The goal of this thesis was to determine the operational and technical parameters of the separation objects in water treatment. The first part is a theoretical and provides basic information on this issue. The second part contains the evaluation criteria created by the obtained information for individual objects and gained in practice by personal visits of selected treatment plants of water. In the last part we can find application of these criteria in water treatment in practice. There is also included the final evaluation of the researched condition.

Pharmaceuticals are biological active compounds with different functional groups, physico-chemical and biological properties. These chemical compounds are called as “new contaminants” which cumulate in various environmental components. These contaminants input to environment from industrial processes, hospitals and health care institutions or household sources and these pollutants can to negatively interact with environmental components. Pharmaceuticals are separated according to structure and their effects to live organisms. On the basis of drug consumption in Czech Republic the non-steroidal anti-inflammatory drugs are the most using pharmaceuticals, because these drugs can be obtain without prescriptions. The choosing analgesics for study were monitored in waste water from waste waters treatment plant (WWTP Brno – Modřice) and in surface water from two sampling sites of river Kretinka. Pharmaceuticals were monitored in surface waters in Czech Republic, in Scotland (river Thurso) and in Taiwan (river Erren, Agongdian, Yanshuei and canal of Tainan) Solid phase extraction (SPE) is used for extraction of study pharmaceutical from water system. The high performance liquid chromatography (HPLC) with diode array detection or mass spectrometry was used for determination of drugs in surface waters from Czech Republic. The water samples from Scotland and Taiwan were analysed and the high performance liquid chromatography with mass spectrometry (HPLC/MS) was used for determination of pharmaceuticals. The method of HPLC/MS enables the determination of study compounds in the very low range of concentrations (ng ? l-1). All monitored pharmaceuticals were identified and quantified in water samples from river Kretinka in Czech Republic, river Thurso (Scotland) and rivers Erren, Agongdian, Yanshuei and canal of Tainan in Taiwan and the obtained data were compared.

This work is focused on the study of penetration of pesticides and pharmaceuticals in the aquatic environment. The aim was to develop and verify the optimal method for long-term monitoring of the occurrence of selected pesticides and pharmaceuticals in surface waters. Two frequently used analgesics ibuprofen and diclofenac, and carbamazepine that is used to treat epilepsy, were chosen from the group of drugs. A group of 41 pesticides were selected for monitoring too. The attention was focused on a group of urea pesticides and phenoxyacetic acids, as well as on selected pesticides falling to the group of priority substances or identified as environmental quality standards. Some of pesticides were selected because their consumption in the Czech Republic exceeds 30 tons a year. Liquid chromatography with tandem mass spectrometry (LC / MS / MS) was used for the determination of selected analytes in surface waters. Two optimized analytical method were developed. Ten analytes were determined in negative ion mode and 34 analytes in positive ion mode. Solid phase extraction (SPE) was used for purification and concentration of the samples. Developed methodology was validated and used for monitoring of selected compounds in samples of surface waters from the Morava River basin. Samples were collected on the rivers Morava and Svratka monthly for two years. Samples from the river Blata and stream Nivnička were collected for one year. Surface water samples were also collected from the river Litava. Four samples were taken throughout the length of the flow during one day. Smaller streams were chosen for monitoring because of the probability of occurrence of pesticides. They flow abundantly agriculturally cultivated areas. Drugs ibuprofen and diclofenac were detected in all taken samples, carbamazepine mostly. Among the most commonly occurring pesticides were bentazon, diuron, isoproturon, carbendazim, MCPA, MCPP, propiconazole, tebuconazole and 2,4-D.

This work is focused on the determination of polar pesticides in surface and waste waters. In this study Mecoprop-P, MCPA, Dichlorprop-P, 2,4-D and MCPBA in differently loaded surface waters and communal waters from sewage treatment plants were analyzed. These herbicides are included in the group identified as environmental quality standards. Some of herbicides (2,4-D and MCPA) were selected because their consumption in the Czech Republic exceeds 30 tons a year. Samples were collected prom three rivers near town of Jaroměř (Elbe, Úpa and Metuje Rivers), from one river near the town of Brno (Svratka River) and from inflow and outflow of two sewage treatment plants (WWTP Jaroměř, WWTP Brno – Modřice). Particular rivers were chosen for monitoring due to the probability of occurrence of herbicides, because they flow through agriculturally cultivated areas. Solid phase extraction (SPE) was used for the isolation of target compounds and their concentration. Gas chromatography with tandem mass spectrometry (GC/MS/MS) was used for the determination of target analytes in surface and waste waters. Selected herbicides were detected in all collected samples.

