Reductive dechlorination is a significant natural attenuation process in chloroethene-contaminated aquifers where organic carbon combined with reducing redox conditions support active dechlorinating microorganisms. At sites where natural organic carbon (NOC) associated with the aquifer matrix provides fermentable organics, the ability to measure the NOC is needed to assess the potential for the long-term sustainability of reductive dechlorination. This study focused on developing a method to measure the potentially bioavailable organic carbon (PBOC) associated with aquifer sediment. To measure NOC and evaluate its biodegradability, liquid extraction techniques on aquifer sediment were investigated. Single extractions with different extracting solutions showed that extractable organic carbon associated with the sediment ranged from 1-38% of the total organic carbon content (TOCs). Bioassay experiments demonstrated that 30-60% of the extractable organic carbon can be utilized by a microbial consortium. Alternating between 0.1% pyrophosphate and base solutions over multiple extractions increased the rate of removal efficiency and targeted two organic carbon pools. The result of the investigation was a laboratory method to quantify organic carbon from the aquifer matrix in terms of the PBOC. In the second part, the extractable PBOC was shown to biodegrade under anaerobic conditions, to produce H2 at levels necessary to maintain reductive dechlorination, and to support reductive dechlorination in enrichment cultures. For the third part of the research, the difference in extractable organic carbon inside and outside of a chloroethene-contaminated plume was examined through the combination of PBOC laboratory data and field parameters. Supported by ground-water constituent data, the PBOC extraction and bioassay studies showed that less extractable organic carbon was present inside than outside of the chloroethene plume. The final part of the research investigated the distribution of PBOC extractions across six contaminated sites. PBOC extractions were directly correlated to the TOCs, soft carbon content, and level of reductive dechlorination activity at the sites. Based on these correlations, a range for organic carbon potentially available to subsurface microorganisms was proposed where the upper bound consisted of the soft carbon and the lower bound consisted of the PBOC. / Ph. D.

Lateral perturbations in anelasticity (Q) and wave speed together provide important constraints on thermal and chemical structures in the mantle. In present-day tomography studies of global wave speed and anelasticity, the significance of 3-D wave speed and 3-D Q structures on surface wave travel times and amplitudes has not been well understood. In this dissertation, the effects of lateral perturbations in anelasticity (Q) and wave speed on surface wave observables are quantified based upon wave propagation simulations in 3-D earth models using a Spectral Element Method. Comparison between phase delays caused by 3-D wave speed structures and those caused by 3-D Q variations show that anelastic dispersion due to lateral perturbation in Q is important in long-period surface wave and can account for 15-20% observed phase delays. For amplitude perturbations, elastic focusing/defocusing effects associated with 3-D wave speed structures are dominant while energy dissipation is important in short-period (~ 50 s) surface waves but decreases quickly with increasing wave period. Anelastic focusing/defocusing associated with 3-D anelastic dispersion becomes more important than wave attenuation in longer period surface waves. In tomography studies, ray theory breaks down and finite frequency effects become important when the length scale of heterogenities are smaller than seismic wavelength. Finite frequency effects in 3-D earth models are investigated by comparing theoretical predictions of travel times and amplitudes with "ground truth" measurements made on synthetic seismograms generated in SEM simulations. The comparisons show that finite frequency effects are stronger in amplitudes than in phases, especially at long periods. / Ph. D.

