abstract: Phase change materials (PCMs) are combined sensible-and-latent thermal energy storage materials that can be used to store and dissipate energy in the form of heat. PCMs incorporated into wall-element systems have been well-studied with respect to energy efficiency of building envelopes. New applications of PCMs in infrastructural concrete, e.g., for mitigating early-age cracking and freeze-and-thaw induced damage, have also been proposed. Hence, the focus of this dissertation is to develop a detailed understanding of the physic-chemical and thermo-mechanical characteristics of cementitious systems and novel coating systems for wall-elements containing PCM. The initial phase of this work assesses the influence of interface properties and inter-inclusion interactions between microencapsulated PCM, macroencapsulated PCM, and the cementitious matrix. The fact that these inclusions within the composites are by themselves heterogeneous, and contain multiple components necessitate careful application of models to predict the thermal properties. The next phase observes the influence of PCM inclusions on the fracture and fatigue behavior of PCM-cementitious composites. The compliant nature of the inclusion creates less variability in the fatigue life for these composites subjected to cyclic loading. The incorporation of small amounts of PCM is found to slightly improve the fracture properties compared to PCM free cementitious composites. Inelastic deformations at the crack-tip in the direction of crack opening are influenced by the microscale PCM inclusions. After initial laboratory characterization of the microstructure and evaluation of the thermo-mechanical performance of these systems, field scale applicability and performance were evaluated. Wireless temperature and strain sensors for smart monitoring were embedded within a conventional portland cement concrete pavement (PCCP) and a thermal control smart concrete pavement (TCSCP) containing PCM. The TCSCP exhibited enhanced thermal performance over multiple heating and cooling cycles. PCCP showed significant shrinkage behavior as a result of compressive strains in the reinforcement that were twice that of the TCSCP. For building applications, novel PCM-composites coatings were developed to improve and extend the thermal efficiency. These coatings demonstrated a delay in temperature by up to four hours and were found to be more cost-effective than traditional building insulating materials. The results of this work prove the feasibility of PCMs as a temperature-regulating technology. Not only do PCMs reduce and control the temperature within cementitious systems without affecting the rate of early property development but they can also be used as an auto-adaptive technology capable of improving the thermal performance of building envelopes. / Dissertation/Thesis / Doctoral Dissertation Civil, Environmental and Sustainable Engineering 2018

Though economically favorable when compared to other renewable energy storage technologies, thermal energy storage systems for concentrating solar thermal power (CSP) plants require additional cost reduction measures to help transition CSP plants to the point of grid-parity. Thermocline packed bed storage is regarded as one potential low cost solution due to the single tank requirement and low cost storage media. Thus sensible heat storage (SHS) and latent heat storage (LHS) packed bed systems, which are two thermocline varieties, are frequently investigated. LHS systems can be further classified as single phase change material (PCM) systems or cascaded systems wherein multiple PCMs are employed. This study compared the performance of SHS, single PCM, and cascaded PCM direct storage systems under the conditions that may be encountered in utility-scale molten salt CSP plants operating between 565°C and 288°C. A small-scale prototype SHS packed bed system was constructed and operated for use in validating a numerical model. The drawbacks of the latent heat storage process were discussed, and cascaded systems were investigated for their potential in mitigating the issues associated with adopting a single PCM. Several cascaded PCM configurations were evaluated. The study finds that the volume fraction of each PCM and the arrangement of latent heat in a 2-PCM and a 3-PCM system influences the output of the system, both in terms of quality and quantity of energy. In addition to studying systems of hypothetical PCMs, real salt PCM systems were examined and their selection process was discussed. A preliminary economic assessment was conducted to compare the cost of SHS, single-PCM LHS, cascaded LHS, and state-of-the-art 2-tank systems. To the author's knowledge, this is the first study that compares the cost of all three thermocline packed bed systems with the 2-tank design. The SHS system is significantly lower in cost than the remaining systems, however the LHS system does show some economic benefit over the 2-tank design. If LHS systems are to be viable in the future, low cost storage media and encapsulation techniques are necessary.