Cette thèse porte sur l’étude de quelques questions liées à l’identifiabilité et l’identification d’un problème inverse non-linéaire de source. Il s’agit de l’identification d’une source ponctuelle dépendante du temps constituant le second membre d’une équation de type advection-dispersion-réaction à coefficients variables. Dans le cas monodimensionnel, la souplesse du modèle stationnaire nous a permis de développer des réponses théoriques concernant le nombre des capteurs nécessaires et leurs emplacements permettant d’identifier la source recherchée d’une façon unique. Ces résultats nous ont beaucoup aidés à définir la ligne de conduite à suivre afin d’apporter des réponses similaires pour le modèle transitoire. Quant au modèle bidimensionnel transitoire, en utilisant quelques résultats de nulle contrôlabilité frontière et des mesures de l’état sur la frontière sortie et de son flux sur la frontière entrée du domaine étudié, nous avons établi un théorème d’identifiabilité et une méthode d’identification permettant de localiser les deux coordonnées de la position de la source recherchée comme étant l’unique solution d’un système non-linéaire de deux équations, et de transformer l’identification de sa fonction de débit en la résolution d’un problème de déconvolution. La dernière partie de cette thèse discute la difficulté principale rencontrée dans ce genre de problèmes inverses à savoir la non identifiabilité d’une source dans sa forme abstraite, propose une alternative permettant de surmonter cette difficulté dans le cas particulier où le but est d’identifier le temps limite à partir duquel la source impliquée a cessé d’émettre, et donc ouvre la porte sur de nouveaux horizons. / The thesis deals with the two main issues identifiability and identification related to a nonlinear inverse source problem. This problem consists in the identification of a time-dependent point source occurring in the right hand-side of an advection-dispersion-reaction equation with spatially varying coefficients. Starting from the stationnary case in the one-dimensional model, we derived theoritical results defining the necessary number of sensors and their positions that enable to uniquely determine the sought source. Those results gave us a good visibility on how to proceed in order to obtain similar results for the time-dependent (evolution) case. As far as the two-dimensional evolution model is concerned, using some boundary null controllability results and the records of the generated state on the inflow boundary and its flux on the outflow boundary of the monitored domain, we established a constructive identifiability theorem as well as an identification method that localizes the two coordinates of the sought source position as the unique solution of a nonlinear system of two equations and transforms the identification of its time-dependent intensity function into solving a deconvolution problem. The last part of this thesis highlights the main difficulty encountred in such inverse problems namely the nonidentifiabilityof a source in its abstract form, proposes a method that enables to overcome this difficulty in the particular case where the aim is to identify the time active limit of the involved source. And thus, this last part opens doors on new horizons and prospects.