Streams and rivers are a vital part of our ecosystem. They are imperiled by human ecological activities such as urbanization, industrialization, and agriculture which discharge excess nitrate and other pollutants into our waterways. Here, this dissertation seeks to understand the physical and biogeochemical processes which attenuate pollutants in stream corridors. The focus is hyporheic zones which form the interface between surface water and groundwater below and adjacent to stream channels, and riparian zones which form the interface between channels and adjacent uplands, both of which can attenuate pollutants. In this context, soil-pipes can dominate subsurface hydraulics. This research first employed MODFLOW and MT3D-USGS to model transient hyporheic hydraulics and nitrate transport in a length of riparian/riverbank soil to probe the effects of soil pipes on hydraulics and denitrification due to peak flow events in the channel. Findings showed that inserting just one soil pipe 1.5 m in length caused a ~75% increase in both hyporheic exchange and denitrification. A rough upscaling showed soil pipes could remove up to ~3% of nitrate along a 1-km reach. Next, the ability of soil pipes to bypass the often championed ability of riparian buffers to remove nitrate migrating from uplands to the channel was evaluated. This effort also employed MODFLOW and MT3D-USGS to simulated hydraulics and nitrate removal along a length of riparian soil. Findings showed that soil pipes increased flow of nitrate to the banks by five orders of magnitude in some cases. We posited a non-dimension parameter which governs when nitrate bypass is significant. In addition to soil pipes, dune bedforms can also enhance hyporheic exchange, primarily in the stream/riverbed. Again employing MODFLOW but now pairing with the transport code SEAM3D to simulate microbially-mediated aerobic metabolism of dissolved organic carbon and dissolved oxygen, the combined effects of dune translation and microbial growth and death were explored. Major findings include that neglecting microbial growth can lead to inaccurate modeling of biogeochemistry, and that aerobic metabolism increased with celerity. The results herein bolster knowledge of natural pollutant attenuation in stream and river corridors, and have implications for pollutant mitigation strategy and stream credit allocation. / Doctor of Philosophy / Streams are a vital part of our ecosystem. They are imperiled by human ecological activities such as urbanization, industrialization, and agriculture which discharge nitrate and other pollutants into our waterways. Here, this dissertation seeks to understand the physical and biological processes which attenuate pollutants. The hyporheic zone is the interface between surface water and groundwater below the bed and adjacent to stream banks, and can attenuate pollutants. Transient peak flow events such as a storm or snow melt raise the stream water levels, causing the water pressure in the stream channel to temporarily outweigh the water pressure in the soil pore spaces adjacent to the stream channel. This drives water into the banks subjecting it to pollutant attenuation processes. Soil pipes (long cylindrical void spaces created by decayed plant roots) are prevalent along stream banks, and they dominate subsurface hydraulics. This dissertation implemented a numerical study on a chunk of riparian soil to probe the effects of soil pipes on hydraulics and denitrification. Findings showed that inserting just one – 1.5 m soil pipe caused a ~75% increase in both water flow volume into the bank and nitrate removal. Riparian buffers are the vegetated strips adjacent to stream channels and have long been championed as stalwarts of pollutant removal. Soil pipes undermine this by acting as a bypass mechanism. A numerical study was again performed on a chunk of riparian soil to quantify the effects soil pipes on riparian bypass of nitrate. Findings showed that soil pipes increased flow of nitrate to the banks by five orders of magnitude in some cases. This means that a buffer enhancement strip with fine roots that prevent the formation of soil pipes should be installed along riparian buffers. In addition to soil pipes, dune bedforms can increase flowrate of water into the hyporheic zone. This dissertation modeled the combined effects of dune translation and microbial growth and death. Major findings include that neglecting microbial growth can lead to inaccurate modeling of biogeochemistry, and that biodegradation increases with increased dune velocity. The results herein bolster knowledge on natural pollutant attenuation in streams, and have implications in terms of pollutant mitigation strategy and stream credit allocation.