The objective of this study is to synthesize nanomaterials by mixing molten salt (alkali nitrate salt eutectics) with inorganic nanoparticles. The thermo-physical properties of the synthesized nanomaterials were characterized experimentally. Experimental results allude to the existence of a distinct compressed phase even for the solid phase (i.e., in the nanocomposite samples). For example, the specific heat capacity of the nanocomposites was observed to be enhanced after melting and re-solidification - immediately after their synthesis; than those of the nanocomposites that were not subjected to melting and re-solidification. This shows that melting and re-solidification induced molecular reordering (i.e., formation of a compressed phase on the nanoparticle surface) even in the solid phase - leading to enhancement in the specific heat capacity. Numerical models (using analytical and computational approaches) were developed to simulate the fundamental transport mechanisms and the energy storage mechanisms responsible for the observed enhancements in the thermo-physical properties. In this study, a simple analytical model was proposed for predicting the specific heat capacity of nanoparticle suspensions in a solvent. The model explores the effect of the compressed phase – that is induced from the solvent molecules - at the interface with individual nanoparticles in the mixture. The results from the numerical simulations indicate that depending on the properties and morphology of the compressed phase – it can cause significant enhancement in the specific heat capacity of nanofluids and nanocomposites. The interfacial thermal resistance (also known as Kapitza resistance, or “Rk”) between a nanoparticle and the surrounding solvent molecules (for these molten salt based nanomaterials) is estimated using Molecular Dynamics (MD) simulations. This exercise is relevant for the design optimization of nanomaterials (nanoparticle size, shape, material, concentration, etc.). The design trade-off is between maximizing the thermal conductivity of the nanomaterial (which typically occurs for nanoparticle size varying between ~ 20-30nm) and maximizing the specific heat capacity (which typically occurs for nanoparticle size less than 5nm), while simultaneously minimizing the viscosity of the nanofluid. The specific heat capacity of nitrate salt-based nanomaterials was measured both for the nanocomposites (solid phase) and nanofluids (liquid phase). The neat salt sample was composed of a mixture of KNO3: NaNO3 (60:40 molar ratio). The enhancement of specific heat capacity of the nanomaterials obtained from the salt samples was found to be very sensitive to minor variations in the synthesis protocol. The measurements for the variation of the specific heat capacity with the mass concentration of nanoparticles were compared to the predictions from the analytical model. Materials characterization was performed using electron microscopy techniques (SEM and TEM). The rheological behavior of nanofluids can be non-Newtonian (e.g., shear thinning) even at very low mass concentrations of nanoparticles, while (in contrast) the pure undoped (neat) molten salt may be a Newtonian fluid. Such viscosity enhancements and change in rheological properties of nanofluids can be detrimental to the operational efficiencies for thermal management as well as energy storage applications (which can effectively lead to higher costs for energy conversion). Hence, the rheological behavior of the nanofluid samples was measured experimentally and compared to that of the neat solvent (pure molten salt eutectic). The viscosity measurements were performed for the nitrate based molten salt samples as a function of temperature, shear rate and the mass concentration of the nanoparticles. The experimental measurements for the rheological behavior were compared with analytical models proposed in the literature. The results from the analytical and computational investigations as well as the experimental measurements performed in this proposed study – were used to formulate the design rules for maximizing the enhancement in the thermo-physical properties (particularly the specific heat capacity) of various molten salt based inorganic nanomaterials. The results from these studies are summarized and the future directions are identified as a conclusion from this study.

This thesis seeks to examine the effective convective heat exchange of sand as a heat exchange medium. The goal of this exploratory research is to quantify the heat transfer coefficient of sand in a proposed Thermal Energy Storage (TES) system which intends to complement solar thermal power generation. Standard concentrator solar thermal power plants typically employ a heat transfer fluid (HTF) that is heated in the collector field then routed to the power generators or TES unit. A fairly clear option for a TES system would be to utilize the existing HTF as the working storage medium. However, the use of conventional HTF systems may be too expensive. These fluids are quite costly as the quantity needed for storage is high and for some fluids their associated high vapor pressures require expensive highly reinforced containment vessels. The proposed storage system seeks to use sand as the storage medium; greatly reducing the expenses involved for both medium and storage costs. Most prior TES designs using sand or other solids employed them in a fixed bed for thermal exchange. The proposed TES system will instead move the sand to drive a counter flow thermal exchange. This counter flow design allows for a much closer temperature of approach when compared to a fixed bed. As cost and performance are the primary goals to tackle of the proposed system, the evaluation of the sandâ s thermal exchange effectiveness in a flowing state is necessary. Experiments will be conducted to measure the effective heat transfer coefficient between the sand and representative solid surfaces used as the heat transfer conduits. Additional experiments that will be looked at are wear caused by the sand as a consideration for long term design viability as well as angle of repose of the sand and its effect on scoop design for improved materials handling. Key investigational aspects of these experiments involve the sand grain size as well as shape of the heat exchanger surfaces. The thesis will evaluate the resulting convective heat transfer coefficient of the sand as related to these features. The data will then be compared and verified with available literature of previously studied characteristic thermal properties of sand. The measured and confirmed data will then be used to further aid in a design model for the proposed TES system.