<p>Vi&scaron;e od 100 vrsta virusa ljudi i životinja se izlučuje u spolja&scaron;nju sredinu. Prisustvo ovih virusa u povr&scaron;inskim vodama reflektuje fekalnu kontaminaciju i ukazuje na<br />opasnost za zdravlje ljudi i životinja. Na području Srbije se ne prati prisustvo patogenih virusa u povr&scaron;inskim vodama, pa&nbsp; čak ni u vodama za piće, a nije uspostavljena&nbsp; ni&nbsp; metodologija ovih ispitivanja. Shodno tome, cilj disertacije je da se utvrdi i analizira prisustvo animalnih i humanih virusa u povr&scaron;inskim vodama primenom najsavremenijih metoda koncentrovanja i detekcije virusa. U okviru disertacije ispitano je prisustvo sledećih virusa u povr&scaron;inskim vodama na teritoriji Vojvodine: humanih adenovirusa (HAdV); norovirusa (NoV) i hepatitis A virusa (HAV), adenovirusa svinja (PAdV),&nbsp; poliomavirusa goveda (BPyV) i hepatitis E virus (HEV).</p><p>Ispitano je ukupno 108 uzoraka povr&scaron;inskih i otpadnih voda koji su prikupljani od oktobra 2012. godine do juna 2014. godine. U radu su primenjene najsavremenije metode koncentrovanja i detekcije virusa u vodi, koje se u Srbiji nisu koristile za ovu namenu. Sprovedenim ispitivanjima dokazano je da su animalni i humani virusi prisutni u povr&scaron;inskim vodama na području Vojvodine. Najče&scaron;će detektovan&nbsp; virus u povr&scaron;inskim vodama je humani adenovirus (42,4%), a potom norovirusi GII i GI (40,4% i 15,2%), adenovirus svinja (11,1%), poliomavirus goveda (7,1%) i hepatitis E virus (3,0%). U ukupno 9 testiranih uzoraka gradske kanalizacione vode najče&scaron;će je detektovan HAdV (44,4%), NoV GII i GI&nbsp; (66,7% i 22,2%), BPyV je detektovan u samo jednom od 9 uzoraka, a niti u jednom nisu detektovani PAdV i HEV. Hepatitis A virus nije detektovan u uzorcima, a eksperimentalno je potvrđeno da su metode primenljive i za detekciju ovog virusa. Na osnovu rezultata prinosa procesne kontrole i utvrđenog prisustva virusa u uzorcima,&nbsp; zaključeno&nbsp; je da se ove metode mogu veoma uspe&scaron;no koristiti za detekciju virusne kontaminacije&nbsp; povr&scaron;inskih voda. Izvr&scaron;ena je igenotipizacija virusa iz odabranih uzoraka metodom sekvenciranja dela virusnog genoma. Indirektno je potvrđeno da su infekcije&nbsp;&nbsp; detektovanim virusima prisutne u populaciji životinja i ljudi. Prisustvo virusa u&nbsp;&nbsp; povr&scaron;inskim vodama i uzorcima gradske kanalizacije odražava infektivni status stanovni&scaron;tva, ali predstavlja i značajan rizik za zdravlje životinja i ljudi na području koje gravitira ispitanim vodama.&nbsp;</p> / <p>Over 100 types of pathogenic viruses are excreted in human and animal wastes. The presence of human and animal pathogenic enteric viruses in water environments reflects fecal contamination and indicates a risk to public health.&nbsp; Republic of Serbia does not implement surveillance for the presence of pathogenic human and animal viruses in surface waters and even in drinking water, neither is the established methodology of these studies in any institution in Serbia.&nbsp; Accordingly, the aim of the study was to determine and analyze the presence of human and animal viruses in surface water,&nbsp; using the latest methods&nbsp; of&nbsp; concentration and detection of the viruses.&nbsp; Within the dissertation examined the presence of the following viruses in surface waters in Vojvodina:&nbsp; Human adenoviruses&nbsp; (HAdV), noroviruses (NoV)&nbsp; and hepatitis A virus), Porcine adenovirus (PAdV) and Bovine polyomavirus (BPyV)&nbsp; and&nbsp; Hepatitis E virus (HEV).<br />A total of 108 samples of surface water and waste water were collected from October 2012 to June 2014. The paper are applied the most advanced methods and the concentration of virus detection in water, which in Serbia are not used for this purpose. The conducted tests have proven that the animal and human viruses present in surface waters in Vojvodina. The most commonly detected virus in surface water was human adenovirus (42.4%), followed by Norovirus GI&nbsp; and GII (40.4% and 15.2%),&nbsp; Porcine adenovirus&nbsp; (11,1%),&nbsp; Bovine polyomavirus&nbsp; (7.07%) and hepatitis E virus (3,0%).<br />In total of&nbsp; nine analysed sewage samples human adenovirus was detected in 44,4%&nbsp; of&nbsp; samples. The prevalence of norovirus GII and GI in sewage&nbsp; samples was&nbsp; 66,7%&nbsp; and 22,2%. Bovine&nbsp; polyomavirus was detected in one of nine samples while porcine adenovirus and hepatitis E virus were not detected in any of analyzed samples.