Employing the Finite Element Method (FEM), we numerically study three problems involving free and forced vibrations of linearly and nonlinearly elastic plates with a third order shear and normal deformable theory (TSNDT) and the three dimensional (3D) elasticity theory. We used the commercial software ABAQUS for analyzing 3D deformations, and an in-house developed and verified software for solving the plate theory equations. In the first problem, we consider trapezoidal load-time pulses with linearly increasing and affinely decreasing loads of total durations equal to integer multiples of the time period of the first bending mode of vibration of a plate. For arbitrary spatial distributions of loads applied to monolithic and laminated orthotropic plates, we show that plates' vibrations become miniscule after the load is removed. We call this phenomenon as vibration attenuation. It is independent of the dwell time during which the load is a constant. We hypothesize that plates exhibit this phenomenon because nearly all of plate's strain energy is due to deformations corresponding to the fundamental bending mode of vibration. Thus taking the 1st bending mode shape of the plate vibration as the basis function, we reduce the problem to that of solving a single second-order ordinary differential equation. We show that this reduced-order model gives excellent results for monolithic and composite plates subjected to different loads. Rectangular plates studied in the 2nd problem have points on either one or two normals to their midsurface constrained from translating in all three directions. We find that deformations corresponding to several modes of vibration are annulled in a region of the plate divided by a plane through the constraining points; this phenomenon is termed mode localization. New results include: (i) the localization of both in-plane and out-of-plane modes of vibration, (ii) increase in the mode localization intensity with an increase in the length/width ratio of a rectangular plate, (iii) change in the mode localization characteristics with the fiber orientation angle in unidirectional fiber- reinforced laminae, (iv) mode localization due to points on two normals constrained, and (iv) the exchange of energy during forced harmonic vibrations between two regions separated by the line of nearly stationary points that results in a beating-like phenomenon in a sub-region of the plate. This technique can help design a structure with vibrations limited to its small sub-region, and harvesting energy of vibrations of the sub-region. In the third problem, we study finite transient deformations of rectangular plates using the TSNDT. The mathematical model includes all geometric and material nonlinearities. We compare the results of linear and nonlinear TSNDT FEM with the corresponding 3D FEM results from ABAQUS and note that the TSNDT is capable of predicting reasonably accurate results of displacements and in-plane stresses. However, the errors in computing transverse stresses are larger and the use of a two point stress recovery scheme improves their accuracy. We delineate the effects of nonlinearities by comparing results from the linear and the nonlinear theories. We observe that the linear theory over-predicts the deformations of a plate as compared to those obtained with the inclusion of geometric and material nonlinearities. We hypothesize that this is an effect of stiffening of the material due to the nonlinearity, analogous to the strain hardening phenomenon in plasticity. Based on this observation, we propose that the consideration of nonlinearities is essential in modeling plates undergoing large deformations as linear model over-predicts the deformation resulting in conservative design criteria. We also notice that unlike linear elastic plate bending, the neutral surface of a nonlinearly elastic bending plate, defined as the plane unstretched after the deformation, does not coincide with the mid-surface of the plate. Due to this effect, use of nonlinear models may be of useful in design of sandwich structures where a soft core near the mid-surface will be subjected to large in-plane stresses. / Doctor of Philosophy / Plates and shells are defined as structures which have thickness much smaller as compared to their length and width. These structures are extensively used in many fields of engineering such as, designing ship hulls, airplane wings and fuselage, bodies of automobile, etc. Depending on the complexity of a plate/shell deformation problem, deriving analytical solutions is not always viable and one relies on computational methods to obtain numerical solutions of the problem. However, obtaining 3-dimensional (3D) numerical solutions of deforming plates/shells often require high computational effort. To avoid this, plate/shell theories are used for modeling these structures, which, based on certain assumptions, reduce the 3D problem into an equivalent 2-dimensional (2D) problem. However, quality of the solution obtained from such a theory depends on how suitable the assumptions are for the specific problem being studied. In this work, one such plate theory called as the Third Order Shear and Normal Deformable Theory (TSNDT) is used to model the mechanics of deforming rectangular plates under different boundary conditions (constraint conditions for the boundaries of the plate) and loading conditions (conditions of applied loads on the plate). We develop the TSNDT mathematical model of plate deformations and solve it using a computational technique called as the Finite Element Method (FEM) to analyze three different problems of mechanics of rectangular plates. These problems are briefly described below. vi In the first problem, we study vibrations of rectangular plates under time dependent (dynamic) loads. When a dynamic load acts on a plate, due to the effects of inertia, the plate continues to vibrate after the removal of the load. This is analogous to ringing of a bell long after the strike of the hammer on the bell. In this study we show that such vibrations of a rectangular plate can be varied by changing time dependencies of the applied load. We observe that under certain particular loading conditions, vibrations of the plate becomes