a well-established model organism for the study of effects of ED on reproduction. It has been modified and broadened for the purpose of this study, and it was combined with chemical methods for water analyses. It is possible to assess water pollution with ED by detecting effects on repro-ductive biology of one particular substance, and then by looking for this substance in environmental water samples. We showed the feminizing potency of Bisphenol A (BPA) in conducting exposure experiments with tadpoles, in examining histological samples of gonads and in detecting the induction of the expression of a molecular estrogenic biomarker. BPA was recognized to mediate its effects via binding to the estrogen receptor. Moreover, analysis of BPA during exposure experiments revealed that BPA is taken up by tadpoles and is not readily degradable during a time period of 48 hours. Chemical analyses of environmental water samples from the river Alb or samples from sewage treatment works (STW) showed that BPA is released into the environment by STW effluents. In surface waters, there are different kinds of ED with different modes of action. Thus, it is another possibility to assess water pollution with ED by fractionating environmental water samples and by testing these fractions in rapid in vitro-screening methods. In the present work, receptor binding assays were carried out, both examining the binding to estrogen and androgen receptors. Furthermore, Xenopus laevis hepatocyte cultures were treated with fractions of environmental samples and biomarker expression was detected. A new biomarker to assess (anti)androgenic or (anti)estrogenic modes of action, respectively, was established. This new biomarker was the Retinol-binding Protein. The results obtained by these methods revealed that the river Alb is mainly polluted with estrogenic ED. Samples from STW effluents possessed the highest endocrine activity.

In dieser Dissertation wurden das Auftreten und die ökologische Bedeutung Vivianits in Süßwassersedimenten erforscht. Vivianit ist das am weitensten verbreitete reduzierte Eisenphosphatmineral, das sich in Gewässersedimenten bildet. Über die Mechanismen der Vivianitbildung in Sedimenten und die quantitative Rolle des Minerals für die Speicherung von Phosphor ist bisher wenig bekannt. Die neuen Erkenntnisse dieser Arbeit basieren auf der Entwicklung einer neuartigen Methode, die eine direkte Identifikation Vivianits mittels Röntgendiffraktometrie in Sedimenten erlaubte. Es gelang erstmalig, Vivianit in Oberflächensedimenten zu quantifizieren. Die vorliegende Arbeit zeigt, dass Vivianit signifikant, mit 10-40 %, zur Phosphorretention in Süßwassersedimenten beitragen kann. Die Untersuchung der Bildungsbedingungen Vivianits in unterschiedlichen Gewässersedimenten Norddeutschlands zeigte, dass das molare Schwefel zu Eisen Verhältnis des Sediments als ein wichtiger Indikator für die Bedingungen identifiziert, welche die Triebkräfte für die An- und Abwesenheit Vivianits darstellen. Eine Eutrophierung von Gewässern und der damit verbundene Anstieg der Sulfidproduktion kann dabei die Bildung Vivianits beeinträchtigen, und eine Abnahme des Phosphorbindungsvermögens des Sediments zur Folge haben. Die vorliegende Arbeit macht deutlich, dass eine artifizielle Erhöhung des Eisengehaltes des Sediments im Rahmen einer Seenrestaurierung eine Vivianitbildung induzieren kann und so langfristig zu einem erhöhten Phosphorrückhalt führt. Sättigungsberechnungen ergaben, dass ein hinsichtlich Vivianits übersättigtes Porenwasser kein sicheres Indiz für die Anwesenheit des Minerals ist. Die Berechnungen sind nicht in der Lage die kleinskaligen chemischen Bedingungen im Porenraum des Sediments abzubilden. Die Untersuchungen zeigen, dass die Bildung von Vivianit einen wichtigen Prozess der Phosphorbindung in Gewässersedimenten darstellt, der bislang jedoch weitestgehend vernachlässigt wurde. / In this thesis, the occurrence and environmental relevance of vivianite in freshwater sediments were explored. Vivianite is the most common reduced iron phosphate mineral which forms in sedimentary environments. Not much is known about the mechanisms which lead to vivianite formation in surface sediments, and about the quantitative role of vivianite in phosphorus sequestration. The development of a novel sediment preparation technique allowed the direct identification of vivianite by powder X-ray diffraction. Notably, for the first time, vivianite was quantified in surface freshwater sediments. The study examplifies that vivianite can significantly contribute to the phosphorus retention in surface freshwater sediments, accounting for 10-40 % of total sedimentary phosphorus. The exploration of vivianite in different surface freshwater sediments located in northern Germany revealed that the sedimentary sulphur to iron ratio is a valuable indicator for the conditions that are important drivers behind the formation or absence of vivianite. It has been demonstrated that eutrophication and the accompanied increase in sulphide production hampers vivianite formation, leading to a decreased phosphorus binding capacity of sediments through increased sediment sulphidization. The present study also revealed, that an iron addition as a measure of lake restoration can trigger vivianite formation, and significantly increases the long-term phosphorus retention of sediments. Pore water equilibrium calculations demonstrated that supersaturated pore water is not sufficient to predict the occurrence of the mineral in situ. Those calculations often fail to predict the occurrence of vivianite because they do not adequately represent chemical conditions within sediment microenvironments. In summary, the formation of vivianite in aquatic sediments constitutes an important process in phosphorus sequestration which has so far largely been ignored.