&nbsp; Hepatitis A virus was not detected in samples, but&nbsp; it has been experimentally confirmed that the methods applicable for detection of the virus. Based on the results of process control and yield determined the presence of virus insamples, it was found that these methods can be successfully used to detect viral contamination of surface waters. Also, in these study was performed genotyping of viruses from selected samples by sequencing a part of the viral genome. Indirectly it is confirmed that the infection detected viruses present in a population of animals and humans. The presence of virus in samples of surface water and urban sewage reflects the infectious status of the population, but also constitutes a significant risk to the health of animals and people in the area that gravitates with tested waters.</p><p>&nbsp;</p>

Detta examensarbete består av en resiliensanalys av ett stadbyggnadsprojekt i området Ulleråker, straxsöder om Uppsalas stadskärna. Resiliensanalysen kan bidra med perspektiv till planeringen för att säkraUppsalas dricksvattenförsörjning då stadsbyggnadsprojektet, enligt programförslaget, är planerat attligga på känsliga delar av Uppsalas grundvattentäkt och därför riskerar att förorena grundvattnet.Området Ulleråker ligger inom zon för vattenskyddsområde. Resiliensanalysen har tidigare inte använts i stor utsträckning för planeringkontexten och metoden hardelvis kritiserats för brister i praktisk användbarhet. Examensarbetet ämnar därför till att fylla håletmellan teori och praktik och därför testa metoden på ett praktiskt planeringsfall (Ulleråker) och ommöjligt föreslå förbättringar för dess användbarhet. Dessutom ska examensarbetet bidra till denpraktiska fallstudien för Ulleråker där Sweco och Uppsala kommun får nya perspektiv kring vilkaaspekter som är relevant att inkludera i planeringen. Metoden följer Resilience Alliance praktikerns handbok ”Assessing Resilience in Social-EcologicalSystems: Workbook for Practitioners”, vilken används för att analysera systemet utifrån handbokensfem steg, inkluderat vägledande frågor. Det första steget fokuserade på att definiera systemgränser samtidentifiera huvudproblem. Det andra steget handlade om systemdynamik i form av den adaptiva cykelnoch önskvärda eller icke önskvärda systemlägen. Det tredje steget fokuserade på tvärvetenskapligasamverkansprocesser mellan andra system på högre och lägre nivåer. Det fjärde steget handlade omaktörssamverkan. Slutligen, i det femte steget, sammanfattades analysen och adaptiva lösningar försystemet diskuteras vilka kan användas för att bygga ett resilient system. Analysen avstadsbyggnadsprojektet Ulleråker gjordes utifrån tillgängligt underlag från planprocessen samtintervjuer av nyckelpersoner, och fokuserade på riskerna för grundvattentäkten och ytvattnet i Fyrisån. Slutsatserna från resiliensanalysen är att metoden är svår att använda i en komplex planeringkontextutifrån handbokens utformning och fokus på mindre komplexa system. Även om det finns vissabegränsningar i analysmetodens praktiska användbarhet finns det faktorer som kan bidra tillplaneringskontexten, t.ex. ett ökat systemtänkande (Ulleråker som system), risktänk kringtröskeleffekter (irreversibel förorening av grundvattentäkten) samt längre tidsperspektiv (framtidaosäkerheter). Modellen ball-in-the-basin med systemlägen är relevant för att förstå ett systems önskade,oönskade eller irreversibla förändring liksom den adaptiva cykeln för att systemet ständigt utvecklas.Dessutom är en viktig poäng med de tvärvetenskapliga interaktionerna att kunskapen från systemetsminne bör utnyttjas i större grad. Finns redan kunskapen inom kommunen bör det social-ekologiskasystemet mycket snabbare kunna återhämta sig och återgå till ett fungerande dricksvattensystem (högresystemnivå). Resiliensanalysen har också identifierat och diskuterat strategiska åtgärder, som skullekunna skapa ett mer resilient Ulleråker, bland annat i form av att öka samverkansprocesserna(governance) och att initiera förändring. Avslutningsvis är de viktigaste slutsatserna kopplade till de tre pelarna: Social-ekologiska system(systemtänk), komplexa adaptiva system (risker för tröskeleffekter och att utvecklingen inte alltså skerlinjärt