miniscule after the load removal. We call this phenomenon as Vibration Attenuation and investigate this computationally in different problems of plate deformation using FEM solutions. In the second problem, we computationally investigate the effects of presence of internal fixed points (points within the volume of the plate restricted of motion) on the vibration characteristics of rectangular plate using TSNDT FEM solutions. We observe that when one or more points at locations inside a rectangular plate are fixed, vibration behavior of the plate significantly changes and the deformations are localized in certain regions of the plate. This phenomenon is called as Mode Localization. We study mode localization in rectangular plates under different boundary and loading conditions and analyze the effects of plate dimensions, locations of the internal fixed points and dynamic load characteristics on mode localization. In the third problem, we investigate the effects of introduction of nonlinearities into the TSNDT mathematical model of plate deformations. Simple models in mechanics consider materials to be linearly elastic, which means that the deformations of a body are proportional to the applied loads in a linear relation. However, most materials in nature undergoing large deformations (human tissues, rubbers, and polymers, for example) do not behave in this fashion and their deformation depends nonlinearly to applied loads. To investigate the effects of such nonlinearities, we study the behavior of nonlinearly elastic plates under different boundary and loading conditions and delineate the differences in the results of linearly elastic and nonlinearly elastic plates using the TSNDT FEM solutions. Findings of this study establishes that linear models overestimate the plate deformation under given boundary and loading conditions as compared to nonlinear models. This understanding may help in developing better design criteria for plates undergoing large deformations.

The hyporheic zone is the reactive interface between surface water and groundwater found beneath streams and rivers, where chemical gradients and an abundant biological presence allow beneficial attenuation of contaminants. Such attenuation often requires reactants from surface water and groundwater to mix, but few studies have explored the controls on mixing of upwelling groundwater water in the hyporheic zone and its potential to foster mixing-dependent reactions. The goals of this dissertation are therefore to evaluate the effects of (1) hydraulic controls and (2) reaction kinetic controls on hyporheic mixing and mixing-dependent reactions, and (3) use two-dimensional visualization techniques to quantify patterns of hyporheic mixing and mixing-dependent reactions. These objectives were addressed by hyporheic zone simulations using a laboratory sediment mesocosm and numerical models. In the laboratory, a hyporheic flow cell was created to observe both conservative dye mixing and abiotic mixing-dependent reaction. The numerical models MODFLOW and SEAM3D were then used to simulate the experimental data to better understand hydraulic and transport processes underlying laboratory observations and provide sensitivity analysis on hydraulic and reaction kinetic parameters. Visualization techniques showed a distinct mixing zone developing over time for both conservative and reactive conditions. Mixing zone thickness in both conditions depended on surface water head drop and the ratio of boundary inflows of surface water and groundwater (inflow ratios). The abiotic reaction caused the mixing zone to shift even under steady-state hydraulics indicating that hyporheic zone mixing-dependent reactions affect the location of mixing as chemical transformations take place. The numerical model further showed the production zone to be thicker than the mixing zone and located where reactants had already been depleted. Finally, mapping of two-dimensional microbial respiration (i.e., electron acceptor utilization) patterns in streambed sediments using dissolved oxygen and carbon dioxide planar optodes showed that coupling multiple such 2D chemical profiles can enhance understanding of microbial processes in the hyporheic zone. Temporal dynamics for these chemical species revealed development of spatial heterogeneity in microbial respiration and hence microbial activity. Our results show key hydrologic and biogeochemical controls on hyporheic mixing and mixing-dependent reactions. These reactions represent a last opportunity for attenuation of groundwater borne contaminants prior to entering surface water. / Doctor of Philosophy / The boundary between surface water and groundwater beneath streams and rivers is known to have an abundant biological presence that allows for beneficial reduction of contaminants when chemicals combine. This combination of chemicals due to mixing of the waters is an important characteristic of the boundary area (defined as the hyporheic zone). However, controls on mixing and the impact on contaminant reduction are not fully understood. Therefore, the goals of this dissertation are to evaluate (1) the effects of varying water level and flow and (2) the effects of the rates of the reaction on mixing of chemicals and chemical transformation, and (3) use two-dimensional visualization processes to quantify the reactions and mixing occurring at the boundary area of surface water and groundwater. We used both laboratory and numerical model simulations to study mixing at the boundary area. The two-dimensional visualization in both laboratory and numerical models show distinct regions where mixing occurred between the surface water and groundwater. The extent of the mixing (mixing thickness) was most dependent on the flow ratio between the upward groundwater and downward surface water. The observations were made with non-varying surface and groundwater flow rates but changes on the mixing thickness and location were seen throughout the duration of the experiments revealing that chemical reaction dynamics have an influence on the mixing process. Ultimately, these types of reactions represent a last opportunity for attenuation of groundwater borne contaminants prior to entering surface water.