Concentrated solar power (CSP) has the potential of fulfilling the world’s electricity needs. Parabolic-trough system using synthetic oil as the HTF with operating temperature between 300 and 400o C, is the most matured CSP technology. A thermal storage system is required for the stable and cost effective operation of CSP plants. The current storage technology is the indirect two-tank system which is expensive and has high energy consumption due to the need to prevent the storage material from freezing. Latent heat storage (LHS) systems offer higher storage density translating into smaller storage size and higher performance but suitable phase change materials (PCMs) have low thermal conductivity, thus hindering the realization of their potential. The low thermal conductivity can be solved by heat transfer enhancement in the PCM. There is also lack of suitable commercially-available PCMs to cover the operating temperature range. In this study, a hybrid cascaded storage system (HCSS) consisting of a cascaded finned LHS and a high temperature sensible or concrete tube register (CTR) stages was proposed and analysed via modelling and simulation. Fluent CFD code and the Dymola simulation environment were employed. A validated CFD phase change model was used in determining the heat transfer characteristics during charging and discharging of a finned and unfinned LHS shell-and-tube storage element. The effects of various fin configurations were investigated and heat transfer coefficients that can be used for predicting the performance of the system were obtained. A model of the HCSS was then developed in the Dymola simulation environment. Simulations were conducted considering the required boundary conditions of the system to develop the best design of a system having a capacity of 875 MWhth, equivalent to 6 hours of full load operation of a 50 MWe power plant. The cascaded finned LHS section provided ~46% of the entire HCSS capacity. The HCSS and cascaded finned LHS section have volumetric specific capacities 9.3% and 54% greater than that of the two-tank system, respectively. It has been estimated that the capital cost of the system is ~12% greater than that of the two-tank system. Considering that the passive HCSS has lower operational and maintenance costs it will be more cost effective than the twotank system considering the life cycle of the system. There is no requirement of keeping the storage material above its melting temperature always. The HCSS has also the potential of even lower capital cost at higher capacities (>6 hours of full load operation).

The heat flux demands for electronics cooling applications are quickly approaching the limits of conventional thermal management systems. To meet the demand of next generation electronics, a means for rejecting high heat fluxes at low temperatures in a compact system is an urgent need. To answer this challenge, in this work a gasketed chevron plate heat exchanger in conjunction with a slurry consisting of highly endothermic solid ammonium carbamate and a heat transfer fluid. A reduced-order 1-dimensional model was developed and used to solve the coupled equations for heat, mass, and momentum transfer. The feasibility of this chosen design for satisfying the heat rejection load of 2kW was also explored in this study. Also, a decomposition reaction using acetic acid and sodium bicarbonate was conducted in a plate heat exchanger (to simulate a configuration similar to the ammonium carbamate reactions). This enabled the experimental validation of the numerical predictions for the momentum transfer correlations used in this study (which in turn, are closely tied to both the heat transfer correlations and chemical kinetics models). These experiments also reveal important parameters of interest that are required for the reactor design. A numerical model was developed in this study and applied for estimating the reactor size required for achieving a power rating of 2 kW. It was found that this goal could be achieved with a plate heat exchanger weighing less than 70 kg (~100 lbs) and occupying a volume of 29 L (which is roughly the size of a typical desktop printer). Investigation of the hydrodynamic phenomena using flow visualization studies showed that the flow patterns were similar to those described in previous studies. This justified the adaptation of empirical correlations involving two-phase multipliers that were developed for air-water two-phase flows. High-speed video confirmed the absence of heterogeneous flow patterns and the prevalence of bubbly flow with bubble sizes typically less than 0.5 mm, which justifies the use of homogenous flow based correlations for vigorous gas-producing reactions inside a plate heat exchanger. Absolute pressure measurements - performed for experimental validation studies - indicate a significant rise in back pressure that are observed to be several times greater than the theoretically estimated values of frictional and gravitational pressure losses. The predictions from the numerical model were found to be consistent with the experimental measurements, with an average absolute error of ~26%