och förutsägbar utan inkluderar stora osäkerheter) samt utveckling över skalor av tid och rum(långa tidsperspektiv, men också olika geografiska skalor). Eftersom det utifrån handbokens utformningkrävs kunskap kring resiliens från analysören och dessutom mycket tid och resurser som det sällan finnsgott om i planeringsprocessen bör dessa tre pelare, tillsammans med anpassningsbarhet,omställningsbarhet och specifik samt generell resiliens, implementeras i traditionell planering. / This master thesis contains of a resilience assessment of an urban development project in the area called Ulleråker, a bit south of the center of Uppsala city. The resilience assessment aims to give newperspectives for obtaining water security in Uppsala, since the program proposal affects sensitive areasof the groundwater aquifer of Uppsala and is posing risks of contaminating the ground water aquifer.The area of Ulleråker is highly sensitive and therefore secured by a water protection area. The resilience assessment has not earlier been used to a large extent in the urban planning context andthe method has earlier been criticized for lack of practical usefulness. The thesis aims to fill the gapbetween scientific studies of practical cases. The method is therefore used on a practical case (Ulleråker)and propose improvements connected to the usability. The thesis should also contribute to the case,Ulleråker, where Sweco and the municipality of Uppsala are given new perspectives of what should beimportant to consider in planning. The method is based on the Resilience Alliance’s workbook ”Assessing Resilience in Social-EcologicalSystems: Workbook for Practitioners”, which is used to analyze the system based in five steps, includingguiding questions. The first step of the workbook focused on defining the system and limiting the systemtogether with identifying main problems. The second step of the assessment focused on the systemdynamic exploring the adaptive cycle as well as desired and undesired system regimes. The third stagefocused on interactions between different hierarchical levels of time and scale. The fourth stage focusedon governance, and on how actors cooperate with decision-making. The last stage focused onsyntezeising the assessment findings and adaptive solutions for building resilience. The analysis ofUlleråker is based on already completed investigations and material from the planning process togetherwith interviews of main actors and is focused on risks connected to ground- and surface water. The conclusions are that the resilience assessment is hard to use in a planning context with theconformation of today. Even though there are difficulties, the assessment can contribute with factors asthe resilience thinking about social-ecological systems (Ulleråker as a system with social and ecologicalsystems interacting), risks of thresholds (contaminating the groundwater) and the longer timeperspective (future uncertainties), to the planning context. The model ball-in-the-basin with systemregimes are relevant to understand the systems desirable, undesirable or irreversible development andthe adaptive cycle for the constant development (adaptation and transformation) of the system. Anotherimportant aspect with the cross-scale interactions (between levels) are to a higher extent use the memoryof the system. If the knowledge already exists in the municipality, the social-ecological system wouldbe able to reorganize faster and return to a functional drinking water system (on higher level). Theresilience assessment has also identified strategic actions that possibly could create a more resilientUlleråker, by for example increase the governance and initiating change. In conclusion, the most important aspects of the assessment to bring in to the planning process are thethree aspects: Social-ecological system (resilience thinking), complex adaptive system (risks connectedto thresholds and non-linear development including uncertainties) and cross-scale interactionsdevelopment (long time perspectives and geographical scales). The conformation of the workbookrequires great knowledge about resilience from the assessor, and there are seldom enough time andresources available in the conventional process. The three aspects together with adaptability,transformability and specified and general resilience should be implemented in conventional planning.