Groundwater remediation strategies have advanced toward more effective and economical remedial technologies. Monitored natural attenuation (MNA) has become accepted by federal regulatory agencies as a viable remediation strategy for contaminants under site-specific conditions. At chloroethene contaminated sites where MNA is used as a remediation strategy, microbially-mediated reductive dechlorination is typically the dominant pathway for natural attenuation. The efficacy of reductive dechlorination at sites with no anthropogenic carbon sources is often influenced by the availability of readily-biodegradable natural organic carbon along with favorable geochemical conditions for supporting microbial dehalogenation. Recent research studies have suggested that the pool of labile natural organic carbon, operationally defined as potentially bioavailable organic carbon (PBOC), may be a critical component related to sustaining reductive dechlorination at MNA sites. The objective of this study was to evaluate PBOC as a quantitative measure of the labile organic carbon fraction of aquifer sediments in relation to microbial reductive dechlorination of chlorinated solvents. In the first phase of this study, the variability of PBOC in aquifer sediments was examined among 15 chloroethene contaminated sites. Results showed that PBOC displayed considerable variability among the study sites, ranging over four orders of magnitude. Regression results demonstrated that a positive correlation existed between PBOC, solid phase total organic carbon (TOCs), and reductive dechlorination activity at the sites. Results supported that greater levels of PBOC and TOCs corresponded to higher reductive dechlorination activity at the sites. Composition results showed that 6-86% of PBOC consisted of proteins and amino acids. Results also suggested a positive relationship existed between PBOC, concentrations of potentially bioavailable organic compounds present in the aquifer system, expressed as hydrolyzable amino acids (HAA), and the natural attenuation capacity (NAC) at the sites. Higher PBOC levels were consistently observed at sites with greater NAC and levels of HAA. The results of this study suggested that the variability of PBOC in the aquifer sediments exhibited a reasonable correlation with TOCs, hydrolyzable amino acids, and chloroethene transformation among the selected sites. In the second phase of this study, the relationship between PBOC in aquifer sediments and site specific performance data was evaluated among 12 chloroethene contaminated sites. Results demonstrated that PBOC in aquifer sediments was directly correlated to independent field metrics associated with reductive dechlorination. Levels of PBOC demonstrated direct relationships with hydrogen (H2) and dissolved oxygen (DO) concentrations within the groundwater system at the selected study sites. Results also indicated that PBOC demonstrated positive relationships with reductive dechlorination activity and the natural attenuation capacity of the sites. The findings of this study suggested that the level of PBOC in aquifer sediments may be a key factor in sustaining conditions favorable for microbial reductive dechlorination. In the third phase of this study, the distribution of PBOC was investigated at a chloroethene contaminated site. PBOC was measured in surficial aquifer sediment samples collected at varying depths in the vicinity of a chloroethene plume. Results demonstrated that levels of PBOC were consistently higher in aquifer sediments with minimal chloroethene exposure relative to samples collected in the PCE-contaminated source zone. Regression results demonstrated that a statistically significant inverse correlation existed between PBOC levels and chloroethene concentrations for selected temporary wells in the contaminated source zone at the study site. Consistent with these findings, results also indicated a similar trend of increased PBOC in aquifer sediments outside the chloroethene plume relative to aquifer sediments inside the plume. Results from this study further suggested that differences in extracted carbon levels at the site for surficial aquifer sediment samples in the PCE-contaminated source zone could impact the extent of reductive dechlorination within the hydrographic unit. / Ph. D.