Natürliche Niederungsgebiete wirken als effektive Phosphor Senke. Landwirtschaftliche Nutzung und Drainage führt zur Transformation zu Phosphor Quellen. Dem Spreewald, ein Feuchtgebiet und seiner Funktionsweise als Phosphor Quelle oder –Senke, kommt im Einzugsgebiet der Spree eine wichtige Rolle zu. Die vorhandenen Kenntnisse der Phosphor Umsatzprozesse und des Phosphor Austausches zwischen den Flächen und dem Fließgewässernetz sind jedoch gering. Praktikable Ansätze zur Beschreibung des Phosphor Austauschverhaltens von Nährstoffen in den ausgedehnten Polderregionen liegen nicht vor. Anhand hydrologischer, geohydraulischer und biogeochemischer Prozessuntersuchungen in einer Polderlandschaft mit typischer Stauhaltung konnten die Phosphor Freisetzungs- und Retentionsprozesse ausgewiesen werden. Unter Nutzung verschiedener Modellansätze (geohydraulische Modellierung, Stofftransportmodellierung und Statistische Modelle) und der Berechnung von Phosphor Prozessraten werden horizontale und vertikale Phosphor Fluxe in den Flächen-Wasser Übergangszonen quantifiziert. Die Ergebnisse gehen in ein Phosphor Bilanzmodell ein, das die P-Quellen und Senkenfunktion von Polder Teilflächen (überstaut, genutzt) und des gesamten Polders in Monatsschritten abbildet. Die biogeochemischen Phosphor Umsatzprozesse sowie der horizontale und vertikale Transport werden wesentlich von den hydrologischen und den klimatischen Bedingungen gesteuert. Sie stellen die primären Einflussgrößen der P Senken oder -Quellenfunktion dar. Im Polder wird die Phosphor Netto Freisetzung der genutzten Bereiche durch eine hohe Phosphor Netto Retention in den überstauten Flächen abgemindert. Szenario Untersuchungen zeigen, dass sinkende Grabenwasserstände zu einer erheblichen Erhöhung der Phosphor Emissionen aus dem Grundwasserpfad führen. Ansteigende Phosphor Fluxe bei sinkenden Wasserständen legen ein zunehmendes Eutrophierungsrisiko in den Gräben sowie für unterhalb gelegene aquatische Systeme nahe. / Natural wetlands effectively retain phosphorus. Agricultural cultivation and drainage by ditches transform them to phosphorus sources. In the Spree catchment, the Spreewald, a large scaled lowland has a strategic importance operating as a phosphorus sink or phosphorus source. Anyhow, knowledge of its phosphorus turnover processes and the phosphorus exchange behavior between the plain and the river and ditch network are marginal. Practicable approaches to reproduce the phosphorus exchange behavior in its typical polder areas are missing. Based on process investigations in a polder area with typical weir regulation, phosphorus retention and remobilization processes are characterized. Combining different model approaches (groundwater modeling, matter transport modeling and statistical models) and calculating process rates, the horizontal and vertical phosphor fluxes in the water soil/sediment transition zones are quantified. The outcomes are used as input data for a phosphorus balance model reproducing the phosphorus source and sink character of used and rewetted polder areas and for the whole polder in monthly time steps. Results from process and transport investigations point out that biogeochemical turnover processes and horizontal or vertical phosphorus transport are driven by hydrological and climatological conditions. Net phosphorus release found in the extensive used polder areas is counteracted by significant net phosphorus retention in the rewetted parts. Scenario analyses identify decreasing ditch water levels to cause a considerable increase of phosphorus emissions from the groundwater pathway. Consequently, the increasing phosphorus fluxes at decreasing water levels provoke a growing risk for eutrophication in the ditches but also in the downstream aquatic systems.