Surface water hydrology is a deeply studied subject, yet there are barely any studies concerning surface water connectivity, neither micro- nor macro scale. With the explosive development of GIS over the past decade, tools for measuring and analysing rivers and lakes are inumerable. Light detection and ranging (LiDAR) has also seen tremendous improvements over the years. This study uses high resolution digital elevation models and georeferenced aereal photographs to carry out a detailed GIS-analysis of river-lake connectivity in three catchments in Västerbotten, Sweden: Bjurbäcken, Hjuksån and Gargån. Hjuksån is located beneath the highest coast line (HCL) wheras the other catchments are located above this line. A second pupose of the study is also to test if lake size varies above and below HCL. Lakes were digitized at 1:2000 scale and the rivers were digitized and categorized in Strahler stream order using tools in ArcGIS Pro. The data from the study was compared to data from the Swedish Meteorological and Hydrological Institute (SMHI), as well as data from international studies. The results show a surface water connection of 71,4% for Bjurbäcken, 62% for Hjuksån and 73,1% for Gargån. Comparing this data to data from SMHI results in a lowering of the surface water connection by 20 percentage points för Bjurbäcken, 30,3 for Hjuksån and 8,2 for Gargån. Lake size was tested between the catchments using an ANOVA, yielding a significant difference between Hjuksån and Bjurbäcken as well as Hjuksån and Gargån, backing up the hypothesis that HCL affects lake size.

<p>  </p> <p>The management of water resources in East Africa is inherently challenged by rainfall variability and the uneven spatial distribution of freshwater resources. In addition to these issues, meteorological and water data collection has been inconsistent over the past decades, and unclearly defined purposes or end goals for collected data have left many datasets ineffectively curated. In light of the data intensiveness of current modelling and planning methods, data scarcity and inaccessibility have become substantial impediments to informed decision-making. Among the outputs of this research are 1) a revised technique for evaluating bias correction performance on reanalysis data for use in regions where precipitation data is temporally discontinuous which can potentially be applied to other types of climate data as well, 2) a new methodology for quantifying qualitative information contained in legislation and official documents and websites for the assessment of relationships between documented meteorological and water data policies and resulting outcomes in terms of data availability and accessibility, and 3) a fresh look at data needs and the value data holds with respect to water resources decision-making and management in the region.</p>

In countries with harsh winter climates extensive winter road maintenance is necessary to achieve traffic accessibility and road safety. These measures have high economic and environmental costs as snow free roads and winter road maintenance in Sweden today is achieved by a combination of mechanical snow clearance and the spreading of salt to prevent ice formation. The salt ends up in the roadside environment and has negative effects on groundwater and vegetation. An alternative to traditional winter road maintenance to obtain non-skid winter roads is the use of hydronic pavement(HP) systems. Existing HP systems in Sweden are powered by district heating which limits the application to urban locations. The goal is to utilize renewable energy sources such as geoenergy which can be used in both rural and urban locations. This thesis suggests Hamnbacken in Visby as a pilot project for a full-scale application of the proposed HP system using surface water source heat.The weather related road surface conditions on Hamnbacken, and the potential of a renewable energysource have been examined in this study and the proposed location has been found favourable for a HP system. / Länder med övervägande kallt vinterklimat är halkbekämpning en nödvändighet för trafikens framkomlighet och säkerhet. Åtgärderna som vidtas för att få snö- och isfria vägar är kostsamma samt har en hög miljöpåverkan, ett vedertagligt exempel är plogning och saltning. Saltet hamnar i slutändan inom vägens omgivande områden och har en negativ påverkan på grundvatten och vegetation. En alternativ lösning till traditionell halkbekämpning är uppvärmda vägar för att uppnå ett halkfritt vinterväglag. Befintliga väguppvärmningssystem i Sverige försörjs av fjärrvärme vilket är en begräsning då tillgången till fjärrvärme finns i anslutning till tätorter. Målet är att utnyttja förnybara energikällor såsom geoenergi som är tillgänglig både i tätorter och på landsbygden. Det här examensarbetet undersöker Hamnbacken i Visby som ett pilotprojekt för en fullskalig implementering av väguppvärmningssystem där sjövärme används som energikälla. Denna studie har undersökt väderrelaterade vägförhållanden på Hamnbacken samt potentialen för användning av sjövärme. Den föreslagna platsens förutsättningar har visat sig vara gynnsamma i detta avseende.