Contaminant transport modeling is being used more often at petroleum hydrocarbon contaminated sites in an attempt to aid engineers in evaluating the feasibility of natural attenuation as a remediation alternative in groundwater systems. In this research, a three-dimensional sequential electron acceptor computer model, SEAM3D, developed by Waddill and Widdowson (1997) was used to simulate contaminant transport at a leaking underground storage tank site in Beaufort, South Carolina. Gasoline containing benzene, toluene, ethylbenzene, and xylene (BTEX) as well as methyl tertiary butyl ether (MTBE) leaked into the subsurface at the site late in 1990, and monitoring of the water table elevations and contaminant concentrations began in 1993. Using the field data, the groundwater flow model MODFLOW was used to develop and calibrate a flow model for the Laurel Bay site using GMS (Groundwater Modeling System) v2.1. MODFLOW was coupled with the SEAM3D contaminant transport model, and the available concentration levels were used to calibrate, verify, and validate the site model. The results indicated that SEAM3D simulated complex, interconnected processes including biodegradation, and the transport of multiple hydrocarbon compounds, electron acceptors, and end products over time and space at a specific petroleum hydrocarbon contaminated site. Once the model was calibrated and verified, the model output was used to study the changes in contaminant mass distribution, contaminant mass loss, and mass loss rates for each terminal electron accepting process (TEAP) over time. It was found that the natural attenuation capacity of the aquifer was insufficient to stabilize the plume and prevent it from reaching the defined point of contact (POC). Contamination was shown to have reached the POC by 1994, just four years into the simulation. Results indicated that despite oxygen limitation within the BTEX plume, aerobic biodegradation was responsible for the greatest amount of mass loss, close to 70 %, relative to the sum of the anaerobic processes after 20 years. / Master of Science

The understanding of the impact of site effects on ground motions is crucial for improving the assessment of seismic hazards. Site response analyses (SRA) can numerically accommodate the mechanics behind the wave propagation phenomena near the surface as well as the variability associated with the input motion and soil properties. As a result, SRA constitute a key component of the assessment of site-specific seismic hazards within the probabilistic seismic hazard analysis framework. This work focuses on limitations in SRA, namely, the definition of the elastic half-space (EHS) boundary condition, the selection of input ground motions so that they are compatible with the assumed EHS properties, and the proper consideration of near-surface attenuation effects. Input motions are commonly selected based on similarities between the shear wave velocity (Vs) at the recording station and the materials below the reference depth at the study site (among other aspects such as the intensity of the expected ground motion, distance to rupture, type of source, etc.). This traditional approach disregards the influence of the attenuation in the shallow crust and the degree to which it can alter the estimates of site response. A Vs-κ correction framework for input motions is proposed to render them compatible with the properties of the assumed EHS at the site. An ideal EHS must satisfy the conditions of linearity and homogeneity. It is usually defined at a horizon where no strong impedance contrast will be found below that depth (typically the top of bedrock). However, engineers face challenges when dealing with sites where this strong impedance contrast takes place far beyond the depth of typical Vs measurements. Case studies are presented to illustrate potential issues associated with the selection of the EHS boundary in SRA. Additionally, the relationship between damping values as considered in geotechnical laboratory-based models, and as implied by seismological attenuation parameters measured using ground motions recorded in the field is investigated to propose alternative damping models that can match more closely the attenuation of seismic waves in the field. / Ph. D.