L'utilisation de la réfrigération secondaire permet de réduire l'impact environnemental des systèmes frigorifiques grâce à une réduction de l'utilisation de gaz à effet de serre, néanmoins un tel procédé abaisse l'efficacité des systèmes. Afin de rendre ce procédé plus efficace et viable, l'utilisation de fluide à forte densité énergétique ainsi qu'un couplage avec un dispositif de stockage thermique a été envisagé comme réponse à une problématique industrielle de distribution de froid (climatisation, procédés de refroidissement). Un montage expérimental constitué d'une boucle de circulation et d'un réacteur de formation a été utilisé afin d'évaluer les caractéristiques de charge et décharge d'un réseau utilisant des fluides diphasiques. Cette étude a également permis l'élaboration et la validation de modèles prédictifs (réservoir de stockage, échangeur de chaleur, écoulement) de dynamique de stockage et déstockage pour différents matériaux. Ces modèles ont ensuite été appliqués au cas d'un réseau industriel afin d'étudier l'impact du matériau de stockage choisi sur le dimensionnement du système, sur la consommation énergétique mais aussi sur sa viabilité économique. Ainsi, les résultats ont d'abord montré que l'utilisation d'un dispositif améliorait l'efficacité d'un système et que le retour sur investissement dépendait des scénarios de stockage envisagés. Enfin, une forte dépendance sur le choix du matériau a également été soulevée. / The use of secondary refrigeration can reduce cooling system impact on environment by greenhouse gas reduction, nevertheless this kind of technology reduce the system efficiency. The use of high energetic density and thermal energy storage was considered to improve system efficiency and to answer to industrial cooling process issue (air-conditioning, cooling process or temperature preservation). An experimental set-up composed by a stired tank reactor and circulation loop was used in order to evaluate the charging and discharging dynamic of a cooling district using phase change slurry. This experimental study offers the opportunity to elaborate and validate further models (stirred tank reactor, heat exchanger, flow behavior) to predict the charging and discharging behaviors for various storage materials. Then, these models were used in the case of an industrial system to observe the impact of the storage material or system sizing, energy consumption and economic sustainability. Thus, results show that the impact of the storage device on system energy efficiency and the return on investment depends on storage scenarios. Finally the impact of the chosen material on system efficiency was pointed out.

abstract: Phase Change Material (PCM) plays an important role as a thermal energy storage device by utilizing its high storage density and latent heat property. One of the potential applications for PCM is in buildings by incorporating them in the envelope for energy conservation. During the summer season, the benefits are a decrease in overall energy consumption by the air conditioning unit and a time shift in peak load during the day. Experimental work was carried out by Arizona Public Service (APS) in collaboration with Phase Change Energy Solutions (PCES) Inc. with a new class of organic-based PCM. This "BioPCM" has non-flammable properties and can be safely used in buildings. The experimental setup showed maximum energy savings of about 30%, a maximum peak load shift of ~ 60 min, and maximum cost savings of about 30%. Simulation was performed to validate the experimental results. EnergyPlus was chosen as it has the capability to simulate phase change material in the building envelope. The building material properties were chosen from the ASHRAE Handbook - Fundamentals and the HVAC system used was a window-mounted heat pump. The weather file used in the simulation was customized for the year 2008 from the National Renewable Energy Laboratory (NREL) website. All EnergyPlus inputs were ensured to match closely with the experimental parameters. The simulation results yielded comparable trends with the experimental energy consumption values, however time shifts were not observed. Several other parametric studies like varying PCM thermal conductivity, temperature range, location, insulation R-value and combination of different PCMs were analyzed and results are presented. It was found that a PCM with a melting point from 23 to 27 °C led to maximum energy savings and greater peak load time shift duration, and is more suitable than other PCM temperature ranges for light weight building construction in Phoenix. / Dissertation/Thesis / M.S. Mechanical Engineering 2010