Measuring void fraction distribution in two-phase flow has been a challenging task for many decades because of its complex and fast-changing interfacial structure. In this study, a non-intrusive X-ray measurement system is developed and calibrated to mitigate this challenge. This approach has several advantages over the conventional methods such as the multi-sensor conductivity probe, wire-mesh sensor, impedance void meter, or direct optical imaging. The X-ray densitometry technique is non-intrusive, insensitive to flow regime changes, capable of measuring high temperature or high-pressure flows, and has reasonable penetration depth. With the advancement of detector technology, the system developed in this work can further achieve high spatial resolution (100 micron per pixel) and high temporal resolution (1000 frames per second). This work mainly focuses on the following aspects of the system development: establishing a geometrical model for the line detector system, conducting spectral analysis for X-ray attenuation in two-phase flow, and performing calibration tests. The geometrical model has considered the measurement plane, geometry of the test-section wall and flow channel, relative position of the X-ray source and detector pixels. By assuming axisymmetry, an algorithm has been developed to convert void fraction distribution along the detector pixels to the radial void profile in a circular pipe. The X-ray spectral analysis yielded a novel prediction model for non-chromatic X-rays and non-uniform structure materials such as the internal two-phase flow which contains gas, liquid and solid wall materials. A calibration experiment has been carried out to optimize the detector conversion factor for each detector pixels. Finally, the data measured by the developed X-ray system are compared with the double-sensor conductivity probe and gas flow meter for sample bubbly flow and slug flow conditions. The results show reasonable agreement between these different measuring techniques. / Master of Science

Identical experiments were conducted between two acoustical-testing laboratories to determine the inter-laboratory differences of using two different hearing protection device (HPD) fitting procedures for testing the real-ear attenuation at threshold (REAT) of a popular vinyl foam earplug and a multi-sized premolded PVC single-flanged earplug. The first fitting procedure tested in the experiment is included in the revision of the American National Standards Institute (ANSI) standard S12.6-1984 by the ANSI Working Group ANSI S12/WG11, <i>Field Effectiveness and Physical Characteristics of Hearing Protectors</i>. This fitting procedure, “subject fit,” is intended to estimate “...the attenuation obtained in the top 10-20% of today’s industrial and military hearing conservation programs, i.e. the attenuation that should be obtained by an informed and motivated work force” (ANSI S12.6-199X, Draft 1.4, p. 4). The subject-fit procedure employs HPD-naive subjects, minimizes experimenter involvement, enforces subject-selection controls, and requires subjects to fit the HPD with reasonable comfort using only the manufacturer’s fitting instructions. The subject-fit method differs from the second procedure tested in this investigation, experimenter fit, in both procedure and objective. In the ANSI S3.19-1974 “experimenter-fit” method, which is the procedure currently required by the Environmental Protection Agency (EPA) for the testing and labeling of HPDs (EPA, 1990), the experimenter fits the HPD to the subject (comfort is not a consideration) to determine the optimum attenuation of the HPD. The development of the subject-fit protocol was motivated by the large discrepancy between the attenuation achieved in the field and that claimed by manufacturers of HPDs using experimenter fit from ANSI S3.19-1974. Some experts have developed schemes to derate manufacturers’ laboratory data to approximate attenuation typically achieved in the field. In addition to investigating the differences between the two fitting protocols, other factors relevant to the revision of ANSI S12.6-1984 were studied: subject and experimenter gender effects, ear canal size effects, inter-laboratory differences, and the number of replications and subjects needed for REAT tests. Results indicated that the subject-fit method provided statistically significantly less attenuation than the experimenter-fit method. Subject-fit tended to overestimate in-field attenuation, but not by as much as experimenter-fit. No consistent subject-gender effects were found in the analysis. Experimenter gender did not have a significant effect on subject-fit foam-earplug attenuation. The lack of significant trial effects indicated that the goodness of fit did not change for either fitting condition or across trials. Ear canal size and attenuation effects were documented with mixed results. / Master of Science