Residential space and water heating accounts for around 13% of the greenhouse gas emissions of the UK. Reducing this is essential for meeting the national emission reduction target of 80% by 2050 from the 1990 baseline. One of the strategies adopted for achieving this is focused around large scale shift towards electrical heating. This could lead to unsustainable disparity between the daily peak and off-peak electricity loads, large seasonal variation in electricity demands, and challenges of matching the short and long term supply with the demands. These challenges could impact the security and resilience of UK electricity supply, and needs to be addressed. Rechargeable Thermal Energy Storage (TES) in residential buildings can help overcome these challenges by enabling Heat Demand Shifts (HDS) to off-peak times, reducing the magnitude of the peak loads, and the difference between the peak and off-peak loads. To be effective a wide scale uptake of TES would be needed. For this to happen, the benefits and impacts of TES both for the demand side and the supply side have to be explored, which could vary considerably given the diverse physical, thermal, operational and occupancy characteristics of the UK housing stock. A greater understanding of the potential consequence of TES in buildings is necessary. Such knowledge could enable appropriate policy development to help drive the uptake of TES or to encourage development of alternative solutions. Through dynamic building simulation in TRNSYS, this work generated predictions of the space and water heating energy and power demands, and indoor temperature characteristics of the UK housing stock. Twelve building archetypes were created consisting of: Detached, semi-detached, mid-terrace and flat built forms with thermal insulation corresponding to the 1990 building regulation, and occupied floor areas of 70m2, 90m2 and 150m2. Typical occupancy and operational conditions were used to create twelve Base Case scenarios, and simulations performed for 60 winter days from 2nd January. HDS of 2, 3 and 4 hours from the grid peak time of 17:00 were simulated with sensible TES system sizes of 0.25m3, 0.5m3 and 0.75m3, and water storage temperatures of 75°C and 95°C. Parametric analysis were performed to determine the impacts and benefits of: thermal insulation equivalent to 1980, 1990 (Base Case), 2002 and 2010 building regulation; locations of Gatwick (Base Case) and Aberdeen; heating durations of 6, 9 (Base Case), 12 and 16 hours per day; thermostat settings of 19°C, 21°C (Base Case) and 23°C, and number of occupiers of 1 person and 3 persons (Base Case) per household. Good correlation was observed between the simulated results and published heat energy consumption data for buildings with similar thermal, physical, occupancy and operational conditions. The results allowed occupied space temperatures and overall daily and grid peak time energy consumption to be predicted for the range of building archetypes and parameter values considered, and the TES size necessary for a desired HDS to be determined. The main conclusions drawn include: The overall daily energy consumption predictions varied from 36.8kWh to 159.7kWh. During the critical grid peak time (17:00 to 21:00) the heat consumption varied from 4.2kWh to 58.7kWh, indicating the range of energy demands which could be shifted to off-peak times. On average, semi-detached, mid-terrace, and flat built forms consumed 7.0%, 13.8% and 22.7% less energy for space heating than the detached built form respectively. Thermal insulation changing from the 1990 building regulation level to the 1980 and 2010 building regulation levels could change the mean energy use by +14.7% and -19.6% respectively. A 0.25m3 TES size with 75°C water storage temperature could enable a 2 hour HDS, shifting 4.3kWh to 11.7kWh (mean 8.7kWh) to off peak times, in all 70m2 Base Case archetypes with the 60 day mean thermal comfort of 100%, but with the minimum space temperature occasionally dropping below an 18°C thermal comfort limit. A 0.5m3 TES size and water storage of 95°C could allow a 3 hour HDS, shifting 9.8kWh to 28.2kWh (mean 18.7kWh) to off peak times, in all 90m2 Base Case archetypes without thermal comfort degradation below 18°C. A 0.75m3 TES with a 95°C water temperature could provide 4 hour HDS, shifting 13.9kWh to 47.7kWh (mean 27.2kWh) to off peak times, in all 150m2 Base Case archetypes with 100% mean thermal comfort but with the 60 day minimum temperature occasionally dropping below the 18°C thermal comfort limit in the detached built form. Improving the thermal insulation of the buildings was found to be the best way to improve the effectiveness of HDS with TES, in terms of the demand shift period achievable with minimal thermal comfort impact. A 4 hour HDS with 100% thermal comfort is possible in all 90m2 floor area buildings with a 0.25m3 tank and a water storage temperature of 75°C provided that the thermal insulation is as per 2010 building regulation. Recommendations for further research include: 1) creating larger number of archetype models to reflect the housing stock; 2) using heat pumps as the heat source so that the mean effect on the grid from electric heating loads can be predicted; 3) taking into account the costs associated with taking up HDS with TES, in terms of capital expenses and space requirement for housing the TES system; 4) considering alternative methods of heat storage such as latent heat storage to enhance the storage capacity per unit volume; and 5) incorporating zonal temperature control, for example, only heating rooms that are occupied during the demand shift period, which could ensure better thermal comfort in the occupied space and extend the demand shift period.

abstract: This thesis examines using thermal energy storage as a demand side management tool for air-conditioning loads with the goal of increasing photovoltaic penetration. It uses Arizona State University (ASU) as a case study. The analysis is completed with a modeling approach using typical meteorological year (TMY) data, along with ASU’s historical load data. Sustainability, greenhouse gas emissions, carbon neutrality, and photovoltaic (PV) penetration are all considered along with potential economic impacts. By extrapolating the air-conditioning load profile from the existing data sets, it can be ensured that cooling demands can be met at all times under the new management method. Using this cooling demand data, it is possible to determine how much energy is required to meet these needs. Then, modeling the PV arrays, the thermal energy storage (TES), and the chillers, the maximum PV penetration in the future state can be determined. Using this approach, it has been determined that ASU can increase their solar PV resources by a factor of 3.460, which would amount to a PV penetration of approximately 48%. / Dissertation/Thesis / Masters Thesis Electrical Engineering 2016